Material Safety Data Sheet

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Material Safety Data Sheet
Issuing Date 21-Jun-2007
Revision Date
MSDS PN: 4325970
REV. E
1. PRODUCT AND COMPANY IDENTIFICATION
Product Name
DNA Precipitation Solution 2
Product Code(s)
Trade Name(s)
4325964
Not Applicable
UN-No
UN1170
Recommended Use
For research use only. Not for use in diagnostic procedures.
Supplier Address
APPLIED BIOSYSTEMS850 LINCOLN
CENTRE DRIVEFOSTER CITY CA
USA 94404TELEPHONE: (650) 5706667 (USA)
Emergency Telephone Number
CHEMTREC: +1-703-527-3887 (INTERNATIONAL)
1-800-424-9300 (NORTH AMERICA)
2. HAZARDS IDENTIFICATION
WARNING!
Emergency Overview
FLAMMABLE LIQUID AND VAPOR
May be harmful if swallowed, inhaled, or absorbed through skin
May cause skin, eye, and respiratory tract irritation
May cause drowsiness and dizziness
May cause central nervous system depression
May cause adverse liver effects
May cause adverse kidney effects
Appearance Colorless
Potential Health Effects
Principle Routes of Exposure
Acute Toxicity
Eyes
Skin
Inhalation
Ingestion
Chronic Effects
Physical State Liquid
Odor Alcohol
Inhalation, Skin contact, Eye contact.
Irritating to eyes.
May be harmful in contact with skin. May cause irritation. May discolor the skin.
May be harmful if inhaled. Inhalation of vapors in high concentration may cause irritation of
respiratory system.
May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting
and diarrhea.
No known effect based on information supplied
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Aggravated Medical Conditions
Central nervous system. Preexisting eye disorders. Liver disorders. Skin disorders. Kidney
disorders.
Interactions with Other Chemicals
Use of alcoholic beverages may enhance toxic effects.
Environmental Hazard
See Section 12 for additional Ecological information.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name
Ethyl alcohol
Water
CAS-No
64-17-5
7732-18-5
Weight %
>60
10-30
4. FIRST AID MEASURES
General Advice
In case of injury caused by fire:. Flush with plenty of water immediately. Continue flushing
during transport to hospital or medical center.
Eye Contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye
irritation persists, consult a specialist.
Skin Contact
Wash skin with soap and water. If skin irritation persists, call a physician.
Inhalation
Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen
if breathing is difficult. If symptoms persist, call a physician.
Ingestion
Never give anything by mouth to an unconscious person. Clean mouth with water and
afterwards drink plenty of water. Do not induce vomiting. If symptoms persist, call a physician.
Notes to Physician
Treat symptomatically.
Protection of First-aiders
Remove all sources of ignition. Ensure that medical personnel are aware of the material(s)
involved, and take precautions to protect themselves.
5. FIRE-FIGHTING MEASURES
Flammable Properties
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Flash Point
< 21°C / < 70°F
Suitable Extinguishing Media
Water spray. Carbon dioxide (CO2). Foam. Dry powder. Cool containers with flooding
quantities of water until well after fire is out.
Unsuitable Extinguishing Media
Do not use a solid water stream as it may scatter and spread fire.
Explosion Data
Sensitivity to mechanical impact
Sensitivity to static discharge
None
Yes.
Specific Hazards Arising from the Chemical
Flammable. Vapors may travel to source of ignition and flash back.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus and full protective gear.
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NFPA
Health Hazard 2
Flammability 3
Stability 0
Physical and Chemical
Hazards -
HMIS
Health Hazard 2*
Flammability 3
Stability 0
Personal Precautions -
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions
Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures
against static discharges. Stop leak if you can do it without risk.
Methods for Containment
A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand
or other non-combustible material and transfer to containers.
Methods for Cleaning Up
Use clean non-sparking tools to collect absorbed material. Dike far ahead of liquid spill for later
disposal.
Other Information
Water spray may reduce vapor; but may not prevent ignition in closed spaces.
7. HANDLING AND STORAGE
Handling
Handle in accordance with good industrial hygiene and safety practice. Wear personal
protective equipment. Avoid contact with skin and eyes. Do not breathe vapors or spray mist.
Ensure adequate ventilation. Keep away from open flames, hot surfaces and sources of
ignition. Take precautionary measures against static discharges. Use only in an area
containing flame proof equipment. To avoid ignition of vapors by static electricity discharge, all
metal parts of the equipment must be grounded.
Storage
Keep in a dry, cool and well-ventilated place. Keep in properly labeled containers. Keep away
from heat and sources of ignition.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Chemical Name
Ethyl alcohol
ACGIH TLV
TWA: 1000 ppm
OSHA PEL
TWA: 1000 ppm
3
TWA: 1900 mg/m
TWA: 1000 ppm
NIOSH IDLH
3300 ppm
NIOSH IDLH: Immediately Dangerous to Life or Health
Engineering Measures
Showers, eyewash stations, and ventilation systems.
Personal Protective Equipment
Eye/Face Protection
Skin and Body Protection
Respiratory Protection
Safety glasses with side-shields.
Protective gloves.
In case of inadequate ventilation wear respiratory protection.
Hygiene Measures
When using, do not eat, drink or smoke. Regular cleaning of equipment, work area and
clothing.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Colorless.
Odor
Alcohol.
Odor Threshold
No information available.
Physical State
Liquid.
pH
No information available.
Flash Point
< 21°C / < 70°F
Autoignition Temperature
363°C / 685°F
Decomposition Temperature
No information available.
Boiling Point/Range
No information available.
Melting Point/Range
No information available.
Flammability Limits in Air
No information available.
