1
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
MATERIAL SAFETY DATA
SHEET(MSDS)
SECTION 1:
CHEMICAL PRODUCT AND COMPANYIDENTIFICATION
PRODUCT NAME: POTASSIUM PERMANGANATE
PRODUCER: CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADDRESS: NO 242 DIANCECUN JIANGBEI CHONGQING CHINA
POSTCODE: 400020
E-MAIL: liu.qianqian@jialingchemical.com
TEL: 0086-23-67957983
FAX: 0086-23-67959523
TECHNICAL INSTRUCTIONS CODE NO: JHQS/JS-37-2002
SECTION 2:
COMPOSITION/INFORMATION ON INGREDIENTS
PURE □
MIXTURE □
PRODUCT NAME: POTASSIUM PERMANGANATE
HAZARDOUS COMPOSITION
CONTENTS
POTASSIUM PERMANGANATE
≥99.0%
SECTION 3:
HAZARDS IDENTIFICATION
CAS NO
7439-96-5
2
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
HAZARD CLASSIFICATION: CLASS 5.1 OXIDIZING AGENT
POSSIBLE WAYS OF EXPOSURE: INHALATION, PERORAL INGESTION,
TRANSCUTANEOUS INGESTION
HEALTH HAZARDS: CASUAL INGESTION MAY CAUSE POISONING AND
CORRODE THE MOUTH, THROAT AND DIGESTIVE TRACT. TAKEN ORALLY
AT 1% CONCENTRATION, ITS SOLUTION MAY CAUSE A BURNING SENSE IN
THE MOUTH, VOMITING, NAUSEA AND PAIN IN THE UPPER ABDOMEN; AT
2-3% IT MAY CAUSE SWELLING IN THE MOUTH AND THROAT AND
DIFFICULTY IN TALKING AND SWALLOWING, WHILE AT 4-5% OR WHEN
TAKEN ORALLY AFTER DISSOLVING POTASSIUM PERMANGANATE
CRYSTALS IN WATER, IT MAY TURN THE MUCOSA OF THE MOUTH AND
LIPS BROWN-BLACK AND CAUSE ITS SWELLING AND EROSION, ACUTE
PAIN IN THE ABDOMEN, VOMITING, BLOOD IN STOOL AND SHOCK,
LEADING TO DEATH RESULTING FROM CIRCULATION FAILURE. IN THE
POWDERED FORM THE PRODUCT MAY IRRITATE THE EYES. ITS DILUTE
SOLUTION IS IRRITATING TO THE SKIN, WHILE CONCENTRATED
SOLUTION IS CORROSIVE AND MAY DEGRADE THE SKIN OR MUCOSA.
ENVIRONMENTAL HAZARDS: NO DATA AVAILABLE.
EXPLOSION HAZARDS: MAY EXPLODE WHEN COMING INTO CONTACT
WITH CONCENTRATED SULPHURIC ACID, AMMONIUM SALTS, PEROXIDES,
ETHANOL, ETHER, SULPHUR OR PHOSPHOR. MIXING WITH ORGANIC
MATTERS, SULPHUR, PHOSPHOR, CARBON, REDUCING AGENTS OR
INFLAMMABLES IN ACIDIC MEDIA MAY CAUSE STRONG REACTION,
IGNITION OR EVEN EXPLOSION.
SECTION 4:
FIRST AID MEASURES
SKIN CONTACT: TAKE OFF CLOTHES, RINSE IMMEDIATELY WITH PLENTY
OF WATER, THEN WASH THE AFFECTED AREAS WITH OXALIC ACID
SOLUTION.
EYE CONTACT: OPEN THE UPPER AND LOWER EYELIDS IMMEDIATELY
3
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
AND RINSE WITH FLOWING CLEAN WATER FOR AT LEAST 15 MINUTES.
SEEK MEDICAL ATTENTION.
IN HALATION: LEAVE THE SITE IMMEDIATELY FOR A WELL VENTILATED
PLACE. HAVE A GOOD REST AND TAKE WARMING MEASURES. SEEK
MEDICAL ATTENTION.
INGESTION: RINSE THE MOUTH AND TAKE MEASURES TO CAUSE
VOMITING IMMEDIATELY GO TO HOSPITAL FOR MEDICAL ATTENTION.
SECTION 5:
FIRE-FIGHTING MEASURES
FIRE HAZARDS: THE PRODUCT IS A STRONG OXIDIZING AGENT, AND
WILL BE DECOMPOSED TO RELEASE OXYGEN AT 200 ℃ . WHEN IN
CONTACT WITH REDUCING AGENTS OR ORGANIC MATTERS, ITS
SOLUTION WILL RELEASE ACTIVE OXYGEN[O], A STRONG
COMBUSTION-SUPPORTING AGENT. CONTACT WITH ORGANIC MATTERS
OR ROBBING OR IMPACTS MAY CAUSE IT TO BURN. MIXING WITH
GLYCERINE MAY LEAD TO AUTOIGNITION. WHEN A FIRE BREAKS OUT
WITH INFLAMMABLES IT MAY BOOST COMBUSTION.
