Pipeline Flow of Settling Slurries Presentation to Institution of Engineers Australia (Mechanical Branch) Jeff Bremer - 23 rd April 2008 Overview and Aims 1. Explain physical laws underlying the behaviour of settling solids in slurry pipeline flow. 2. Compare theories associated with pipeline flow. Why are there so many? 3. Show where and how the theories disagree. 4. Present some preliminary results from recent work (J. Bremer, V.Lim & R.Gandhi ) ?? QUESTIONS 1. Where and why are slurry pipelines used? 2. What is a settling slurry? 3. What are the main features in pipeline flow? 4. Engineers are good at using theoretical and empirical “best fit” theories. What’s the problem? 5. What are the underlying equations and physical phenomena? 6. What are the theories of pipeline flow? 7. What do we know that is right, and can we easilly confirm that we have the “right answer”? 8. What’s the latest, and where to in future? Slurry Pipelines Slurry pipelines are used mostly for “short haul” duties, e.g. dredging (~300m ), process plants (~300m) and tailings (~3 km) In some “long haul duties”, minerals are pumped many hundreds of kilometres. Alumbrera copper concentrate pipeline (316 km), Argentina ENGINEERED BY PSI Photo’s with permission of PSI Australia Pty. Ltd., 66 Kings Park Rd.,West Perth, WA 6005,Tel. no. (08) 9463-6606. Slurry Pipelines Each type of duty has its own “best operation point”, where the size of the particles and the tendency to settle has a strong impact on capital and operating cost. ENGINEERED BY PSI Photo’s with permission of PSI Australia Pty. Ltd., 66 Kings Park Rd.,West Perth, WA 6005,Tel. no. (08) 9463-6606. Settling Slurries Non Settling Slurries contain particles that remain in suspension for a long time NON-SETTLING Settling Slurries contain particles that will fall and settle at the bottom of a container SETTLING • Particles < 40 µm Particles > 40 µm • Viscosity modified by particles Wide range of sizes from • Increasingly non-Newtonian as concentration increases Small (suspensions) 40 µm Medium (transition) 200 µm Large (heterogeneous) 2 mm Very Large (hetero “ “ ) 5 mm Transport velocity must increase as size increases ~ 200 µm ~ 2 mm ~ 5 mm ~ >200 mm? Settling Slurries SETTLING Particles > 40 µm Wide range of sizes from Small (suspensions) 40 µm Medium (transition) 200 µm Large (heterogeneous) 2 mm Very Large (hetero “ “ ) 5 mm ~ 200 µm ~ 2 mm ~ 5 mm ~ >200 mm? Transport velocity must increase as size increases Settling Slurries SETTLING Particles > 40 µm Wide range of sizes from Small (suspensions) 40 µm Medium (transition) 200 µm Large (heterogeneous) 2 mm Very Large (hetero “ “ ) 5 mm Dead Donkeys? ~ 200 µm ~ 2 mm ~ 5 mm ~ >200 mm? Pipeline Flow of Newtonian Liquids ΔP HW = ρg L V2 = f D 2g Darcy-Weisbach equation f L D HW = head loss due to friction (m) f = friction factor (dimensionless) L = length of pipe (m) D = internal diameter of pipe (m) g = accelaration due to gravity (m /s) V = mean Flow velocity (m/s) 2 Moody Diagram Head Loss HW P 2 v ρg 2g H1 = 1 + + z1 P 2 v ρg 2g H2 = 2 + + z1 Pipe Flow C.Y. O’Connor Pipeline c.a. 1899 Features of Settling Slurry Pipeline Flow Fixed Bed Fluidised Fluidised Bed Homogeneous Homogeneous Flow Heterogeneous Heterogeneous Flow 1. Size does matter. Hydraulic gradient, i (m/m ) V1 V2 V4 V3 =Vdep Settling Slurry • Larger particles require increased transport velocity • Smaller particles (particularly fines <40 µm) can modify viscosity. Helps to suspend larger particles. 2. Flow velocity generates turbulence which keeps particles suspended. Water Carrier Mean Velocity , V (m/s) 3. The system curve has a minimum that bounds different flow / friction processes Newitt’s Classification of Slurry Pipeline Flow Solids Concentration Newitt et al (1955) described a range of flow flow/deposition phenomena after observing sand and coal particles in 25mm Perspex pipes. His classifications are still used today. Newitt, D. M., J. F. Richardson, M. Abbott, and R. B. Turtle. 