a quarterly journal of KPIT Cummins Infosystems Limited VOL. 4 ISSUE 3, JULY - SEPT 2011 NANOTECHNOLOGY Nanotechnology : Origin and History Applications of Nanotechnology : Overview Automotive Applications of Nanotechnology : Sensors Automotive Applications of Nanotechnology : Body and Chassis, Comfort and Emission Systems Automotive Applications of Nanotechnology : Memory, Electronic Components, and Displays Future of Nanotechnology Nanomanufacturing : from Research to Commercial Colophon TechTalk@KPITCummins is a quarterly journal of Science and Technology published by KPIT Cummins Infosystems Limited, Pune, India. Foreword Dr. Vijayamohanan Pillai Acting Director Central Electrochemical Research Institute Karaikudi-630006 Tamil Nadu, India Chief Editor Dr. Vinay Vaidya CTO-Engineering IT, VP KPIT Cummins Infosystems Limited, Pune, India vinay.vaidya@kpitcummins.com Editorial and Review Committee Sanjyot Gindi Chaitanya Rajguru Krishnan Kutty Aditi Athavale Priti Ranadive Smita Nair M. N. Babu Tarun Kancharla Aniket Dhawade Reenakumari Behera Pranjali Modak Pranali Dhane Ankita Jain Designed and Published by Minds'ye Communication, Pune, India Contact : 9673005089 Write your suggestions to crest@kpitcummins.com Disclaimer The individual authors are solely responsible for infringement, if any. All views expressed in the articles are those of the individual authors and neither the company nor the editorial board either agree or disagree. The information presented here is only for giving an overview of the topic. For Internal Circulation Only TechTalk@KPIT Cummins Contents Editorial Foreword - Dr. Vijayamohanan Pillai 2 Editorial - Dr. Vinay Vaidya 3 Profile of a Scientist Richard Smalley - Father of Nanotechnology Krishnan Kutty 9 Book Review Mechanics of Patent Claim Drafting, John Landis Pranjali Modak Crossword 15 27 Articles 4 Nanotechnology : Origin and History Aditi Athavale Applications of Nanotechnology Tarun Kancharla 10 Automotive Applications of Nanotechnology : Sensors Swati Ojha and Reenakumari Behera 16 Automotive Applications of Nanotechnology : Body and Chassis, Comfort and Emission Systems Ashish Waykar 22 Automotive Applications of Nanotechnology : Memory, Electronic Components, and Displays Vaishnavi Poharkar 28 Future of Nanotechnology Nikhil Jotwani and Prasad Pawar 34 Nanomanufacturing - from Research to Commercial Smita Nair 40 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 1 Foreword Dr. Vijayamohanan Pillai Acting Director Central Electrochemical Research Institute Karaikudi-630006 Tamil Nadu The very small world (i.e., nano-world) has big horizons and uncanny surprises. Although many of Feynman's nanomachines that could be built atom-by-atom and molecule-by-molecule precisely, promising great opportunities and an unprecedented era of have not been realized completely, his vision of miniaturization has expanded our capabilities to unprecedented level, often reaching even to supernatural capabilities with respect to material design and innovation across multiple disciplines. Today, Feynman's dream is surely being realized on a grand and global scale as explained in this special issue of Techtalk. The remarkable increase in performance of nanoelectronic devices, possibility of design materials with controllable intelligence for specific applications, ultralight but super-hard and impact resistant nanocomposites, personalized health care with controlled drug delivery systems, self-healing smart bridges, self-cleaning and superhydrophobic surfaces --- all these illustrate the power of nanomaterials which are inextricably linked with innumerable applications. An important feature of all these wonderful materials (i.e., materials with at least one dimension in the quantum size regime) is its ability to bridge the crucial dimensional gap between the atomic and molecular fundamental sciences and the micro-structural scale of engineering and manufacturing. It is generally accepted that the quantum confinement of charge carriers by the potential wells of nanometer size structure provides one of the most powerful, yet versatile means to control the properties of these materials by modulating their size and shape. All the articles presented here deal with fascinating aspects of nano-materials to provide many recent excitements to the general reader. Many people often talk about nanotechnology revolution although until now it amounts only a revolution more in terms of ideas on materials and devices rather than tangible industrial benefits. Proponents hail nanotechnology as a panacea for all our global challenges like availability of cheap and clean energy, environment clean-up, affordable healthcare, supply of drinking water to all etc although critics point out that nanotechnology has not really delivered major benefits despite the Europhobia. However, some of the most significant and cutting edge research that have happened in the last decade is in nanotechnology where new materials like carbon nanotubes, graphene, quantum dots, metallic Nanowires etc have caused enormous excitement. The shaper and size dependant properties of many of these nanomaterials are very useful for making nanocomposites with unprecedented applications potential due to the possibility of tailoring their dimensionality to facilitate a change in their fundamental properties including mechanical, electrical, optical or electrochemical behavior in comparison with similar behavior of their bulk analogues. For example, the behavior of monolayer protected gold and silver nanoclusters have been found to vary dramatically with both size and shape. Similarly, the insertion of conducting polymers in layered host materials and other structurally organized environments can result nanostructures with novel electrical, structural, and mechanical properties. Such systems can potentially show hybrid properties synergistically derived from both the host and the guest which could be profitably utilized for energy storage applications. This issue of tech talk focuses on applications of nanotechnology . There also needs a cautionary note on some aspects of nanotechnology, popularly known among skeptics as “anti-nanotechnology” While nanomaterials create a wealth of new opportunities, they also pose tremendous environmental and human risks. Potentially harmful effects of nanotechnology might arise as a result of the nature of the nanoparticles themselves, the characteristics of the products made from them, or aspects of the manufacturing process involved. The large surface area, crystalline structure, and reactivity of some nanoparticles may facilitate transport in the environment or lead to harm because of their interactions with cellular material. The size of nanomaterials could facilitate and exacerbate any harmful effects caused by the composition of the material. Little is known about the fate, transport, and transformation of nanomaterials after they enter the environment. Although there have been few studies to date on the potential toxicity of nanomaterials, research efforts should be intensified in order to prevent the possibility of damage to human health and the environment. High reactivity and tendency of accumulation in tissues pose threats to living organisms and more regulatory and safety measures are needed for the production and use of many nanomaterials. 2 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Editorial This issue is a very special issue from the perspective of cutting edge technology. The topic of nanotechnology has taken a firm grip on everyone's mind. Many look at it with awe. Even the world of physics, as we understand, has been challenged by it. Nano particles behave differently than the laws of Physics we know. For example, magnetic behavior of nanoparticles defies the laws of physics. It's a completely new world down there. Dr. Vinay Vaidya CTO - Engineering IT, VP KPIT Cummins Infosystems Limited, Pune, India Our first research work, at KPIT Cummins, in the area of nanotechnology started about a year ago. We started carrying out joint research with the National Chemical Laboratories (NCL) under the guidance of Dr. Vijayamohanan. Using nanomaterials, we developed a supercapacitor also called ultracapacitor. To connect this supercapacitor, we built a special circuit. This circuit and the supercapacitor were connected to a bicycle. Energy generated during peddling was captured through a generator. This electrical energy was captured in the supercapacitor. The captured energy was then used for running the bike as an electric bicycle. In the last 25 years, nano technology has become a common word. In general, for technology under development it takes much longer for it to become part of layperson's talk. Nanotechnology has found multiple applications in wide spectrum of domains. In health care, nanotechnology is helping us make advances in detecting, diagnosing and treating diseases. In aerospace, nanotechnology is providing new tougher and lighter materials. There are multiple applications in the automotive industry. They range from a cooler engine, scratch free surface, change of car color, sensors, batteries, to fuel cells. For the textile industry, it is useful in developing stain resistant, wrinkle free cloth. In the electronics industry, it can help create a memory device with one terabit per square inch. It has also wide applications in other areas such as food processing, cosmetics, and construction. The list is never ending. What use can we make of nanotechnology in the future is up to our imagination. In the late 80's, Life magazine had come up with an issue that talked about a futuristic scenario. It said that in the future humans would live beyond 350 years. In the article they had weaved a very interesting life story of such a couple. At around 75 both of them decide to change their career. Thus, they go back to school, get another degree, and change their profession. At around 125, they get tired of it, go back to school, and repeat the process. The present state is quite different. Recently, a 115-year-old woman passed away and she has set the record of longevity. We still have a long ways to go before life can be extended to 150 years. Since nano technology deals at the same scale as the size of an individual cell, perhaps nano technology would shed some more light and help us get to that dream. Please send your feedback to : vinay.vaidya@kpitcummins.com TechTalk@KPITCummins, Volume 4, Issue 3, 2011 3 Prof. Richard “Rick” Errett Smalley (1943 – 2005) “Be a scientist, save the world” 35 & 36, Rajiv Gandhi Infotech Park, Phase - 1, MIDC, Hinjawadi, Pune - 411 057, India. y “Be a scientist, save the world” TechTalk@KPITCummins July - September 2011 4 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Nanotechnology: Origin and History About the Author Junior Scientist CREST, KPIT Cummins Infosystems Ltd, Pune, India Areas of Interest Cryptography, Multicore Programming Aditi Athavale TechTalk@KPITCummins, Volume 4, Issue 3, 2011 5 1. Introduction Did you ever wonder what is it that makes a stained glass so unique in colors? You may think it has to do with the addition of some colored elements to the molten glass. In reality, these particles of gold and silver give rise to red and yellow shades in the glass. Surprised? The artists of medieval period (500 AD- 1450 AD) used to mix compounds of gold and silver into the molten glass. The color was due to the extremely small size of these metal particles [1]. lization of the technology, followed by the instances of development of machines that operate at nanoscale. II. What is Nanotechnology? Nanotechnology is manipulation of matter at a very tiny scale, that is, at the scale of molecules and atoms. Nanoscale means measurement in the range of 1 to 100 nano-meters, where one nanometer is one billionth of a meter. Every material has its own physical properties like color, frequency, electric conductivity etc. These properties are retained even if we divide the material into smaller parts. However, at nanoscale, the properties of the material may change abruptly. A single blink of an eye is about one-billionth of a year. An eye blink is to a year what a nano-meter is to a meter stick [2]. Fig.1. Stained glass Even before this, way back during the Roman period, a unique cup called as 'Lycurgus Cup' was prepared using a similar technique. The cup is now displayed at the British Museum, London. It appears green when light is passed through it from outside and red when it is illuminated from within [1]. This miraculous display of colors, mentioned in the above cases, is due to the presence of extremely minute particles called as nanoparticles. Fig.2: Lycurgus Cup. It turns red if illuminated