HAZARDOUS COMBUSTION PRODUCTS: NONE.
EXTINGUISHING MEDIA: WATER OR SAND
SECTION 6:
ACCIDENTAL RELEASE MEASURES
REMOVE ANY LEAKAGE FROM THE FLOOR IMMEDIATELY, THEN RINSE
WITH WATER AND WIPE CLEAN WITH A WET CLOTH. USE PLASTIC TOOLS
INSTEAD OF METAL ONES FOR REMOVING LITTERINGS FROM THE FLOOR.
WIPE THE SURFACES OF CONTAINERS CLEAN WITH A WET CLOTH.
CONTAMINATED WATER SHOULD BE DISCHARGED INTO WASTE-WATER
TREATMENT SYSTEM AFTER BEING DILUTED. FOR INDIVIDUALS WHO
GET CONTAMINATED WITH THE PRODUCT, RINSE IMMEDIATELY WITH
4
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
PLENTY OF WATER, THEN WASH THE AFFECTED AREA WITH OXALIC
ACID SOLUTION, THOSE WHO BREATHE IN THE PRODUCT IN POWDERED
FORM SHOULD LEAVE THE SITE IMMEDIATELY FOR A WELL-VENTILATED
PLACE, HAVE A REST AND TAKE WARMING MEASURES.
SECTION 7:
HANDLING AND STORAGE
HANDLING:
THE
PRODUCT
SHOULD
BE
HANDLED
IN
A
WELL-VENTILATED PLACE WHICH IS AWAY FROM ANY FIRE OR HEAT
SOURCES. OPERATING PERSONNEL SHOULD WEAR DUST GAUZE MASK
AND PROTECTIVE GLASSES AND GLOVES.
STORAGE: STORE IN A COOL, VENTILATED AND DRY WAREHOUSE, AT AN
INDOOR TEMPERATURE BELOW 32℃. KEEP AWAY FROM ANY FIRE OR
HEAT SOURCES OR DIRECT SUNLIGHT. AVOID BEING RAINED OR
GETTING DAMP. AVOID BEING STORED IN A PLACE WHERE ORGANIC
MATTERS, GLYCERINE, STRONG ACIDS, CHLORATES, NUTRATES,
PEROXIDES, INFLAMMABLES, REDUCING AGENTS, AMMONIUM SALTS OR
ANY OTHER OXIDIZING AGENTS ARE STORED. DO NOT STORE IT
DIRECTLY ON THE FLOOR. AVOID IMPACTS, SHOCKS OR RUBBING
DURING HANDLING OPERATIONS. GENTLE HANDLING IS REQUIRED TO
PROTECT PACKAGING FROM BREAKAGE OR DAMAGE. DO NOT USE
MACHINERY OR TOOLING WHICH MAY PRODUCE SPARKS.
SECTION 8:
EXPOSURE CONTROLS/PERSONAL PROTECTION
MAXIMUM ALLOWABLE CONCENTRATION: [CHINA] MAC 0.2mg／M3(ON A
Mn BASIS)
MONITORING METHOD: REDOX METHOD
ENGINEERING CONTROL: SUITABLE VENTILATION EQUIPMENT SHOULD
BE INSTALLED IN A CLOSE PRODUCTION PROCESS.
5
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
RESPIRATORY SYSTEM PROTECTION: WEAR DUST GAUZE MUSK IN THE
OPERATING AREA. OXYGEN BREATHING APPARATUS WILL BE NEEDED IN
EMERGENCY RESCUE OR EVACUATION.
EYE PROTECTION: WEAR CHEMICAL SAFETY GLASSES.
BODY PROTECTION: WEAR ORDINARY ANTI-TOXIC PROTECTIVE
CLOTHES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE：DEEP- PURPLE GRANULAR OR ACICULAR CRYSTAL WITH A
METALLIC LUSTER. WATER SOLUTION IS DEEP-PURPLE
TASTE: SWEET AND PUCKERY
PH VALUE: ITS SOLUTION IS STRONGLY ALKALINE
MELTING POINT: DECOMPOSED WHEN HEATED TO 200℃
RELATIVE DENSITY： 2.7（WATER=1）
BOILING POINT：N/A
RELATIVE VAPOUR DENSITY：NO DATA
OCTYL ALCOHOL/WATER DISTRIBUTION FACTOR：NO DATA
FLASHING POING（℃）：NO DATA
IGNITION TEMPERATURE；NO DATA
UPPER EXPLOSION LIMIT； NO DATA]
LOWER EXPLOSION LIMIT：NO DATA
SOLUBILITY: EASILY SOLUBLE IN WATER AND MARGINALLY SOLUBLE IN
METHANOL, ICE ACETIC ACID, ACETONE AND SULPHURIC ACID. MAIN
APPLICATIONS: WIDELY USED IN INDUSTRIES SUCH AS CHEMICALS,
PHARMACENTICALS, FOOD PROCESSING, WATER TREATMENT AND
ANIMAL FARMING AS OXIDIZING AGENT, BLEACHER, BACTERICIDE,
ODOL SUPRESSOR, DETOXIFIER, IRON REMOVER, METAL COLOURING
AGENT, OZONE REMOVER, ETC.
