農藥理化性質試驗指引文件清單 1 2 3 4 物理狀態、顏色 1.1 中國國家標準 CNS 6661 C5076 色碼用之標準顏色 UDC 535.6.61。 1.2 中國國家標準 CNS 7163 K6644 透明液顏色檢驗法-加登納色標 UDC 535.65。 1.3 中國國家標準CNS 11351 Z7197物體色之測定方法。 1.4 Handbook of chemistry and physics, CRC Publishing Co., BocaTaton, EL, Latest edition. 1.5 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPP TS 830.6302, EPA 712–C–96–019. 1.6 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6303, EPA 712–C–96–020. 氣味 2.1 Handbook of chemistry and physics, CRC Publishing Co., BocaTaton, EL, Latest edition. 2.2 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6304, EPA 712–C–96–019. 酸鹼度 3.1 CIPAC. 1970. MT 75 Determination of pH values. In “CIPAC Handbook F. Analysis of Technical and Formulated Pesticides.” Hatching Green, Harpenden, Hertfordshire, England. 3.2 CIPAC. 1999. MT 75.3 Determination of pH values. In “CIPAC Handbook J. Analysis of Technical and Formulated Pesticides.” Hatching Green, Harpenden, Hertfordshire, England. 3.3 CIPAC. 1970. MT 31 Free Acidity or Alkalinity. In “CIPAC Handbook F. Analysis of Technical and Formulated Pesticides.” Hatching Green, Harpenden, Hertfordshire, England. 3.4 United States Environmental Protection Agency (U.S. EPA). 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines OPPTS 830.7000, pH. EPA 712-C-96-030. 熔點 4.1 中國國家標準。2005。CNS 8835 K0016 化學製品熔點及熔融範圍測定 法。UDC 536.421.1:54.03。 4.2 CIPAC. 1970. MT 2 Melting Point. In “CIPAC Handbook F. Analysis of Technical and Formulated Pesticides”, Harpenden, Hertfordshire, England. 4.3 OECD. 1995. Guideline for Testing of Chemicals, OECD102 Melting Point/Melting Range. Organization for Economic Cooperation and Development. Paris, France. 4.4 Offical Journal of European Communities, Dir/92/69/EEC A.1, Melting/Freezing Temperature. 4.5 United States Environmental Protection Agency (U.S. EPA). 1998. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product 農藥理化性質試驗指引文件清單 2009-09-16 1/7 Properties Test Guidelines, OPPTS 830. 7200 Melting Point/Melting Range. EPA 712-C-96-033. 5 6 7 沸點 5.1 OECD. 1995. Guideline for Testing of Chemicals No. 103, Boiling Point. Organization for Economic Cooperation and Development, Paris, France. 5.2 Offical Journal of European Communities, Dir/92/69/EEC A.2, Boiling Temperature. 5.3 United States Environmental Protection Agency (U.S. EPA). 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7220 , Boiling Point/ Boiling Range, EPA 712-C-96-034. 密度、比重或積密度 6.1 中國國家標準 CNS 12450 Z8070 液體比重測定法 UDC 531.756. 6.2 中國國家標準 CNS 8834 K0015 化學製品密度及比重測試法 UDC 534.75:54.03. 6.3 CIPAC. 2003. MT 186 Bulk Density. In “CIPAC Handbook K. Analysis of Technical and Formulated Pesticides, p151-152. 6.4 CIPAC. MT 159 Pour and Tap Density of Granular Matrials. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides, p.390. 6.5 CIPAC. MT 169 Tap Density of Water Dispersible Granules. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides, p418-420. 6.6 CIPAC. MT 3 Specific gravity, density, and weight per millilitre. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides, p.11-21. 6.7 CIPAC. MT 33 Tap Density. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides, p.105-108. 6.8 CIPAC. MT 58.4 Apparent density after compaction without pressure. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides, p.176. 6.9 OECD; Guideline for Testing of Chemicals (No. 109, Density of Liquids and Solids). 6.10 Official Journal of the European Communities, Dir/92/69/EEC A.3. Relative density. 6.11 United States Environmental Protection Agency (U.S. EPA). June 2002. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7300, Density/Relative Density/Bulk Density, EPA 712-C-02-035. 蒸氣壓 7.1 OECD. 2006. Guideline for Testing of Chemicals, OECD 104 Vapour Pressure. Organization for Economic Cooperation and Development. Paris, France. 7.2 Offical Journal of European Communities, Dir/92/69/EEC A.4, Vapour Pressure. 7.3 United States Environmental Protection Agency (U.S. EPA). 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830. 830.7950 Vapor Pressure. EPA 712-C-96-043. 