from within, and green when illuminated from outside. Thus, knowingly or unknowingly, nanotechnology has been in use for thousands of years. This article gives a glimpse of its journey mentioning some incidents of unintentional use of the nanotech principles, milestones for the formal conceptua- 6 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Multiple phenomena are responsible for change of physical properties of a material at nano-scale. The change in color of metal particles as described in the above section occurs due to a phenomenon called as Plasmon resonance. It is caused by the unique interaction of nanoparticles when they are exposed to light. III. How did it Evolve as a Science? There is plenty of room at the bottom This was the title of the talk given by the American Physicist and Nobel laureate, Richard Feynman, in 1959 at an American Physical Society meeting. In the talk, he presented the possibility of manipulation of atoms or molecules. He also brought out the possibility of building extremely tiny machines that "arrange the atoms the way we want" and achieving chemical synthesis through mechanical manipulation. He also suggested that due to the extreme small nature, various forces that act on molecules might act differently. Forces like 'Gravity' may not retain their importance, but forces like surface tension or Van der Waal's force may have greater role to play. Van der Waal's force is the relative force of attraction or repulsion between two molecules. He also presented ideas on building a very small robot for carrying out surgeries, having dense computer circuits to increase the computation power of computers, and building a microscope that can be used at a scale of molecules and atoms. Origin of the term 'Nanotechnology' Fullerenes and Carbon tubes In 1974, Japanese scientist Norio Taniguchi coined the term 'Nanotechnology' for the first time in a conference while referring to a semiconductor process at minute scale. Carbon exists in different allotrope forms like graphite, diamond etc. Fullerenes are also allotropes of carbon. Richard Smalley, Robert Curl, James Heath, Sean O'Brian and Harold Kroto at Rice University discovered first fullerene molecule in 1985. Spherical fullerenes resemble football in appearance as shown in Figure 4. Fullerenes doped with some elements form superconducting materials. Fullerenes having cylindrical shapes are called as carbon nanotubes. Cross-sectional view of a carbon nanotube is shown in Figure 5. Due to their unique physical properties, they are found very useful in domains of material science and electronics. A quote from the book 'Engines of Creation: The Coming Era of Nanotechnology': “Arranged one way atoms make up soil, air, and water; arranged another, they make up ripe strawberries. Arranged one way, they make up homes and fresh air; arranged another, they make up ash and smoke.” In 1979, K. Eric Drexler came across Feynman's talk 'There is plenty of room at the bottom'. In 1986, he wrote a book 'Engines of Creation: The Coming Era of nanotechnology' [3] in which he presented concept of second-generation nanomachines called as 'Assemblers'. He proposed that these will serve as devices for assembling molecular structures and will let us place atoms in any reasonable arrangements allowed by basic laws of nature. According to him, advancements in the field of technology, medicine, computation, production etc. will all depend on the ability to rearrange atoms. Fig.4. Spherical Fullerene, also called as 'Buckyballs' In 1981, an instrument called as Scanning Tunneling Microscope (STM) was build for taking images at atomic scale. The creators, Gerd Binning and Heinrich Rohrer got Nobel Prize in Physics in 1986. Its resolution of the order of 0.1nm enabled scientists to observe and manipulate the materials at atomic level. Figure 3 shows atoms of Silicon observed using STM. Fig.5. Spherical Fullerene, also called as Carbon Nanotubes Nano-tubes or Magical Wands? Nano-tubes are found highly useful in surprisingly distinct domains. They are used in: high tensile strength fibres, body-armours, replacement of muscle tissues, tiny radios, solar cells, displays, loud speakers, water filters, treatment of cancer etc. Fig.3. Silicon atoms as observed by STM TechTalk@KPITCummins, Volume 4, Issue 3, 2011 7 Around 1980, Nadrian Seeman from New York University pioneered the concept of DNA nanotechnology. A DNA Machine is a molecular machine constructed from DNA. Molecular machines are nothing but machines that produce some physical or mechanical output at molecular level based on the input. Such machines are considered as an important step towards the realization of 'assemblers', the molecular reassemblers conceptualized by K. Eric Drexler. In 2001, Researchers at IBM successfully built the first logic gate using carbon nano-tubes [4]. This achievement has opened the gates for building sophisticated electronic devices using nanotechnology. In 2003, Eric Drexler and Rice University professor Richard Smalley engaged in a debate on the feasibility of molecular reassembly [5]. Drexler claimed that such reassembly is possible through mechanical process where as Smalley insisted on the chemical assembly part of it. This debate is considered important in the sense of realization of nano-techniques. There have been numerous experiments that use nanoparticles in different domains. For last few decades, they have opened up a new area of research for scientists from all over the world. This article covers only few milestones in the history of nanotechnology. IV. Conclusion Though scientifically formulated in 1980s, nanotechnology has been prevalent for thousands of years. Since the last few decades, however, there have been numerous efforts that have contributed to the evolution of nanotechnology as a modern science. Considering its huge scope in futuristic technologies, it will definitely progress at a much faster pace in future. References [1] “History of Nano Timeline”, DiscoverNANO, Northwestern University, 2005. [2] Kim Duncan and Greta Zenner, “Cutting It Down to Nano”, Program Guide, University of Wisconsin-Madison Materials, [3] K. Eric Drexler, “Engines of Creation: Coming Era of Nanotechnology”, 1986. ISBN No: 0-385-19973-2. [4] V. Derycke, R. Martel, J. Appenzeller, and Ph. Avouris, “Carbon Nanotube Inter- and Intramolecular Logic Gates”, American Chemical Society, 2001. [5] Otavio Bueno, “The Drexler-Smalley Debate on Nanotechnology”, HYLEInternational Journal for Philosophy of Chemistry, Vol.10 (2004), pp. 83-88. There's a nuclear scientist, a genetic engineer and a nanotechnologist all being held at the barrel of a gun by a crazy man. The captor says he'll shoot all of them unless they can convince him they are doing something good for the world. The nuclear scientist tries first, explaining that nuclear power is “clean, cheap, and will solve climate change.” Unconvinced, his captor shoots him dead and turns next to the nanotechnologist to plead his case. Before he can say a word however, the genetic engineer intervenes. “No!” pleads the genetic engineer “please shoot me first – I'd rather die than hear yet another lecture on why nanotechnology is going to save the world!” 8 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Profile of a Scientist Prof. Smalley was born in Akron, Ohio, on June 6, 1943. He earned his bachelor's degree from the University of Michigan in 1965, and his Ph.D. from Princeton University. He did his post-doc work at the University of Chicago, where he developed the molecule-cooling nozzle. After his post-doc, Smalley joined the Rice University as an assistant professor in chemistry in 1976. He was instrumental in launching Rice's Quantum Institute and the Center for Nanoscale Science and Technology, and was cross-appointed as a professor of physics in 1990. He was later named to the rank of University Professor, Rice's highest professorial distinction, in 2002. Prof. Smalley's interest in science since his childhood had many roots. Some came from his mother who loved science, particularly, as a result of her classes on the Foundations of Physical Science taught by a brilliant mathematics professor at the University of Kansas City, Dr. Norman N. Royall, Jr. Prof. Smalley was influenced by this professor indirectly, through hundreds of hours of conversations at his mother's knees. It was from his mother that he first learnt of Archimedes, Leonardo da Vinci, Galileo, Kepler, Newton, and Darwin. He spent hours together with his mother, collecting single-celled organisms from a local pond and watching them with a microscope she had received as a gift from his father. His research at Princeton and Chicago started changing the face of Molecular Physics. It was the three articles that Prof. Smalley published, along with Sir Harold Kroto and Robert F. Curl Jr., that earned them their Nobel Prize in Chemistry in 1996. The first article was based on the discovery of C60 molecule in the Nov. 14, 1985, issue of Nature "C60: Buckminsterfullerene". The second article described in detail the discovery of the endohedral fullerenes in "Lanthanum Complexes of Spheroidal Carbon Shells" in the Journal of the American Chemical Society v. 107 p 7779 (1985). The third one announced the discovery of the fullerenes in "Reactivity of Large Carbon Clusters: Spheroidal Carbon Shells and Their Possible Relevance to the Formation and Morphology of Soot" in the Journal of Physical Chemistry v. 90 p 525 (1986). Prof. Richard “Rick” Errett Smalley (1943 – 2005) “Be a scientist, save the world” Prof. Smalley was a fellow of the American Association for the Advancement of Science, the American Academy of Arts and Sciences, and the American Physical Society, and a member of the National Academy of Sciences. In his later years, Smalley was very outspoken about the need for cheap, clean energy, which he described as the number one problem facing humanity in the 21st century. He felt that improved science education was the key, and went to great lengths to encourage young students to consider careers in science. His slogan for this effort was "Be a scientist, save the world." Prof. Smalley died of leukemia on October 28, 2005, at the age of 62. He was a leading advocate of nanotechnology and its many applications like its use in creating strong but lightweight materials and also its potential to fight cancer. The US Senate passed a resolution to honor Smalley posthumously crediting him as the “Father of Nanotechnology”. Krishnan Kutty Principal Scientist CREST, KPIT Cummins Infosystems Ltd, Pune, India Areas of Interest Computer Vision, Image Processing, Pattern Recognition TechTalk@KPITCummins, Volume 4, Issue 3, 2011 9 10 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Applications of Nanotechnology About the Author Senior Research Associate, CREST, KPIT Cummins Infosystems Ltd., Pune, India. Areas of Interest Speech and Image processing Tarun Kancharla TechTalk@KPITCummins, Volume 4, Issue 3, 2011 11 I. Introduction Nanotechnology is becoming a buzzword in many areas. From health to security and from automotive to airplanes, the fields are replete with many examples of applications. Nanotechnology deals with the manipulation of matter at near atomic level to produce new materials, structures, systems and devices that exhibit properties and phenomenon that are unique at these scales. These materials are called as nanotechnology materials or nanomaterials. Nanomaterials have at least one dimension less than 100nm which is 1/20th the size of a red blood cells (2,000 nm) or 1/1000th the diameter of human hair (100,000nm). The potential benefits of miniaturization and unique properties of the materials open the doors for possibilities of newer technologies in diverse fields. delivery systems that only target the diseased tissue and not the surrounding healthy tissues. Some diseases do not exhibit recognizable symptoms until they are well advanced. Often, earlier the disease is detected, the better the benefits of treatment. Nanoparticles can be attached to proteins or other molecules, allowing detection of disease indicators in a lab sample at a very early stage. Major effort is underway to develop nanoparticle disease detection systems. Nanoparticles are being developed so that they are attracted to the diseased cells. This helps in identifying and localizing the infected portion and medication can be given in a localized manner so as to target only the infected portion, keeping the healthy portion unaffected. This process can revolutionize the treatment of diseases like cancer. Fig. 2 shows how cancer cells are treated using nanotechnology. Fig. 1 Nanoparticles are small enough to enter a cell – National