Section 1 - Guardian Protective Coatings

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Material Safety
Data Sheet
PRODUCT IDENTIFICATION
Product Name:
Campoxy SFE600 Part B
Synonyms:
Campoxy SFE600 Hardener
Recommended Use:
Curing agent for Campoxy SFE600 Part A(s)
Supplier Information:
Cameleon Coatings
26 Paramount Drive
Wangara WA 6065
Phone (08) 9302 2577
www.cameleon.com.au
Emergency Phone: 0413 610 147 (24 hours)
HAZARD IDENTIFICATION
Hazard Classification:
DANGEROUS according to the criteria of the ADG code
HAZARDOUS according to the criteria of Safe Work Australia
Risk Phrase(s):
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R34
Causes burns
R41
Risk of serious eye damage
R43
May cause sensitization by skin contact.
R51/53
Toxic to aquatic organisms, may cause long term adverse
effects in the aquatic environment
R67
Vapours may cause drowsiness and dizziness
Safety Phrase(s)
S1
S23
S26
S28
water
S36/37/39
Keep locked up
Do not breath vapour /spray
In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice
After contact with skin, wash immediately with plenty of
Wear suitable protective clothing, gloves and eye/face
protection
In case of insufficient ventilation, wear suitable respiratory
S38
equipment
S45
In case of accident or if you feel unwell, contact a doctor
or Poisons Information Centre (show label where possible)
COMPOSITION
Ingredient
CAS Number
Proportion
Benzyl Alcohol
100-51-6
HIGH
4,4’-Methylenebis(cyclohexylamine)
1761-71-3
HIGH
Proportion (% weight per weight)
VHIGH >60%, HIGH 30-60%, MED 10-29%, LOW 1-9%, VLOW <1%
All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS)
Product Name:
Campoxy SFE600 Part B
Issued: May 2014
Version: 1.04
Page 1 of 5
Material Safety
Data Sheet
FIRST AID MEASURES
Poisons Information Centres in each State capital city can provide additional assistance for scheduled poisons.
Ingestion: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Prevent
aspiration of vomit. Rinse mouth thoroughly with water and contact a Poisons Information Centre. Urgent
hospital treatment is likely to be needed.
Eye Contact: Immediately irrigate with copious quantities of water for at least 1 hour with eyelids held open.
Take care not to rinse contaminated water into the unaffected eye or onto the face. Seek medical advice. Take
special care if the person is wearing contact lenses.
Skin Contact: Immediately wash contaminated skin with lukewarm, gently flowing water for at least 1 hour. DO
NOT INTERRUPT FLUSHING. Remove contaminated clothing and wash before re-use. Destroy contaminated
leather apparel. Strongly basic ingredients tend to penetrate the skin and so need longer rinsing than other
substances. Seek Medical Attention.
Inhalation: If breathing has stopped or is laboured, give assisted respiration. Supplemental oxygen may be
indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately.
Move to fresh air.
Most important symptoms/effect, acute and delayed: Aggravated medical conditions: Eye disease, skin
disorders and allergies. Asthma. Neurological disorders. Liver disorders.
FIRE FIGHTING MEASURES
Specific Hazards:
May generate toxic, irritating or flammable combustion products. Contact of liquid with skin must be prevented.
Sudden reaction and fire may result if product is mixed with an oxidising agent. Incomplete combustion may
form carbon monoxide. May generate ammonia gas. May generate toxic nitrogen oxide gases.
Fire Fighting Advice:
On burning this product may emit toxic nitrogen oxide gases. May generate ammonia gas. Personnel in vicinity
and down-wind should be evacuated. Fire fighters to wear self-contained breathing apparatus, butyl rubber
boots, gloves, and body suit if risk of exposure to vapour or decomposition products.
Suitable Extinguishing Media:
Alcohol-resistant foam, carbon dioxide, dry chemical, dry sand, limestone powder
ACCIDENTAL RELEASE MEASURES
Clear area of all unprotected personnel. Remove all possible sources of ignition.
