FACULTY OF ENGINEERING LAB SHEET EEN2056 PHYSICAL ELECTRONICS TRIMESTER 2 (2010-2011) PHE 2 – Characteristics of a Solar Cell *Note: On-the-spot evaluation may be carried out during or at the end of the experiment. Students are advised to read through this lab sheet before doing experiment. Your performance, teamwork effort, and learning attitude will count towards the marks. EEN2056 Physical Electronics Experiment PHE2 Experiment PHE2: Characteristics of a Solar Cell Introduction Solar cell directly converts sunlight to electrical energy and is the most promising of all alternative resources known to date. Solar cells are inexhaustible in power generation with no fuel except sunlight for nearly 30 years of lifetime guarantee. Solar cells are basically large area pn junction photo diode. Basing on the junction structure, solar cells are categorized into two types (a) homogeneous junction Si, Ge or GaAs solar cells (b) heterogeneous junction solar cells are based on II-VI compounds like CdS/CdTe, CdS/CIGS etc. Homogeneous solar cells may be either single crystal or poly crystalline material. The wafers are suitably doped to get ‘n’ or ‘p’ type materials. A suitable ohmic contact from the top of the solar cell is formed. For the n-type, aluminium is one of the suitable materials and for p-type silver is the apt one. The current-voltage characteristics of a solar cell are to be measured at different light intensities, the distance between the light source and the solar cell being are to be varied. The dependence of no-load voltage and short-circuit current on temperature is to be determined. As additional tasks, the series resistance and ideality factor (of the diode) are to be figured out. Equipment: Solar battery, 4 cells, 2.5x5 cm Thermopile, molltype Universal measuring amplifier Rheostat, 330 Ohm, 1.0 A Lamp socket E27, mains conn. Filament lamp, 220 V/120 W, w. ref l. Hot-/Cold air blower, 1000 W Meter scale, demo, l = 1000 mm Tripod base Right angle clamp Plate holder Universal clamp G-clamp Glass pane, 150x100x4 mm, 2 off Digital multimeter Lab thermometer, -10...+100 oC Connecting cord, l = 500 mm, red Connecting cord, l = 500 mm, blue 1 1 1 1 1 1 1 1 2 2 1 1 2 1 2 1 3 2 Objectives: 1. To collect the light intensity with the thermopile at various distances from the light source. 2. To measure the short-circuit current and open-circuit (no-load) voltage at various distances from the light source. 3. To test the dependence of open-circuit (Voc) voltage, and short-circuit current (Isc) on temperature. 4. To analyse the current-voltage characteristics (I-V) at different light intensities. 5. To compare the current-voltage (I-V) characteristics under different operating conditions: cooling the equipment with a blower, no cooling, shining the light through a glass plate. 6. To calculate the Series Resistance of the solar cell. Page 2 of 12 EEN2056 Physical Electronics Experiment PHE2 7. To determine the Ideality factor of the Solar cell. (Optional) Fig. 1: Experimental set-up for determining characteristic curves. Fig. 2: Circuit for measuring the current-voltage characteristic. Theory Pure silicon is deliberately ‘impurified’ (doped) with tri- and pentavalent impurity atoms to make a p- or n-type semi-conductor. If we put a p-and n-type crystal together we get a junction (pn-junction, Fig. 3) whose electrical properties determine the performance of the solar cell. In equilibrium (with no external voltage) the Fermi characteristic energy level E F will be the same throughout. Because of the difference in the concentrations of electrons and holes in the p- and n-regions, electrons diffuse into the p-region and holes into the n-region. The immobile impurity atoms create a space charge-limited current region; the diffusion current and the field current offset one another in equilibrium. The diffusion potential UD in the pn-junction depends on the amount of doping and corresponds to the original difference between the Fermi energy Page 3 of 12 EEN2056 Physical Electronics Experiment PHE2 levels of the separate p- and n-regions. The distance between the valence band and the conduction band in silicon at room temperature is E = 1.1 eV. For silicon, the diffusion potential is UD = 0.5 to 0.7 V. If light falls on the pn-junction, the photons create electron-hole pairs separated by the space charge. The electrons are drawn into the n-region