WFD Compliant Transnational Monitoring Network in the Danube River Basin Igor Liska ICPDR Secretariat Major drivers DRPC (According to the Article 9 of the DRPC the Contracting Parties to DRPC have agreed to cooperate in the field of monitoring and assessment of the water resources) EU WFD (establishing of WFD compliant monitoring networks by 22 December 2006) Trans National Monitoring Network – TNMN until 2007 – only surface waters o o 10 o 15 17 30' 20 UA Sa Zo g H01 H03 Bere Cri r sul Cris ul N egro Ismail H08 o a SCG15 S av SCG16 SCG17 BG08 Be a in a M Dr av or am a Za p. Ta ra Mo Piva r av Sofia a BG FYROM 100 150 Monitoring location on the Danube River on the tributary 250 250 km t ra m ta li L om Lo os ût z. Og Ja n s. BG03 Sk Ju Sarajevo RO03 BG04 BG02 Danube m Lo BLACK SEA Ru ra v BG01 RO04 BG05 RO02 Mo FRY BIH Bucuresti RO09 SCG08 Os a SCG07 es O lt ri n SCG14 Beograd SCG06 RO01 SCG05 a Vrbas na Uk Ialomita A rg J iu BIH04 SCG13 B osn Sa BIH03 Tamis SCG04 HR08 BIH02 a ga ar va HR02 BIH01 Un Be SCG11 SCG02 SCG03 SCG09 SCG12 a SCG01 HR05 HR07 SCG10 RO0 5 si c H05 H07 HR01 HR 45 RO ca Aran Ro Dr a va Is k HR06 MD04 Alb Vit s po H06 Kupa o Körös H04 Danube Ka a HR04 Zagreb trit ja es str Ra HR03 Sa SL ur S om Mures va Ljubljana I M Bis e Kishinev ov a et SL01 Sa v Dravina in ja M old thlyd ed l Rep C risu Tisza Sa a Zala a Som es H Budapest Sio Drava a Sir In n Pe s nic yv 47 30' MD a Cr as na - H02 z Tis 3 SK03 E nns z Tis Elo ch v itz an ne l A jo H09 Ipel SK04 a Le th MD01 Jijia M D0 Rim Bratislava Wien A04 Pru t Siret Sla n a a av g SK SK01 Danube ad o Hro n Bo dr o CZ02 A03 A02 A01 ba a ch Iller t ra Kü ht ea reib m er Lech s Ni ut Pr Salz D03 o H orn a av a o ch D04 or yje M D rn Ta B rig München In n ra tk a CZ01 D02 Isar Ris lav a je Va h Naab Dy n a J ih ge Sv a e cv av Ond Re D01 50 30 a l 47 30' 0 o 27 30' av üh B a va CZ e nub Da Breg o 25 PL Sv it Al tm o 22 30' Praha o D 45 o o r Mo 50 o 12 30' o 42 30' Revision of TNMN in 2007 The major objective overview of the overall status and long-term changes of surface water and – where necessary – groundwater on a basin-wide scale particular attention paid to the transboundary effects like pollution load link Danube nutrient loads and eutrophication Black Sea monitoring of nutrient sources and pathways of nutrients in the DRB and the effects of measures to reduce the nutrient loads into the Black Sea. address all biological quality elements SURFACE WATERS TNMN Surveillance Monitoring I Surveillance Monitoring II Operational monitoring Investigative monitoring Key activity at the basin-wide level = JDS Organized once in each RBM Plan period Trans National Monitoring Network – TNMN new setup surface waters Surveillance monitoring I Monitoring of surface water status Provides assessment of the overall surface water status in the DRB Sampling and assessment: Once in the RBM plan period Quality elements: all biological quality elements, hydromorphological parameters, all general physico-chemical quality parameters, priority list pollutants which are discharged into the basin, other pollutants discharged in significant quantities Operational Monitoring Objectives: assess status of those water bodies identified as being at risk of failing to meet their environmental objectives assess any changes in the status of such bodies resulting from the programmes of measures. The selection of parameters for the operational monitoring is individual for a particular sampling site that represents an affected water body. Status/Potential of Rivers - 2009 Ecological Status Chemical Status Investigative monitoring ……primarily a national task. At the basin-wide level: Joint Danube Surveys (every 6 years) will be used to carry out investigative monitoring as needed testing of new methods checking the impact