Cancer Institute [5] While several nanomaterials are still in the process of being developed and researched in various laboratories in the world, some of these nanomaterials are already being used in different areas in the society. The following sections give a brief overview of some of the applications of nanotechnology. II. Health Care The first significant benefits of nanotechnology would undoubtedly be seen in the health care area. The driving force behind this prediction is that the biological structures are within the size scale that researchers are now able to manipulate and control with the help of nanotechnology. Use of nanotechnology benefits all the stages of medication, it can be used to detect, diagnose and treat a disease. Research is being carried out to develop highly sensitive disease detectors and drug 12 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Fig. 2 Treatment of cancer cells using near infrared light with the help of nanoshells– National Cancer Institute [5] For centuries, people have longed to escape their short life spans, but all the attempts have met with failure. Medical advances have chiefly reduced early death but could not extend maximum life-span. The current research in nanotechnology provides a promising solution in this regard. Nanotechnology can help in reproducing or repairing damaged tissue [2]. “Tissue engineering” makes use of artificially stimulated cell proliferation by using suitable nonmaterial-based scaffolds and growth factors. For example, bones can be re-grown on carbon nanotube scaffolds. Tissue engineering might replace today's conventional treatments like organ transplants or artificial implants. Advanced forms of tissue engineering may lead to life extension. III. Energy Nanotechnology has the potential to impact all the stages of energy value chain. Research is being done to improve the efficiency of generation, distribution and storage of energy [3]. Researchers at Rice University are developing wires that contain carbon nanotubes. These wires have less resistance than the conventional wires, which helps in reducing the transmission losses. Richard Smalley envisioned the use of nanotechnology to radically change the electricity distribution grid. Carbon nanotubes are being used to make windmill blades that are stronger and lighter in weight. These resulting longer blades increase the amount of electricity generated by each windmill. The commercially available solar cells have very low efficiency of the order of 15-20%. Nanotechnology is being used to increase the efficiency and reduce cost of the solar cells. For example, materials like Titanium dioxide nanotubes filled with a polymer are being used to produce low cost solar cells. Physicists from the University of Illinois at Urbana-Champaign (UIUC) have improved the performance of solar cells by 60 percent by coating the solar cells with a film of 1-nanometer thick silicon fluorescing nanoparticles. Researchers at the Ohio State University have developed a new technique that reduces the cost of solar cells. A mixture of ruthenium and titanium or zinc oxide particles is used to absorb sunlight. Nanowires are implanted in the cells, which serve as connection between the cells on the panel and serve as the link for power transfer. The solar cells developed by researchers at the Ohio State University are shown in Fig. 3. Nanotechnology is being used to develop materials, which can be used as catalysts in fuel cells thereby reducing the cost of the fuel cells. Silicon Nanoparticles have been shown to dramatically expand the storage capacity of lithium ion batteries without degrading the silicon during the expansion/contraction cycle that occurs as power is charged and discharged. With further research in developing better and efficient storage mechanisms and by using renewable sources of energy like solar and wind, the dependence on the fossil fuels can be greatly reduced and we can step towards a future that is sustained by “green energy”. IV. Aerospace and Automotive Lighter and stronger materials will be of immense use to aircraft manufacturers, as they not only help to protect the aircraft from external impacts but also decrease the amount of fuel consumed. These materials will also benefit spacecraft where weight is a major factor. Nanotechnology would help to reduce the size of equipment and there by decrease fuel-consumption required to get it airborne [1]. Different areas in an aircraft like electronics, fuel cells etc., can be improved using nanotechnology. Fig. 4 shows the different areas in an aircraft. Fig. 4 Nanotechnology will have a tremendous impact on the aerospace and space flight industry by affecting many different areas [6] Lighter and stronger materials will also be useful for creating vehicles that are both faster and safer. They protect engine parts from wear and tear thereby increasing the lifespan and efficiency [1]. Fig. 3 Solar cells made from nanotechnology by researchers at Ohio State University [7] MEMS (Micro Electro Mechanical Systems) techniques allow both electronic circuits and mechanical devices to be manufactured onto a TechTalk@KPITCummins, Volume 4, Issue 3, 2011 13 single silicon microchip. NEMS (Nano Electro Mechanical Systems) is the next miniaturized version of MEMS. MEMS technology allows for the miniaturization of the electronic components used in aircrafts or vehicles. For example, MEMS accelerometers have replaced the previously bulky accelerometers used for air-bag deployment in automobiles. Similarly, MEMS gyroscopes and MEMS inertial sensors are being used in automobiles and for consumer electronics. The newer MEMS chips are both tiny and costeffective. The basic areas where nanotechnology can benefit automobiles are – lighter and stronger materials for better safety of the passengers, improved and miniaturized electronic systems, improved engine and fuel efficiency, lower component failure, smart materials for self-repair and greater service life. V. Security Advances in nanotechnology may play a critical role in national security. They can aid military personnel in detecting biological weapons. Manufacturing of lighter and stronger materials can be used to build armor to protect personnel and military equipment. With the increase in chemical and biological weaponry over the decades, protection of civilians is of primordial importance to any government. Protection against these types of attacks depends on the ability to detect and respond to the threats. The ability of nanoparticles to operate at molecular or atomic level provides significant advantage in dealing with afore mentioned circumstances. In health care, the nanosensors are used to detect the infected/diseased area, the same application can be used for defense purposes to detect radioactive materials or biological weapons like anthrax. Nanotechnology can be used to produce lighter and smaller autonomous vehicles (robots) for reconnaissance, surveillance and communication. Nanotechnology ultimately raises the prospect of microscopic mobile robots that can be used for surveillance or in war [4]. VI. Other Applications Nanotechnology has been used in various industries like cosmetics, textiles, food processing, construction, electronics, communication etc. 14 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 A sunscreen based on mineral nanoparticles such as titanium dioxide or zinc oxide offer several advantages. These nanoparticles have a comparable UV protection property and are transparent in appearance thereby avoiding the undesirable whitening, which comes with other sunscreens. Clothes that are water and stain resistant and wrinkle free can be manufactured using nanotechnology. Nanosensors are being weaved along with the clothes that can be used to monitor a person's health. The most prominent application of nanotechnology in the household is self-cleaning or easy-to-clean surfaces on ceramics or glasses. Nano ceramic particles have improved the smoothness and heat resistance of common household equipment. Nanotechnology can be applied in the production, processing, safety and packaging of food. A nanocomposite coating process could improve food packaging by placing anti-microbial agents directly on the surface of the coated film. Summary With nanotechnology, the products obtained will be cheaper and more efficient. Further advances in usage of nanotechnology and developing new nanomaterials may provide solutions to problems that would not have been thought to be possible a couple of decades ago. The ability to manipulate matter at molecular level offers nanotechnology endless possibilities and we may be seeing just the tip of the iceberg now. This article gives a brief introduction to applications of nanotechnology in some of the major fields. The more is yet to come. After all, who has seen the future? References [1] http://en.wikipedia.org/wiki/List_of_nanotechnology_applications [2] K.Eric Drexler, “Engines of Creation: The Coming Era of Nanotechnology,” Anchor Books, 1986. [3] Steve Gillett, “Nanotechnology for Clean Energy and Resources,” White paper in Foresight Institute, October 2002. [4] Altmann J, Gubrud MA, “Military arms control and security aspects of nanotechnology,” Baird D, Nordmann A, Schummer J (eds) Discovering the nanoscale, Amsterdam: IOS Press, pp 269–277, 2004. [5] http://www.cancer.gov/cancertopics/understanding cancer/nanodevices [6] http://nanopedia.case.edu/NWPage.php?page=aerospace [7] http://www.ecofriend.com/entry/nanotechnology-helps-better-thecolor-and-cost-of-solar-cells/ Book Review Mechanics of Patent Claim Drafting An invention can be protected by filing a patent application. The patent application is a legal document in a predefined format describing your invention in detail. The most important section of the patent application is claims, which define the boundaries of protection granted by a patent. In patent infringement litigation, the first phase of trial is generally of claim construction wherein the meaning and scope of each word in a claim is defined. Many patent cases may be won or lost based upon claim construction rulings. One such interesting case is Altair Engineering vs. LEDdynamics. Altair Engineering sued LEDdynamics for infringing their patent claiming an LED light fixture. The claim of subject patent included a term “closely spaced” which was contested in the trial. Altair Engineering had not sufficiently defined the term “closely spaced” in the claim and the description of the patent. This resulted into different interpretations of the term based on which Altair engineering lost the case. Thus, well drafted claims are the backbone of a patent application and patent enforcement. Drafting a patent application is an art and drafting the claim section of the patent application, which is the legal heart of a patent application, requires a lot of knowledge and skill. The book, 'Mechanics of Patent Claim Drafting', by John L. Landis is one of the basic books which provide the reader with a complete insight into the art of claim drafting. The book discusses at length how to draft quality claims which will satisfy the requirements of the United States Patent Office. The book begins with discussion on the basic principles of claim drafting which includes information on statutory provisions and the claim forms and formats in general. It provides details about the claim structure, claim language, parts of a claim, claim placement, claim numbering and claim order. Different types of claim and claim structure is used for different types of invention. The book discusses various types of claims in thorough details. Individual chapters are dedicated to apparatus or machine claims, method or process claims, article of manufacture claim, composition of matter (chemical) claims and claims for biotechnology inventions. Each of these chapters explains the claim elements, the claim limitations and the types of inventions covered for each of these claim types. MECHANICS OF PATENT CLAIM DRAFTING John L. Landis balance between a broad claim and a narrow claim. Causes for which a claim may be rejected, like duplicate claiming, undue multiplicity, over claiming, incompleteness, etc. are discussed in the section of nonart rejection. Finally, the book concludes with thoughts on claim writing, wherein all the information is precisely summarized. With sufficient examples and a simple language, the complicated task of claim drafting has been explained in an easy manner by the author. The book serves as a basic tool for patent practitioners to draft healthy patent applications. Although the book is heavy for a first-time reader, it is a must read before you attempt to draft a patent application. If you