農藥理化性質試驗指引文件清單 2009-09-16 2/7 8 9 溶解度 8.1 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC). MT 157 Water solubility. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides p.383-390. ” 8.2 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC). MT 5 Material soluble in acetone. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides p.21-22. ” 8.3 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC). MT 7 Material soluble in ethanol. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides p.23-24. ” 8.4 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC). MT 9 Materials soluble in water. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides p.26. ” 8.5 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC). MT 181 Solubility in organic solvents. In “CIPAC Handbook H. Physio-chemical Methods for Technical and Formulated Pesticides p.314-317. ” 8.6 Official Journal of the European Communities, ‘‘A.6. Water Solubility. 8.7 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 105 Water Solubility (Adopted: 27.07.95), OECD, Paris, France. 8.8 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 116 "Fat Solubility of Solid and Liquid Substances (Flask Method) " (Adopted: 12 May 1981), OECD, Paris, France. 8.9 United States Environmental Protection Agency (U.S. EPA). March 1998. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7840, Water Solubility: Column Elution Method; Shake Flask Method , EPA 712–C–98–041. 8.10 United States Environmental Protection Agency (U.S. EPA). March 1998. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7860, Water Solubility (Generator Column Method) , EPA 712–C–98–042. 8.11 USEPA. 1997. U.S. Environmental Protection Agency. Chemistry Assistance Manual for Premanufacture Notification Submitters. EPA744-R-97-003. 分配係數 9.1 Official Journal of the European Communities, ‘‘A.8. Partition Coefficient,’’ Dir 92/69/EEC. No L 383 A. 9.2 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 107 Partition Coefficient (n-Octanol/Water), Shake Flask Method, Paris, France. 9.3 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 117 Partition Coefficient (n-Octanol/Water), High Performance Liquid Chromatography (HPLC) Method, Paris, France. 9.4 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 123 Partition Coefficient (n-Octanol/Water), Slow-Stirring Method, Paris, France. 農藥理化性質試驗指引文件清單 2009-09-16 3/7 9.5 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7550, Partition Coefficient (n-Octanol/Water), Shake Flask Method, EPA 712–C–96–038. 9.6 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7560, Partition Coefficient (n-Octanol/Water), Generator Column Method, EPA 712–C–96–039. 9.7 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7570, Patition Coefficient (n-octanol/water), Estimation by Liquid Chromatography, EPA 712–C–96–040. 9.8 USEPA. 1997. U.S. Environmental Protection Agency. Chemistry Assistance Manual for Premanufacture Notification Submitters. EPA744-R-97-003. 10 解離常數 10.1 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 112 Dissociation Constants in Water (Titration method - spectrophotometric method - conductometric method), OECD, Paris, France. 10.2 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7370, , EPA 712–C–96–036. 11 黏度 11.1 中國國家標準 CNS 3390 K6329。透明與不透明液體之黏度測定法(動 力及公制黏度)。 11.2 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC). MT 22 Viscosity. In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides p.75-84.” 11.3 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 114 Viscosity of Liquids, OECD, Paris, France. 11.4 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.7100, Viscosity, EPA 712-C-96-032. 12 燃燒性 12.1 化學品全球分類及標示調和制度(全球調和制度),2005 年,工研院。 ST/SG/AC. 10/30/Rev.1, ISBN 92-1-116927-5。 12.2 克氏開口杯閃點與著火點測定法,中華民國國家標準 CNS 總號 3775,類號 K6377。 12.3特氏閉杯式閃點試驗法,中華民國國家標準 CNS 總號 13429,類號 農藥理化性質試驗指引文件清單 2009-09-16 4/7 K61019。 12.4閃點測定法(潘-馬氏閉杯式法),中華民國國家標準 CNS 總號 3574, 類號 K 6365。 12.5 噴霧性產品可燃性之測定法,中華民國國家標準 CNS 總號 7180,類 號 Z6038。 12.6 ASTM D93-02, Standard Test Methods for Flash-Point by Pensky-Martens Closed Cup Tester,American Society for Testing and Materials,West Conshohocken, PA 19428-2959, U.S., 2002. 