Purposes for the Center

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Center for NanoScience and NanoTechnology National Sun Yat-sen University
http://www.nano.nsysu.edu.tw/nano/index.htm
在液體內讓分子以自我組裝方式長出 1.5 奈米厚中山大學 LOGO (化學系蔣昭明教授)
主持人:何扭今 教授 (Professor New-Jin Ho)
TEL:+886-7-5252000 ext.4067
E-mail:njho@mail.nsysu.edu.tw
Developing Potential
Nano-science and –technology has been known to be the star of future, its development and
application will promote the world into a scene that was used existence in science fictions. All
groups in this center will be expanded to include more interdisciplinary experts across various
departments in NSYSU but also over other domestic and international distinguished research
institutions. In the present, the center of nanoscience and nanotechnology (CNN) will provide best
support with core-facilities. Besides the supporting from hardware, the software such as enough
funds for research personnels, international training and collaboration, dynamic and periodic
international workshops and conferences are important for further performance and competition
with international recognition.
Purposes for the Center
•(1) to provide an efficient atmosphere for research
•(2) to offer initiative funding for innovative ideas
•(3) to provide international collaborative opportunity
•(4) to assure international quality of research.
International Collaboration
University of Houston, USA
University of Wisconsin, Madison, USA
University of Tennessee/Oak Ridge National Lab, USA
Paul Drude Institute, Germany
SSLDC, University of California at Santa Barbara, USA
More connection with international outstanding researchers will be setup in the future.
Facilities
The center provides wide variety of instruments for faculty who are interested in researches in
the fields related to nanoscience and/or nanotechnology. Most of the instruments are operated
either by skillful technicians or Ph.D. students with the required expertise.
Nano/micro analysis Lab
Tecnai G2 FEG-TEM/EDS/GIF/CCD, Philips CM200 LaB6-TEM/CCD, JEOL 3010
LaB6-TEM/EDS/CCD, JEOL 6330F FEG-SEM/EDS/EBSD/CL, JEOL 7000
FEG-SEM/EDS/CL, JEOL 6700 FEG-SEM/EDS, JOEL MicroAuger, EMPA, DI NS4 AFM,
Seiko HV300 SPM, MTS NanoIndenter, Gatan Ion Polisher, D8 powder x-ray, D1 double
crystal x-ray.
Chemical Analysis Lab
Bruker 500MHz NMR, Burker 500 MHz Solid State NMR, Bruker FT-MS, Bruker Vacuum
FT-IR, Time resolved Spectrometer, Micro Raman/PL, ICP-MS
Processing Lab
Double Side Mask Aligner, ICP Etcher, ICP-CVD, Laser Ablation, MBE, Seiko Deal-beam
FIB
Research projects
(a) Low-dimension semiconductor
one-dimensional (nano-rod and nano-wire) and zero-dimensional (nano-dot) shown in
the SEM and TEM image of GaN nano-rods on Si(111) substrate, respectively, revealed
unique features of nano-rods which are vertical to the substrate. Further investigation on the
growth mechanism, the surface state, the optical behavior, the transport properties and the
device applications will be carried on. A proposal entitled “N-Based III-V Semiconductor
Nanostructures “ has been granted as National Science and Technology Program for
Nanoscience and Nanotechnology by National Science Council in Taiwan.
In the nano-dots filed, spherical and well-separated W nano-dots embedded in the SiO2
layer are demonstrated for the first time to be used as the low-power nonvolatile memory
device. The tungsten dots are formed with a mean size and aerial density of 4.5 nm and
3.71011/cm2, respectively. The band diagrams of “write” and “erase” operate with different
gate polarities of the memory device with W nano-dots. A significant C-V hysteresis of Vt
shift of 0.95 V was observed and the endurance of the memory device was not degraded up to
106 write/erase cycles. In addition, a nonvolatile memory device embedded with Ge
nano-dots is fabricated by the thermal oxidation of Si0.8Ge0.2 . The tunnel oxide in the
nonvolatile memory is controlled to be 4.5 nm-thick and embedded with 5.5-nm Ge nano-dots.
A low operating voltage, 5V, is implemented and a significant threshold-voltage shift, 0.42V,
is observed. When the electrons are trapped in the Ge nanocrystals, the effect of Coulomb
blockade prevents the injection and storage of more electrons and decreases the leakage
current.
In the nano-wire filed, we have successfully fabricated polycrystalline silicon thin-film
transistors (poly-Si TFTs) with multiple nano-wire channels. The channel length and width
are 0.5 um and 67 nm, respectively. Superior electrical characteristics, such as higher
ON/OFF current ratio (>108), better subthreshold slop (SS) of 110mV/decade, free of drain
induced barrier lowing (DIBL), and suppressed kink-effect, can be achieved, compared to the
single channel TFTs. This will be promising for the proposed TFTs device with nano-wire
channels to be applied to active matrix liquid crystal display technologies. Also, this project
has been granted recently as National Science and Technology Program for Nanoscience and
Nanotechnology by National Science Council in Taiwan.
