DRAFT Low Level Waste and Mixed Low Level Waste National Business Strategy Phase I Introduction The Environmental Management (EM) program of the U.S. Department of Energy (DOE) is committed to the environmental remediation of the DOE’s sites throughout the nation. Central to this mission is the restoration of contaminated sites from nuclear weapons research and production and the disposal of the resulting radioactive and hazardous wastes. In the process, the Department seeks to reduce risk and minimize lifecycle costs. Facility Deactivation and Decommissioning (D&D) and the environmental restoration of contaminated sites produce large amounts of Low Level Waste (LLW), Mixed Low-Level Waste (MLLW), as well as transuranic waste (TRU) and hazardous wastes. This DOE LLW/MLLW National Disposition Strategy, hereafter referred to as the National Disposition Strategy, discusses the Department’s long range strategy for managing its LLW and MLLW. A recent GAO report1 examined the national LLW disposal capacity and concluded that LLW disposal availability was adequate in the short term. In the long term, there may be a lack of disposal options for Class B and C LLW. In addition, EM is possesses a number of MLLW streams without a current treatment or disposal path, referred to as “orphan waste”. For example, there is no offsite disposal path available today for MLLW with radionuclide concentrations levels of 10 – 100 nCi/g (alpha MLLW). In some cases Federal or commercial treatment capacity for a given waste stream may exist, but these treatment facilities may have limited throughput and storage space. The objective of the National Disposition Strategy is to evaluate DOE LLW and MLLW disposition options for that waste which is transported off the generating site for disposition, i.e., off-site waste disposal. Orphan waste streams will be discussed in detail. The National Disposition Strategy will be developed in two phases. Phase I will examine selected DOE sites with a significant quantity of EM LLW/MLLW, specifically: Oak Ridge, Savannah River, Idaho, Hanford, Fernald, Miamisburg, Portsmouth and Paducah. Phase I will consider LLW/MLLW requiring off-site disposal from the present to approximately 2030. Phase II will examine those DOE LLW/MLLW streams not included in Phase I. TRU and hazardous waste are beyond the scope of this study because EM already manages a program for the complex-wide integration of TRU waste disposal. In addition, there is no compelling need for a hazardous waste national strategy because disposal of this waste has not been a problem within the complex. Rev.0 1 17 May 05 DRAFT LLW Commercial Disposal and Treatment Market There are currently three commercial disposal facilities that can accept DOE LLW and an additional facility that may become available. Envirocare Since 1988, Envirocare has operated a 540 acre disposal facility 80 miles west of Salt Lake City. Prior to 1988, DOE used the area for the disposal of uranium mill tailings. Much of the waste disposed at Envirocare comes from cleanup of commercial and government facilities. Also, Envirocare is the only commercial disposal facility to accept mixed waste. In 2003, Envirocare accepted about 99% of the nation’s Class A waste. The Utah Department of Environmental Quality (DEQ) has licensing and regulatory authority for the Envirocare facility. Utah originally approved Envirocare to accept naturally occurring radioactive material – large volume, low activity LLW. Since then, Envirocare’s license has been amended at multiple times to allow more types of radioactive waste including in 1991 when the state permitted disposal of LLW. In 1992 the Utah Division of Solid and Hazardous Waste granted Envirocare a RCRA Part B permit allowing the operation of a separate disposal cell for MLLW. In 1995 Envirocare constructed a mixed waste treatment facility to treat mixed waste subsequent to disposal. In July 2001, the Utah DEQ approved Envirocare’s license application to accept Class B and C wastes. Appeals were filed and, in February 2002, the department affirmed the approval. In March 2003, the Governor of Utah signed a bill placing a moratorium on any acceptance of Class B or C wastes through February 2005, and requiring legislative and gubernatorial approval for acceptance of these wastes. However, in February 2005, after a change in ownership, Envirocare formally withdrew its Class B and C license application. Envirocare has operated the disposal facility since its inception in 1988. The company has about 400 employees and about 250 employees are directly involved with