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Clements Chemicals
SAFETY DATA SHEET
BLACK DISINFECTANT
Revision Date: 10 Jul. 03
Date of Printing: 15 Feb. 16
MSDS Revision: 01
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
Product Name:
Product NO:
Use of the substance/preparation:
Supplier:
Telephone:
Black Disinfectant
A065, A066
Disinfectant liquid
William Clements (Chemicals) Ltd
The Old Transport Museum
Witham Street
BELFAST BT4 1HP
(028) 9073 8395
2. COMPOSITION/INFORMATION ON INGREDIENTS
3.
Ingredient Name
Carbolic oil
Cas No
84650-03-3
Contents (%)
5-15
Xylenols, mixed
1300-71-6
0-5
Neutral Oil
Chloroxylenols, mixed
090640-84-9
1321-23-9
5-15
0-5
Health (class)
T
N
T
N
Xi
Xi
N
Risk (R No.)
10,24/25,34,65
51/53
24/25, 34
51/53
36/38
36/37/38, 43
51/53
HAZARDS IDENTIFICATION
Causes burns
Harmful in contact with skin and if swallowed
May cause sensitisation by skin contact
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
4.
FIRST AID MEASURES
Inhalation:
Ingestion:
Skin Contact:
Eye Contact:
5.
Remove to fresh air if affected and obtain medical attention if symptoms persist.
Do not induce vomiting. Provided patient is conscious wash out mouth with water and give water to drink. Obtain medical
attention immediately.
Remove contaminated clothing. Wash skin thoroughly with plenty of running water. Swab with glycerol/meths (70/30%).
Obtain medical attention if irritation persists.
Keeping eye open, immediately irrigate thoroughly with water or eye-wash for 15 minutes. Obtain medical attention.
FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:
Special Fire-Fighting Procedures:
Hazardous Decomposition Products:
6.
Water-spray, foam or dry chemical.
Wear self-contained breathing apparatus in case of large fire. Col fire-exposed surfaces with water-spray.
Non-flammable and not normally a fire risk. Gives off toxic fumes if involved in a fire so avoid breathing
vapors.
ACCIDENTAL RELEASE MEASURES
Spill Cleanup Procedures: Do not discharge into drains or rivers. Contain spillage using bunding. Absorb with sand, earth or granules. Transfer
to a closable, labelled salvage container for disposal, refer to section 13.
7. HANDLING AND STORAGE
Usage Precautions:
Storage Precautions:
Use only in well-ventilated areas, wearing the personnel protection detailed in Section 8. Avoid contact with skin
and eyes.
Store in closed containers in a cool place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits:
Hazardous Ingredient
LTEL
8hr
TWA
STEL
ppm
mg/m3
ppm
mg/m3
At elevated temperatures the occupation exposure standard for naphthalene should be observed:
10
53
15
80
Protective measures:
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Ensure adequate ventilation.
Not normally required
PVC or nitrile gloves
Goggles or face shield
Overalls
Respirators:
Protective Gloves:
Eye Protection:
Other Protection:
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Odour:
pH:
Flash point ○C:
Relative Density (20○C):
Solubility in water:
dark liquid
phenolic
10.1 typical
>65
1.01 typical
miscible
10. STABILITY AND REACTIVITY
Stability:
Conditions to Avoid:
Materials to Avoid:
Hazardous Decomposition Products:
Stable
High temperatures
Natural rubber
None when stored and handled correctly. Toxic vapours given off at high temperatures.
11. TOXICOLOGICAL INFORMATION
Inhalation:
Skin Contact:
Eye Contact:
Ingestion:
Usually no risk from vapours if ventilation is adequate. Harmful vapours are released at high temperatures.
Will cause irritation, possibly burns. Repeated or prolonged contact may lead to dermatitis or toxic effects due to skin
absorption.
Will cause irritation or chemical burns.
Risk of irritation and possibly chemical burns to mouth, gullet and stomach. Toxic effects may result including nausea,
dizziness, stomach pains and collapse.
12. ECOLOGICAL INFORMATION
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Do not release into surface waters.
13. DISPOSAL CONSIDERATIONS
Product:
Packaging:
Dispose of according to national and local authority regulations for special waste via an appropriately licensed waste
contractor.
Dispose of according to national and local authority regulations for special waste via an appropriately licensed waste
contractor
14. TRANSPORT INFORMATION
UN No:
Road Carriage
TREM card No:
ADR/RID Class:
IMDG Class and Packing Group:
Proper Shipping Name:
Marine Pollutant:
Customs Tariff (Harmonised system):
1760
Corrosive liquid
80G20b
Class 8
Class 8 Packing Group III
Corrosive Liquid, N.O.S. (carbolic oil mixture)
Yes (containes carbolic oil)
3808-40-90
15. REGULATORY INFORMATION
Label for Supply:
Risk Phrases:
C
Corrosive
N
Dangerous for the Environment
21/22
34
Harmful in contact with skin and if swallowed
Causes burns
43
51/53
May cause sensitisation by skin contact
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
2
26
36/37/39
45
Keep out of reach of children
Toxic in contact with skin and if swallowed
Wear suitable protective clothing, gloves and eye/face protection
In case of accident or if you feel unwell, seek medical advice immediately
Safety Phrases:
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(show label where possible)
Avoid release to the environment. Refer to special instructions/safety data sheet.
16. OTHER INFORMATION
Text of the R-phrases that are allocated to the ingredients listed in section 2 of this safety data sheet:
R10
R24/25
R34
R36/37/38
R36/38
R43
R51/53
R65
Flammable
Toxic in contact with skin and if swallowed
Causes burns
Irritating to eyes, respiratory system and skin
Irritating to eyes and skin
May cause sensitisation by skin contact
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Harmful: may cause lung damage if swallowed
This Data Sheet was prepared in accordance with directive 91/155/EEC and regulation6 of the Chemicals (Hazard Information and Packaging for
Supply Regulations 1994 or as amended. The information this sheet contains does not constitute on its own the users own assessment of
workplace risk as required by other health and safety legislation eg. HSW ACT COSHH, MHSW Regulations or other
Occupations exposure standards were taken for the current edition of EH40 (UK HSE).
The information given in this safety data sheet is based on knowledge available at the time of completion and is intended to describe the product o