(b)
Spintronics in Oxide
Since the discovery of Giant Magnetoresistance (GMR) in the Fe and Cr multiplayer
system the conduction of polarized carrier (the spintronics) raises massive attention in
application especially in the read-head. The recent development of of Tunneling
Magnetoresistance (TMR) with MR higher than GMR exhibits great capability in Magnetic
Random Access Memory (MRAM). Though the colossal Magnetoresistance (CMR) has a
colossal MR signal at high magnetic field of few Tesla, its low Cure’s temperature (Tc) and
high cerosivity makes it less applicable in application.
Up to date, the TMR is base on magnetic metal mostly, only few example has shown
high low-field MR on CMR. However, the insulator layer in TMR has to be very thin, free
of pin-holes and smooth to prevent from scattering and result in loss polarization properties.
If there has magnetic impurities in the insulator layer, the polarized carrier will experience the
spin flip during tunneling and than lower the MR. Eventhough the extra ferromagnetic layer
inside the insulator layer may enhance the MR, it creates only on the complexity of the
processing. In our preliminary experiment, a magnetic insulator with subsequence
superstructure was mixed with ferromagnetic CMR bulk, the low-field magnetoresistance was
dramatically enhanced. The further research direction will apply this idea in films. The
goal of this project is objectively to overcome these problems in CMR and to development (1)
a single device exhibited the low-field MR and (2) the full oxide PN junctions and transistors.
(c)
Nanoclustering
Imperfect oriented attachment of nanoparticles over specific surfaces is rationalized to
cause accretion and defects for the rutile condensates. Analytical electron microscopy
indicates that rutile nanoparticles prepared by Nd:YAG laser ablation on Ti targets have
well-developed {110} and {011} surfaces with steps. These surfaces are beneficial to {similar
to110} and {similar to011} vicinal attachment, causing, respectively, edge dislocations and
planar defects, i.e., fault and twin for rutile crystal. The {011}-interface relaxation, by
shearing along <011> directions, accounts for a rather high density of edge dislocations near
the planar defects thus formed. Brownian motion may proceed above a critical temperature for
anchorage release at the interface of imperfect attached nanoparticles until an epitaxial
relationship is reached.
Also, Imperfect oriented attachment of nanoparticles over specific surfaces is
rationalized to cause accretion and defects for the hexagonal inorganic surfactant mesophase.
Analytical electron microscopy indicates that silicate MCM-41 particles, prepared in alkaline
hydrothermal condition and then surfactant (cetyltrimethylammonium bromide) leached, have
well-developed {10} surfaces with monolayer steps and a rather uniform base with constant
tubular wall thickness. These surfaces are beneficial to {similar to10} vicinal and head-on
attachment, causing respectively edge dislocation and twist boundary for hexagonal
silicatropic liquid crystal. Brownian motion may proceed above a critical temperature for
anchorage release at the interface of imperfectly attached particles until an epitaxial
relationship is reached. This project was the first granted project as National Science and
Technology Program for Nanoscience and Nanotechnology by National Science Council in
Taiwan based on his achievement published in Science
(d) Nanocomposites
The majority of current applications of the nano technology appear to be the nano
materials, especially nano powders. 3D bulk materials and composites are still under the
research stage. Limited successful results are all focused on the polymer matrix composites
with the semi-uniform dispersion of nano ceramic particles. This subproject is aimed on the
synthetize, aggregation, phase transformation and the motion of nano-particles., and on the
fabrication and characterization of nano-cluster, light-weight metallic nano materials and
composites. The matrix materials are based on Mg, Al, Ti, or Zr. The processing means are in
two folds; one through the top-down and the other through the bottom-up routes. Through
various top-down processing methods, the grain size can be effectively refined from 100 m
down to 3 nm or below, from which level sudden transformation into isotropic and amorphous
state will occur. On the other hand, through the bottom-up methods by rapid quenching via
drop-melting or melt-spinning, complete amorphous matrix will be yielded, from which
uniform nano phase measuring 1-100 nm could be obtained.
In cooperation with Cheng Kung University, nanocomposites based on the above matrix
will be fabricated through the advanced concurrent co-spray forming technique. Nanoceramic
particles, wires, or tubes will be sprayed together or parallel with the matrix materials. High
performance Mg based nano composites, not reported previously worldwide, can be prepared
in our laboratory.
(e) Molecular wiring and motors
The spectroscopic and electrochemical characterizations of electrochemically stable
biferrocene-modified Au clusters and chemisorbed biferrocenylalkanethiols on Au(111)
surface were studied. Two successive reversible one-electron redox waves were observed for
the biferrocenylalkanethiol Au nanoclusters and biferrocenylalkanethiol monolayers on
Au(111) surface in the cyclic voltammetry. Furthermore, the positive and negative current
peaks for each redox wave occur at almost the same potential, and the peak current increases
almost linearly with the sweep rate. Repeat scanning does not change the voltammograms,
demonstrating that these monolayers are stable to electrochemical cycling. The coverages of
electroactive biferrocene in the monolayers were calculated from the cyclic voltammograms.
The standard electron-transfer rate constant was calculated from the splitting between the
oxidation and reduction peaks.
The preparations of multinuclear supramolecules assembled from 1’,1’’’-bis
(terpyridyl)biferrocene redox-active subunit with Ru(II) metal centers are described. The
appreciable variations detected in the Fe2+/Fe3+ oxidation potentials indicate that there is an
interaction between the spacer and terminal ferrocenyl moieties.
