CHEMISTRY 102A and E ASSIGNMENTS WEEK 0 (August 20-24) M T W Th Lecture F W Discussion Th Lecture F Discussion Reading: Syllabus WEEK 1 M T (Aug. 27-Aug. 31) Lecture Part 1 - Tuesday/Wednesday Topics: The Scientific Method, Measurements, Significant Figures, Unit Conversions, Density, Matter Reading: Zumdahl, Chapter 1.1-1.9 Problems: Zumdahl, Chapter 1: 19, 25, 27, 29, 31, 33, 37, 38, 45, 46, 48, 54, 59, 64, 65, 74 Part 2 - Thursday/Friday Topics: Fundamental Chemical Laws, Atomic Structure, Naming Compounds Reading: Zumdahl, Chapter 2.1-2.8 Problems: Zumdahl, Chapter 2: Quiz 1: Significant figures, dimensional analysis 12, 13, 15, 19, 21, 41, 46, 47, 49, 57, 59, 61, 63, 65, 67, 70, 72, 75, 77, 78, 80, 81, 87 WEEK 2 M T (Sept. 3-Sept. 7) Lecture Part 1 - Tuesday/Wednesday W Discussion Topics: The Mole, Atomic Masses, Percent Composition Reading: Zumdahl, Chapter 3.1-3.5 Problems: Zumdahl, Chapter 3: Th Lecture F Discussion 18, 19, 21, 23, 29, 33, 35, 37, 39, 41, 43, 53, 55, 56, 59, 60, 65, 66, 68, 70, 105, 107, 109 Homework 1 due Wednesday, Sept. 5 Part 2 - Thursday/Friday Topics: Balancing Chemical Equations, Limiting Reagents Reading: Zumdahl, Chapter 3.6-3.9 Problems: Zumdahl, Chapter 3: Quiz 2: Naming compounds, Empirical Formulas 77, 78, 83, 84, 86, 92, 93, 95, 100, 101, 121, 122, 124, 125, 126 WEEK 3 M T (Sept. 10-Sept. 14) Lecture Part 1 - Tuesday/Wednesday Topics: Solutions, Electrolytes Reading: Zumdahl, Chapter 4.1-4.3 Problems: Zumdahl, Chapter 4: W Discussion Th Lecture F Discussion 10, 11, 12, 14, 15, 17, 19, 21, 23, 25, 26, 28, 70 Homework 2 due Wednesday, Sept. 12 Part 2 - Thursday/Friday Topics: Types of Chemical Reactions Reading: Zumdahl, Chapter 4.4-4.8 Problems: Zumdahl, Chapter 4: Quiz 3: Balancing equations, limiting reagents, % yield 29, 31, 33, 35, 40, 41, 43, 44, 45, 47, 51, 54, 55, 72, 75, 77, 78, 80, 81, 87 WEEK 4 M T (Sept. 17-Sept. 21) Lecture Part 1 - Tuesday/Wednesday Topics: Oxidation-Reduction Reading: Zumdahl, Chapter 4.9 Problems: Zumdahl, Chapter 4: W Discussion Th Lecture F Discussion Th Lecture F Discussion 57, 59, 60 Homework 3 due Wednesday, Sept. 19 Part 2 - Thursday/Friday Topics: Balancing Redox Reactions Reading: Zumdahl, Chapter 4.10 Problems: Zumdahl, Chapter 4: Quiz 4: Ionic equations 61, 63, 65, 67 WEEK 5 M T (Sept. 24-Sept. 28) Lecture Part 1 - Tuesday/Wednesday W Discussion Topics: Gases - P, V, T Relationships, Ideal Gas Law, Stoichiometry Reading: Zumdahl, Chapter 5.1-5.4 Problems: Zumdahl, Chapter 5: 4, 5, 6, 11, 12, 16, 17, 30, 32, 33, 35, 37, 43, 44, 49, 52, 54, 57, 59, 93, 94, 95, 96, 104, 117 Homework 4 due Wednesday, Sept.26 