ZODIAC POOL CARE SOUTH AFRICA Reg No. 1987/001774/07 Private Bag X 127, Halfway House, 1685 4 Slate Road, N1 Business Park Old Johannesburg & Tolkwa Streets, KOSMOSDAL Tel : +27 (0) 11 237 3900 Fax : +27 (0) 11 314 5225 MSDS - ACRYLAMIDE Product Names Two Ten – Gel Block 1. PRODUCT AND COMPANY IDENTIFICATION Trade name: Two Ten Gel Block Chemical family: Acrylamide Chemical name: Polyacrylamide Synonyms: Chemical abstract no.: NIOSH no.: Hazchem code: UN : 2. COMPOSITION Gel formation of Polymer flocculant and cationic coagulant Hazardous components: EEC classification: R Phrases: 3. HAZARDS IDENTIFICATION Emergency overview- Gel is extremely slippery when wet Main hazard: Flammability: Chemical hazard: Biological hazard: Reproduction hazard: Eye effects - eyes: Health effects - skin: Health effects - ingestion: Health effects - inhalation: Carcinogenicity: Mutagenicity: Neurotoxicity: 4. FIRST AID MEASURES Doc: SDS – 017 Issue:23/6/2014 Material Safety Data Sheet – Occupational Health & Safety Act GAR 1 Product Name: Polyacrilamide Version: 2 Page 1 of 4 Product in eye: Product on skin: Product ingested: Immediately flush with water, continuing for 15 miunutes. If irritation persists, seek medical attention Flush with plenty of soap and water for at least 15 minutes. . If irritation persists, seek medical attention Product is virtually non toxic, but in the case of ingestion, consult a physician Product inhaled: N/A . 5. Fire Fighting Measures Extinguishing media: n/a Special hazards: n/a Protective clothing: n/a 6. ACCIDENTAL RELEASE MEASURES Personal Precautions - Avoid excessive contact with hands and skin by using gloves, and wear plastic apron. Environmental Precautions Small Spills: To scoop up materials use absorbent material such as clay, wood shavings. After mopping up spills, dispose of according to applicable municipal regulations. Large Spills: Slippery when wet. To scoop up materials use absorbent material such as clay, wood shavings. After mopping up spills dispose of according to applicable municipal regulations. 7. HANDLING AND STORAGE Suitable Material – Can be stored in cardboard packaging cartons, in a cool dry place. Handling / storage precautions Store in a cool dry place. Use normal personal hygiene and housekeeping methods. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational Exposure Limits Engineering Control Measures Personal Protection – Respiratory N/A Personal Protection – Hands N/A Personal Protection – Eyes N/A Personal Protection – Skin N/A Other Protection - Natural ventilation 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Solid Blue Gel block Odour: Slight chemical smell Doc: SDS – 017 Issue:23/6/2014 Material Safety Data Sheet – Occupational Health & Safety Act GAR 1 Product Name: Polyacrilamide Version: 2 Page 2 of 4 pH: N/A Boiling point: N/A Melting point: N/A Flash point: N/A Flammability: N/A Auto flammability: N/A Explosive properties: Oxidizing properties: Vapour pressure: N/A Density: N/A Solubility - water: Infinite Solubility - solvent: Solubility - coefficient: Neurotoxicity: N/A N/A N/A N/A N/A 10. STABILITY AND REACTIVITY Conditions to Avoid Slippery when wet Incompatible Materials N/A Hazardous decomposition products Thermal Decomposition 11. TOXICOLOGICAL INFORMATION Acute toxicity: Acute testing in rats was conducted on polyacrilimide polymers with different degrees of aniocity. Based on the findings of studies the LD50 for the product would be >5g/kg Skin and eye contact: Acute testing on rabbits showed the product was not toxic even at high doses. Chronic toxicity: In a 2 year feeding study on albino rats, animals fed at a dose level of 5% of the animal feed, showed no signs of toxicity. A similar feeding study of a year with dogs showed similar results Carcinogenicity: Mutagenicity: Reproductive hazards: 12. ECOLOGICAL INFORMATION Aquatic toxicity - fish: The 48hr LC50 was greater than 1000mg/lt Aquatic toxicity - daphnia: Aquatic toxicity - algae: For fresher algae, Selenastrum capricornumium, the EC50 was found to be greater than the 500mg/lt Biodegradability: N/A Bio-accumulation: N/A Mobility: German wgk: 13. DISPOSAL CONSIDERATIONS Disposal methods: Incineration and/or disposal in chemical landfill. Doc: SDS – 017 Issue:23/6/2014 Material Safety Data Sheet – Occupational Health & Safety Act GAR 1 Product Name: Polyacrilamide Version: 2 Page 3 of 4 Disposal of packaging: Dispose of in domestic conditions according to municipal by laws. 14. TRANSPORT INFORMATION UN no.: Substance identity no.: ADR/RID class: Not restricted ADR/RID item no.: ADR/RID hazard identity no.: IMDG - shipping name: IMDG - class: Not restricted IMDG - packaging group: IMDG - marine pollutant: IMDG - EMS no.: IMDG - MFAG tabel no.: IATA - shipping name: IATA - class: Not restricted IATA - subsidiary risk(s): ADNR - class: Not restricted UK - description: UK - emergency action class: UK - classification: Tremcard no.: 15. REGULATORY INFORMATION Anionic polymers are approved in numerous countries worldwide as food additives EEC hazard classification: Risk phases: low Safety phases: low National legislation: None 16. OTHER INFORMATION DISCLAIMER Zodiac Pool Care SA (Pty) Limited believes that this information is correct at date of publication but does not warrant the accuracy thereof. The use of the product designated herein will be at the sole risk of the user and Zodiac Pool Care SA (Pty) Limited will not accept any liability for any loss or damage, including consequential loss, howsoever caused by or arising from the use of this information of the use, application, adaption or processing of the product described herein or its use in combination with any other product, material or in any process. Date of General Update- 20 June 2014 Doc: SDS – 017 Issue:23/6/2014 Material Safety Data Sheet – Occupational Health & Safety Act GAR 1 Product Name: Polyacrilamide Version: 2 Page 4 of 4