Unit Test Review Q# 1 2 3 answer # D B B Q# 4 5 6 answer # A C B Q# 7 8 9 answer # D B D Q# 10 11 answer # C C 1. Identify as Endothermic or Exothermic exothermic a) a substance was dissolved in water and the temperature of the water increased endothermic b) liquid gas exothermic c) liquid solid exothermic d) in an _________-thermic reaction, the products always possess more potential energy than the reactants exothermic e) gas solid endothermic f) 2H2O(l) 2H2(g) + O2(g) endothermic g) melting of solid salts endothermic h) evaporation of water exothermic i) condensation of water _A___2. As ice cools from 273K to 263K, the average kinetic energy of its molecules will a) decrease b) increase c) remain the same __D___3. The molecules of which substance has the highest average kinetic energy: a) He(g) at O0C b) CO2(g) at 200C c) HCl(g) at 400C d) N2(g) at 600C __C___4. As ice at O0C changes to water at O0C, the average kinetic energy of the molecules a) decrease b) increase c) remain the same __A___5. As water vapor condenses at 1000C the potential energy of the molecules a) decrease b) increase c) remain the same __B___6. Calculate the total number of joules of heat that must be absorbed to change the temperature of 100 g of water from 250C to 300C a) 420 J b) 2100 J c) 10,500 J d) 12,600 J __A___7. The term below that represents a form of energy is: a) heat b) degree c) joule d) temperature __D___8. The formula that represents a compound is: a) C b) Cl2 c) N2 d) HF __D___9. The substance that cannot be decomposed by a chemical change is: a) H2SO4 b) NH3 c) H2O d)Ar __C___10. 840 J are added to 20g of water at 300C, calculate the final temperature of the water? a) 200C b) 350C c) 400C d) 500C __C___11. How many grams of water will absorb a total of 2520 J of energy when the water’s temperature water changes from 100C to 300C a) 10 g b) 20 g c) 30 g d) 60 g __D___12. The material that is a pure substance is: a) air b) earth c) fire d) water __D___13. The pair of substances that can be decomposed by chemical means is: a) CaO & Ca b) MgO & Mg c) Co & Mg d) CaO & MgO __A___14. An example of a heterogeneous mixture is a) soil b) sugar c) carbon dioxide d) carbon monoxide __D___15. A homogeneous mixture is represented as: a)NaCl(s) b)NaCl(l) c)NaCl(g) d) NaCl(aq) _C____16. At which temperature would the molecules in a one gram sample of water have the lowest average kinetic energy: a) 50C b) -1000C c) 5K d) 100K __C___17. As electrical energy is converted into heat energy, the total amount of energy in the system: a) decreases b) increases c) remains the same __B___18. The following statement best describes exothermic chemical reactions: a) they never release heat c) they never occur spontaneously b) they always release heat d) the always occur spontaneously __B___19. If Joules of energy are added to a sample of water, the temperature will: a) decreases b) increases c) remains the same _C____20. The type of energy stored in a chemical bond is: a) electrical b) nuclear c) chemical d) heat __A___21. The temperature of a substance changes from 100C to 200C. Calculate the number of Kelvin degrees that the temperature changes: [remember: 1 degree change in Celsius = 1 degree change in Kelvin] a) 10 b) 20 c) 273 d) 283 _______22. A 60g sample of water at 100C absorbs 1.3KJ of heat. Calculate what the temperature changes to. Q=mcΔT 1300J = (60g)(4.18J/gºC)( ΔT) 5.18ºC = ΔT ΔT = Tf - Ti 5.18ºC = Tf - 10ºC 15.18ºC = Tf _______23. 5 g of water is raised to 150C by adding 200J of heat. Calculate the initial temperature. Q=mcΔT 200J = (5g)(4.18J/gºC)( ΔT) 9.57ºC = ΔT ΔT = Tf - Ti 9.57ºC = 15ºC – Ti -5.43ºC = -Ti 5.43ºC = Ti _______24. 50g of water is raised to 600C by adding 3150J of heat. Calculate the initial temperature. Q = mcΔT ΔT = Tf - Ti 3150J = (50g)(4.18J/gºC)( ΔT) 15.07ºC = 60ºC – Ti 15.07ºC = ΔT -44.93ºC = -Ti 44.93ºC = Ti MATTER Matter is anything that has mass and occupies space The three states of matter are: solid, liquid and gas Describe physical properties of matter. Explain & give examples. use senses to observe physical properties: color, texture, odor, state of matter measure: o physical constants: bp, mp, density o mass, volume Describe chemical properties of matter. Explain & give examples. how matter behaves in presence of other matter (chemical reactions) How do you distinguish between a physical change and a chemical change? physical change: change in form or appearance o maintains same identity o no new matter is created o properties do not change o can go back o can be separated according to physical properties chemical change: change in identity o create something new o new matter has different properties than matter formed from According to the Law of Conservation of Matter, the mass of substances involved in a chemical reaction cannot be created or destroyed.. The total mass of reactants equals the total mass of products. Atoms are just rearranged, not created or destroyed. Ex: 2KClO3 → 2KCl + 3O2 500g 300g ? If 500 g of KClO3 decomposes and produces 300g of KCl, how many grams of O2 are produced? 