Slide 1/25 Weathering the Storm Space Weathering in the Solar System and the Laboratory Graz in Space, 4-5th September 2008 Mark S. Bentley (mark.bentley@oeaw.ac.at) Slide 2/25 Contents 1. Importance of regolith 2. Mysteries of the lunar soil 3. Space weathering in the Solar System 4. Space weathering in the laboratory 5. In-situ analysis and instrumentation 6. Summary Slide 3/25 What is weathering? Weathering is “the process of chemical or physical breakdown of the minerals in rocks” 1. Physical weathering 1. 2. 3. 4. 5. 6. Thermal expansion Frost disintegration Pressure release Hydraulic action Salt-crystal growth Biological Weathering x x x x x x 2. Chemical weathering 1. 2. 3. 4. 5. 6. Dissolution Hydration Hydrolysis Oxidation Biological Carbonation x x x x x x x Slide 4/25 What is regolith? “a layer of loose, heterogeneous material covering solid rock. It includes dust, soil, broken rock, and other related materials” Slide 5/25 Importance of regolith Slide 6/25 Importance of regolith Airless bodies mainly considered here Most remote sensing instruments actually measure regolith Regolith records surface environment over geologic times Often hard to find anything BUT regolith! (Relatively) easy to penetrate and sample Instrument type Typical sampling depth Data returned X-ray spectrometer ~ 1 – 100 μm Elemental composition VISVNIR spectrometer ~ few mm Mineralogical composition Gamma-ray spectrometer ~ 10 cm Elemental composition Neutron spectrometer ~ 100 cm Changes in elemental composition Slide 7/25 The lunar regolith Regolith: broken up rock material Soil: <1 cm portion of the Regolith Dust: < 50 µm portion of the Soil Slide 8/25 The lunar regolith Impact-Glass Bead Agglutinate Volcanic Glass Bead Rock Chips Impact Glass 1 mm Plagioclase Slide 9/25 The lunar regolith © Discovery Channel 2008 Slide 10/25 Mysteries of the lunar soil Difference in reflectance spectra between rock and soil - Lower albedo (darker) - Spectral reddening (redder) - Reduced spectral contrast (more boring ☺) Data from RELAB, mare basalts collected at Apollo 15 Station 4 on the rim of Dune Crater Crushing lunar rocks does not result in the same spectrum as the soil Slide 11/25 Mysteries of the lunar soil Unusual magnetic properties of the soil: - Magnetic susceptibility higher in regolith - ESR “characteristic” resonance - Curie point shows carrier is pure metallic Fe Magnetic fraction shows greatest spectral difference Runcorn et al, 1970 Hapke, 2001 Slide 12/25 Mysteries of the lunar soil The story so far… • Regoliths are found all over the Solar System • They are important to understand • On airless bodies form differently from on Earth • The lunar regolith is different from crushed rock • Unexpected optical and magnetic properties • These properties are due to fine metallic iron Slide 13/25 How does this iron form? So we know these is “extra” iron in the regolith, not in the original soil. Where does it come from? Possible explanations: 1. Reduction of solar wind hydrogen in impact heating 2. Solar wind sputtering 3. Re-condensation of impact vapour Post Apollo view: reduction during impacts forms Fe in agglutinates Slide 14/25 Nanophase iron Sub-microscopic iron (SMFe) found everywhere in the regolith! 10s-100s nm in diameter In amorphous grain coatings Even on grains that contain no native Fe2+ (Pieters et al., 2000) Paradigm shift Re-condensation of impact and sputter products creates SMFe. Slide 15/25 Baking lunar bricks Regolith containing SMFe can be heated and melted by a domestic microwave! Taylor and Meek, “Microwave Processing of Lunar Soil” Slide 16/25 Weathering in the Solar System Asteroids / Comets Moon Mercury Galilean Satellites Slide 17/25 Weathering in the laboratory To better understand this process, laboratory experiments are needed, requiring: 1. A method of simulating meteorite impacts and/or the solar wind 2. Appropriate conditions (pressure, temperature) 3. Appropriate samples 4. Analyses to confirm the optical and magnetic changes Light Gas Gun Van der Graaf Slide 18/25 Pulsed laser simulation IR Mirror Nd:YAG 1064 nm, 10 ns, 5 Hz Laser interface Optical window XY motor controller Pt100 ADC Heater PSU Heater (RT – 500 °C) Sample <63 μm Baseplate PC Slide 19/25 The samples decreasing size Slide 20/25 Optical analyses Fo90 Slide 21/25 In search of metallic iron Mössbauer Magnetic Susceptibility SPM Attempted at RT and 12 K No obvious Fe0 signature wt% below detection limit SD 0.465 kHz & 4.65 kHz Slide 22/25 In search of metallic iron Ferromagnetic Resonance g ~ 2.1 ΔH ~ 65 mT 4 – 33 nm Vibrating Magnetometry Slide 23/25 In-situ instrumentation Impact & sputtering processes ⇓ Fine-grained iron in regolith grains ⇓ Superparamagnetism ⇓ High and freq. dependent magnetic susceptibility ⇓ Regolith gardening ⇓ 180 g 8 kHz oscillator 100 x 65 x 25 mm Magnetic susceptibility depth profile Slide 24/25 Deployment options NOT TO SCALE ☺ Tether ~5m max depth Self-penetrating mole with integrated instrument package Slide 25/25 Space Weathering Summary • Regolith is important – it is the surface we remotely sample • As the lunar regolith evolves, its VNIR signature changes • Optical and magnetic effects caused by sub-microscopic Fe0 • Iron is produced in micrometeorite and sputtering events • The longer a soil is exposed, the more mature/SMFe rich • Magnetic susceptibility detects SPM material and iron content • Would be a useful in situ instrument to determine SW degree Request for input… Opps for collab Any questions…? mark.bentley@oeaw.ac.at