are an inventor for a patent application and you wish to know why the claims in your patent application seem as they seem to be- complicated and confusing- this book will surely provide you the required insight. The 1970 edition of 'Mechanics of Patent Claim Drafting' published by the Practicing Law Institute is the original reference. The versions that have been revised with collaboration of various other authors are available in different editions under the title of 'Landis on Mechanics of Patent Claim Drafting'. About the Author Pranjali Modak Senior Research Associate CREST, KPIT Cummins Infosystems Ltd, Pune, India Areas of Interest Intellectual Property Rights, Patents The latter part of the book talks about claims of varying scope, wherein the importance of the scope of a claim is discussed. A claim should not be too broad or too narrow. This section helps you understand how to achieve the finer TechTalk@KPITCummins, Volume 4, Issue 3, 2011 15 16 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Automotive Applications of Nanotechnology: Sensors About the Authors Research Associate, CREST, KPIT Cummins Infosystems Ltd., Pune, India. Areas of Interest Image Processing, Embedded systems Swati Ojha Senior Research Associate, CREST, KPIT Cummins Infosystems Ltd., Pune, India. Areas of Interest Computer Vision, Digital Signal Processing Reenakumari Behera TechTalk@KPITCummins, Volume 4, Issue 3, 2011 17 Introduction: Sensors are devices that convert a physical parameter to a signal that can be measured electrically. Once the physical parameter has been converted to an electrical equivalent, it can be easily used as an input to a computer or microprocessor for manipulating, analyzing and displaying. Most commonly used sensors are pressure, temperature, position, speed etc. Unlike the bulky and expensive traditional sensors, the Figure 3: Structure of SWNTs [10] Figure 4: Structure of MWNTs [11] new age, miniscule nano sensors can help lower materials cost, weight, and power consumption in CNTs have a complex structure where each of their manufacturing processes. The automotive market atoms is attached to its neighbors with a sp2 is one of the important application segments of nano sensors as shown in figure 1. bonding similar to a graphite atom. They form a sequence of layers when seen together. CNTs have many advantages over other materials due to their small size, high strength, high electrical and thermal conductivity, and high specific area. Therefore, they are extensively used as the sensing material in pressure, thermal, gas, optical, position, and biological sensors. Due to the need to improve performance, reduce cost, and improve reliability, nano sensors have a substantial utility in the automotive industry [2]. Some of the important applications are described below: Figure 1: Automotive applications of nano sensors [9] 1. Pressure Sensing: Carbon Nanotube (CNT): Carbon Nanotube (CNT) is gaining popularity as new functional structures in micro and nano systems .CNTs are hexagonal networks of carbon atoms of approximately 1 nm diameter and 1 to 100 microns of length. They can essentially be thought of as a layer of graphite rolled-up into a cylinder. Depending on the arrangement of their graphene cylinders, there are two types of nano tubes: single-walled nano tubes (SWNTs) and multi-walled nano tubes (MWNTs) [2]. SWNT has only one single layer of graphene cylinders; while MWNTs have many layers (approximately 50), as shown in Figure 3 and 4. 18 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 In vehicles, pressure sensors are used for many applications and their location varies accordingly. Pressure sensor can be used to determine when an air filter is dirty. This can be done by measuring the pressure difference between the air at the filter intake and air on the other side of the diaphragm. They can also be used to calculate mass airflow rate, engine speed and air temperature by measuring the pressure from intake fold [2]. The pressure sensor devices used in tire pressure monitoring system (TPMS) can be installed inside the tire (internal sensor) or mounted on the valve stem (external sensor). Internal sensors have to be fitted to the wheel rim as shown in figure 5. system's current state of operation. The two systems of the vehicle that are primary users of temperature sensors are: l Engine/power train management system l Heating, Ventilation and Air Conditioning (HVAC) system. The most common applications of temperature sensors are sensors for measuring coolant Figure 5: TPMS sensing module [12] The sensors measure the pressure in each tire and transmit the data wirelessly to a central receiver in the vehicle, which analyzes the information and displays it to the driver. The information varies from simple warning lights when pressure gets too low, to readouts of pressure measurements. Some temperature, intake air temperature, transmission oil temperature and, cylinder head temperature The coolant temperature sensor measures the temperature of the coolant and interfaces with the electronic control module (ECM). An ECM, also known as power-train control module (PCM) is a systems may also include pressure information type of electronic control unit that determines the about the spare tire. amount of fuel, ignition timing and other parameters that an internal combustion engine needs to keep running. The coolant temperature sensor provides feedback to the ECM regarding the temperature of the coolant at a single point on the engine. Similarly, the cylinder head temperature sensor provides the temperature of the metal at a single point on the engine. Using this temperature data and previous engine calibration information, Figure 6: Schematic of a CNT based pressure sensor. [4] CNT based pressure sensor is shown in figure 6.The sensor is made of a double layer membrane of 70nm SiO2 and 70nm of Al2O3. The SWNT is embedded between the two layers and contacted by a source and a drain metal electrode. A nearby the ECM controls the operation of the engine management system to achieve optimal engine control. Engine intake air temperature is also a key temperature used by the ECM. Similar to the coolant sensor, this sensor also interfaces with the ECM. Most temperature sensors on vehicles are located underneath near the front bumper bar [6]. gate electrode (not shown) is used to bias the SWNT in a transistor configuration. The top and bottom oxide layers are used to encapsulate the SWNTs to protect them from the environment [4]. 2. Temperature Sensing: Temperature sensors provide a key parameter to the electronic module to enable feedback of the Figure 7: Design of a CNT based temperature sensor. [7] TechTalk@KPITCummins, Volume 4, Issue 3, 2011 19 Design of CNT based temperature sensor is absorption spectra. Most gases can be detected by shown in figure 7. This design consists of using a measuring their absorption at particular CNT network patterned on a suitable substrate frequencies of IR. with metal electrodes lithographically patterned There are certain basic components common to all on either ends of the CNT network. The CNT IR gas sensors: an IR source, an IR detector, a means network would be the resistive element of the to select appropriate wavelengths and a sample cell. device that can be correlated to the temperature The simple sensing setup is shown in Figure 10. change of the sensing environment [7]. 3. Air Quality Monitoring: Vehicle cabins commonly show concentrations of toxic gases such as carbon monoxide (CO), hydrocarbons (HC), volatile organic compounds (VOC), and oxides of nitrogen (NOx) higher than safety limits. Air pollution in vehicle cabins is usually generated by the following scenarios: l Pollutant gases entering the vehicle via the ventilation system. l Lack of fresh airflow resulting in low O2 and high Figure 10: Simplified diagram of a single beam IR absorption gas sensor. [1] The setup has IR source at one end and IR detector at the other end. The band pass optical filter corresponds with the absorption wavelength of the gas being measured. As the concentration of gas being measured increases, the output signal from the sensor reduces due to more absorption of IR by the gas molecules. CO2 concentrations. l Pollutant gases entering from the external Advances in nano-robotic manipulation systems environment via window openings, imperfect have allowed the recent development of a new seals and other holes. single CNT-based nano-infrared detector. The design of an individual (SWNT) Single Wall Nano Tube-based IR detector is illustrated in Figure 11. It consists of a pair of electrodes bridged by a single nano tube. The characteristics of CNTs can change with diameter and angle of carbon atom pattern, which makes them sensitive to infrared radiation. The CNT based IR nano sensor has potential to replace conventional IR sensor due to their compact size and fast response time [8]. Figure 8: An overview of a typical HVAC system. [1] Figure 8 shows overview of a typical HVAC (Heating, Ventilation, and Air Conditioning) system. Infra red (IR) based sensors are suited for air quality monitoring applications since they are physically small, consume low power, are selective and are rapidly reducing in cost. IR based gas sensors identify gases by analyzing their unique IR 20 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Figure 11: Diagram of an individual SWNT-based IR sensor [8] Future Scope: Nano sensor applications have the potential to re- References [1] Kosmas Galatsis, Wojtek Wlodarski,”Car define the automotive industry. Vehicle dynamic Cabin Air Quality Sensors and Systems", control (VDC), rollover detection and antitheft Encyclopedia of Sensors Vol. X, pp. 1–11, systems are other important areas where CNTbased sensors can be potentially applied. It is [2] expected that many applications of CNT-based sensors will be explored in future as the interest of the nanotechnology research community in this [3] field increases. The future cars based on nanotechnology will be lighter, stronger, faster, safer, and more intelligent than the driver and eco friendly. [4] Conclusion: Automotive industry has been greatly influenced [5] by nanotechnology and the fundamentally new capabilities offered by it. CNTs play a major role in the advancement of nanotechnology in various applications. The exceptional properties of CNT allow them to be used in sensors, which help in [6] increasing the sensitivity and dynamic range of sensors. Nano sensors are used to acquire [7] information about vehicle parameters such as pressure, vehicle altitudes, temperature, heat, humidity, speed, exhaust gas, engine knock and [8] torque apart from enabling new desirable features. CNT-based sensors are replacing old technologies with cheaper and more reliable devices. [9] 2006. Niraj Sinha, Jiazhi Ma, and John T. W. Yeow,” Carbon Nanotube-Based Sensors”, Journal of Nano science and Nanotechnology Vol.6, pp. 573–590, 2006. Christofer Hierold, Thomas Helbling, Cosmin Roman1,Lukas Durrer1, Alain Jungen and Christoph Stampfer, ”CNT Based Sensors”, Advances in Science and Technology Vol. 54, pp. 343-349, 2006. T. Helbling, S. Drittenbass, L. Durrer, C. Roman, and C. Hierold, ”Ultra Small Single Walled Carbon Nanotube Pressure Sensors”, IEEE 22nd International Conference on Micro Electro Mechanical Systems, pp. 575 - 578, 2009. David Eddy and Douglas Spanks, “Application of MEMS Technology in Automotive Sensors and Actuators”, Proceedings of the 1998 International Symposium on Micro mechatronics and Human Science, pp. 9-15, 1998. Nasser Y. El-Awar, David J. Geer,Theodore J. Krellner and Peter J. Straub, ”Automotive Temperature Sensing”, 1999. Brendan Crawford,Dan Esposito,Vishal Jain and David Pelletier, ”Flexible Carbon Nanotube Based Temperature Sensor for Ultra-Small-Site Applications”, 2008. Jiangbo Zhang,Ning Xi and King Lai, ”Single carbon nano tube infrared detectors”, 2007. http://www.nanowerk.com/spotlight/spotid= 18972.php Trivia [10] http://nano.cancer.gov/objects/img_news/ l The prefix "nano" comes from a ... [11] http://www.topnews.in/usa/files/ multiwall.jpg 'Greek word meaning dwarf', Mf0601_single-walled.jpg [12] www.memagazine.org/.../features/ pumpedup/36a.jpg l How many oxygen atoms lined up in a row would fit in a one nanometer space? 'Seven'. The diameter of one oxygen atom is approximately 0.14 nanometers other words: 100,000 nanometers. Let's assume l If you were to shrink yourself down until the average height of a person to be 1.7 meters. If you were only a nanometer tall, how thick this person is shrunk to be only 1 nanometer tall, would a sheet of paper appear to you? the thickness of a sheet of paper would be 100,000 The answer is: 170 kilometers. An average times taller and therefore appear to be 170 km sheet of paper is approx. 