12.7CIPAC. MT 12 Flash Point In “CIPAC Handbook F. Physio-chemical Methods for Technical and Formulated Pesticides, pp.31-43 12.8 Official Journal of the European Communities, A.10 Flammability (solids). 12.9 Official Journal of the European Communities, A.11 Flammability (gases). 12.10 Official Journal of the European Communities, A.15 Auto-ignition Temperature (liquids and gases). 12.11 Official Journal of the European Communities, A.16 Relative self-ignition Temperature for solids 12.12 Official Journal of the European Communities, A.9. Flash Point. 12.13 U.N. Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria. Fourth revised edition. New York and Geneva, 2003. ST/SG/AC.10/11/ Rev.4. 12.14 United States Environmental Protection Agency (U.S. EPA). August 1995. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6315, Flammability, EPA 712-C-95-024. 13 混合性 13.1 American Society for Testing and Materials, ‘Standard Practice for Evaluation of Physical Compatibility of Pesticides in Aqueous Tank Mixtures by the Dynamic Shaker Method, E 1518,’’ ASTM. 13.2 Collaborative International Pesticide Analytical Council, Ltd. (CIPAC) Handbook, ‘‘MT 23 Miscibility with Hydrocarbon Oil,’’ CIPAC, Hatching Green, Harpenden, Hertfordshire, England (1970). 13.3 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6319, Miscibility, EPA 712-C-95-027. 14 爆炸性 14.1 化學品全球分類及標示調和制度(全球調和制度) ,2005 年,工研院。 ST/SG/AC. 10/30/Rev.1, ISBN 92-1-116927-5。 14.2 Official Journal of the European Communities, ‘‘A.14. Explosive Properties,’’ No L 383 A/87. 251/74. 14.3 U.N. Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria. Fourth revised edition. New York and Geneva, 2003. 農藥理化性質試驗指引文件清單 2009-09-16 5/7 ST/SG/AC.10/11/ Rev.4 and -/Amend.1. 14.4 U.N. Recommendations on the Transport of Dangerous Goods, Model Regulations. Fourteenth revised edition. New York and Geneva, 2005. ST/SG/AC.10/1/ Rev.14. 14.5 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6316, Explodability, EPA 712-C-96-025. 15 腐蝕性 15.1 化學品全球分類及標示調和制度(全球調和制度),2005 年,工研院。 ST/SG/AC. 10/30/Rev.1, ISBN 92-1-116927-5。 15.2 ASTM G 31. 1990. ”Standard practice for laboratory immersion corrosion testing of metals”, ASTM international [Fon] N.G.. Fontana, N. D. Greene, “Corrosion engineering”, 3rd edition, McGraw Hill. 15.3 U.N. Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria. Fourth revised edition. New York and Geneva, 2003. ST/SG/AC.10/11/ Rev.4 15.4 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6320, Corrosion Characteristics, EPA 712-C-96-028. 15.5 United States Environmental Protection Agency (U.S. EPA). June 2002. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6317, Storage Stability, EPA 712–C–02–026. 16 貯存安定性 16.1 CIPAC. 1995. MT 46 Accelerated storage procedure. In “CIPAC Handbook F. Physic-chemical Methods for Technical and Formulated Pesticides (W. Dobrat and A. Martijn eds.)”, p. 148-152. 16.2 CIPAC. 2000. MT 46.3 Accelerated storage procedure. In “CIPAC Handbook J. Analysis of Technical and Formulated Pesticides (W. Dobrat and A. Martijn eds.)” , p. 128-130. 16.3 CropLife.1993 Guidelines for Specifying the Shelf Life of Plant Protection Products. Technical Monograph n°17 p4-6. 16.4 United States Environmental Protection Agency (U.S. EPA). August 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830.6317, EPA 712–C–96–019. 17 面表張力 17.1 Official Journal of the European Communities, ‘‘A.5. Surface Tension,’’ No L 383 A/87. 251/74. 17.2 Organization for Economic Cooperation and Development, Guidelines for The Testing of Chemicals, OECD 115 Surface Tension of Aqueous Solutions, OECD, Paris, France. (Adopted: 27.07.95). 18 相容性 18.1 Offical Journal of European Communities, Dir/92/69/EEC A.12, 農藥理化性質試驗指引文件清單 2009-09-16 6/7 Flammability (Contact with Water). 18.2 United States Environmental Protection Agency (U.S. EPA). 1996. Office of Prevention, Pesticide and Toxic Substance (OPPTS). Product Properties Test Guidelines, OPPTS 830. 6314 Oxidation/Reduction: Chemical Incompatibility. EPA 712-C-96-023. 農藥理化性質試驗指引文件清單 2009-09-16 7/7