TWO-STAGE DIKING AT THE DYING OF THE GALWAY BATHOLITH by Paul Mohr [“Igneous is irruptive, unlooked for and peremptory; sedimentary is steady-keeled, dwelt upon, graduated” (Seamus Heaney)] INTRODUCTION Profuse diking is a feature common to many if not most granite batholiths. In the majority of cases the diking peaked late in the formation of the batholith. That was the case for the Galway Batholith in the West of Ireland. Galway Batholith The Galway Batholith is the westernmost exposed Caledonian batholith on the European side of the Atlantic basin (Fig. 1), It is located immediately north of the Iapetus suture which marks the Laurentia-Avalonia collision line, and south of the allochthonous Connemara terrane (Dalradian crust that was strikeslipped and thrust south of the Highland Boundary Fault some 40 Ma before the intrusion of the batholith). The Galway Batholith is 90 x 35 km in elliptical plan, its long-axis aligned ESE-WNW, oblique to the ENE-WSW Caledonian tectonic trend (Fig. 2). The southern half of the batholith is hidden under Galway Bay and a cover of Carboniferous Limestone strata; Emplacement of the batholith sutured the Ordovician Skerd Rocks Fault, a westerly continuation from the Southern Uplands Fault in Scotland: - to the north of the Fault, the batholith intruded the plutonic roots of a 470 Ma-old island-arc that had been deformed into a metagabbro and granite gneiss complex; - to the south of the Fault, the batholith intruded an Ordovician accretionary prism. Disregarding its satellite plutons, the main batholith comprises an irregular pattern of a spectrum of granodiorites and subordinate granites (Fig. 3). Two major syn-late-intrusive fault zones, Shannawon (SFZ) and Barna (BFZ), divided the batholith into three structural blocks, the central block the more uplifted and thus more deeply unroofed. Fig. 1 - Irish & Scottish Caledonian batholiths Fig. 2 – The Galway Batholith Fig. 3 - The component granites of the main Galway batholith Summary of Intrusive History The Galway Batholith was assembled in two major intrusive episodes (Table 1): 420-400 Ma - emplacement of the bulk of the granodiorite plutons/sheets, ending with highlevel microgranitic sills; 385-380 Ma - high-level tabular alkali granite intrusions. Diking followed each of the two plutonic episodes: 1. Richly quartz-pllagioclase-microphyric dacite dikes, zircon dated at 405-400 Ma; 2. Composite dolerite-rhyolite dikes, dated at ca. 375 Ma. Table 1 – Galway pluton and dike age-ranges MAJOR EVENTS IN THE LIFE OF THE GALWAY BATHOLITH LIFE I 420 – 400 Ma 405 – 400 Ma LIFE II 385 – 380 Ma ca. 375 Ma Assemblage of perhaps 90% by volume of the batholith: axial granodiorite magma was charged with abundant enclaves/dikes of appinite (hydrous diorite). Uplift, faulting and unroofing of the batholith late in this period. Diking by richly q-pl-microphyric dacitic /granodioritic magmas. Local intrusion of high-level tabular granites, typically alkali granites. Diking by coeval dolerite and subordinate rhyolitic magmas. [dates courtesy of Dr. Martin Feely and colleagues] THE DACITE DIKING (The Earlier Dike Suite) At the end of the first and most active episode of batholith formation, structural relaxation perpendicular to the batholithic long-axis produced numerous N- to NE-trending fissure zones cutting the batholith (Fig. 4). Dike Fissures Fissures were concentrated into sets (fissure numbers were too small to perhaps warrant the term swarms), each set comprising up to 13 closely spaced and parallel fissures; Fissure widths ranged 10 to 50 m. Maximum crustal extension across any set was 30%. Granodioritic magma ascended the fissures, carrying abundant microphenocrysts of Na- plagioclase, K-feldspar, quartz and biotite – the liquid then crystallising to alkali feldspar and biotite (see Mohr 2003 for detailed mineralogy). Fig. 4 - Dacite dike zones in the Galway batholith. (The AGG and SCB dike sets are highlighted in yellow) The Ard Mhóir-Gabhla-An Gharmain (AGG) dike set The prominent AGG dike set is situated in the western block of the Batholith (Fig. 4), (n.b. The dense but only briefly exposed Salthill (SCB) dike set in the eastern block is now buried under an explosively expanding Galway City!) The AGG dikes can be traced 20 km north from the batholith axis, across the northern exposed half of the batholith and on through the 70 Ma-older gneissic envelope (Figs. 4 and 5). The number and widths of AGG dikes decrease northwards. The AGG dikeset was no sooner emplaced than it was subjected to dextral displacements along a grid of ENE-WSW oblique-slip faults (Fig. 5), the initial movement on which overlapped with the terminal dike irruptions. Fig. 5 - The AGG dike set, showing its individual dikes (simplified) and the ENE-trending faults that displaced it soon after emplacement. (The individual sectors between the faults are named) Geochemistry Compared with the four major granitoid lithologies comprising the batholith, dike dacite most closely matches the predominating megacrystic granodiorite in its geochemistry: In both suites, SiO2 = 67 3% . Figure 6 confirms close similarities in the abundances of FeO, MgO, Ni, TiO2 and most trace elements (green = dacite, red = megacrystic granodiorite). Significant differences are restricted to the mobile elements: notably, K and Rb are reduced in dacite cf. granodiorite, although K/Rb remains almost identical. Low Nb (c.15 ppm) and high Ba/La values for the dacites are typical of subduction-related silicic magmas. Fig. 6 - Dacite geochemistry compared with that of the major granitoids of the Galway batholith There is a further, both singular and striking geochemical feature of the AGG dikes (Fig. 7): Fig. 7 - along-strike AGG geochemistry (see Fig. 5 for map) Dike geochemistry (& mineralogy) reveals a progressive increase in maficity away from the batholith axis. This lateral progression, from rhyodacite through dacite and micromonzonite to trachyandesite, is undeflected where it crosses the batholith margin. From this it would appear that the contrasting contaminations to be expected from granitic cf. amphibolitic inputs have not operated significantly in the AGG dikes. An alternative possibility, that of magma mixing, would require an unexposed mafic body in the north. If such a body exists, one could speculate that the rise of mafic magma here followed from an easier path of ascent outside of the zone of contemporary granitoid plutonism. Such mafic magma is envisaged to have had the appinitic (water-rich dioritic) composition of the near-coeval enclaves in the axial granodiorite of the batholith. Indeed, small such enclaves are present in the root zone of the Spiddal dacite dike, deeply exposed in the central block of the batholith (Fig. 4). A third possibility is that crystal fractionation in a single dacitic magma progressed northward as the magma moved with a lateral component out from the batholith axis. This however would be contrary to the flow direction well displayed in an AGG dike at An Maoileann (Fig. 8). Fig. 8 - successive flows in the AGG dike at An Maoileann (the batholith axis lies southward to the right. ‘mg’ = countryrock microgranite) The indicators of flow direction here reveal a horizontal component directed southward toward the batholith axis. How to reconcile this flow with the diminishment of diking intensity northward is not yet answered, but the possibility of local convective cells in the cooling dike requires further field examination. Tectonics The cross section provided in Figure 9 shows three profiles: 1. the original roof of batholith, after displacement by major syn-plutonic faulting (dashed line); 2. the topographic surface at the time of diking and presumed coeval volcanism (solid line); 3. the present topography can be represented by a roughly horizontal line through the subvolcanic magma chambers (shown as high-level sills). The dacite dike sets in the batholith dip steeply in toward the N-S short-axis of the batholith, as though toward a central magmatic focus. The AGG & SCB dike sets each face a complementary normal fault-zone. The resulting downward-converging dips have the form of an asymmetric graben. Such graben associated with diking have been described from other batholiths, for example from mid-Eocene Washington State, U.S.A. Fig. 9 - Batholith long-axis cross-section at the time of diking (SFZ = Shannawon Fault Zone, BFZ = Barna Fault Zone, MFZ = Maam Fault zone) THE COMPOSITE DIKING (The Later Dike Suite) The 2nd diking episode followed the 2nd plutonic phase in the building of the Galway batholith. It provided the final Caledonide igneous activity in the West of Ireland. Fig. 10 - Dolerite and composite dikes in the Galway batholith and its envelope. The major dikes are named (‘NA hU’ = na hUilíInní). TD = Teach Dóite (Maam Cross). Dolerite dikes are indicated in green; red termini signify that rhyolite members occur in the dike thus marked. Pattern of composite diking The Mid-Devonian, second episode of fissuring in Connemara had a wider extent and a greater freedom from batholithic structural control than did the earlier, dacite diking episode (Fig. 10). Notable in this regard, however, is the northern barrier to the fissuring provided by the Connemara Dalradian crustal terrane. Single fissures, not associated in sets (cf. the dacite dikes), were subject to one of three structural controls: 1. NNE trend: along now-extinct normal-fault zones active during the evolution of the batholith; 2. ENE trend: along oblique-slip fault zones initiated during the waning of the 1st dike episode, and movement ending during this 2nd dike episode; 3. ESE trend: conformable in 3-D with the steep southern limb of the folded Connemara Dalradian rocks. Basaltic magma then took advantage of these three fissure trends. Mineralogical summary (see Mohr 2004 for detailed mineralogic descriptions) Dolerite: labradorite and augite (non-ophitic), subsequently hydrated in a greenschist-grade metamorphism with some associated iron-enrichment. Rare serpentinised olivine crystals are present in only a few samples. Rhyolite: felsitic groundmass carries abundant resorbed quartz and albite microphenocrysts. Some rhyolites evidence incomplete mixing of two magmatic inputs. Mingled and mixed hybrid rocks have xenocrysts that circulated across the magmatic interphase layer, and occasionally back again. There is a wide spectrum of mineralogy