of “new” chemical substances Surveillance monitoring II Monitoring of specific pressures Provides assessment of long term trends of specific pollutants Sound basis for load estimation transferred in marine environment Sampling and assessment: annually Quality elements: organic pollution nutrient pollution hazardous substances Biology (selected) hydromorphological parameters (site specific) SM2 Chemistry Surveillance Monitoring 2 Water Water concentrations load assessment Parameter Flow Temperature Transparency (1) Suspended Solids (5) Dissolved Oxygen pH (5) Conductivity @ 20 °C (5) Alkalinity (5) Ammonium (NH4+ -N) (5) Nitrite (NO2- -N) Nitrate (NO3- -N) Organic Nitrogen Total Nitrogen Ortho-Phosphate (PO43- -P) (2) Total Phosphorus Calcium (Ca2+) (3, 4, 5) Magnesium (Mg2+) (4, 5) Chloride (Cl-) Atrazine Cadmium (6) Lindane Lead (6) Mercury (6) Nickel (6) Arsenic (6) Copper (6) Chromium (6) Zinc (6) p,p´-DDT and its derivatives (7) CODCr (5) CODMn (5) Dissolved Silica BOD5 anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 12 x per year anually / 1 or 12 x per year anually / 12 x per year anually / 12 x per year daily anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 26 x per year anually / 12 x (1) Only in coastal waters (2) Soluble reactive phosphorus SRP (3) Mentioned in the tables of the CIS Guidance document but not in the related mind map (4) Supporting parameter for hardness-dependent eqs of PS metals (5) Not for coastal waters (6) Measured in a dissolved form. Measurement of total concentration is optional (7) ; In areas with no risk of failure to meet the environmental objectives for DDT the monitoring frequency is once per year; in case of risk the frequency is 12 x year SM2 - Biology PHYTOPLANKTON chlorophyll-a BENTHIC MACROINVERTEBRATES Saprobic index and number of families (ASPT and EPT taxa optional) PHYTOBENTHOS benthic diatoms –optional parameter SM2 - Temporal changes of nitrate-nitrogen (c90) in the Danube and its tributaries 6 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 NO3-N mg/l 5 4 3 2 1 0 2538 2204 2204 2113 1935 1879 1869 1806 1806 1768 1768 1708 1560 1435 1429 1427 1367 1337 1287 1258 1174 1155 1077 1071 955 851 834 834 641 554 503 432 375 375 132 18 0 0 DE5 DE2 AT1 AT5 AT3 AT6 SK1 SK2 HU1 SK3 HU2 HU3 HU4 HU5 HR1 RS1 RS2 HR2 RS9 RS3 RS4 RS5 RS6 RO1 RS7 RS8 RO2 BG1 BG2 BG3 BG4 RO3 RO4 BG5 RO5 RO6 RO7 RO8 Monitorings sites / distance from the mouth [km ] 14 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 12 NO3-N mg/l 10 8 6 4 2 0 DE3 Inn DE4 CZ1 CZ2 Inn/ Morava Morava/ Salzach Dyje SK4 HU6 Vah Sio Sl1 HR9 HR4 Drava HR5 HU7 HU9 RS10 RS11 Tisza RS12 HU8 Tisza/ Sajo SI2 HR6 HR7 HR8 RS13 Sava RS14 RS15 RS16 RS17 Velika Morava RO9 RO10 Jantra Russ.Lom Arges BG14 BG15 Siret MD1 RO11 MD3 Prut Monitoring site / Tributary Analytical Quality Control Distribution Date of Sample type round 2009/I. Determinands distribution Week 15 Surface water SO 24 , K, Na, Fe, Mn - 06.04 - 10.04. Cl ,Ca, Mg, TH NH NO + 4 , NO 3 , PO 34 , TP, Kj-N 2 COD Mn, DOC MBAS phenol index AOX 2009/II. Week 24 Surface water petroleum hydrocarbons COD 08.06 - 12.06. Cr , BOD 5 , DOC pH, conductivity TN Al, As, Cd, Cr, Cu, Ni, Pb, Zn Hg 2009/III. Week 39 Surface water 21. 09 - 25.09. 