Product is slippery when spilt. Avoid accidents and clean up immediately.
Wear protective equipment to prevent skin, eye contamination or inhalation of vapours. Use self-contained
breathing apparatus and chemical protective clothing. Evacuate personnel to safe areas,
Contain immediately – prevent run-off into drains and waterways. Use absorbent (soil, sand, or other inert
material). Collect and seal in properly labelled containers for disposal per local regulations. If contamination of
sewers or waterways has occurred advise the local emergency services.
Product Name:
Campoxy SFE600 Part B
Issued: May 2014
Version: 1.04
Page 2 of 5
Material Safety
Data Sheet
HANDLING AND STORAGE
Storage:
Store in a cool, dry, well ventilated area. Keep away from acids and oxidisers. Do not store in reactive steel
containers.
This material is Harmful and a Scheduled Poison S5. It must be stored, maintained and used in accordance
with relevant regulations. Use only in well ventilated areas. Avoid breathing vapours and aerosols. Avoid
contact with skin and eyes. Use personal protective equipment. When using, do not eat, drink or smoke.
EXPOSURE CONTROLS / PERSONAL PROTECTION
National Exposure Limits.
No exposure standards have been set for this product or constituents
Engineering Controls: Ensure adequate ventilation; keep containers closed when not in use.
Personal Protective Equipment: Overalls, Safety Shoes, Chemical Goggles, and Gloves.
Avoid skin and eye contact, and inhalation of vapour. Wear overalls, chemical goggles and impervious gloves.
Uses with adequate ventilation – if inhalation risk exists then wear an organic vapour / particulate respirator
meeting the requirements of AS/NZS 1715 and AS/NZS 1716.
Always wash hands before smoking, eating, drinking, or using the toilet. Wash contaminated clothing and other
protective equipment before storage or re-use.
PHYSICAL PROPERTIES
Appearance:
Colourless mobile liquid
Solubility:
<1%
Odour:
Ammoniacal
Density @ 20°C:
1.03 kg/lt
pH:
Alkaline
Flash point & Method:
Vapour Pressure 20°C (mm Hg):
<10.34
Upper Explosive Limit (UEL):
NAV
NAV
Lower Explosive Limit (LEL):
NAV
Ignition Temperature °C:
NAV
Vapour Density (Air = 1)
Initial Boiling Point °C:
~207°C
Freezing Point °C:
NAV
~112°C (Abel)
Percent Volatiles (by weight):
0%
NAP = Not Applicable, NAV = Not Available
STABILITY AND REACTIVITY
Stability: Product is stable; however, avoid contact with acids, oxidising agents, reactive metals, Sodium or
Calcium Hypochlorite. Product will slowly corrode copper, aluminium, zinc and galvanised surfaces. Reactive
with hydroxyl compounds.
Hazardous Decomposition Products: Nitrogen Oxide can react with water vapours to form corrosive nitric
acid. Oxides of carbon and nitrogen in a fire. Ammonia when heated. Irritating and toxic fumes at elevated
temperatures. Nitric acid in a fire. Aldehydes. The oxides of nitrogen gases (except nitrous oxide) emitted on
decomposition are highly toxic. Reaction with peroxides may result in violent decomposition of peroxide
possibly creating an explosion.
Product Name:
Campoxy SFE600 Part B
Issued: May 2014
Version: 1.04
Page 3 of 5
Material Safety
Data Sheet
TOXICOLOGICAL INFORMATION
Main Symptoms: No adverse health effects are expected if the product is handled in accordance with this
Material Safety Datasheet, and the product label. Symptoms that may arise if this product is mishandled are:
Ingestion: Swallowing can result in severe burns of the mouth and throat, as well as danger of perforation of
the stomach and oesophagus. If the victim is uncoordinated, there is a greater likelihood of vomit entering the
lungs and causing serious complications.
