EURO Safety Data Sheet
Product name: Release agent LPZ/II®
Product No.: 001
Issue:
February 2009
1. Substance / Preparation and Company Description
A special oil dissolved in Ethanol
Manufacturer / Supplier Information
Manufacturer / Supplier:
Riepe GmbH & Co. KG
Street Adress / PO Box:
Postfach 2624
Country ID / City, State / Zip Code: D-32226 Bünde
Phone:
(+49 52 23) 6 09 90 u. 6 13 33
Area providing information:
Laboratory
Emergency Information:
Poison Control Center Bonn
Phone:
Phone:
Telefax:
(+49 52 23) 6 09 90
(+49 2 28) 2 87 32 11
(+49 2 28) 2 87 33 14
2. Possible Dangers during Preparation
Hazard designation: F = Highly flammable
Special hazard warnings for humans and the environment
R11= Highly flammable
S16 = Keep away from sources of ignition – no smoking
3. Composition / Component Information
Chemical characterization: Mixture of Ethanol with non dangerous constituents
Hazardous components:
CAS-No.
Designation acc. to EEC Directive
Content
Unit
Characteristic letter
R-Codes
64-17-5
Ethanol
EINECS: 200-578-6
> 85
%
F
R 11
Note:
The danger notes listed here are explained in greater detail in Chapter 15.
(Comment P of the EC-Material list / Annex I of Directive 67/548/EEA)
4. First Aid Measures
Note: In case of eye contact, rinse with clean, running water and seek medical attention, If swallowed, consult a doctor
immediately. Keep victim calm. Do not induce vomiting. Drink water with activated carbon.
5. Measures in Case of Fire
Suitable extinguishing agents: Foam (alcohol-resistant), carbon dioxide, powder
6. Measures in Case of Accidental Release
Person-related safety measures: Keep away from sources of ignition, ensure free circulation of air.
Environmental protection measures: Do not allow to escape into the sewage system.
Procedure for cleaning / adsorption: Confine leaked material with fire-proof absorbent agent, e. g. sand, soil, diatomite,
vermiculite and collect in the containers provided for removal according to local regulations.
7. Handling and Storage
Avoid exceeding the MAK limit values and keep the product stored in the original drums at all times.
Fire and explosion protection: Keep away from sources of ignition – no smoking. Take measures to prevent electrostatic
charging.
Storage: Keep it away from direct sunlight and other sources of heat and ignition.
Store it in firmly-sealed, cool, dry drums.
Storage rooms and containers: Comply with the laws and regulations governing the storage and use of materials which
are hazardous to water.
Instructions on storing materials together:
Comply with the instructions in the Flammable Liquids Decree (VbF), keep the containers firmly sealed, store it in firmlysealed, cool, dry drums. Comply with the VbF regulations and the TRbF technical rules associated with it.
Storage class: 3 A (VCI-concept, 1998)
Classification in accordance with the Industrial safety regulation (BetrSichV): highly flammable
8. Limitation of exposure and personal protectiv equipment
Technical Security Measures:
Avoid exceeding MAK values
Components with workplace-related limit values to be monitored:
CAS-Nr.
Description
Type
Value
Unit
64-17-5
Ethanol
MAK
980
mg/cbm
The values specified are taken from the lists that were valid at the time this safety data sheet was created (e. g. TRGS
900 for the Federal Republic of Germany).
Product name: Release agent LPZ/II®
Product No.: 001
Issue:
February 2009
Personal protective equipment:
General protective and sanitary measures: Wash hands before breaks and at the end of work. Avoid touching the
eyes and skin. Do not inhale vapors. Remove soiled, saturated clothing immediately. Keep away from beverages, food
and animal feed.
Breathing protection: Breathing protection required when ventilation/evacuation is inadequate
Hand protection: Protective gloves made from butyl or fluorine rubber (Viton) which can resist solvents
Eye protection: Airtight protective goggles
Body protection: Standard protective work clothing, chemical-resistant safety shoes or boots. If skin contact is likely
to occur, wear protective clothing that is impermeable for this solution.
9.
Physical and Chemical Properties
Form: liquid
Colour: colourless
Value:
Flashpoint:
< 21
Ignition temperature:
425
Selfignitability:
non selfignitable
Viscosity:
at 20°C
1,19
Density:
at 20°C
0,790
Vapour pressure: at 20°C
59
Lower ex-limit:
3,5
Upper ex-limit:
15,0
Solubility in water:
partly soluble
Solvent concentration:
approx. 90
organic solvents
Smell: alkohol like
Unit:
°C
°C
mPas
g/cbcm
mbar
Vol. %
Vol. %
Method:
DIN 53213
DIN 51794 for pure Ethanol
DIN 51794 for pure Ethanol
DIN 51757
Literature values
Literature values
%
10. Stability and Reactivity
When the recommended regulations on storage and handling are applied, no dangerous decomposition products can
be produced.
11. Information on Toxicology
Slightly irritating, has an astringent effect on the skin. Vapors in high concentrations can cause drowsiness.
12. Information on Ecology
The product is slightly hazardous to waters - Water hazard class 1. Due to the rapid evaporation from the solution and
from water surfaces, the product does not represent a significant threat to aquatic life. Must not enter the ground water,
bodies of water or the sewage system.
13. Instruction for Disposal
Must not be disposed of with the household garbage. Do not allow to escape into the sewage system. If possible, take to
recycling. Otherwise, burn or dump at an approved facility. Since January 1, 1999, most waste code numbers relate to application as well as the product. The waste code number valid for this application is listed in the European Waste Catalogue.
Dispose of uncleaned packaging in accordance with official regulations.
14. Information on Transport
Transport only in accordance with transport regulations for street (ADR) and rail (RID)
Land transport ADR / RID and GGVS/GGVE (transnational/domestic)
ADR / RID-GGVS/E Cl. 3
F1 Flammable fluids
Number/Letter:
F1 II
Number of danger designation (Kemler-Number): 33
UN-Number:
1170
Packaging group:
II
Label:
3
Proper Shipping Name:
ETHANOL-Solution
Transport by sea IMDG/GGVSee
IMDG/GGVSee-Cl.:
3
UN-Number:
1170
Label:
3
Packaging Group:
II
EMS-Number:
F-E, S-D
Proper Shipping Name:
ETHANOL-Solution
Transport by Air ICAO-TI
ICAO/IATA-Cl.:
UN/ID-Number:
Label:
Packaging Group:
Proper Shipping Name:
and IATA-DGR
3
1170
3
II
ETHANOL-Solution
15. Regulations:
Designation according to the Ordinance on Hazardous Substances
Identifier and hazard designation of the product:
F = highly flammable
R-Sets:
S-Sets:
R11 = highly flammable
S16 = keep away from sources of ignition – no smoking
Information according to the Water Resources Act: Water hazard class: WGK 1 (low hazard to water)
Statutory order on hazardous incidents: Substance group 2 (F = highly flammable liquid)
16. Additional Information:
The information is correct to the best of our knowledge but should not be taken as a warranty of specific product
characteristics and does not represent a contractually-binding relationship.