2009/IV. Week 46 09.11. - 13.11. surface water sample atrazine, lindane, simazine, alachlor, endosulfane, 4,4'-DDT , PAHs, PCBs Surface water Determinands with more than 15% rejected results will be redistributed Analytical Quality Control Variation in the reported values of PO4-P and DDT in AQC samples Load assessment programme Integrated with the TNMN Loads are calculated for BOD5, inorganic nitrogen, ortho-phosphate-phosphorus, dissolved phosphorus, total phosphorus, suspended solids and chlorides (voluntary) Minimum sampling frequency - at least 24 per year Annual loads of BOD5 at monitoring stations along the Danube River in 2008 400 7000 350 6000 300 4000 200 3000 RO2 150 2000 AT5 1000 SK1 50 HU3 100 0 2800 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 distance from the m outh (km ) BOD5 discharge 0 600 400 200 0 discharge (m 3.s -1) RO5 250 DE2+AT1 BOD5 (x 103 tons) RO4 5000 GROUNDWATERS Groundwater bodies of a basinwide importance in the DRBD Parameters and frequency for the surveillance monitoring program AT/DE Transboundary GWB* 1 BG 2, 4 CS 7 HU 5, 6, 7, 8, 9, 10, 11 MD 3 RO SK 2, 3, 4, 5, 6, 7 8, 9, 10, 11 x 1/a 1/a 1/a 1/a 1/a 1/a x 1/a 1/a 1/a 1/a 1/a >1/a (selected stations) x x x x x x x CHEMICAL (with estimation of frequency) Oxygen pH-value Electrical conductivity Nitrate Ammonium Temperature Further parameters, e.g. major ions 1/a 1/a 1/a 1/5a 1/a cont. x operational >1/a >1/a >1/a >1/a >1/a >1/a x 1/a 1/a 1/a 1/a 1/a 1/a x x >1/a >1/a >1/a >1/a >1/a QUANTITY GW levels/well head pressure spring flows Flow characteristics Extraction (not obligatory) Reinjection (not obligatory) x x x x x x x GW monitoring design in TNMN Monitoring parameters Agreed obligatory parameters: conductivity, NH4 and NO3 All parameters for which GWBs are ‘at risk’ or having ‘poor status’ Additional parameters characterising the GWB Aggregation procedures Minimum (of all sites - mean per site) Mean (based on mean per site) Maximum (of all sites - mean per site) standard deviation 10, 25, 50, 75, 90 Percentile Reporting frequencies - Reference year: 2007, reporting year: 2008, then every 6-years (in line with reporting to EC) Objective WFD intercalibration exercise high good high Comparison of national quality classes among countries … good moderate moderate country A country B EC GIG – Common Intercalibration Stream Types • ecoregion • catchment area • altitude • geology • substrate R-E1 Small to medium-sized, mid-altitude streams in the Carpathians (CZ, HU, RO, SK) R-E2 Medium-sized, lowland streams in the Plains (HU, RO, SK) R-E3 Large and very large, lowland rivers in the Plains (BG, HU) R-E4 Medium-sized, mid-altitude streams in the Plains (AT, HU, RO, SK) R-E6 Middle and downstream section types of the Danube River (AT, SK, HU, RO, BG) Results EC GIG IC exercise R-E4 Medium-sized, mid-altitude streams in the Plains (AT, HU, RO, SK) national assessment index 0,9 0,8 0,7 good good good good 0,6 0,5 0,4 pre-IC intercalibrated Austria pre-IC intercalibrated Slovak Republic EC GIG IC exercise EC GIG IC exercise • Q1. Do all national assessment methods meet the requirements of the Water Framework Directive? • Q2. Do all national methods address the same common type(s) and pressure(s), and follow a similar assessment concept? • Q3. Do all countries apply the same assessment method (but different status classifications)? • Q4. Is the BQE sampling and data processing generally similar, so methods can reasonably be applied to the data of other countries? EC GIG IC exercise Phytoplankton Comments on Q1 3.06 Key source(s) to derive reference conditions 3.07 Reference site characterisation: Criteria 3.10 Setting of ecological status boundaries Hungary Romania Slovakia • Reference site selection criteria are not specified by Romania. • Boundary setting procedure by Romania needs further specification. Existing near-natural reference sites, Least Disturbed Conditions, Modelling (extrapolating model results) No off-river and in-channel reservoirs on the watershed. The species composition is close to those proposed by the model. Minimal organic pollution. High-good boundary derived from metric variability at near-natural reference sites Existing near-natural reference sites, Expert knowledge, Historical data Least Disturbed Conditions Natural (undisturbed) sites or near natural sites. No reference sites