Molecules that involve spontaneous bond formation between metals and multidentate
ligands that have potentially versatile coordination modes were also studied. One
fascinating phenomenon discovered in Professor Liang’s laboratory is the formation of double
helical molecules mediated by selected metals that inherently adopt a tetrahedral geometry.
For instance, addition of dibutylmagnesium or diethylzinc to a THF solution of
N,N’-ethylenedi(5-tert-butyl-pyrrol-2-ylaldimine) generates the double helical dinuclear metal
complexes.
Highlight of some research results
State-of-art extra low dislocation density
2-in LAO single crystal, the next generation
substrate to grow GaN LED,
TEM(lattice image -PbO2-type, anatase and
rutile structure) of titania particles generated by
laser-ablation condensation,. Scale bar, 50 nm.
in PRL
The nano-capillary brings within it a huge imbalance in equilibrium partial pressure of Ga relative to the
growth ambient. GaN nanorods thus always grow out of a holding nanotrench and conform to the
boundaries of surrounding islands. The nanorods are epitaxially orientated with <0001> GaN // <111>Si and
<2110>GaN // <110>Si similar to the matrix.
SiO2
Si
W dot
20 nm
Ni Oxide MRTA 400 (5V~ -8V)
Ni Oxide MRTA 400 (-8V~ 5V)
1.0
C/Cox
0.8
0.6
0.4
0.2
0.0
-10
-8
-6
-4
-2
0
2
4
6
8
10
voltage(V)
nano-dot with excellent tunneling effects
By applying a simple room-temperature
accumulative roll bonding (ARB) process, the
multilayered Zr/Ni and Zr/Ti elemental foils can
be mixed and transformed into nanocrystalline
and eventually amorphous bulk materials.
Buffer chamber 1
N
N
2+ N
N
N
Ru2+ N
N
N
N
Fe
Optical tweezer
Ru
N
N
100
X
NA
= 0.8
Particle A
n
N
1a n=1
1b n=2
1c n=3
Reservoir 1
Sample chamber
Function area
Particle B
Reservoir 2
N
N
N
N
Ru2+ N
N
N
N
Fe
N
Ru2+ N
N
Electrokinetic focusing
Optical sorting
n
N
2a n=1
2b n=2
2c n=3
“Fine-Turning the Electronic Communication
Across Ferrocenyl-Bridged Ruthenium(II)
Terpyridine Complexes”
with nanografting technique, thinol
self-assembled a NYSSU logo with 1.5nm
height in liquid
Buffer chamber 2
Micro fluid system with optical
tweezers for cell sorting
Publications
(Affiliation or acknowledgement with Center for NanoScience & NanoTechnology, National Sun Yat-sen
University ), ranking in categories by impact factor: ☆5%, ★ 10%, ★☆ 15%, ★★ 20%, ★★☆ 25%,
★★★ 30%
2006-sci up to July
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W.J. Tseng, C.C. Lin, P.W. Shen and P. Shen (2006):“Directional/acidic dissolution kinetics of
(OH,F,Cl)-bearing apatite,” Journal of Biomedical Materials Research: Part A. 76[4], pp. 753-764.
2006☆
Hwang SL, Chu HT, Yui TF, et al., Nanometer-size P/K-rich silica glass (former melt) inclusions in microdiamond from
the gneisses of Kokchetav and Erzgebirge massifs: Diversified characteristics of the formation media of metamorphic
microdiamond in UHP rocks due to host-rock buffering , EARTH AND PLANETARY SCIENCE LETTERS 243 (1-2):
94-106 MAR 15 2006☆
Lo I, Tsai JK, Yao WJ, et al.,Reply to "Comment on 'Spin splitting in modulation-doped AlxGa1-xN/GaN heterostructures'
" , PHYSICAL REVIEW B 73 (3): Art. No. 037302 JAN 2006★
Lo I, Wang WT, Gau MH, et al., Wurtzite structure effects on spin splitting in GaN/AlN quantum wells , PHYSICAL
REVIEW B 72 (24): Art. No. 245329 DEC 2005★
Lee CJ, Huang JC, Hsieh PJ, Mg based nano-composites fabricated by friction stir processing ,SCRIPTA MATERIALIA
54 (7): 1415-1420 APR 2006★
Y. N. Wang, C. I. Chang, C. J. Lee, H. K. Lin, and J. C. Huang, “Texture and weak Grain Size Dependence
of Yield Stress in Friction Stir Processed Mg-Al-Zn Alloy”, Vol. 55, Scripta Mater., 2006, pp. 637-640. ★
Wu YC, Chang TC, Liu PT, et al., High-performance metal-induced lateral-crystallization polysilicon thin-film transistors
with multiple nanowire channels and multiple gates, IEEE TRANSACTIONS ON NANOTECHNOLOGY 5 (3):
157-162 MAY 2006★
Lee GB, Lin CH, Lee KH, et al., On the surface modification of microchannels for microcapillary electrophoresis chips ,
ELECTROPHORESIS 26 (24): 4616-4624 DEC 2005★
Li LL, Lin KJ, Ho CJ, et al., A coordination pi-pi framework exhibits spontaneous magnetization , CHEMICAL
COMMUNICATIONS (12): 1286-1288 2006★