Explosion Limits
Explosion Limits
Upper
19.0
Lower
3.3
Specific Gravity
No information available.
Water Solubility
Soluble in water.
Solubility
No information available.
Evaporation Rate
No data available
Vapor Pressure
59
Vapor Density
1.6
VOC Content
80
Partition Coefficient (noctanol/water)
No information available.
10. STABILITY AND REACTIVITY
Stability
Stable under recommended storage conditions.
Incompatible Products
Oxidizing agents. Acids. Bases. Peroxides. Combustible materials. Ammonia.
Conditions to Avoid
Keep away from open flames, hot surfaces and sources of ignition.
Hazardous Decomposition Products Carbon oxides.
Hazardous Polymerization
Hazardous polymerization does not occur.
11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
Chemical Name
Ethyl alcohol
LD50 Oral
1501 mg/kg (rat)
LD50 Dermal
LC50 Inhalation
124.7 mg/L ( Rat ) 4 h
Chronic Toxicity
Target Organ Effects
Blood, Central nervous system (CNS), Eyes, Liver, Reproductive System, Respiratory system,
Skin.
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12. ECOLOGICAL INFORMATION
Ecotoxicity
Ecotoxicity effects of component substances.
Chemical Name
Ethyl alcohol
Toxicity to Algae
Persistence and Degradability
Toxicity to Fish
Microtox
Daphnia Magna (Water Flea)
EC50 = 34634 mg/L 30 min
EC50 = 10800 mg/L 24 h
LC50= 12900 mg/L
EC50 = 35470 mg/L 5 min
EC50 = 9268 mg/L 48 h
Oncorhynchus mykiss 96 h
LC50= 14.2 mg/L Pimephales
promelas 96 h
No information available.
Chemical Name
Ethyl alcohol
Log Pow
-0.32
13. DISPOSAL CONSIDERATIONS
Waste Disposal Method
This material, as supplied, is a hazardous waste according to federal regulations (40 CFR
261).
Contaminated Packaging
Dispose of in accordance with local regulations.
US EPA Waste Number
D001
This product contains one or more substances that are listed with the State of California as a hazardous waste.
Chemical Name
Ethyl alcohol
California Hazardous Waste Status
Toxic; Ignitable
14. TRANSPORT INFORMATION
DOT
Proper Shipping Name
Hazard Class
UN-No
Packing Group
Description
Ethanol solution
3
UN1170
II
Ethanol solution,3,UN1170,PG II
Proper Shipping Name
Hazard Class
UN-No
Packing Group
Description
Ethanol
3
UN1170
II
ETHANOL,3,UN1170,PG II
Proper Shipping Name
Hazard Class
UN-No
Description
Etanol
3
UN1170
UN1170 Etanol,3,
TDG
MEX
ICAO
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14. TRANSPORT INFORMATION
UN-No
Proper Shipping Name
Hazard Class
Packing Group
Description
UN1170
Ethanol solution
3
II
Ethanol solution,3,UN1170,PG II
UN-No
Proper Shipping Name
Hazard Class
Packing Group
ERG Code
Description
UN1170
Ethanol solution
3
II
3L
UN1170,Ethanol solution,3,PG II
IATA
IMDG/IMO
Proper Shipping Name
Hazard Class
UN-No
Packing Group
EmS No.
Description
Ethanol (Ethyl alcohol)
3
UN1170
II
F-E, S-D
UN1170, Ethanol (Ethyl alcohol),3,PG II
RID
Proper Shipping Name
Hazard Class
UN-No
Packing Group
Classification Code
Description
ADR/RID-Labels
Ethanol (Ethyl alcohol)
3
UN1170
II
F1
UN1170 Ethanol (Ethyl alcohol),3,II,RID
3
Proper Shipping Name
Hazard Class
UN-No
Packing Group
Classification Code
ADR/RID-Labels
Ethanol (Ethyl alcohol)
3
UN1170
II
F1
3
Proper Shipping Name
Hazard Class
Packing Group
Classification Code
Special Provisions
Description
Hazard Labels
Limited Quantity
Ventilation
Ethanol
3
II
F1
144, 330, 601
UN1170 Ethanol,3,II
3
LQ4
VE01
ADR
ADN
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15. REGULATORY INFORMATION
International Inventories
TSCA
Listed on inventory. For purposes of 40 CFR 720.36, this product is for Research and
Development (R&D) Use Only.
Complies
Complies
Does not Comply
Complies
Complies
Complies
Complies
DSL
EINECS/ELINCS
ENCS
CHINA
KECL
PICCS
AICS
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories
Acute Health Hazard
Chronic Health Hazard
Fire Hazard
Sudden Release of Pressure Hazard
Reactive Hazard
Yes
Yes
Yes
No
No
Clean Water Act
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR
122.42)
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive
Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization
Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of
this material.
U.S. State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals:
Chemical Name
Ethyl alcohol
CAS-No
64-17-5
California Prop. 65
Developmental
U.S. State Right-to-Know Regulations
Chemical Name
Ethyl alcohol
Water
Massachusetts
X
New Jersey
X
Pennsylvania
X
Illinois
Rhode Island
X
International Regulations
Mexico - Grade
Serious risk, Grade 3
Chemical Name
Ethyl alcohol
Carcinogen Status
Exposure Limits
Mexico: TWA= 1000 ppm
3
Mexico: TWA= 1900 mg/m
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Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the
MSDS contains all the information required by the CPR.
WHMIS Hazard Class
B2 Flammable liquid
D2B Toxic materials
16. OTHER INFORMATION
Issuing Date
21-Jun-2007
Revision Date
Revision Note
No information available
Disclaimer
The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The
information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to
be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for
such material used in combination with any other material or in any process, unless specified in the text.
End of MSDS
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