500g = 300g + x 200g = x (grams of oxygen produced) Sketch in the appropriate boxes below pictures of molecules, showing their different arrangement when found in solid, liquid and gas phases. solid liquid gas What are the two broad categories of matter? pure substances and mixtures What’s the difference between an element and a compound? element is the simplest form of matter that cannot be broken down further and still maintain the properties of that element compound is two or more DIFFERENT elements chemically combined together What’s the difference between a mixture and a compound? mixture is a physical combination of two or more different types of pure substances compound is a chemical combination of two or more different types of pure substances Explain the difference between homogeneous and heterogeneous mixtures. homogeneous mixture: heterogeneous mixture: uniform composition variable composition transparent/translucent cloudy/opaque individual particles too small to individual particles are big enough scatter light so light passes to scatter light so light does not straight through pass through solutions suspensions (including colloids) Mixtures can be separated according to their physical and chemical properties. Explain how you would separate the following mixtures into their individual components. 1. sand and water 2. sugar and water filtration 1. evaporate/boil off water (bp water much lower than bp of sugar) 2.crystallization 3. mixture of heptane (bp = 98˚C) and heptanol (bp = 176˚C) distillation 4. mixture of sand and iron pellets magnet (iron is magnetic and sand is not) ENERGY The SI unit of energy is called the JOULE. You put a rock in the oven and heat it up. Then you put the rock in a large pail filled with cold water (about 15˚C). You observe the temperature of the water before and after the rock is placed in it. What happens? Why? essentially placing a HOT rock in cooler water; heat always travels from hotter object to colder object so heat travels from rock to water causing the water temp to rise and the temp of the rock to decrease; eventually the temp of the water stops changing indicating the water and the rock are the same temperature. According to the KMT, atoms and molecules are in constant motion. How does temperature affect the movement of particles in a substance? [temperature motion of particles] Increasing temperature causes particles in a substance to move faster, while decreasing the temperature causes the particles to slow down. Energy changes accompany all chemical and physical changes. If energy leaves the “system” we say the energy change is EXOTHERMIC because the system had more energy before the change than after. If energy enters the “system” we say the energy change is ENDOTHERMIC because the system had more energy after the change than before. Identify the following according to their being a physical/chemical change; identify each change as being an endothermic/exothermic change. change burning coal boiling water burning propane in BBQ drying clothes in clothes dryer physical/chem chemical physical exo/endo exo endo chemical exo physical endo change melting ice activation of a light stick evaporation of sweat from skin lg hammering copper into flat sheet physical/chem physical chemical exo/endo endo exo physical endo physical exo: hammer endo: copper A cold pack is placed on your injured leg. Indicate the direction of the flow of energy between your leg and the cold pack. heat travels from leg to cold pack What is the difference between potential and kinetic energy? potential energy (PE) is stored energy of position kinetic energy (KE) is the energy of motion Name the six phase changes and state whether they are endothermic or exothermic. ENDOTHERMIC phase changes sl melting EXOTHERMIC phase changes gl condensation lg vaporization (boiling) ls solidification (freezing) sg sublimation gs deposition Show in the particle diagrams below what happens to the particles as they change phase: need to draw the same number of atoms/molecules in each diagram solid liquid gas Energy changes can be calculated using: Q = mcΔT where: Q = energy m = mass c = specific heat ΔT = change in temperature [ΔT= Tfinal – Tinitial] Solve the following: 1. What quantity of heat would have to be added to 5000g of water to change its temperature from 20˚C to 80˚C? Q = mcΔT = (5000g)(4.18J/gºC)(60ºC) = 1,254,000J 2. How much heat energy is required to raise the temperature of 8.0g of aluminum from 293K to 298K? [specific heat of aluminum is 0.90J/gK] Q = mcΔT = (8g)(0.90J/gK)(5K) = 36J 3. An exothermic reaction releases 800 Joules of heat to a calorimeter containing 40 grams of water. Calculate the temperature change of the water. 800J = mcΔT = (40g)(4.18J/gºC)(ΔT) 4.78ºC = ΔT 4. What is the final temperature when 168 joules of heat is added to 4 grams of water at 283K? 168J = mcΔT = (4g)(4.18J/gK)(ΔT) 10.0K = ΔT 5. ΔT= Tfinal – Tinitial 10.0K = Tf – 283K 293K = Tf 500 gram sample of water loses 1.05 x 104 joules of heat. The temperature of the water, after the heat loss, is found to be 25˚C. What was the initial temperature of the water? Q = mcΔT 1.05 x 104J = (500g)(4.18J/gºC)(ΔT) 5.02ºC = ΔT ΔT= Tfinal – Tinitial 5.02ºC = 25ºC - Ti 30.02ºC = -x -30.02ºC = x