and the holes into the p-region. Photons are absorbed not only in the pn-junction but also in the p-layer above it. The electrons produced are minority carriers in those areas: their concentration is greatly reduced by recombination and with it their efficiency. The p-layer must therefore be sufficiently thin for the electrons of diffusion length LE to enter the n-layer. LE >> t, where t = thickness of p-layer. Fig. 3: pn-junction in the energy-band diagram-acceptors, + donors, UD is the diffusion potential, EF is the Fermi characteristic energy level, and e is the elementary charge. Fig. 4: Construction of a silicon solar cell. If g is the number of electron-hole pairs produced per unit area and of a voltage U is applied across the pn-junction, a stream of electrons and holes of density i = e . (exp eU/kT – 1)…………………………………. (1) (n0 De t/L2e + p0 Dh/Lh) – e . g Page 4 of 12 EEN2056 Physical Electronics Experiment PHE2 is produced, where e is the elementary charge, k is Boltzmann’s constant, T is the temperature, L is the diffusion length of electrons and holes, D is the diffusion constant for electrons and holes, n0 and p0 are equilibrium concentrations of the minority carriers. Fig. 5: Light intensity J at distances s normal to the light source. The short-circuit current density (U = 0) is = – e . g…………………….. (2) is proportional to the intensity of the incident light at fixed temperature. g becomes very slightly greater (less than 0.01 %/K) as the temperature rises. The voltage U can become as high as the diffusion potential UD but no higher. As the temperature rises the no-load voltage decreases typically by –2.3 mV/K, since the equilibrium concentrations n0and p0 increase with the temperature: n0 = exp (– E/2kT) Page 5 of 12 EEN2056 Physical Electronics Experiment PHE2 Experimental Procedures: Task 1: Measure the light intensity with the thermopile and digital multimeter/amplifier with the equipment at different distances from the light source e.g. 10 points beginning at 200cm till 50cm. The inlet aperture marks the position of the thermopile. The distance between the lamp and the thermopile should be at least 50 cm, since the angular aperture of the thermopile is only 20 degree. The light intensity is varied by varying the distance between the light source and the solar cell. To determine the intensity with the thermopile it is assumed that all the light entering the aperture (dia. 2.5 cm) reaches the measuring surface. (see Fig.5 for reference). Collect the data and plot the graph for report. Notes: The maximum output voltage of the amplifier is 10 V in case if used. The sensitivity is 0.16 mv/mW. By extrapolating the straight line one can determine the intensity at distances s cm. Task 2: The solar cell measures the diffused light as well as the direct light from the lamp. As the lamp has a slim light cone of approx. 30 degree, the diffused light chiefly arises as a result of reflection from the bench top, and can be suppressed by covering the bench with a black cloth. Using the measured values in Fig. 5 one can obtain the relationship between the light intensity and the short-circuit current and open-circuit voltage measured at various distances away from the light source. Collect the Ligh Intensity (J)-Short Circuit Current (Isc)-Open circuit voltage (Voc) data and later prepare graph for report. (see Fig. 6 for reference). Task 3: The open circuit voltage (Voc) and the short-circuit current (Isc) of the solar cell depend on temperature. To demonstrate the temperature effect, blow hot air (no air, medium hot, high hot air and screening with glass plate: 4 categories) over the solar cell. A glass plate which absorbs light in the infrared region can be used to reduce a rise in temperature of the solar battery. To measure the temperature, put the thermocouple tip along any side of the panel and insert the socket to the multimeter. Do not touch the cell as its thin p-layer can easily be damaged. Now, measure Voc and Isc individually and tabulate the data. Task 4 & 5: Please refer to figure 2 for circuit setup for I-V measurement. Change the voltage with the potentiometer (also called voltage divider) and record the current to get the I-V characteristics. Repeat the I-V characteristics for various light intensities and temperatures from the readings of the Voltmeter and Ammeter. Make sure to put at High Impedance and amplification