Part 2 - Thursday/Friday Topics: Partial Pressures, Kinetic Molecular Theory, Real Gases Reading: Zumdahl, Chapter 5.5-5.8 Problems: Zumdahl, Chapter 5: Quiz 5: Oxidation State and Redox Reactions 7, 8, 15, 22, 24, 63, 65, 67, 68, 69, 70, 73, 75, 76, 78, 79, 80, 81, 99, 102, 110, 111, 118, 120 WEEK 6 M T (Oct. 1-Oct. 5) Lecture Part 1 - Tuesday/Wednesday Topics: W Discussion Th Lecture F Discussion Review for HE I Homework 5 part 1 (5-1 through 5-5) due Wednesday, October 3 Part 2 - Thursday/Friday HOUR EXAM I: 7:00 pm Wednesday, October 3 (Locations to be announced) Topics: Electromagnetic Radiation, Atomic Spectra, The Bohr Model Reading: Zumdahl, Chapter 7.1-7.4 Problems: Zumdahl, Chapter 7: 3, 18, 39, 40, 41, 43, 44, 45, 47, 51, 54, 55 WEEK 7 M T (Oct. 8-Oct. 12) Lecture Part 1 - Tuesday/Wednesday W Discussion Th Lecture Topics: Quantum Numbers, Orbitals and Electronic Structure Reading: Zumdahl, Chapter 7.5-7.9 Problems: Zumdahl, Chapter 7: 60, 62, 64, 70, 71, 73, 77, 79, 81, 82 Homework 5 part 2 (5-6 through 5-13) due Wednesday, October 10 Part 2 - Thursday/Friday Topics: The Periodic Table, Periodic Trends Reading: Zumdahl, Chapter 7.10-7.13 Problems: Zumdahl, Chapter 7: 85, 87, 89, 101, 102121, 122 Quiz 6: Dalton's Partial Pressures F Discussion WEEK 8 M T (Oct. 15-Oct. 19) Lecture Part 1 - Tuesday/Wednesday Topics: W Discussion Th Lecture F Discussion Introduction to Bonding, Polarity Reading: Zumdahl, Chapter 8.1-8.4 Problems: Zumdahl, Chapter 8: 1, 3, 13, 14, 19, 21, 23, 25, 27, 33, 35, 37, 38, 95 Homework 6 due Wednesday, Oct. 17 Part 2 - Thursday/Friday Topics: Lewis Structures, Exceptions, Resonance Reading: Zumdahl, Chapter 8.7-8.12 Problems: Zumdahl, Chapter 8: Quiz 7: Electron Configurations and Periodic Trends 12, 16, 18, 61, 63, 65, 66, 67, 70, 72, 73, 74, 100 WEEK 9 M T (Oct. 22-Oct. 26) Lecture Part 1 - Tuesday/Wednesday W Discussion Topics: VSEPR, Polarity, Hybrid Orbitals, Delocalization Reading: Zumdahl, Chapter 8.13, 9.1, 9.5 Problems: Zumdahl, Chapter 8: Chapter 9: Th Lecture F Discussion 15, 17, 70, 80-91, 102, 103, 105, 113, 115, 116 5, 6, 10-14, 19, 20, 21, 25, 26, 27, 29, 49, 53 Homework 7 due Wednesday, Oct. 24 Part 2 - Thursday/Friday Topics: Intermolecular Forces, the Liquid State, Vapor Pressure Reading: Zumdahl, Chapter 10.1-10.2, 10.8 Problems: Zumdahl, Chapter 10: 5, 7, 10, 11, 12, 14, 15, 16, 31, 34, 35, 36(a, d-g), 37, 38, 39, 40, 91, 93 Quiz 8: Lewis Structures, Molecular Shape, Hybridization WEEK 10 M T (Oct. 29-Nov. 2) Lecture Part 1 - Tuesday/Wednesday W Discussion Th Lecture F Discussion Topics: Chemical Equilibrium Reading: Zumdahl, Chapter 13.1-13.4 Problems: Zumdahl, Chapter 13: 9, 11, 13, 15, 16, 17, 18, 19, 20, 21, 24, 26, 27, 31, 33, 34 Homework 8 and 9 due Wednesday, Oct. 31 HOUR EXAM II: 7:00 pm Wednesday, October 31 (Locations to be announced) Part 2 - Thursday/Friday Topics: Equilibrium Calculations, LeChatelier’s Principle Reading: Zumdahl, Chapter 13.5-13.7 Problems: Zumdahl, Chapter 13: 2, 35, 37, 39, 41, 45, 46, 53, 54, 55, 57, 58, 59, 60, 63, 64, 67, 73, 75 WEEK 11 M T (Nov. 5-Nov. 9) Lecture Part 1 - Tuesday/Wednesday W Discussion Topics: Introduction to Acids and Bases Reading: Zumdahl, Chapter 4.8, Appendix A1.2 Problems: Zumdahl, Chapter 4: Th Lecture F Discussion 46, 47, 50, 51, 52, 53, 54, 56 Part 2 - Thursday/Friday Topics: Acid Strength, the pH Scale Reading: Zumdahl, Chapter 14.1-14.4 Problems: Zumdahl, Chapter 14: 16, 19, 26, 28, 29, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 45, 46 Equilibrium Quiz 9: WEEK 12 M T (Nov. 12-Nov. 16) Lecture Part 1 - Tuesday/Wednesday W Discussion Th Lecture Topics: Weak Acids and Bases Reading: Zumdahl, Chapter 14.5-14.6, 14.12, Appendix A1.4 F Discussion Problems: Zumdahl, Chapter 14: 47, 48, 49, 53, 57, 61, 62, 63, 65, 67, 69, 72, 73, 74, 75, 79, 81, 83, 85, 86, 88, 95, 139, 140, 141, 142 Homework 10 due Wednesday, Nov. 14 Part 2 - Thursday/Friday Topics: Polyprotic Acids, Acidic and Basic Salts Reading: Zumdahl, Chapter 14.7-14.8, 14.10 Problems: Zumdahl, Chapter 14: 12, 94, 96, 98, 99, 103, 105, 106, 107, 108, 111, 112, 135, 138, 151 Quiz 10: Acids, bases, pH WEEK 13 (November 19-23) Thanksgiving Break M T W . Th F . WEEK 14 M T (Nov. 26-Nov. 30) Lecture Part 1 - Tuesday/Wednesday Topics: Common Ion Equilibria Reading: Zumdahl, Chapter 15.1 Problems: Zumdahl, Chapter 15: 14, 15, W Discussion Th Lecture F Discussion Homework 11 due Wednesday, Nov. 28 Part 2 - Thursday/Friday Topics: Buffers Reading: Zumdahl, Chapter 15.2-15.3 Problems: Zumdahl, Chapter 15: 1, 3, 21, 22, 23, 25, 33, 34, 35, 39, 41, 42, 45, 47, 48 salts, common ion Quiz 11: WEEK 15 M T (Dec. 3-Dec. 7) Lecture Part 1 - Tuesday/Wednesday Topics: W Discussion Th Lecture F Discussion Catch up and review for HE III Homework 12 due Wednesday, Dec. 5 Part 2 - Thursday/Friday Topics: Titration Curves Reading: Zumdahl, Chapter 15.4-15.5 Problems: Zumdahl, Chapter 15: 4, 5, 16, 51, 52, 53, 54, 55, 56, 57, 59, 60, 61, 63, 64, 114, 115, 116 Buffers and titrations. Quiz 12: HOUR EXAM III: 7:00 pm Wednesday, December 5 (Locations to be announced) Homework 13 due Wednesday, Dec. 12 FINAL EXAM 102A : 1:30 – 4:30 pm Tuesday, December 11 FINAL EXAM 102E : 1:30 – 4:30 pm Wednesday, December 12