0.1 mm thick; in thick. TechTalk@KPITCummins, Volume 4, Issue 3, 2011 21 22 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Applications of Nanotechnology: Body and Chassis, Comfort, and Emission Systems About the Author Research Trainee, CREST, KPIT Cummins Infosystems Ltd., Pune, India Areas of interest High Performance Computing Ashish Waykar TechTalk@KPITCummins, Volume 4, Issue 3, 2011 23 Introduction: The United Nations estimates that the number of vehicles will double from 750 million to 1.5 billion by 2030. With such a rapid growth in the automotive market across BRICK countries, questions concerning safety, intelligent traffic guidance systems, pollutant reduction and effective recycling are becoming more urgent. Therefore, companies and research institutes are focusing their research and development efforts more on adapting the safety, comfort and ecofriendliness of the automobile to future needs. Materials with nanoparticles or layers at nanoscale are very useful in this respect, to ensure safety of drivers against car crashes and accidents. They are used on inner and outer surfaces of the car body as well as on the engine and drive. cars is increasing. The world's largest steel maker, ArcelorMittal, is developing a new kind of steel that is as light as aluminum and costs less too. A possible way to produce such high-strength steels is using nanotechnologies. Nano steel is stable and inexpensive steel [1]. Currently, high-strength steel alloys are developed using dispersion hardening which involves uniform distribution of fine particles over the entire matrix. This process is too expensive to be used for mass production. Japanese scientists observed that use of 0.002 per cent of finely dispersed carbon could increase the stability of the steel significantly. Strength of steel can also be increased by using embedded nanoparticles of metallic carbon nitride. 1.2 Nano coating for car paint: 1. Body and Chassis Car body and chassis are important parts in car manufacturing. Safety of the road users is a prime objective for the development of nanostructured materials and substances. At the same time, highstrength, light weight and flexible nanostructured car body parts can be used to increase the performance. Apart from safety and performance, appearance of car i.e. paint and coating are also significant factors. For the supplier industry, the aspects relating to the production technology will be the most interesting in the near future. 1.1 Nano steel: Figure : 2 Nano coating. Source: Matallurgy for dummies Nano coatings consist of very small particles due to which it acquires unique properties like flexibility, quick adhesion and resistance to corrosion and microbial growth. Such coatings could keep the car body from getting scratches and reduce adhesion of dirt and dead bugs. Nano coating is cheaper, easier to apply and more environment friendly than substances currently in use. The use of such coatings could potentially change the manufacturing process radically. As shown in figure 2, nano coating is used in cars because of following reasons: Figure : 1 Nano steel Source: www.automotivetrends.info Steel is most important material in car body construction. However, in recent times the demand to develop lighter and stronger steel for 24 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 1. The better grip of polymer on the surface (substrate) does not allow another substance or element to break through the coating. 2. Since nano coating particle size is typically less than 100 nanometers, it fills micro-size pits in glossy surfaces and improves the gloss. 3. Nano-particle UV inhibitors are perfectly clear, yet they absorb UV light energy. Nano-coating for car paint consists of twocomponent mixture based on nanotechnology. Aqueous and oily liquids transporting contaminants are simply repelled surfaces. Paints manufactured based on nanotechnology are being used on Mercedes E, S, CL, SL and SLK models in metallic and non-metallic finishes. Figure : 4 Nano-Rim Source: www.nanodetailing.com 1.3 Nano Wiper - Invisible Wiper 2. Comfort Driving during heavy rain is dangerous because of Comfort is a sense of physical or psychological ease. Comfort is also particularly related to healthcare. Often, car drivers experience problems while sitting in the car, which are aggravated by spending long days behind the wheel. Here, not only comfort but also safety is an important aspect. In automobiles, comfort could mean having desirable features for the car interior, like, anti-glare, antireflection coating on dashboard and windshield, dirt-repellent seats, fragrance in cabin, and air filters. Let us look at a few applications of nanotechnology for improving comfort of the car. poor visibility due to raindrops on the windshield and water sprayed by wheels of other vehicles. This problem of limited view led to the invention of permanent hydrophobic nano-coating for glass surfaces, by German scientists. Example of a hydrophobic surface observed in nature is a lotus leaf surface that is extremely difficult to wet. NANOPROTECT.co.uk, in collaboration with German scientists, came up with a solution called Nano-Wiper, which is a ready-to-use set that modifies the glass into super-hydrophobic surface (Figure 3). Use of such windscreens causes raindrops to fall away, leaving the surface dry [2]. Figure : 3 Invisible Wiper Source: Matallurgy for dummies 1.4 Nano Rim - Rim Sealant Nano Rim Sealant is developed based on nanotechnology, which is being used for vehicle wheels and rims coating. Its microscopic nano particles create a long-lasting, invisible film on surfaces that repel water and oil, reduce the adhesion of dirt, dust and other contaminants. Nano-coating modifies surface to be smoother that makes them easy to clean [3]. 2.1 Anti-glare and anti-reflective coatings Glare and reflection is a major problem while driving, since it affects the visibility. A surface coating at nanometer scale can directly influence the behavior of light incident onto a transparent material. Anti-glare deals with external sources like bright sunlight, reflecting off a surface, while antireflection deals with both internal and external sources. Anti-glare mechanism uses diffusion to break up the reflected light off the surface. Thereby the visibility improves, which is particularly noticeable while driving at night. Nano-structuring of the surface results in a refraction index gradient moving from the outside to the inside, so that light waves are practically not reflected. This kind of coating can be used on dashboard, front and rear windshield, mirror [4] . 2.2 Car seats: Figure : 5 fiber with and without anti adhesion coating Source: http://en.percenta.com TechTalk@KPITCummins, Volume 4, Issue 3, 2011 25 When the door or window of a car is opened, raindrops or snow may fall onto the seats causing water and dirt stains. These unwanted effects can be minimized or even avoided completely by using specific materials of fabric and leather coverings. Nano textile and leather is such a material that surrounds every fiber with an anti adhesion coating. As a result, dry dirt does not stick to the material and the liquid cannot be soaked up by the Fuel additive is used as a catalyst for combustion reaction that reduces formation of soot, tar and clinker ensuring complete combustion at lower excess air. This improves fuel utilization and overall combustion efficiency. Nano fuel additives such as F2-21, EeFuel are non-toxic and non-fossil and increase mileage by 10% to 20%. They increase the vaporization of the fuel and serve as a catalytic agent to increase the amount of fuel burnt as well as to stabilize its burn rate. fibers. 3.2 Nanocrystalline Coatings for Friction Reduction 2.3 Fragrance in cabin It is observed that approximately 10-15% of the fuel consumption is due to engine friction. It is caused due to interaction between multiple moving parts. Nanotechnology can be applied for reducing this friction. Reduction in friction can be achieved by improvement in material used in mechanical part and lubricants. Nano-crystalline coatings that are applied on the cylinder wall reduce friction and abrasion and thus fuel consumption. Imagine, getting some good fragrance when we open the car door. Car-interior contains hundreds of different chemicals like paints and solvents, adhesives. This is one good application of nanotechnology making it possible to produce purer and completely natural perfume compounds. This can be achieved by using nanoparticles such as gold-palladium that can replace expensive and potentially toxic reagents that promote oxidation of aromatic primary alcohols to aldehydes. Another nano encapsulation procedure proposes the use of nanoparticles coated in natural enzymes in the process of manufacturing expensive perfume compounds. 2.4 Nanofilters for clean air in the interior of the car Filtration of particles and gaseous pollutants are essential for the improvement of the air quality inside the car. Nanofilter such as Novel filters covered with nanofibers significantly reduces the pollutant emissions in passenger and utility vehicles. Since the fibers are in the nanometer range, they cause lower air resistance. Therefore, energy is saved and the air can be transported almost without any loss of pressure. 3. Emission System Emission refers to combustion of fuel. Hydrocarbons, carbon monoxide and oxides of nitrogen are created during the combustion process and are emitted into the atmosphere. Thus, the need to control the emissions from automobiles gave rise to the nanotechnology in emission system. Nanotechnology can be used as fuel additive, catalyst, for minimization of engine friction by new nano layer systems that will result in fuel savings in future. 26 3.1 Fuel Additive TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Industrial Research DaimlerChrysler AG has started the research project called NaCoLab together with other partners from the industry and universities. This project falls within the framework of the lead innovation project Nanomobil of the BMBF (Federal Ministry of Education and Research). Main objective of NaCoLab is to develop 'Nanocrystalline composite coatings for cylinder tracks with nanostructured surface and abrasion prediction for highly stressed petrol and diesel engines' which provide direct coating to the tracks of the aluminum crankcase with nano materials. Coating materials with embedded nanocrystals of sizes from 60 nm to 130 nm on the basis of iron carbide and boride result in extremely hard surfaces with low friction properties. [6] Conclusion: Nanotechnology in cars is getting a lot of attention due to their improved efficiency and low environmental effects. Nanotechnology provides good applications for safety, pollutant reduction and comfort in car. However, they have not yet been adopted in large scale. Researchers worldwide are up to the challenge and new research promises to bring exciting future. References: [1] http://www.autoblog.com [2] http://www.nanoprotect.co.uk/nano-for-car.html [3] http://www.tspinc.com/antiglarevantireflec [4] http://www.popularmechanics.com/cars/news/4229510 [5] http://www.automotivetrends.info [6] Nanotechnologies in Automobiles Innovation Potentials in Hesse for the Automotive Industry and its subcontractor CROSSWORD 2 1 3 4 5 6 7 8 9 Across Down 1 One billionth of a meter (9) 1 3 A small group or bunch (7) 7 One of the scientific advancements helps 2 Centre of an atom (7) speed up reactions (8) 3 Internal framework that supports manmade 8 9 The world of very tiny things such as atoms and molecules (14) Atoms arranged in a long thin cylindrical objects (7) structure (9) 4 Insulator at nanoscale (7) The scale/size at which nanotechnology is 5 Home of a nanotechnology research centre at worked upon (6) a university in the UK (7) 6 Wheeled motor vehicle used for transporting passengers/ goods (10) *Solution on page No. 33 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 27 28 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Automotive Applications of Nanotechnology: Memory, Electronic Components, and Displays About the Author Jr. Scientist, CREST, KPIT Cummins Infosystems Ltd., Pune, India Areas of interest Image processing, Embedded Systems Vaishnavi Poharkar TechTalk@KPITCummins, Volume 4, Issue 3, 2011 29 In recent years, research and development activity resistance in nano scale related technologies has started on a l Metal alloys with greater mechanical strength large scale. The National Science Foundation has l Automotive sensors with nano-sensing predicted $1 trillion nanotechnology related