6
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
SECTION 10
STABILITY AND REACTIVITY
STABILITY: STABLE UNDER NORMAL CONDITIONS OF USE
IMCOMPATIBILITY: ORGANIC MATTERS, CONCENTRATED SULPHURIC
ACID, GLYCERINE, CHLORATES, NUTRATES, PEROXIDES, AMMONIUM
SALTS, REDUCING AGENTS AND INFLAMMABLES.
CONDITIONS WHICH THE PRODUCT SHOULD BE KEPT AWAY FROM: OPEN
FLAMES, HEAT, SUNLIGHT, SHOCK, RUBBING: IMPACT, ETC.
AGGREGATION HAZARDS: NONE
DECOMPOSITION PRODUCTS: MnO2, O2, K2O
SECTION 11
TOXICOLOGICAL INFORMATION
ACUTE TOXICITY DATA: ORL-RAT LD50＞1090mg/kg;
HYPODERMIC-MOUSE: LD50 500mg/kg
IRRITATIVENESS: NO DATA
OTHER INFORMATION: LETHAL DOSE FOR DEATH DUE TO POISONING
AND CORROSION CAUSED BY CASUAL INGESTION: 5-19g
SECTION 12
ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: UNKNOWN
BIODEGRADABILITY : NO DATA
NON-BIODEGRADABILITY: NO DATA
7
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
SECTION 13
DISPOSAL CONSIDERATIONS
TYPE OF WASTE MATERIAL: HAZARDOUS WASTE MATERIAL
INDUSTRIAL SOLID WASTE
WASTE DISPOSAL METHOD: DISSOLVE IN PLENTY OF WATER ADD
SUFFICIENT AMOUNTS OF OXALIC ACID UNTIL THE SOLUTION TURNS
COLOURLESS, THEN DILUTE WITH WATER BEFORE DISCHARGING.
WASTE DISPOSAL INSTRUCTIONS: OPERATING PERSONNEL SHOULD
WEAR PROTECTIVE GLOVES AND CLOTHES.
SECTION 14
TRANSPORT INFORMATION
HAZARDOUS CARGO CLASIFICATION CALSS: 5.1
51048
UN NO: 1490
PACKING MARK: OXIDIZING AGENT
PACKING CLASSIFICATION: Ⅱ
PACKING : PE BAGS IN FULLY-OPEN IRON-MADE DRUMS WHICH ARE
TIGHTENED BY HOOPS AT THE DRUM OPENING
TRANSPORT INSTRUCTIONS: HANDLE GENTLY, AND AVOID IMPACTS,
SHOCKS OR RUBBING. KEEP AWAY FROM RAIN AND DIRECT SUNLIGHT.
DO NOT ROLL PACKING DURMS ON THE FLOOR. COMBINED TRANSPORT
OF THE PRODUCT WITH ORGANIC MATTERS, REDUCING AGENTS OR
OTHER OXIDIZING AGENTS IS FORBIDDEN.
SECTION 15
REGULATORY INFORMATION
HAZARDOUS CHEMICALS CONTROL REGULATIONS (ISSUED BY THE
CHINESE STATE COUNCIL ON FEB.17, 1987) CONTAINS COMPLETE
8
重庆嘉陵化学制品有限公司
CHONGQING JIALING CHEMICAL PRODUCTS LTD
ADD：NO.151 DONGJIAXI JIANGBEI
CHONGQING,P.R.CHINA
E-mail: liu.qianqian@jialingchemical.com
TEL:86-23-67957983
FAX:86-23-67959523
INSTRUCTIONS FOR ENSURING SAFETY IN THE PRODUCTION, USE,
TRANSPORTATION AND HANDLING OF HAZARDOUS CHEMICALS.
FIRE CONTROL RULES FOR INFLAMMABLE AND EXPLOSIVE CHEMICALS
(ISSUED IN MAR.24, 1994 UNDER THE CHINESE MINISTRY OF PUBLIC
SECURITY’S MANDATE NO.18) CONTAINS COMPLETE IMPROVING FIRE
CONTROL IN THE PRODUCTION, USE, STORAGE, TRANSPORTION AND
DESTRUCTION OF INFLAMMABLE AND EXPLOSIVE CHEMICALS.
CLASSIFICATION AND MARKING OF COMMON HAZARDOUS
CHEMICALS (GB13690-1992) DESIGNATES KOH AS CLASS 5.1 OXIDITING
AGENT.
SECTION 16
PACKING:
PACKING CODE: Ⅱ OUTER:PACKED IN 50KG GALVANIZED IRON DRUM
INNER: PLASTIC BAG
SECTION 17
OTHER INFORMATION
THIS MSDS WAS PREPARED ON MAY 14,2002. BY CHONGQING JIALING
CHEMICAL PRODUCTS LTD
DATA VERIFIED BY:
REVISION NOTES: