Teacher Guide Including Student Activities Module 2: Illustrating Exothermic and Endothermic Reactions ACTIVITY GUIDE Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Summary: Chemical reactions are occurring all around us, from the changing color of the autumn leaves, to the cooking of our food. Muffins baked without baking powder (NaHCO3) added are going to turn out as flat as tortillas. Chemical reactions are responsible for most of the energy we use every day. The coal burned in power plants and the gasoline burned in cars fill our lives with activity. In a chemical reaction, a new substance is formed when two or more substances react. These reactions result in heat being produced or absorbed. It is important to remember that neither of these reactions results in a loss of energy, merely redistribution. When watching the video, think about the glycerin and potassium permanganate reaction and the making of ice cream. Here we have two examples: the first being an exothermic reaction (producing heat) and the second being an endothermic reaction (absorbing heat), reactions in both cases where energy is being redistributed, but never lost. Endothermic and exothermic reactions surround us everyday, from plants growing, to automobiles driving down the road. Science is always at work around us. Objective: Describe the difference between endothermic and exothermic reactions and their relationship to energy transformations, specifically the loss or production of heat. Module 2: Segment Length – 8:00 minutes Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Page 2 Ohio Standards Connection: Grade Nine Physical Science Benchmark F: Explain how energy may change form or be redistributed but the total quantity of energy is conserved. Organizer: Nature of Matter Indicator 16: Illustrate that chemical reactions are either endothermic or exothermic (e.g., cold packs, hot packs and the burning of fossil fuels). OSIC Y2003.CSC.S03.G09-10.BF.L09.I16 Suggestions for the teacher: 1. Preview each segment before showing. 2. Prepare the class and gather all necessary materials. 3. Review segment content with class at each pause screen. 4. Begin “lesson sequence” activity after viewing lesson. Safety: Always be careful! Teachers and students should always exercise appropriate safety precautions and utilize appropriate laboratory safety procedures and equipment when working on science performance tasks. Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Page 3 Activity: Making Ice Cream – Endothermic Reaction Materials: • ½ cup milk • ½ cup whipping cream • ¼ cup sugar • ¼ teaspoon vanilla or vanilla flavoring • ½ to ¾ cup sodium chloride (salt) as table salt or rock salt • 2 cups ice • 1 quart zippered plastic bag • 1 gallon zippered plastic bag • thermometer • measuring cups and spoons • cups and spoons for eating your treat Procedure: 1. Add ¼ cup sugar, ½ cup milk, ½ cup whipping cream, and ¼ teaspoon vanilla to the quart zippered plastic bag. Seal the bag securely. 2. Put two cups of ice into the gallon zippered plastic bag. 3. Use a thermometer to measure and record the temperature of the ice in the gallon bag. 4. Add ½ to ¾ cup salt (sodium chloride) to the bag of ice. 5. Place the sealed quart bag inside the gallon bag of ice and salt. 6. Seal the bag. 7. Gently rock the gallon bag from side to side. It is best to hold it by the top seal or to have gloves or a cloth between the bag and your hands because the bag will be cold enough to damage your skin. 8. Continue to rock the bag for 10-15 minutes or until the contents of the quart bag have solidified into ice cream. 9. Open the gallon bag and use the thermometer to measure and record the temperature of the ice/salt mixture. 10. Remove the quart bag, open it, and serve the contents into cups with spoons. Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Page 4 Explanation: Ice has to absorb energy in order to melt, changing the phase of water from a solid to a liquid. When you use ice to cool the ingredients for ice cream, the energy is absorbed from the ingredients and from the outside environment including your hands, when you are holding the bag of ice. When you add salt to the ice, it lowers the freezing point of the ice, so even more energy has to be absorbed from the environment in order for the ice to melt. This makes the ice colder than it was before, cold enough to freeze the ice cream. Ideally, you would make your ice cream using 'ice cream salt', which is just salt sold as large crystals instead of the small crystals you see in table salt. The larger crystals take more time to dissolve in the water around the ice, which allows for evenly distributed cooling of the ice cream, making the ice cream “creamier”. You could use other types of salt instead of sodium chloride. Compounds that break into two pieces upon dissolving, like NaCl breaks into Na+ and Cl -, are better at lowering the freezing point than substances that don't separate into particles. The more particles there are, the greater the disruption and the greater the impact on particle-dependent properties (colligative properties) like freezing point depression, boiling point elevation, and osmotic pressure. The salt lowers the point at which water will re-freeze into ice; you can't add salt to very cold ice and expect it to freeze your ice cream. This is why salt (NaCl) is not used to deice sidewalks in areas that are very cold. Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Page 5 Quiz: Endothermic and Exothermic Reactions 1. A solid at a temperature of 80 C is immersed into a liquid with a temperature at 60 C. Which statement correctly describes the energy changes between A and B? a) Solid A releases heat and B absorbs heat. b) Solid A absorbs heat and B releases heat. c) Both solid A and B absorb heat. d) Both solid A and B release heat. Answer choice A is correct. Heat always moves from a warmer to a cooler object. 2. When ammonium chloride crystals are dissolved in water the temperature of the water decreases. What does this temperature change indicate about the dissolving of ammonium chloride in water? a) It is an endothermic reaction because it absorbs heat. b) It is an endothermic reaction because it releases heat. c) It is an exothermic reaction because it absorbs heat. d) It is an exothermic reaction because it releases heat. Answer choice A is correct. In an endothermic reaction heat is being absorbed. Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Page 6 Ohio Content Provider Recommendations: Search String: chemical reactions – endothermic chemical reactions – exothermic Additional curricular resources can be found at the following websites using one or more of the search strings listed above to narrow your search. INFOhio http://www.infohio.org/ Ohio Resource Center http://ohiorc.org/ Ohio Department of Education http://ims.ode.state.oh.us/ODE/IMS/Lessons/ Finding Additional Resources Using D3A2: The D3A2 helps educators analyze data, and points them to resources such as lesson plans, assessments and activities designed specifically to address the academic need identified by the data. In addition to linking content to data analysis, educators will have general search capabilities to locate education content resources aligned to the Ohio’s Academic Content Standards. Sample D3A2 Standard Search Results: • • Simple Thermodynamics of Transportation: Retrieved from the Ohio Resource Center o http://www.ohiorc.org/record/2310.aspx What’s Going on with Temperature: Retrieved from the Ohio Department of Education o http://ims.ode.state.oh.us/ODE/IMS/Lessons/Web_Content/CSC_LP_S 03_BF_L09_I11_01.doc Science @ Work II Module 2: Illustrating Exothermic and Endothermic Reactions Page 7