Tu CH, Chang TC, Liu PT, et al., Formation of silicon germanium nitride layer with distributed charge storage elements ,
APPLIED PHYSICS LETTERS 88 (11): Art. No. 112105 MAR 13 2006★
Seo HW, Chen QY, Iliev MN, et al. Epitaxial GaN nanorods free from strain and luminescent defects APPLIED
PHYSICS LETTERS 88 (15): Art. No. 153124 APR 10 2006★
Lo I, Wang WT, Gau MH, et al., Gate-controlled spin splitting in GaN/AIN quantum wells , APPLIED PHYSICS
LETTERS 88 (8): Art. No. 082108 FEB 20 2006★
Chou MMC, Huang HC, Chang YF Defects and acoustic properties of LiAlO2 APPLIED PHYSICS LETTERS 88
(16): Art. No. 161906 APR 17 2006★
Wu YC, Lu HY, Dislocation-containing planar faults in metastably retained hexagonal barium titanate, JOURNAL OF THE
AMERICAN CERAMIC SOCIETY 89 (8): 2625-2631 AUG 2006★
Cheng SY, Ho NJ, Lu HY, Transformation-induced twinning: The 90 degrees and 180 degrees ferroelectric domains in
tetragonal barium titanate, JOURNAL OF THE AMERICAN CERAMIC SOCIETY 89 (7): 2177-2187 JUL 2006★
Wu YC, Chen CY, Lu HY, et al., Dislocation loops in pressureless-sintered undoped BaTiO3 ceramics, JOURNAL OF
THE AMERICAN CERAMIC SOCIETY 89 (7): 2213-2219 JUL 2006★
Wu YC, Lee CC, Lu HY, et al., The {1(1)over-bar1} growth twins in tetragonal barium titanate, JOURNAL OF THE
AMERICAN CERAMIC SOCIETY 89 (5): 1679-1686 MAY 2006★
Cheng SY, Ho NJ, Lu HY, Dissociation of the < 001 > dislocations and their interactions with dislocation loops in
tetragonal BaTiO3, JOURNAL OF THE AMERICAN CERAMIC SOCIETY 89 (5): 1659-1667 MAY 2006★
C. Pan, P. Shen, W.L. Huang, S.L. Hwang, T.F. Yui and H.T. Chu (2006): “High temperature-pressure
synthesis of Ti-doped tohdite and corundum from hydrous Al2O3-TiO2 gel,” J. Euro. Ceram. Soc. 26,
pp. 2707-2717,2006★
Cheng YT, Hung TH, Huang JC, et al., Effects of partial replacement of Cu and Y by B in Mg-Cu-Y amorphous alloys,
INTERMETALLICS 14 (8-9): 866-870 Sp. Iss. SI AUG-SEP 2006★
Hsieh PJ, Lo YC, Huang JC, et al., On the latest stage of transformation from nanocrystalline to amorphous phases
during ARB: Simulation and experiment, INTERMETALLICS 14 (8-9): 924-930 Sp. Iss. SI AUG-SEP 2006★
Jang JSC, Chang LJ, Young JH, et al., Synthesis and characterization of the Mg-based amorphous/nano ZrO2
composite alloy, INTERMETALLICS 14 (8-9): 945-950 Sp. Iss. SI AUG-SEP 2006★
Liu CH, Chiang WR, Hsieh KC, et al., Phase equilibrium in the Cu-Ni-Zr system at 800 degrees C ,
INTERMETALLICS 14 (8-9): 1011-1013 Sp. Iss. SI AUG-SEP 2006★
Liang LC, Chien PS, Lin JM, et al., Amido pincer complexes of nickel(II): Synthesis, structure, and reactivity ,
ORGANOMETALLICS 25 (6): 1399-1411 MAR 13 2006★☆
Chen SH, Su AC, Su CH, et al., Phase behavior of poly(9,9-di-hexyl-fluorene) JOURNAL OF PHYSICAL
CHEMISTRY B 110 (9): 4007-4013 MAR 9 2006★☆
Ju SP, Yang SH, Liao ML Study of molecular behavior in a water nanocluster: Size and temperature effect JOURNAL OF
PHYSICAL CHEMISTRY B 110 (18): 9286-9290 MAY 11 2006★☆
27. Tsai MH, Chen SY, Shen RP, et al., Laser ablation condensation of polymorphic ZrO2 nanoparticles: Effects of laser
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parameters, residual stress, and kinetic phase change , JOURNAL OF APPLIED PHYSICS 99 (5): Art. No. 054302
MAR 1 2006★☆
Ding SW, A realistic potential model for N-H vector diffusion in proteins , JOURNAL OF CHEMICAL PHYSICS 124
(7): Art. No. 074902 FEB 21 2006 ★☆
Shen SC, Pan CT, Wang YR, et al., Fabrication of integrated nozzle plates for inkjet print head using microinjection
process, SENSORS AND ACTUATORS A-PHYSICAL 127 (2): 241-247 MAR 13 2006★☆
Liu PT, Tsai CT, Chang TC, et al. Activation of carbon nanotube emitters by using supercritical carbon dioxide fluids with
propyl alcohol , ELECTROCHEMICAL AND SOLID STATE LETTERS 9 (4): G124-G126 2006★☆
Tsai MN, Chang TC, Liu PT, et al., Temperature effects of n-MOSFET devices with uniaxial mechanical strains,
ELECTROCHEMICAL AND SOLID STATE LETTERS 9 (8): G276-G278 2006★☆
Dong TY, Wu HH and Lin MV, Superlattice of octanethiol-protected copper nanoparticles, LANGMUIR 22 (16): 6754-6756 AUG
2006★☆
Chang TS, Chang TC, Liu PT, et al., Integration issues for siloxane-based hydrogen silsesquioxane (HSQ) applied on
TFT-LCDs ,THIN SOLID FILMS 498 (1-2): 70-74 MAR 1 2006★★