among the rhyolites that attests to contamination from an iron-rich source, and this is confirmed in the geochemistry (see below). Table 2 - mean dolerite and rhyolite dike chemistries Geochemistry The basaltic magma had a MORB tholeiitic composition (Table 2), expressed in mean K2O = 0.25%. Dolerite samples from composite dike sectors show evident contamination (cf. from simple dolerite dikes), revealed in significantly higher K2O and Rb contents. The rhyolite magma was a high silica (76% SiO2), low-CaO (0.1%), low ITE melt, the composition of which cannot be derived from any exposed batholithic rock by crystal fractionation of granitoid phases. Fig. 11 - Hybridisation among rhyolite components of nine widely distributed Galway composite dikes. (The Rosmuc rhyolite plot, ‘rm’, is highlighted in red) Hybridisation of rhyolite magma by coeval basalt magma is confirmed in linear two-element plots from nine widely distributed rhyolite samples (Fig. 11). Rosmuc rhyolite provides the least contaminated end-member in all plots. An unexpected feature of the composite dikes is a sympathetic relationship of dolerite and rhyolite geochemistry according to the nature of the countryrock (Table 3), following from the geographical partitioning of the Connemara crust generated by the intrusion of the batholith. Table 3 - dolerite and rhyolite share common geochemical fingerprints Comparative geochemistry of composite-dike lithologies from within and outside the Galway Batholith Dolerite emplaced within cf. outside the batholith: higher Mg, Li, (?Na) lower K, Nb, Y, Zr (?Ti, V) Rhyolite emplaced within cf. outside the batholith: higher Mg, Li, (?Co, Sc, Sr, V, Zn) lower K, Nb, Y, Zr, (?Ce, Cr, La, Ni) [In each case, elements are listed in their order of decreasing differential] Comparing the chemistry of dolerite and rhyolite from outside the batholith with dolerite and rhyolite from inside the batholith reveals almost identical distinguishing fingerprints for the two lithologies (Table 3). How might this be? Accepting the hypothesis that the rhyolites had an anatectic origin (see argument in Mohr 2004), then it can be relevant that restitic lower crust under Ordovician island-arc Connemara had been made even more refractory where the massive Galway Batholith had most recently been sourced. A refractory nature for the rhyolite magma source is consistent with higher Mg and Li in the magma batches generated under and passing up through through the bathollith. The same argument is supported by lower abundances of K and polyvalent elements (sourced from remnant fusible components in restitic crust) in the intrabatholith dike magmas. But why might this rhyolite geochemical division be shared by that of companion dolerite? The geochemical 'fingerprints' common to dolerite and rhyolite, according to whether emplaced inside or outside the batholith, are considered to express three factors linked in succession: 1. ponding of basaltic magma in the lower crust; 2. partial melting of this crust, made more restitic under the batholith, yielded restricted batches of silicic melt; 3. mutual contamination of locally aggregated rhyolitic magma with basaltic magma ascending together up common fissures, leading to the shared geochemical signatures. Mafic magma sources under Caledonian Connemara The remnant subducting slab from the final closure of the Iapetus Ocean supplied mafic magma that penetrated the Connemara crust during two episodes: 1. water-rich appinitic magmas rose from the still-dehydrating slab during the period of batholithic plutonism which they likely facilitated; 2. at the end of that first, 40 Ma-long episode, MORB-type basaltic magma generation then replaced the appinitic magmatism from a now dehydrated slab remnant. SUMMARY Two episodes of diking during the dying of the Galway Batholith expressed two late episodes of upper crustal fissuring and magmatic ascent: 1. N-NE crustal fissuring occurred in response to stress relaxation in the cooling batholith. Residual granodioritic magma residing below the newly emplaced batholith then rose to supply the dacite dikes. Meanwhile, mantle-derived magma reaching up in small volume outside the active batholith that it was fostering, provided a mixing component into the more active and extensive of these dikes. 2. Late regional extension throughout Connemara produced isolated fissuring along preexisting lines of crustal weakness. The batholithic magmatism now extinct, mantle magmas rose with equal ease through the rigid batholith and its envelope, remelting restitic crust en-route and so producing high-level composite dolerite-rhyolite dikes. Acknowledgments Dr. Sadhbh Baxter kindly aided with the provision of Figures 1-3. Dr. Martin Feely gave generous encouragement in facilitating the presentation of this paper to the GSA 2007 Northeastern Section Meeting in Durham, N.H. n.b. detailed accounts of the Caledonian Connemara dikes are to be found in: Mohr, P. 2003. Late magmatism of the Galway Granite batholith: I. Dacite dikes. Irish Journal of Earth Sciences 21, 71-104. Mohr, P. 2004. Late magmatism of the Galway Granite batholith: II. Composite dolerite-rhyolite dikes. Irish Journal of Earth Sciences 22, 15-32.