used. High-good boundary derived from metric variability at near-natural reference sites Equidistant division of the EQR gradient Organic pollution and saprobic index; ecological status boundaries RO 01 type H/G = 1.285; G/M = 1.57. No reference sites for large lowland rivers, derivation of reference values based on expert judgment; confirmation by calculations/statistics. Advance setting of boundaries (data from period 20012005): statistical values (mean of 6 measured values within vegetation period for each metric in monitored sites) were calculated for setting of boundaries. These were verified after calculations by expert judgment and compared (correlated) to chemical quality class boundaries. Q1 3.11 Boundary setting procedure The functional groups of algae were evaluated on basis of their ecological characteristics. Nutrient status, tolerance of turbulent conditions, time sufficient for development of the given assemblage, and general risk. All the groups were given a factor number (1-5). All the boundaries were set by the relative abundance of the reference (F=5) and good (F=4) taxa. These ratios were different in every river type. EC GIG IC exercise Phytoplankton Comments on Q2 1.09a Detected pressure(s) Q2 1.09b Demonstration of pressureimpact-relationship Q3 Comments on Q3 Q4 Comments on Q4 • Similar pressures are addressed by the different methods, however Romania and Slovakia have not demonstrated the pressure-impact-relationship. • Different biological metrics are applied, pointing at deviating assessment concepts (see Annex). Eutrophication, Flow modification, Impact Eutrophication, General degradation, of alien species, Pollution by organic Pollution by organic matter matter Phytoplankton data (394) from 104 HU rivers (including all HU river types) were examined to establish pressure-impact relationship between the HRPI and the stressors indicating nutrient and organic load. The relationship showed significant not demonstrated correlation with the measures of organic pollution (BOD, COD, Oxygen saturation). R2 values ranging from 0.2-0.37 depending on river type. Significant relationship was not observed with the inorganic nutrients. • • • • Eutrophication, Flow modification, Pollution by organic matter not demonstrated All countries apply a different method. Assessment is based on different sample volumes and different numbers of sampling occasions. The level of taxonomical identification differs between methods. The selection of biological assessment metrics differs between methods. BQE method harmonization - general info 1.01 GIG: 1.02 Category: 1.03 BQE: 1.04 Country: 1.05 Specification: 1.06 Method name: Eastern Continental Lakes, Rivers Benthic Diatoms Hungary none Improvement of the Hungarian Ecological Water Qualification System - Phytobenthos 1.07 Original name: 1.08 Status: Method is/will be used First RBMP (2009) 1.09 Detected pressure(s): Eutrophication, General degradation, Pollution by organic matter Has the pressure-impact-relationship been tested? Yes, with qualitative data (e.g. response at reference against impacted sites). On basis of the pressure data (TP, BOD, CODCr, Electrical Conductivity) the Least Disturbed Conditions (LDC) were selected. The relationship between the phytobenthos metrics and BOD, EC, COD, TN, ox. Sat and SRP showed significant correlations in several types (Spearman Correlation Coefficient ranging from 0.17 to 0.61 if the relationship was significant). 1.10 Internet reference 1.11 Pertinent literature 1.12 Scientific 1.13 Method developed by1.14 Method reported by BQE method harmonization - data acquisition 2.01 Sampling/Survey guidelines CEN – European Committee for Standarization, 2003. Water quality – Guidance standard for the routine sampling and pretreatment of benthic diatoms from rivers. - European Standard EN 13946. 