1. Instructor : Dr Mourad Boumaza – Room 2B58, phone 46 79151
2. Catalog Data : (3 Credits – 3 Contact Hours)
3. Course Description : This course deals mainly with advanced thermodynamics as graduate students learn how to apply thermodynamics to phenomena of interest in chemical engineering, with emphasis on phase equilibrium in pure fluid and mixtures, chemical-reaction equilibrium and thermodynamic analysis of process.
4. Textbooks .
J.M.Smith. H.C Van Ness and M.M. Abbott. Introduction to Chemical
Engineering Thermodynamics, McGraw Hill, 5thn edition.
5. References
J.R Elliot and C.T.Lira: Introductory Chemical Engineering Thermodynamics:
Prentice- Hall.
M.Modell and R.C Reid: Chemical Engineering Thermodynamics, Prentice-Hall..
S.I.Sandler: Chemical and Engineering Thermodynamics, Wiley and sons.
B.G Kyle: Chemical and Process Thermodynamics: B.G Kyle, Prentice-Hall.
6. Objectives
The objectives of this course are;
1.
To provide students with tools in applying thermodynamics principles.
2.
To predict physical phenomena and to solve engineering problems.
3.
To teach the students how to use state equations for property calculation.
4.
To define the basic activity coefficient models and how/when to apply them and solve phase equilibria problems for vapor-liquid equilibrium (VLE), liquid-liquid equilibrium (LLE), vapor-liquid-liquid equilibrium (VLLE), solid liquid equilibrium (SLE), and solid-vapor equilibrium (SVE), as well as chemicalreaction equilibrium.
5.
To show how to use thermodynamics principles and concepts for the analysis of chemical processes.
7. Covered Topics
1.
Introduction to Thermodynamics principles. ( 1 ½ class)
2.
Thermodynamics Properties of fluids (2 classes )
Engineering equations of state for PVT properties
Properties relations for homogeneous phases
Residual properties.
3.
Equilibrium and stability in one component system (2 1/2 classes)
Criteria for equilibrium
Fugacity criteria for phase equilibrium
Calculation of fugacity
4.
Thermodynamiques of multi component system. (3 classes)
Introduction to multi component system
Phase equilibrium in mixture by an equation of state
Activity models
Topics in phase equilibrium
Equilibrium in adsorption
5.
Chemical-Reaction equilibria. (2.1/2 classes)
Reaction coordinate
Reaction equilibrium for ideal solutions
Multi reaction equilibria
Complex mixtures
6.
Thermodynamics analysis of Processes (2 classes)
Availability, lost work, and exergy concepts
Power cycle analysis
Mixing and separations processes
8. Class requirement and Evaluation
Homework assignments
Project
1 test in class
Final Exam
9. Assessments and mark scheme
Homework 20%
Tests 30%
Final Exams 50%