1955. Hydraulic Conveying of Solids in Horizontal Pipes. Trans. Institution of Chemical Engineers 33: 94-113. Frictional Head loss Mechanisms Head Loss , 5mm gravel,Cv=10%, DN400 Pipe 500 • Since we understand the behaviour of water (the carrier) we can calculate the frictional head losses caused by wall friction - HW • The remainder must be friction losses between 450 400 350 H M = HW + H S Frictional Head Loss due to solids - Hs )r 300 e ta W ‐ m (s 250 o L d a e 200 H Water Settling Slurry Deposition Point 150 Frictional Head Loss due to wall friction of carrier fluid with pipe- HW 100 (a) particles and fluid 50 0 0.00 2.00 4.00 6.00 8.00 10.00 12.00 Flow Velocity (m/s) 14.00 16.00 18.00 20.00 (b) particles and pipe wall (c) particle-particle collisions. Durand Theory -1952 φ = 82.ψ−1.5 ⎡V 2 ρ ⎤ iM − iW CD ⎥ = 82.⎢ CV .iW ⎣ gD ρS − ρ ⎦ Durand, R. 1952. The Hydraulic Transportation of Coal and Other Materials in Pipes. Colloq. of National Coal Board, London. −1.5 Durand Theory – (contd) Head Loss , 5mm gravel,Cv=10%, DN400 Pipe 500 1. Durand’s Theory is purely correlative. H M = HW + H S 450 400 350 2. The curve fit was for 305 points, for sand and coal running between 200 µm and 25 mm. Frictional Head Loss due to solids - Hs r) 300 te a ‐W m ( 250 s o L d a e H 200 Water Settling Slurry Deposition Point 150 4. As transport velocity becomes large, the slurry curve converges to water head loss from above. Frictional Head Loss due to wall friction of carrier fluid with pipe- HW 100 3. The results are in “Head of Carrier Fluid” – usually water. 50 0 0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16.00 18.00 20.00 Flow Velocity (m/s) i M − iW C V .iW ⎡V 2 ρ = 8 2.⎢ ⎣ gD ρ S − ρ φ = 8 2 . ψ − 1 .5 H M = H W (1 + C V . 8 2 .ψ − 1 .5 ) CD ⎤ ⎥ ⎦ − 1 .5 “Nothing proves that such a formula is rigorously exact. Doubtless exists a more accurate and more complex means of notation, but the one given above groups quite favourably” More Theories (To name a Few) Correlation 1. Durand – 1952 2. Homogeneous Mixture Theory 3. Newitt et. Al - 1955 4. Rose and Duckworth – 1969 Correlation 5. Heyden and Stelson - 1971 Correlation 6. Volcado and Charles 1972 Correlation 7. Wasp et al - 1977 Part theory part correlation Correlation 8. Lazarus – Neilson 1978 9. Wilson - 1992 10. Wilson Addie & Clift 1997 In Current Use Not in Use No Problem – “I’ve got a Computer” Head Loss at 6.6 m/s , 5mm gravel, Cv=10% DN400 Pipe x 1000m 800 700 600 ) 500 m ( s o L 400 d a e H 300 Lazarus ‐ Neilson Wilson‐Addie‐Clift Durand 200 Water 100 0 0 2 4 6 Flow Velocity (m/s) 8 10 Answers Using commonly accepted theories can vary by several hundred percent – AND MORE! Settling and Drag Forces on Particles Depends on density , particle diameter, shape, Reynolds number and surface effects Settling and Drag Forces on Particles Particles > 150 µm Drag coefficient as a function of Reynolds number for smooth spheres and cylinders (Munson et al. 2002, 582) Known correlations to correction CD based on shape effect Slip Velocity to Produce drag force FD Settling and Drag Forces on Particles Turbulent fluctuation of particle velocity in the direction of flow Settling and Drag Forces on Particles Head Loss , 5mm gravel,Cv=10%, DN400 Pipe 500 H Solids concentration approaches input concentration Hs=constant 450 400 350 )r 300 e ta ‐W (m s 250 o L d a e 200 H Hs Frictional Head Loss due to solids - Hs HW Frictional Head Loss due to wall friction of carrier fluid with pipe- HW 50 0 6.00 + H S Settling Slurry 100 4.00 W Water 150 2.00 = H H M = HW (1 + CV .82.