Eye Contact: Product vapour in low concentrations can cause lacrimation, conjunctivitis, and corneal edema
when absorbed into the tissue of the eye from the atmosphere. Burns of the eye may cause blindness.
Skin Contact: Causes skin burns. Product is absorbed through the skin and may cause nausea, headache,
dizziness, confusion, breathing difficulties.
Inhalation: Harmful if inhaled and may cause delayed lung injury. Risk of serious damage to the lungs by
inhalation. Inhalation of aerosol may cause irritation to the upper respiratory tract. May cause central nervous
system effects such as headache, nausea, dizziness, confusion, breathing difficulties. Severe cases of
overexposure can result in respiratory failure.
Long Term Effects: Un-protected repeated and/or prolonged exposure may cause allergic
reaction/sensitization. Repeated and/or prolonged exposure may result in: adverse respiratory effects (such as
cough, tightness of chest or shortness of breath); adverse skin effects (such as defatting, rash or irritation).
Effects from inhalation of vapours may be delayed. Dryness of nasal passages may be experienced when
material is inhaled over a long period of time. Repeated and/or prolonged exposure to low concentrations of
vapour may cause sore throat (which is transient).
Acute Toxicity / Chronic Toxicity:
Oral LD50(Rat):
>2000 mg/kg
Dermal LD50(Rabbit): >2110 mg/kg
ECOLOGICAL INFORMATION
Toxic to aquatic organisms. May cause long term adverse effects in the aquatic environment
DISPOSAL CONSIDERATIONS
This product may be recycled if unused, or if it has been contaminated it may be possible to separate the
contamination in some way. Only if neither of these options is suitable, consider landfill, but we recommend that
the product be neutralised in a controlled manner before disposal. Disposal of empty paint containers via
domestic recycling programs may differ between local authorities. Check with your local council first.
TRANSPORT INFORMATION
Classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for
transport by road or rail.
UN Number:
3066
HAZCHEM:
2X
UN Proper Shipping Name:
PAINT RELATED
MATERIAL
Packaging Group:
III
Class and Sub Risk:
8 Corrosive
Product Name:
Campoxy SFE600 Part B
Issued: May 2014
Version: 1.04
Page 4 of 5
Material Safety
Data Sheet
REGULATORY INFORMATION
Hazardous according to Worksafe Australia. Hazard Category:
Hazard Category: Harmful, corrosive, Dangerous for the environment
C
Corrosive
R-phrase(s):
R20/21/22
R34
R41
R43
R51/53
R67
Harmful by inhalation, in contact with skin and if swallowed
Causes burns
Risk of serious eye damage
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment
Vapours may cause drowsiness and dizziness
S- phrase(s):
S1
Keep locked up
S23
Do not breath vapour /spray
S26
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28
After contact with skin, wash immediately with plenty of water
S36/37/39
Wear suitable protective clothing, gloves and eye/face protection
S38
In case of insufficient ventilation, wear suitable respiratory equipment
S45
In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre (show
label where possible)
Poison Schedule : S5
OTHER INFORMATION
Literary References:
(1) IMCD MSDS issued April 2012
General:
Material Safety Data Sheets are updated frequently. Please ensure that you have a current copy.
This MSDS summarises at the date of issue our best knowledge of the health and safety hazard information of
the product, and in particular, how to safely handle and use the product in the work-place.
Since Cameleon Coatings cannot anticipate or control the conditions under which this product may be used or
handled, each user must, prior to using or handling this product, review this MSDS in the context of how the
user intends to handle and use the product in the workplace.
If clarification or further information is required to ensure that an appropriate assessment can be made, the user
should contact this company.
Our responsibility for product as sold is subject to our standard terms and conditions, a copy of which is sent to
our customers, and is also available from the company upon request.
Product Name:
Campoxy SFE600 Part B
Issued: May 2014
Version: 1.04
Page 5 of 5
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