products in the market by 2015 [1]. The automotive industry is an early taker of nanotechnologies. Automotive manufacturers use the new technologies to offer cost-effective improvements in vehicle performance to meet consumer needs . At the same time, they are also elements l Electrical switching with CNT transistors, quantum transistors, nano-electro-mechanical switches, electron-emission amplification, and more efficient solar cells Few areas like memory and logic, electronic components and display technology, in which the looking to meet the stricter legislation regarding automotive sector is expected to benefit from the emissions and safety. Most of the current use of nanomaterials are discussed below. applications represent progressive developments of existing technologies for the reduction in size of systems. Memory and Logic: Recent developments in low cost reprogrammable memory technologies add to flexibility, Nanotechnology now offers automotive industry, serviceability, customization and intelligence of with improved lubricants, lightweight fuel cells, electronic subsystems. These features will add a catalysts, nanoporous filters, self-cleaning great value to the future of automobiles. UV- windshields, self-repairing and color changing erasable EPROM's, electrically erasable EEPROM's, paints, corrosion protection and lighter and and related Flash erasable EEPROM's are stronger structural materials, for the car of the revolutionizing what is known as 'powertrain' in a future. Figure 2 shows the automotive applications vehicle. Powertrain refers to the components that of nanotechnology. generate power viz. the engine, transmission, drive shafts, differentials, and the drive wheels, etc and embedded controller applications. They are useful in safety, driver information, and comfort applications [3]. A nanotech device, three-dimensional (3D) memory, has been developed by BeSang Inc.. The use of a 3D memory in the processor reduces the size, memory power consumption and ensures faster processing. In this technology, a memory core is stacked on the top of the logic layer within a semiconductor device. In the first step, it combines Figure 2. Automotive applications of nanotechnology separate logic and silicon-on-insulator (SOI) wafers. In the second step, it enables 3D design by using a Some of the potential automotive applications of nanotechnology: flip-chip process. In the next step, it uses metal bonding to combine memory and logic devices. This single-chip, high-density 3D technology provides a l Enhanced mechanical, thermal, and appearance properties for plastics l Joining interfaces for improved crack 30 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 low-cost, high-speed vertical memory solution for the semiconductor industry. The main memory of computers is made from band (in eV, electron volts). Figure 3 shows the DRAM related devices. DRAM is a series of material classification using energy gap. The band capacitors. It stores data as the electrical charge. Each capacitor and its control circuitry, is called as a cell. It holds one bit, and bits can be read or written in large blocks at the same time. By using nanotechnology, IBM is developing a memory device known as Millipede. It is a non volatile computer memory. It gives a data density of more gap is absent in conductors, in insulators it is > 5eV and semiconductors this is around ~ 1eV.If the difference in energy between the highest valence band and the lowest conduction band is more, then more energy is needed to excite the 'quantum dot' – a semiconductor. More energy is released when the crystal returns to its rest state. than 1 terabit per square inch. It connects microelectro-mechanical systems (MEMS) technology to mark ones and zeroes into a soft polymer. It looks similar to a comb-like cantilever or the multilegged 'millipede' insect. With this millipede-like cantilever technology, it will be possible to achieve information densities that will be measured in the hundreds of gigabits per square inch. Electronic Components: Figure 3.Classification of materials using energy gap Nano-wires made from silicon, gallium nitride and indium phosphide have shown remarkable optical, The main advantage is that, with the high level of electronic and magnetic features. For example, control over the size of the crystals, it is possible to silica nano-wires have potential applications in have defined control over the conductive electronic and opto-electronic nanodevices. They properties of the material [5]. In electronic are used as metallic interconnect because they can applications quantum dot operates like a single- turn around very tight at corners. Take the electron transistor and is being researched for use example of the computer/electronics industry. in transistors, solar cells, LEDs and diode lasers. The first transistors were over 1 centimeter in size; the smallest transistors today are less than 30 Quantum dot increases the efficiency and reduce nanometers long, i.e. over three hundred the cost of today's typical silicon photovoltaic cells. thousand times smaller. So today's advanced Today's photovoltaic cells can only manage one semiconductor manufacturing is already well into exciton (An exciton is a bound state of an electron- the nano-area; reaching a gradual miniaturization hole pair within characteristic length) per high- of electronic components. Nano-layers of energy photon, with high kinetic energy carriers semiconducting materials provide high efficiency losing their energy as heat. The quantum dots of electronic components and systems with a longer lead selenide can produce as many as seven lifetime. excitons from one high energy photon of sunlight. The electronic characteristics of a material are advantages such as lower costs, clean power In the future nanocrystal photovoltaics may offer closely related to the size and shape of the generation [5] and could boost the efficiency of individual crystal. As the size of the crystal photovoltaic cells to 65%. decreases, the band gap becomes larger. The band gap generally refers to the energy difference Displays: between the valence band and the conduction As there is a huge market for displays with large TechTalk@KPITCummins, Volume 4, Issue 3, 2011 31 in television However, it may pose adverse environmental, screens and computer monitors, the development area, high brightness, flat-panel health and safety effects [8]. The carbon nanotubes of some nanomaterials is on the rise. For making are used in commercial electronics, but disposal can light-emitting phosphors, Nanocrystalline zinc lead to emission. The production using selenide, zinc sulphide, cadmium sulphide and lead nanotechnology often produces by products that telluride are synthesized by sol–gel techniques. cannot be used. If the production is not suitably, This is a process for making ceramic and glass planned, large quantities of nanoparticles could be materials in which there is a transition from a liquid emitted in wastewater and exhaust gasses, which 'sol' phase to a solid 'gel' phase. Nanotechnology is would cause pollution. The single-walled (SWCNT) used to improve the visual quality of today's LCDs and multi-walled (MWCNT) carbon nano-tubes are by offering extremely thin screens [6]. non-biodegradable [9]. Merging green chemistry Carbon nanotube technology (CNT) is being these challenges in the development of novel nano- and nano-science will give opportunities to meet explored for low voltage field-emission displays. . devices. Green nanotechnology is the development Such displays are lightweight, consume low power of clean technologies. and have excellent viewing characteristics. Carbon nanotubes are lengthened tubes of rolled Conclusion graphene sheets. They are very stiff, elastic about their axis, and good conductor of electricity. All What we are dealing with today is most emerging these properties make CNTs potentially very field nanotechnology. The goal of this evolutionary efficient and long-lasting emitters in applications nanotechnology is to improve existing processes, like nano-electronics. materials and applications by scaling down to the A quantum dot display is a type of light emitting surface phenomena that exhibit at the nanoscale. nano size. It exploits the unique quantum and technology. QDs emit light in very specific This trend is adopted by the companies to improve Gaussian distributions. It shows a bright emission existing products by creating smaller components in the visible and near infrared region of the and better performance materials, all at a lower spectrum. Therefore, they can be incorporated cost. In the future, this new manufacturing into a new generation of applications such as flat- technology will develop lightweight, strong, smart, panel TV screens, digital cameras, mobile phones, and durable products. Like, nanomaterials in personal gaming equipment and PDAs [4]. QDs automotive technologies will help to reduce the are both photoactive (photo luminescent) and weight of vehicle, improve performance of engine, electro-active (electroluminescent). They can be improve exhaust emission control, improve fuel readily incorporated into new emissive display saving, reduce the vehicle vibration and enhance architectures. driver safety, increase vehicle control, increase Displays with improved performance and unique exploring the technology, make sure the technology vehicle security, and enhance driver comfort. While features are made possible by nanotechnology. would be pollution free technology with planned Additionally, lower cost light emission sources, byproducts. such as lasers are possible in the near future. As summarized above, Nanotechnology has promising potential for use in commercial, automotive, defense and security applications [7]. 32 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 References 1. Journal of Nanoparticle Research, Kluwer Academic Publ., Vol. 3, No. 5-6, pp. 353-360, 2001 (based on the presentation at the symposium Global Nanotechnology networking, International Union of Materials Meeting, August 28, 2001) 2. Juliano Fujioka Mologni - Delphi Corp., Unicamp, Frank Kenji Goto - Delphi Corp., Didimo Garcia Neto - Delphi Corp.. : Potential Nanotechnology Applications on Automotive Electrical / Electronic Architecture. Date Published: 2008-10-07. Paper Number: 2008-36-0045. DOI: 10.4271/2008-36-0045 3. Pradeep Shah - Texas Instruments, Gregory Armstrong - Texas Instruments. : Programmable Memory Trends in the Automotive Industry. Date Published: 1990-10-01. Paper Number: 901133. DOI: 10.4271/901133 4. Belle Dumé. : Quantum-dot displays could outshine their rivals. New Scientist, 10 December 2007 5. Ilan Gur, Neil A. Fromer, Michael L. Geier, and A. Paul Alivisatos, (2005).: "Air-Stable AllInorganic Nanocrystal Solar Cells Processed from Solution". Science 310 (5745): 462–465. doi:10.1126/science.1117908. PMID 16239470. 6. Wolfgang Gruener.: Nanotechnology to improve quality, performance of thin displays. April 29, 2005 7. Edward Wallner Delphi Corp., Bruce Myers Delphi Energy and Chassis, D.H.R Sarma, Suresh Shah, Suresh Chengalva, Gary Eesley and Coleen Dykstra Delphi Corp., Richard Parker and David Ihms Delphi Corp.: Nanotechnology Applications in Future Automobiles. SAE International 2010-01-1149 Published 04/12/2010 8. Giulia M. Stella.: Carbon nanotubes and pleural damage: Perspectives of nanosafety in the light of asbestos experience .Biointerphases 6, P1 (2011); doi:10.1116/1.3582324 9. Julie Muller, Franc¸ois Huaux, Nicolas Moreau, Pierre Misson, Jean-Franc¸ois Heilier,Monique Delos, Mohammed Arras, Antonio Fonseca, Janos B. Nagy, Dominique Lison.: Respiratory toxicity of multi-wall carbon nanotubes. Toxicology and Applied Pharmacology 207 (2005) 221– 231. 