ψ−1.5 ) Deposition Point 0.00 M 8.00 10.00 12.00 14.00 16.00 18.00 ΔP HW = ρg L V2 = f D 2g 20.00 Flow Velocity (m/s) • In the limit the slip velocity is roughly constant as the average velocity of particles in direction of flow equals approaches the velocity of the liquid i.e.Vsolid = Vliquid the “homogeneous limit” . In other words Hs << Hw • In Durand Theory in the limit Hs zero Comparison of Theories H e a d Lo s s , 5 m m gra ve l,C v= 1 0 % , D N 4 0 0 P ip e x 1 0 0 0 m 800 700 600 500 ) m ( s Lo 400 d a e H L azar u s N e ilso n W ilso n A d d ie C lift D u r an d 300 200 100 0 0 2 4 6 8 10 12 14 16 18 20 F lo w V e lo cit y (m / s) Location of The Deposition Velocity and Head Loss at Deposition is the Key to having an accurate Theory. Clearly the “state of the art is not good” Comparison of Theories Head Loss, 100µm particle, Cv=10%, DN100 pipe x 1000m 500 450 400 ) 350 m ( 300 s s o l 250 d a 200 e H 150 Wilson Addie Clift Durand Lazarus Neilson Water 100 50 0 0.00 2.00 4.00 6.00 8.00 10.00 Velocity m/s Agreement is less critical at 100 µm Wilson Addie and Clift Theory Slope M Determined in tests on 400 µm sand. Pressure gradient = 0.5 x sliding fr friction factor Lazarus Nielsen Theory (1978) Lazarus Neilsen Theory is a correlation theory that claims to be more accurate than Durand and Newitt’s theories. They proposed that the mass flow rate ratio (M*), defined as the ratio of mass flow of solids to carrier fluid, should be used instead of the volumetric concentration (Cv) Lazarus Nielsen Theory (contd) They plotted friction factor fM for the mixture against the “base” friction factor fB to develop their final correlation. Current Work – Particle Drag & Deposition Head and Velocity Collaborators : J. Bremer (SKM) , Vincent Lim (K.J. Beer), Ramesh Gandhi (PSI – California) Began by describing the equations of drag and pressure loss due to solids at the deposition point. Assumes : All particles fluidised at the minimum in the pressure gradient curve Fixed Bed Fluidised Fluidise d Bed Homogeneous Homogeneou s Flow Heterogeneous Heterogeneou s Flow Hydraulic gradient, i (m/m ) V1 V2 V4 V3 =Vdep Settling Slurry Water Carrier Mean Velocity , V (m/s) Particle Drag and Deposition Velocity and Head Loss(contd) Particle Drag and Deposition Velocity and Head Loss(contd) Pesky mean path length constan Particle Drag and Deposition Velocity and Head Loss(contd) All terms in the final equation are rearranged to solve for the Slip velocity V’ This is Measurable from experiment! Particle Drag a Virtual Experiment Based on Durand Points 4 × 10 −5 Particle Drag a Virtual Experiment Based on Durand Points System Parameter Value Range Unit Lower Upper Carrier density (ρ) 1,000 1,250 kg/m3 Carrier viscosity (μ) 0.0008 0.001 Pa.s 0.1 0.9 m 2,160 4,000 kg/m3 (40 μm) 0.02 (20 mm) m 0.05 0.4 Pipe diameter (D) Particle density (ρp) Particle size (d) Concentration by volume (Cv) Pipe length (L) Pipe roughness 1,000 m Smooth 200 Virtual data points (deposition velocity, and pressure at the deposition point) obtained using Durand equation to 4 × 10 −5 Virtual Experiment – Results Deposition Velocity Deposition Velocity – Average Error 0.05 % -- Maximum Error 0.42 % 4 × 10 −5 Virtual Experiment – Results Head Loss at The Deposition Point Head Loss – Average Error 0.55 % -- Maximum Error 1.8 % 4 × 10 −5 Conclusions 1. Not “all is well” with the theory of slurry transport. 2. There is considerable disagreement amongst theories regarding 1. Deposition velocity 2. Head Loss at Deposition 3. There is no clear agreement on the forces and friction associated with various mechanisms, (e.g. fluidised bed, heterogeneous flow, homogeneous flow etc) or the velocities at which they occur. 4. Many of the theories “blow up” when large particles are involved. Say > 2mm. Comparison between calculations at these sizes indicates a need for model studies in future developments. 5. Where possible don’t pump at sizes > 150 µm.