Tsai MN, Chang TC, Liu PT, et al. Short-diode like diffusion capacitance of organic light emission devices ,THIN
SOLID FILMS 498 (1-2): 244-248 MAR 1 2006 ★★
Luo MF, Chiang CI, Shiu HW, et al. Growth of Co clusters on thin films Al2O3/NiAl(100) JOURNAL OF
CHEMICAL PHYSICS 124 (16): Art. No. 164709 APR 28 2006★★
Yeh SW, Huang HL, Gan DS, et al. The oriented growth of zirconia thin films on NaCl (001) surface JOURNAL OF
CRYSTAL GROWTH 289 (2): 690-702 APR 1 2006★★
Dong TY, Chang SW, Lin SF, et al. Toward the development of molecular wires: A terpyridine spacer containing
polyferrocenylalkyne linkages ORGANOMETALLICS 25 (8): 2018-2024 APR 10 2006★★
Chang SC, Lin SC, Hsieh KC, The formation and growth of intermetallic compounds in Sn-Zn and Sn-Zn-Al solder with
Ni/Au surface finish bond pad , JOURNAL OF ELECTRONIC MATERIALS 35 (3): 399-405 MAR 2006★★☆
Tu CH, Chang TC, Liu PT, et al., A novel method for growing polycrystalline Ge layer by using UHVCVD , SURFACE
& COATINGS TECHNOLOGY 200 (10): 3261-3264 FEB 24 2006★★☆
Jang JSC, Tsao SF, Chang LJ, et al., Crystallization kinetics of the Zr61Al7.5Cu17.5Ni10Si4 alloy using isothermal
DSC and TEM observation , JOURNAL OF NON-CRYSTALLINE SOLIDS 352 (1): 71-77 JAN 1 2006★★★
Young TF, Liu TS, Jung DJ, et al., Microstructural and electrical studies of nitrogen doped diamond thin films grown by
microwave plasma CVD, SURFACE & COATINGS TECHNOLOGY 200 (10): 3145-3150 FEB 24 2006★★★
Hsiao CL, Tu LW, Chi TW, et al.Buffer controlled GaN nanorods growth on Si(111) substrates by plasma-assisted
molecular beam epitaxy JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B 24 (2): 845-851 MAR-APR 2006
★★★
Tseng WJ, Shen PY, Chen SY, Defect generation of rutile-type SnO2 nanocondensates: Imperfect oriented attachment and
phase transformation , JOURNAL OF SOLID STATE CHEMISTRY 179 (4): 1237-1246 APR 2006
Wu YC, Ho NJ, Lu HY, Dissociation of basal dislocations in hexagonal barium titanate, JOURNAL OF
MICROSCOPY-OXFORD 220: 205-220 Part 3 DEC 2005
Pan CT, Cheng PJ, Hwang YM, et al., Three-dimensional micro-flow measurement in a capillary with a diode laser
micro-particle image velocitmetry , MATERIALS SCIENCE FORUM 505-507: 343-348 2006
Shyu RF, Pan CT, Lin SC, Parametric study of spherical micro-lens array, MATERIALS SCIENCE FORUM 505-507:
595-600 2006
Pan CT, Cheng PJ, Shen SC, et al., Applications of LIGA on micro-punching process for metallic materials ,
MATERIALS SCIENCE FORUM 505-507: 55-60 2006
Seo HW, Chen QY, Tu LW, et al. GaN nanorod assemblies on self-implanted (111) Si
substrates MICROELECTRONIC ENGINEERING 83 (4-9): 1714-1717 APR-SEP 2006
Ju SP, Weng CI, Fang KC, et al. A tight-binding molecular dynamics simulation analysis of carbon nanotube growth
process parameters JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE 3 (2): 231-236 APR
2006
Shih CC, Lin YS, Wang CY, et al. Melting of mesoscopic lattices of magnetic fluid thin film subjected to perpendicular
fields JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 300 (2): 306-314 MAY 2006
Lee CJ, Huang JC, Hsieh PL,Using friction stir processing to fabricate Mg based composites with nano fillers, KEY
ENGINEERING MATERIALS 313: 69-75 2006
Hung YP, Wu KJ, Tsao CYA, et al., AZ61 Mg with nano SiO2 particles prepared by spray forming plus extrusion, KEY
ENGINEERING MATERIALS 313: 77-82 2006
Hung YP, Wu KJ, Tsao CYA, et al., AZ61 Mg with nano SiO2 particles prepared by spray forming plus extrusion , KEY
ENGINEERING MATERIALS 313: 77-82 2006
Wang KR, Tu LW, Lin SJ, et al., Unintentionally doped InN grown onto an atomically flat AlN intermediate layer using
plasma-assisted molecular beam epitaxy, PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS 243 (7):
1461-1467 JUN 2006
Chen YJ, Young TF, Lee SL, et al., Electrochemical studies of nano-structured diamond thin-film electrodes grown by
microwave plasma CVD, VACUUM 80 (7): 818-822 MAY 31 2006
Chen A, Wang PY, Yang YC, et al., SUMO regulates the cytoplasmonuclear transport of its target protein Daxx,
JOURNAL OF CELLULAR BIOCHEMISTRY 98 (4): 895-911 JUL 1 2006
Wang HT, Song YY, Chiang MY, et al., Bis[(imidazol-4-ylmethyl)(2-pyridylmethyl)amine-kappa N-3,N ',N '']nickel(II)
58.