factor of 105. The differences are in the distance and the temperature variation by external factors (like hot blowers). Ask the supervisor if any confusion happens. Notes: The short circuit current is proportional to the light intensity (see 2). If the distance between lamp and solar cell exceeds 50 cm, the temperature rise caused by radiation can be disregarded in comparison with that caused by the hot air. Page 6 of 12 EEN2056 Physical Electronics Experiment PHE2 Fig. 6: Short-circuit current Is and open circuit (no-load) voltage Uo as a function of the light intensity J. Fig. 7: Current-voltage characteristic at different light intensities J. Page 7 of 12 EEN2056 Physical Electronics Experiment PHE2 Fig. 8: Current-voltage characteristics of the solar battery a) with blower cooling b) with no blower cooling c) when screened with a glass plate. When measuring the effect of temperature on U0 and Is, the temperature distribution over the hot air area must be taken into account. The measurements can provide only a rough order of magnitude of this. Fig. 9: Spectrum of the sun (T approx. 5800 K) and of an incandescent lamp (T approx. 2000 K), and the spectral sensitivity of the silicon solar cell. The change in short-circuit current with the temperature cannot be measured. The maximum power output is at the turning points on the curves (joined by the broken line) at which the load resistor has the same value as the internal resistance Ri of the solar battery. The internal resistance decreases with increasing light intensity. Page 8 of 12 EEN2056 Physical Electronics Experiment PHE2 If we compare the maximum power output with the incident power, we obtain an efficiency of approx. 6% (area of solar battery 50 cm2). Fig. 8 shows the effect of the various ‘operating modes’ as for reference. Task 6: To measure the series resistance, connect the solar cell and the measurement apparatus as shown in figure 10. This experiment has to be carried out under Dark condition (you have to cover the solar cell area with dark cloth as provided). Step 1: Supply the voltage to the cell from the power supply until the reading on the digital ammeter is equal or close to the Short-circuit current Isc measured in previous experiment. Step 2: Record the applied voltage Va. A higher voltage that the open circuit voltage (Voc) is necessary to obtain the current value equal to Isc. This is because of the additional voltage drop across the series resistance (Rs). This resistance can therefore be determined by the difference between those two voltages: Va - Voc= Rs x Isc Therefore, Rs Va Voc Isc A + Solar Cell V _ _ _ Fig. 10: Series Resistance measurement setup Page 9 of 12 EEN2056 Physical Electronics Experiment PHE2 Task 7: Experiment on Ideality factor of Solar cell (optional) To determine the ideality factor of a given solar cell illuminated at different intensities. The wires are connected to the voltmeter and ammeter to measure current when the solar cell is exposed to the illuminating source. Ideality factor indicates the formation of an ideal diode (as varies in between 1 - 2). The ideality factor is obtained from the equation, qV nkT I sc …………….(1) I Io e 1 Under load condition, current will flow; the total current is given by, Rs I ) q (VnkT V Rs I ………..(2) I I sc I o e 1 Rsh Where ‘Io’ is the reverse saturation current, ‘n’ is the ideality factor, ‘Isc’ is the photocurrent, Rs and Rsh are the series and shunt resistance of the solar cell, ‘k’ is the Boltzmann constant respectively. Hence from the above equation (1), the reverse saturation current ‘Io’ and the ideality factor ‘n’ can be determined. 1. Construct the circuit shown in Fig 11 for measuring the ideality factor of a solar cell. 2. The solar cell is connected in series with a resistance box (variable resistance or voltage divider) and an ammeter. A voltmeter is connected across the solar cell. 3. Cover the whole cell with a black cloth to prevent the external light / radiations. 4. Illuminate the light source to the solar cell. Maintain the solar cell and light source in the same height. Measure the intensity of the light by intensity meter or LUX meter (mW/cm2 or LUX or Lumens). 5. By varying the load resistance to maximum, record the open circuit voltage V oc for different intensities ranging from 10 to 100 mW/cm2 insteps of 10 mW/cm2. 