5 March 2005 10. D. C. Walther - University of California, L. Lin - University of California, A. P. Pisano University of California .: Micro- and Nano-Technologies for Automotive Sensor Research. Paper Number: 2007-01-1012. DOI: 10.4271/2007-01-1012 Crossword Solution N A N O M E T E R N A U N C O L C T E S C W A H A U L U H C A S T A L S I S C S O I O L E M S N O A A N O T T O G B Y I U M B I E E R U I O N T Y S T C L E TechTalk@KPITCummins, Volume 4, Issue 3, 2011 33 34 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Future of Nanotechnology About the Authors Research Trainee, CREST, KPIT Cummins Infosystems Ltd., Pune, India. Areas of Interest Embedded Systems, Image Processing and Telecommunication Nikhil Jotwani Sr. Research Associate, CREST, KPIT Cummins Infosystems Ltd., Pune, India. Areas of Interest Parallel computing, OS, Algorithms and Network Security. Prasad Pawar TechTalk@KPITCummins, Volume 4, Issue 3, 2011 35 Introduction: Imagine going to a car showroom, where the salesperson shows you different small packets instead of car models. All you see are seeds in the packet. Simply spread the seeds in your garden and you would see your car grow from scratch! Unbelievable! Isn't it? Nanotechnology may provide a solution to this wish. The effects of nanotechnology on many other areas such as textiles, paper production, food manufacturing and agriculture are quite commendable. In a recent research, scientists at the Northern Illinois University have found a method of producing high yields of graphene. It is believed that these nanostructures could replace silicon. This invention of graphene would make the consumer electronic devices even smaller and faster. Another research at the University of Strathclyde states that carbon nanotubes would play an important role in desalination of water to meet the everincreasing demand for fresh water. Many such applications are possible with nanotechnology. Future of nanotechnology in medicine: Applications of nanotechnology to medicine are designed to interact with the body at sub-cellular scales. This can potentially be used to translate cellular and tissue specific applications, which results into maximal cure with minimal side effects. This technology is called as nanomedicine. The nanomedicine is the science and technology of diagnosing, treating and preventing diseases [1]. For example, we are using nanomedicine to detect cancerous or tumour cells using molecular imaging therapy. When we inject the nanoparticles in the body, they have a tendency to accumulate near the tumour cells because these cells lack the lymphatic drainage system. Therefore, by viewing the area where nanoparticles have been accumulated, we can know the exact size of the tumour and medicate only those portions. In the future, nanotechnology will form the molecular systems that may be used for regeneration or replacement of body parts that are lost due to infection, accident or diseases [2]. Nanotubes technology could be used to administer drugs more precisely. The nanotubes carry the required drug and being small in size they can enter at the required place. Therefore, we can 36 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Figure 1: molecular imaging therapy [11] deliver the drug at the precise location. Advanced research shows improved functionality of the carbon content in the nanotubes, which makes it water soluble and highly suitable for the biological environment around it. Other areas of on-going research include development of artificial red blood cells to improve blood flow, artificial mitochondria to maintain metabolism in tissues suffering from ischemic injury etc. Nanomedicine can be used as a preventive measure to help a large portion of the population to deal more effectively with cardiovascular disease and hypertension. This technology could be explored and used as new diagnostic tests having monitoring capabilities and therapies to manage many chronic diseases for example Lupus or Arthritis [3]. Future of Nanotechnology in water treatment: Nanotechnology could potentially revolutionize technologies for obtaining clean water and this could become a critical application in future [3]. The researchers see fresh opportunities to create nano-enhanced technologies that will help to generate more clean water. With a Nano Tool shed and a Nano Library, scientists could launch innovative efforts to improve water purification, prevent water pollution and clean up tainted groundwater, lakes and streams. The challenge in this field is to convert the pollutants that are refined out during the process into some useful material like compost. We could use nanotechnology to determine the purity level of water. Researchers can already recommend some nanomaterials that could be used to enhance existing water purification processes. Since nanosize particles have a high surface area and they can be chemically tailored, they show great potential as absorbents that latch on to pollutants and pull them out of water. Nano engineered membranes and filtration devices could be used to detect and remove viruses and other pollutants that are difficult to trap using existing technologies. A preliminary technique of polymer-nanospheres is used to detect pharmaceutical kind of pollution, which was difficult to spot in waterways. Such nanoscale sensors might be helpful for real-time monitoring of these pollutants. Eventually smart membranes with specifically tailored nanopores might be designed to detect and remove such pollutants. With greater ability to filter out unwanted materials and industrial wastewater, even the ocean could become available to boost the supply of clean water. Future of nanotechnology in computers: Future computers are on the forefront of becoming common. In the near future, computers will use nanotechnology to shrink the size of silicon chips, increase speed and power. The future computers will be based upon qubits (quantum bits) rather than the digital bit 1's and 0's. In simple terms, the qubit can have both the states as that of a digital bit and a superposition state analogous to that of an atom. The power of magnetic forces at a subatomic scale will be able to unleash the exponential power of future computers. The information is stored in the nucleus of the atoms. The spin of a quantum bit in one atom is reflected in a spin of another bit far away. Therefore, by manipulating the rotation of atoms, data can be transmitted and stored at an unprecedented rate. Future computers will not be measured in gigabits or terabytes but they will be measured in Qubits and Kets. Currently, there is not enough computational power to pull off true artificial intelligence. There is also not enough computational power to decrypt complicated encryption methodologies. However, with the exponential power of future quantum computers aided by nanotechnology we may actually be able to implement artificial intelligence. Future computers will no longer have RAM or DRAM but rather MRAM (Magneto resistive Random Access Memory) which is being implemented on trail basis [5]. Figure 2 - QCA cell polarisation and representations of binary 1 and 0 [5]. Nanotechnologies are already influencing the computing industry and the influence will be more once they are further developed. The development of VLSI CMOS systems will reach its limit and a new type of nano-computer will be needed to replace it. These systems will use very different computer architectures from today. An architecture that shows particular promise is Quantum Dot Arrays (qdots) [6], which could be a viable alternative to CMOS. Where the speed of CMOS systems will be limited to around 15GHz these new architectures could provide operating frequencies in excess of 100GHz.Figure 2 shows a high level Quantum Dot Array of four dots that can be used to represent the binary value's 0 and 1. The array contains four quantum dots and two electrons. The electrons can be moved between the quantum dots using a process called as electron tunnelling. At the different positions shown in Figure 2, they represent the binary values 1 and 0 encoded in the charge configuration within the quantum dot cells. These qdots cells can then be combined together to make simple logic devices. Future of nanotechnology in textile: The recent research of nanotechnology in the field of textile includes producing fabrics with special properties embedded in them. These would include bullet proof, germ proof, military garments that can change colour etc. Most of the applications of nanotechnology are derived from the remarkable properties of carbon nanotubes viz. the ability to conduct both heat and electricity along and toughness of the fibre. With the introduction of nanotechnology in textiles, spinning fibres with diameters in nanometre range has become possible. Electro spinning is the process used for producing fine filaments from polymer solutions. TechTalk@KPITCummins, Volume 4, Issue 3, 2011 37 Figure 1: schematic view of electro spinning [9] the entire fabric. Nanotech is making a mark in producing versatile fibre composites, which will help in giving better finishing to the fibre. This technology for giving fine finish to the fabric can cause a revolution in producing stain resistant, anti wrinkle, anti static fabrics. The next stage in nano-textile technology would include improving over the already existing techniques. In addition, it aims at adding new functions and properties to the fabric like wearable solar cells, energy storage, embedding sensors, information acquisition and transfer, etc. Future of nanotechnology in Energy: Figure 2: Nano fibres [9] Self-cleaning fabrics are a revolution in the field of textile. It uses the fundamentals of nanotechnology. This technology was introduced by the US Air force. They experimented by making t-shirts which could be worn hygienically without washing for weeks. First nanoparticles are attached to the fibre using microwaves, then chemicals to reject water, oil and bacteria are bound to these nanoparticles. The combination of these two elements forms a protective layer on the fabric. These fabrics were mainly developed to protect the soldiers from biological weapons. Chinese and U.S. researchers have developed a carbon nanotube-coated smart yarn that conducts electricity and it can be woven into textiles. This yarn can be used to detect blood or to monitor health. Also on the same lines, fabrics can be developed which can transfer information from one fabric to another. This is used in museums to cover the wall etc. By sending the information to other fabrics, the pattern and texture of the fabric can be changed. Fabric dyeing can be done with the help of nanotechnology and the material used is called Nanoclay. Usually some chemicals are mixed up with it so that it uniformly spreads over 38 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 The nanoscale energy applications potentially apply to different sources of energy including hydrogen, geothermal, unconventional natural gas, fission, and solar energy. Applying nanotechnology to geothermal energy increases the opportunities to develop geothermal resources by enhancing thermal conductivity or aiding in the development of noncorrosive materials that could be used for geothermal energy production [7]. The recovery of unconventional sources of natural gas is yet another potential application of nanotechnology. Unconventional sources of natural gas include tight sandstones, shale gas and coal bed methane. Nanotechnology applications may prove useful in accessing or exploiting these unconventional natural gas sources. For instance, nanocatalysts and nanoscale membranes may prove useful in assisting in Gas to Liquids production. Furthermore, certain nanostructured materials may assist in compressed natural gas transport. Nanotechnology may also prove useful in solving the waste problems of the nuclear energy industries. For instance, certain nano-engineered barriers may prove useful in preventing the migration of nuclear waste products. Nanotechnology applications may assist in making solar energy more economical. This is because using nanotechnology we can form tiny solar cells and can form thin flexible sheets as compared to the present bulky sheets available. These sheets could actually be laid on rooftops collecting large amount of energy. Nanoscience can be utilized to improve the efficiency of photovoltaic cells, creating costefficient conversion systems, effective solar power storage systems or even the generation of solar energy on a larger scale. Nanotechnology might someday allow for more powerful, more efficient and less expensive energy generation, storage, transmission and distribution. Nanotechnology is being used to optimize production from existing energy sources and to exploit new sources such as geothermal, liquefied natural gas, nuclear and solar energy. The coming years of nanotechnology: Concluding from all the above discussions, we can infer that nanotechnology will change the face of medicines, healthcare and human life more profoundly than many developments of the past. They have potential to bring about significant benefits such as improved health, better use of natural resources and reduced environmental pollution. Advanced nanosystems could be used to build large, complex products cleanly, efficiently and at low cost. Building with atomic precision large manufacturing systems could produce the products as follows [10]: l Desktop computers with a billion processors l Medical devices able to destroy viruses and cancer cells without damaging healthy cells l Materials 100 times stronger than steel References [1] “Nanomedicine”, Forward look report on Nanomedicine by European Science Foundation. [2] Dr. Daniel J. Fiorino,” Voluntary Initiatives, Regulation and Nanotechnology Oversight”, Woodrow Wilson International centre for scholars, a project on emerging nanotechnology. [3] Karen F. Schmidt,”Nanofrontiers visions for the future of nanotechnology”, Woodrow Wilson International centre for scholars, a project on emerging nanotechnology, 6th march 2007. [4] K. Eric Drexler,”Revolutionizing the Future of Technology “. [5] “Future computers”, Future technology 500, an online article. http://www.futuretechnology500.com [6] Gavin Stewart, “The Future of Nanotechnologies in Computing”. [7] “Future energy sources”, an online article. [8] “Future of nanotechnology in textiles”, an online article. www.5magzine.worldpress.com [9] D.Gopalakrishnan,”A big future for small science: nanotechnology in textile”, Sardar Vallabhbhai Patel Institute of Textile Management, Coimbatore – 641004. [10] Mallanagouda Patil, Dhoom Singh Mehta and Sowjanya Guvva, “Future impact of nanotechnology on Medicine and dentistry “. l Solar energy system that is Inexpensive and efficient Q What is the Uncertainty Principle? A The Uncertainty Principle states that people who know just a little physics are Uncertain about nanotechnology. TechTalk@KPITCummins, Volume 4, Issue 3, 2011 39 40 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 Nanomanufacturing: from Research to Commercial About the Author Senior Research Associate CREST, KPIT Cummins Infosystems Ltd, Pune, India Areas of Interest Computer Vision, Signal Processing Smita Nair TechTalk@KPITCummins, Volume 4, Issue 3, 2011 41 1. Introduction Nanotechnology is a field of science that manipulates matter at molecular and atomic levels in order to create materials and systems having significantly improved properties [1]. At dimensions of about one-billionth of a meter, physical phenomena become pronounced due to effects such as quantum phenomenon and/or increase in relative surface area. The materials of same chemical elements at nanoscale change their mechanical, optical, electrical properties giving rise to unpredictable effects. With significant breakthrough in the field of nanotechnology, its applications would penetrate in almost all areas of technology bringing about major changes in our lives. Nanotechnology research has multiplied since 21st Century, with the Nanotechnology Research and Development Act (NRDA) (2003) establishing the seven Program Component Areas (PCA) for research and development [1] . The program areas are as shown in Figure 1. Figure 2 : Approaches to nanoscale structures [11] Figure 2 is an example showing the basic 'top-down' and 'bottom-up' approaches to nanoscale structures. The top-down or down sizing approach has significant role in nanoelectonics , whereas the bottom-up approach plays a significant role in chemical, advanced materials and pharamaceutical industries. The basic nanomanufacturing process and few of its application areas are shown in Figure 3. Figure 1 : Program Component Areas (PCA) The nanomanufacturing program at the U.S National Science Foundation started the National Nanomanufacturing Network(NNN) that plans nanotechnology research from laboratory to production manufacturing phase through various exchange programs and defined roadmaps. U.S National Science Foundation estimates $ 1 trillion worth of products would incorporate nanotechnology materials as the key components by 2015 [3]. II. Nanotechnology Manufacturing Figure 3 : Nanomanufacturing process and few of its application domains In order to achieve systematic research and manufacture at nanoscale, nanotechnology capability is divided into four overlapping generations of products by the National Nanotechnology Initiative (NNI) which can be summarized as follows [3][5]- Nanomanufacturing includes the manufacturing 42 activities to develop a product or system that a) First Generation products (~yr-2000) consisting exploits all the properties of nano materials. It of passive nanostructures such as nanoparticles, basically defines two approaches, 'top-down' nanowires, nanostructured materials etc. approach where in an existing system is analysed b) Second Generation products (~yr-2005) of upto nanoscale level and 'bottom-up' approach active nanostructures such as transistors, which includes developing system parts from amplifiers, targeted drugs and chemicals, sensors, nanoscale materials. actuators and adaptive nanostructures. TechTalk@KPITCummins, Volume 4, Issue 3, 2011 c) Third Generation products (~yr-2010) scale products. The integration should be fast, cost consisting of three-dimensional nanosystems and effective, power efficient and should be able to link systems of nanosystems. Ex: assembly techniques, to products of different size, type and material. networking at nanoscale, nano-robotics. Other challenge would be to handle multilayer and d) Fourth Generation products (~yr-2015) multiprocess manufacturing for batch-type consisting of molecular nanosystems wherein each processing. Currently nanocluster tools as shown in molecule will have a specific functionality and Figure 4 are used to handle multiprocesses on the unique characteristic. These molecules will be substrate without moving it from one machine to used as devices or be a part of the engineering another. But these tools are not used for mass systems. production which would need new manufacturing tools and capabilities. III. Nanomanufacturing areas : Opportunities and Challenges The following section briefs on the areas of opportunity for nanomanufacturing and their associated challenges. Nanoelements such as nanoparticles, nanowires, nanofibers, nanotubes, quantum dots, bulkyball fullerness have been available for laboratory research purpose but there exist a challenge in manufacturing these materials for commercial purpose with sufficient control over physical properties such as size, length, diameter, conductivity etc. such that the characteristics of the manufactured product is well defined. Designing tools required for multidimensional nanostructures is challenging. For example, Figure 4 : Nanocluster tools [5] I V. C o m m e r c i a l l y Av a i l a b l e Nanoscale Products The following section briefs on few nanotechnology products that are available commercially and the tools and process used for their manufacturing. 1) Nanotechnology in cosmetic industry : Liposome-Nanocapsule based lotions. existing manufacturing tools such as Molecular beam epitaxy (MBE) and metal organic chemical vapor deposition (MOCVD) is used in layered semiconductor nanomaterials for commerial applications such as electro-opto and giant magnetoresistance (GMR) devices etc. But no such tools exist for manufacturing three dimensional nanomaterials that would allow high-yield production. Research in nanotechnology shows that the major challenge would be in achieving complete integration of nano-scale with macro and micro Figure 5 : Liposome Nanocapsule TechTalk@KPITCummins, Volume 4, Issue 3, 2011 43 1) Nanotechnology in Health Systems : Silver Nanoparticles for washing machines Silver nano technology introduced by Samsung in 2003, is an antibacterial technology that uses silver nanoparticles in the washing machines, refrigerators, air purifiers etc. Silver is commonly used in antiseptic and disinfectent in medical applications. The silver ions (Ag+) nanoparticles used in 'Samsung WM1245A' Washing Machine penetrate deeply into fabrics of any kind and creates a coat of sterilizing protection with disinfection and added antibacterial effect that last for upto 30 days after washing [9].The sterlization washing machine kills 99% of the bacteria (without boiling) thus saving energy and detergent requirement [5]. Figure 6 : Silver nanoparticle- Washing Machines 3) Nanotechnology in Electronics Industry :Carbon Nanotube Random Access Memory The company Nantero has used carbon nanotubes to develop the nanoscale random access memory (NRAM) [10]. These memory chips have higher memory storage capacity, faster speeds, lower cost and is non-volatile. These memory chips have higher resistance to enviromental factors such as heat cold, radiations etc. The carbon nanotubes used in the NRAM chips have a combination of properties such as higher electrical and thermal conductivity, high tenstile strength and is of small size, that makes it potentially useful in electronic applications. But the manufacturing process of these nanotubes poses a challenge since their properties cannot be easily controlled, and are difficult to align or position them. Figure 8 : Carbon nanotubes V. Conclusion Nanomanufacturing is a field that exploits the commercial usage of the researched nanostructures and brings them into the production phase. In order to achieve significant progress in manufacturing at nanoscale, different branches of science and engineering need to be researched and combined. The commercial areas of importance includes automotive, aerospace, electronics, semiconductors, health and safety, power and energy etc. For commercial success of nanotechnology based products, fields such as nanometrology and instrumentation finds significant importance. References [1] M.E. Davey, 'Manipulating Molecules: Federal Support for Nanotechnology Research', CRS Report for Congress, August 2007 [2] K.W. Lyons, 'Integration, Interoperability, and Information Management: What are the key issues for Nanomanufacturing? ', Proceedings of SPIE Vol. 6648: 66480D. SPIE Optics and Photonics, August 29, 2007. [3] O. Renn, M.C.Roco, 'Nanotechnology and the need for risk governance', J.Nanoparticle Research, Vol. 8(2), 2006, Perspectives, Springer Science, Preprint [4] 'Instrumentation and Metrology for Nanotechnology', Report of the National Nanotechnology Initiative Workshop, January 27-29, 2004, NIST - Gaithersburg, MD [5] 'Manufacturing at nanoscale', Report of the National Nanotechnology Initiative Workshop, 2002-2004, NIST - Gaithersburg, MD [6] L.Mu, R.L.Sprando, 'Application of nanotechnology in Cosmetics', Pharm Res (2010) 27:1746–1749, DOI 10.1007/s11095-010-0139-1 [7] C. Phoenix and M.Treder, 'Safe Utilization of Advanced Nanotechnology' [8] http://courses.engr.uky.edu/CME/cme470/final%20materials/mu%2010.pdf [9] http://wikipedia.atpedia.com/en/articles/s/i/l/Silver_Nano_47ac.html#cite_note-3 [10] http://nanopedia.case.edu/NWPage.php?page=stu.lowry.3 Figure 7 : NRAM using Carbon nanotube 44 TechTalk@KPITCummins, Volume 4, Issue 3, 2011 About KPIT Cummins Infosystems Limited KPIT Cummins partners with global automotive and semiconductor corporations in bringing products faster to their target markets. We help customers globalize their process and systems efficiently through a unique blend of domain-intensive technology and process expertise. As leaders in our space, we are singularly focused on co-creating technology products and solutions to help our customers become efficient, integrated, and innovative manufacturing enterprises. We have filed for 34 patents in the areas of automotive technology, high-performance computing, and semiconductors. About CREST The Center for Research in Engineering Sciences and Technology (CREST) is focused on innovation, technology, research and development in emerging technologies. Our vision is to build KPIT Cummins as the global leader in selected technologies of interest, to enable free exchange of ideas, and to create an atmosphere of innovation throughout the company. Recently, we have received funding to the tune of INR 50 million from World Bank as a recognition and supplementary assistance for research activities. This journal is an endeavor to bring you the latest in scientific research and technology. Invitation to Write Articles We at KPIT Cummins foresee that the journal will grow as envisioned, with due endorsement from you. Our forthcoming issue to be released in January 2012 will be based on “Innovations from the Edge.” We invite you to share your knowledge by contributing to this journal. Format of the Articles Your original articles should be based on the central theme of “Innovations from the Edge.” The length of the articles should be between 1200 to 1500 words. Appropriate references should be included at the end of the articles. All the pictures should be from public domain and of high resolution. Please include a brief write-up and a photograph of yourself along with the article. The last date for submission of articles for the next issue is Sept. 15, 2011. To send in your contributions, please write to crest@kpitcummins.com . To know more about us, log on to www.kpitcummins.com . SM KPIT Cummins Infosystems Limited initiative Innovation for customers You can make a difference