dichloride dihydrate, ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 62:
M1237-M1238 Part 6 JUN 2006
Ding SW, Hong YW, Chen CY, et al., One and two dimensional H-1 and C-13 high resolution NMR investigation of lariat
ethers and their alkali metal ionic complexes: A more tangible evidence for the presence of less common C-H center dot center
dot center dot O hydrogen bonds, BIOPHYSICAL CHEMISTRY 121 (2): 75-83 MAY 20 2006
(2005)
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Tsai MH, Chen SY, Shen PY, Laser ablation condensation of TiO2 particles: Effects of laser energy, oxygen flow rate and
phase transformation , JOURNAL OF AEROSOL SCIENCE 36 (1): 13-25 JAN 2005
Chien PS, Liang LC, Zirconium and hafnium complexes containing bidentate diarylamido-phosphine ligands,
INORGANIC CHEMISTRY 44 (14): 5147-5151 JUL 11 2005
Dong TY, Chen KL, Lin MC, et al., Toward the development of molecular wires: Ruthenium(II) terpyridine complexes
containing polyferrocenyl as a spacer , ORGANOMETALLICS 24 (17): 4198-4206 AUG 15 2005
Seo HW, Chen QY, Tu LW, Hsiao CL, Iliev MN, Chu WK, Catalytic nanocapillary condensation and epitaxial GaN
nanorod growth , PHYSICAL REVIEW B 71 (23): Art. No. 235314 JUN 2005
Kuo MY, Chen CL, Yang HC and Shen PY, First-principles calculation of prevailing faces of alpha-PbO2-type TiO2,
PHYSICAL REVIEW B 71 (12): Art. No. 125405 MAR 2005
Jeng U, Hsu CH, Sheu HS, Lee HY, Inigo AR, Chiu HC, Fann WS, Chen SH, Su AC, Lin TL, Peng KY, Chen SA ,
Morphology and charge transport in poly(2-methoxy-5-(2 '-ethylhexyloxy)-1, 4-phenylenevinylene) films,
MACROMOLECULES 38 (15): 6566-6574 JUL 26 2005
Chen SH, Su AC, Chen SA, Noncrystalline phases in poly(9,9-di-n-octyl-2,7-fluorene) , JOURNAL OF PHYSICAL
CHEMISTRY B 109 (20): 10067-10072 MAY 26 2005
Kuo MY, Chen CL, Hua CY and Shen PY, Density functional theory calculations of dense TiO2 polymorphs: Implication
for visible-light-responsive photocatalysts , JOURNAL OF PHYSICAL CHEMISTRY B 109 (18): 8693-8700 MAY 12
2005
Liang LC, Lin JM, Lee WY, Benzene C-H activation by platinum(II) complexes of
bis(2-diphenylphosphinophenyl)amide , CHEMICAL COMMUNICATIONS (19): 2462-2464 2005
Chen CW, Chang TC, Liu PT, et al., Effects of oxygen plasma ashing on barrier dielectric SiCN film,
ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (1): G11-G13 2005
Chang TC, Liu PT, Yan ST, et al., Electron charging and discharging effects of tungsten nanocrystals embedded in silicon
dioxide for low-voltage nonvolatile memory technology, ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (3):
G71-G73 2005
Tu CH, Chang TC, Liu PT, et al., Enhanced performance of poly-Si thin film transistors using fluorine ions implantation ,
ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (9): G246-G248 2005
Chen CW, Chang TC, Liu PT, et al., Electrical degradation of N-channel poly-Si TFT under AC stress ,
ELECTROCHEMICAL AND SOLID STATE LETTERS 8 (9): H69-H71 2005
Chang TC, Liu PT, Yan ST, et al., Memory effect of oxide/oxygen-incorporated silicon carbide/oxide sandwiched
structure, JOURNAL OF THE ELECTROCHEMICAL SOCIETY 152 (2): G144-G147 2005
Kuo CT, Huang SY, Jiang IM, et al., Multiguide directional coupler using switchable liquid-crystalline optical channels ,
JOURNAL OF APPLIED PHYSICS 97 (10): Art. No. 103113 Part 1 MAY 15 2005
Ju SP, Chang JG, Lin JS, et al., The effects of confinement on the behavior of water molecules between parallel Au plates
of (001) planes , JOURNAL OF CHEMICAL PHYSICS 122 (15): Art. No. 154707 APR 15 2005
Liang LC, Chien PS, Huang MH, Catalytic Suzuki coupling reactions by amido phosphine complexes of palladium,
ORGANOMETALLICS 24 (3): 353-357 JAN 31 2005
Ju SP, A molecular dynamics simulation of the adsorption of water molecules surrounding an Au nanoparticle,
JOURNAL OF CHEMICAL PHYSICS 122 (9): Art. No. 094718 MAR 1 2005
Fu LM, Yang RJ, Lin CH, et al., Novel microfluidic mixer utilizing electrokinetic driving forces under low switching