6. Short circuit the solar cell (fix the zero resistance in the resistance box) and measure the short circuit current, Isc at different light intensities ranging from 10 to 100 mW/cm2 insteps of 10 mW/cm2. 7. Tabulate the values of Voc, Isc and intensity and estimate the ideality factor and reverse saturation current form the graph. 8. Plot the graph between Voc and ln Isc. Estimate the ideality factor ‘n’ from the slope of q , nkT q n , kT slope the curve. slope 9. Extrapolate the IV curve, where it cuts the y-axis is the reverse saturation current Io. Page 10 of 12 EEN2056 Physical Electronics Experiment PHE2 A + Solar Cell V R Fig 11. Setup for Ideality factor experiment S.No 1 2 : 9 10 _ _ _ Table on data exploration of Ideality factor Intensity Open circuit Short circuit ln Isc Voltage Voc current Isc (mW/Cm2) (V) (mA) 10 20 : 90 100 Cautions: Never put the black cloths over the lamp. Put the thermocouple tip any side of the solar panel. Double check the connections before powering on. Please do not handle any of the apparatus roughly and the way that differs from this lab sheet. Any questions should immediately be asked to the instructor/lecturer. References: 1. Solar Cells: Operating Principles, Technology, and System Applications (Prentice-Hall series in solid state physical electronics) by Martin A. Green; Publisher: Prentice Hall (October, 1981) ISBN: 0138222703. 2. Any other “Semiconductor Devices” related books in the MMU library could be good references. NOTE on Report Writing: Students should submit their computer composed report within 7 days of performing the experiment to the same laboratory. Report should include clear graphical representation of the results obtained. Moreover, logical explanations/discussions on the results are to be described for each experiment. Personal comments regarding the topic/experiment are also welcome based on the practical experience. Please refer to all the graphs in this sheet for your own one. Page 11 of 12 EEN2056 Physical Electronics Experiment PHE2 Marking Scheme Lab (10%) Assessment Components Hands-On & Efforts (2%) On the Spot Evaluation (2%) Lab Report (6%) Details The hands-on capability of the students and their efforts during the lab sessions will be assessed. The students will be evaluated on the spot based on the lab experiments and the observations on the solar cell characteristics. Each student will have to submit his/her lab final report within 7 days of performing the lab experiment. The report should cover the followings: 1. Introduction, which includes background information on the working principle of solar cell and their structures. 2. Experimental section, which includes the general summary of the lab experiment work. 3. Results and Discussions, which include the measured results, analysis, and evaluations, with neat graphs/images of the results and recorded data. 4. Conclusion, which includes a conclusion on the experimental. 5. List of References, which includes all the technical references cited throughout the entire lab report. The report must have references taken from online scientific journals (e.g. www.sciencedirect.com, http://ieeexplore.ieee.org/xpl/periodicals.jsp, http://www.aip.org/pubs/) and/or conference proceedings (e.g. http://ieeexplore.ieee.org/xpl/conferences.jsp). Format of references: The references to scientific journals and text books should follow following standard format: Examples: [1] William K, Bunte E, Stiebig H, Knipp D, Influence of low temperature thermal annealing on the performance of microcrystalline silicon thin-film transistors, Journal of Applied Physics, 2007, 101, p. 074503. [2] Hodges DA, Jackson HG, Analysis and design of digital integrated circuits, New York, McGraw-Hill Book Company, 1983, p. 76. Reports must be typed and single-spaced, and adopt a 12-point Times New Roman font for normal texts in the report. Any student found plagiarizing their reports will have the assessment marks for this component (6%) forfeited. The lab report has to be submitted to the Electronics lab staff. Please make sure you sign the student list for your submission. No plagiarism is allowed. Though the electrical characteristics of the measured sample from the same group can be similar, the report write-up cannot be duplicated for group members. The individual report has to be submitted within 7 days from the date of your lab session. Late submission is strictly not allowed. Page 12 of 12