2.02 Short description Rivers: 5 stones or 5 macrophytes stems are randomly selected from 10 to 100 m river stretch Lakes: 5 randomly selected reed stems from 10 to 30 cm above the water level 2.03 Method to select the sampling/survey site or area Random sampling/surveying 2.04 Sampling/survey device Brush 2.05 Specification: n.a. 2.06 Sampled/surveyed habitat Single habitat(s), stones, macrophytes 2.07 Sampled/surveyed zones in areas with tidal influence: not relevant 2.08 Sampling/survey month(s) rivers: May to October, lakes: June to October 2.09 Number of sampling/survey occasions (in time) to classify site or area One occasion per sampling season 2.10 Number of spatial replicates per sampling/survey occasion to classify site or area 5 2.11 Total sampled/surveyed area or volume or total sampling duration to classify site or area - 100 cm2 BQE method harmonization - data acquisition Sample processing 2.12 Minimum size of organisms sampled and processed all diatoms 2.13 Sample treatment Organisms of the complete sample are identified. 2.14 Level of taxonomical identification Species/species groups 2.15 Record of abundance: Relative abundance in relation to Area Unit: number of valves per 400 valves 2.16 Quantification of biomass: n.a. 2.17 Other biological data: none 2.18 Special cases, exceptions, additions: none BQE method harmonization - data evaluation 3.01 List of biological metrics Relative abundance of taxa with indicator and sensitivity values for organic material and nutrients (diatom indices calculated by OMNIDIA) 3.02 Does the metric selection differ between types of water bodies Yes 3.03 Combination rule for multi-metrics Average metric scores 3.04 From which biological data are the metrics calculated? Data from single sampling/survey occasion in time Reference conditions 3.05 Scope of reference conditions 3.06 Key source(s) to derive reference Surface water type-specific Expert knowledge, Least Disturbed Conditions 3.07 Reference site characterisation Number of sites: n.a. Geographical coverage: Location of sites: Data time period: Criteria: It was practically impossible to find reference conditions, especially in case of lowland rivers and large rivers that are the most of Hungarian rivers, so we used the so called “Least Disturbed Sites” for boundary setting. BQE method harmonization - data evaluation 3.08 Reference community description 3.09 Results expressed as EQR? n.a. Yes Boundary setting 3.10 Setting of ecological status boundaries Equidistant division of the EQR gradient 3.11 Boundary setting procedure Reference conditions which could be applied across rivers in Hungary have not been established yet. Nevertheless, unimpacted stretches or sites with low pollution and with smaller hydromorphological alterations can be found in almost every river type. On basis of the pressure data (TP, BOD, CODCr, Electrical Conductivity) the LDS were selected. 10th percentiles of the index values of the selected LDS sites were considered as high/good (H/G) class boundaries and 75th percentiles as good/moderate (G/M) boundaries in every type. The rest of data was divided into 3 equal parts between the minimum value of the index in a given river type and the G/M value in order to set the further boundaries. Theoretical EQR values (H/G= 0.8; G/M= 0.6; M/P= 0.4; P/B= 0.2) were plotted against the index boundaries for all types. By equation of the actual line of best fit the EQR values can be calculated. 3.12 “Good status” community At good status stands of the sensitive taxa are well developed, they are dominant, but significantly decreasing at good-moderate boundary and replaced by tolerant taxa. 3.13 Consideration of uncertainty No (to be done) Thank you for your attention! www.icpdr.org icpdr@unvienna.org