frequency, ELECTROPHORESIS 26 (9): 1814-1824 MAY 2005
Hsiung SK, Lin CH, Lee GB, A microfabricated capillary electrophoresis chip with multiple buried optical fibers and
microfocusing lens for multiwavelength detection, ELECTROPHORESIS 26 (6): 1122-1129 MAR 2005
Lee WY, Liang LC, Organoaluminium complexes incorporating an amido phosphine chelate with a pendant arm,
DALTON TRANSACTIONS (11): 1952-1956 JUN 7 2005
Chou MC, Pan CT, Shen SC, et al., A novel method to fabricate gapless hexagonal micro-lens array, SENSORS AND
ACTUATORS A-PHYSICAL 118 (2): 298-306 FEB 28 2005
Chen SC, Lou JC, Chien CH, Liu PT, Chang TC , An interfacial investigation of high-dielectric constant material
hafnium oxide on Si substrate, THIN SOLID FILMS 488 (1-2): 167-172 SEP 22 2005
Chen CW, Chang TC, Liu PT, et al., Study on etching profile of nanoporous silica, THIN SOLID FILMS 469-70:
377-382 Sp. Iss. SI DEC 22 2004
Chang TC, Tsai TM, Liu PT, et al., Study on the effect of electron beam curing on low-K porous organosilicate glass
(OSG) material, THIN SOLID FILMS 469-70: 383-387 Sp. Iss. SI DEC 22 2004
Chen CW, Liu PT, Chang TC, et al., Cu-penetration induced breakdown mechanism for a-SiCN, THIN SOLID FILMS
469-70: 388-392 Sp. Iss. SI DEC 22 2004
Chen SC, Lou JC, Chien CH, Liu PT, Chang TC , An interfacial investigation of high-dielectric constant material
hafnium oxide on Si substrate, THIN SOLID FILMS 488 (1-2): 167-172 SEP 22 2005
28. Li MY, Shen PY, Interface-specific reorientation of embedded tetragonal ZrO2 particles in Ni1-xO polycrystals ,
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE
AND PROCESSING 398 (1-2): 309-317 MAY 25 2005
29. Pan CT, Hwang YM, Hsieh CW, Dynamic characterization of silicon-based microstructure of high aspect ratio by
dual-prism UV laser system , SENSORS AND ACTUATORS A-PHYSICAL 122 (1): 45-54 JUL 29 2005
30. Chien CH, Pan CT, Hsieh CC, et al., A study of the geometry of microball lens arrays using the novel batch-fabrication
technique, SENSORS AND ACTUATORS A-PHYSICAL 122 (1): 55-63 JUL 29 2005
31. Chou H, Hong ZY, Sun SJ, et al., Strong anisotrpoic maganetoresistance and magnetic interaction in
La0.7Ce0.3Mn0.3/La0.7Ca0.3MnO3 p-n junction , JOURNAL OF APPLIED PHYSICS 97 (10): Art. No. 10A308 Part 2
MAY 15 2005
32. Lin HK, Huang JC, Langdon TG, Relationship between texture and low temperature superplasticity in an extruded AZ31
Mg alloy processed by ECAP , MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS
PROPERTIES MICROSTRUCTURE AND PROCESSING 402 (1-2): 250-257 AUG 15 2005
33. Shen PY, Fahn YY, Su AC, On the rolling of asymmetric inorganic-surfactant membrane into uncapped mesophase tubes,
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS 25 (1): 11-15
JAN 2005
34. Chou H, Tsai MH, Ou MN, et al., Increase in zero-field conductivity and low-field magnetoresistance by proton
irradiated defects in La0.67Sr0.33MnO3 films, JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR
PAPERS SHORT NOTES & REVIEW PAPERS 44 (4A): 1742-1744 APR 2005
35. Pan CT, Cheng PJ, Chen MF, et al., Intermediate wafer level bonding and interface behavior, MICROELECTRONICS
RELIABILITY 45 (3-4): 657-663 MAR-APR 2005
36. Kuo CT, Huang SY, Kuo MS, et al., Temperature and polarization dependence of transient gratings in azo-dye-doped
liquid crystals , JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF
COMMUNICATIONS & REVIEW PAPERS 44 (5A): 3111-3114 MAY 2005
37. Kuo MC, Tsai CM, Huang JC, et al., PEEK composites reinforced by nano-sized SiO2 and Al2O3 particulates,
MATERIALS CHEMISTRY AND PHYSICS 90 (1): 185-195 MAR 15 2005
38. Pan CT, Shen SC, Magnetically actuated bi-directional microactuators with permalloy and Fe/Pt hard magnet,
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS 285 (3): 422-432 JAN 2005
39. Pan CT, Shen SC, Hsieh CC, Magnetically-actuated bending-mode microactuators with excimer laser ablation ,
PLASTICS RUBBER AND COMPOSITES 33 (8): 338-342 2004
40. Shen PY, Hwang SL, Chu HT, et al., On the transformation pathways of alpha-PbO2-type TiO2 at the twin boundary of
rutile bicrystals and the origin of rutile bicrystals , EUROPEAN JOURNAL OF MINERALOGY 17 (4): 543-552
JUL-AUG 2005
41. Yang FM, Chang TC, Liu PT, et al., Damage effect of fluorine implantation on PECVD alpha-SiOC barrier dielectric ,
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH
MATERIALS AND ATOMS 237 (1-2): 301-306 AUG 2005
42. Liu PH, Ding SW, Application of liquid crystalline NMR solvents to a mixture of ketones, JOURNAL OF THE
CHINESE CHEMICAL SOCIETY 52 (1): 1-4 FEB 2005
43. Zhou JL, Wan FX, Yu KC, et al., Synthesis of amphiphilic dimers of Gd (III) complexes and their liver-selective contrast
enhancement in MRI , CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 26 (8): 1391-1394 AUG 10
2005
44. . Zhou JL, Wan FX, Yu KC, Ding SW, Yang NH, Ye CH, Synthesis and relaxivity of neutral dimeric Gd(III) complexes
derived from L-lysine with long chain alkyl esters, CHINESE JOURNAL OF INORGANIC CHEMISTRY 21 (8):
1237-1241 AUG 2005
45. Pan CT, Hwang YM, Hsieh CW Fast fabrication of silicon based microstructures using 355 nm UV laser MATERIALS
SCIENCE AND TECHNOLOGY 21 (11): 1344-1348 NOV 2005
46. Chiang CM, Cho CC Probing the internal competition between alpha- and beta-elimination by fluorine substitution in
adsorbed ethyl groups on Cu(100) JOURNAL OF PHYSICAL CHEMISTRY B 109 (46): 21486-21488 NOV 24 2005
47. Ju SP, Lo YC, Sun SJ, et al. Investigation on the structural variation of Co-Cu nanoparticles during the annealing
process JOURNAL OF PHYSICAL CHEMISTRY B 109 (44): 20805-20809 NOV 10 2005
48. Yeh PH, Yu CH, Chen LJ, et al. Low-power memory device with NiSi2 nanocrystals embedded in silicon dioxide
layer APPLIED PHYSICS LETTERS 87 (19): Art. No. 193504 NOV 7 2005
49. Chuang CH, Huang JC, Hsieh PJ Using friction stir processing to fabricate MgAlZn intermetallic alloys SCRIPTA
MATERIALIA 53 (12): 1455-1460 DEC 2005
50. Hsiao CL, Tu LW, Chen M, et al. Polycrystalline to single-crystalline InN grown on Si(111) substrates by
plasma-assisted molecular-beam epitaxy JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS &
EXPRESS LETTERS 44 (33-36): L1076-L1079 2005
51. Chen CW, Chang TC, Liu PT, et al. High-performance hydrogenated amorphous-Si TFT for AMLCD and AMOLED
applications IEEE ELECTRON DEVICE LETTERS 26 (10): 731-733 OCT 2005
52. Wu YC, Chang TC, Liu PT, et al. Effects of channel width on electrical characteristics of polysilicon TFTs with
multiple nanowire channels IEEE TRANSACTIONS ON ELECTRON DEVICES 52 (10): 2343-2346 OCT 2005
53. Wu YC, Chang TC, Liu PT, et al. Mobility enhancement of polycrystalline-Si thin-film transistors using nanowire
channels by pattern-dependent metal-induced lateral crystallization APPLIED PHYSICS LETTERS 87 (14): Art. No.
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COMMUNICATIONS & REVIEW PAPERS 44 (5A): 3111-3114 MAY 2005
Chen SC, Lou JC, Chien CH, Chang, TC, et al. An interfacial investigation of high-dielectric constant material hafnium
oxide on Si substrate THIN SOLID FILMS 488 (1-2): 167-172 SEP 22 2005
Dong TY, Chen KL, Lin MC, et al. Toward the development of molecular wires: Ruthenium(II) terpyridine complexes
containing polyferrocenyl as a spacer ORGANOMETALLICS 24 (17): 4198-4206 AUG 15 2005
Jeng U, Hsu CH, Sheu HS, et al. Morphology and charge transport in poly(2-methoxy-5-(2
'-ethylhexyloxy)-1,4-phenylenevinylene) films MACROMOLECULES 38 (15): 6566-6574 JUL 26 2005
Lin CC, Huang LC, Shen PY, Na2CaSi2O6-P2O5 based bioactive glasses. Part 1: Elasticity and structure JOURNAL OF
NON-CRYSTALLINE SOLIDS 351 (40-42): 3195-3203 OCT 15 2005
Chen IM, Yeh SW, Chiou SY, et al. Condensation of tetragonal zirconia polycrystals by reactive sputtering THIN SOLID
FILMS 491 (1-2): 339-346 NOV 22 2005
C. J. Hsu, P. W. Kao and N. J. Ho, “Ultrafined-grained Al-Al2Cu composite produced in situ by friction stir processing,
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