LLW operations. Envirocare owns the disposal site land. The disposal site has the capacity for more than 20 years of operation under its current license. Currently the facility contains approximately 1.7 x 106 m3 of Class A waste. U.S. Ecology U.S. Ecology operates a 100 acre radioactive waste disposal facility, the Richland facility, located within the DOE Hanford site. Per the State of Washington Department of Ecology, the Richland facility may only accept LLW generated within the Northwest Compact. This Compact includes the states of Washington, Alaska, Hawaii, Idaho, Montana, Oregon, Utah, and Wyoming. However, regardless of the state of origin, the U.S. Ecology Richland facility may accept naturally-occurring and accelerator produced radioactive material, which is not addressed by the compact. Rev.0 2 17 May 05 DRAFT The State of Washington Department of Health exercises primary regulatory responsibility over the disposal facility. It issues licenses to the facility operator and regulates radioactive material. A Department of Health inspector examines each shipment of waste prior to disposal. The Department of Ecology has primary program responsibility. It issues individual permits for radioactive waste disposal to generators and serves as the site landlord U.S. Ecology currently has 18 employees at its Richland facility in addition to 4 administrative staff. The Richland facility has much unused capacity to accept LLW, approximately 600,000 m3. To date, the facility has disposed of approximately 400,000 m3 of LLW in 20 trenches. About 95% of the waste is Class A. U.S. Ecology also operates a waste disposal facility at Grandview, ID. Although licensed to accept RCRA and PCB wastes, the Grandview facility cannot accept most LLW. However, it can receive naturally occurring, accelerator produced and other NRC-exempt low activity radioactive waste. U.S. Ecology also has the capability to stabilize and encapsulate waste. Barnwell Disposal Facility The Barnwell disposal facility was opened in 1969, but the actual license for shallow burial of LLW was issued in 1971. Chem-Nuclear Systems has operated the Barnwell facility continuously since it opened. In 2000, this company became a subsidiary of Duratek Inc. This commercial disposal site is located near the DOE Savannah River Site. In 1976 the site was expanded to its present size of 235 acres with an original capacity to hold approximately 870,000 m3 of all classes of radioactive waste. Duratek currently employs about 100 people at the Barnwell facility. The South Carolina Department of Health and Environmental Control has licensing and technical regulatory authority. The Barnwell disposal facility is nearing capacity. About 102 acres of the 235 acre site has been filled, with about 13 acres remaining for disposal. There are about 75,000 m3 of space remaining. However, most of the remaining space has been reserved for the decommissioning of 12 nuclear power plants. In addition, the facility is planned for closure to out-of-compact waste by 2008. Furthermore, the South Carolina legislature has imposed volume caps on the amount of waste that Barnwell can accept. Waste Control Specialists (WCS) The Waste Control Specialists (WCS) facility is located 30 miles west of Andrews, Texas. At present this facility is licensed to treat, e.g. stabilization, process and store LLW and MLLW, including Greater than Class C (GTCC), PCB’s and sealed sources. The facility is not currently licensed for LLW disposal. WCS has a license application pending before the Texas Commission on Environmental Quality for near-surface land disposal of Class A, B and C LLW. Texas may license the Rev.0 3 17 May 05 DRAFT compact facility and an adjacent, separate and distinct facility for disposal of Federal low-level waste under Texas regulations. The regulations require that before accepting Federal facility waste, a written agreement must be signed by the Secretary of Energy. This agreement should state that the Federal government will assume all right, title, and interest in land and buildings for the disposal of Federal facility waste, together with requisite rights of access to the land and buildings. Commercial Vendor Matrix The Table on the following page summarizes the above commercial vendor information as well as listing available contract vehicles. LLW Commercial Treatment Market In addition to the commercial waste disposal facilities discussed above, there are a number of commercial vendors that are able to treat DOE radioactive wastes. Duratek Bear Creek Facility The Duratek Bear Creek Facility, located in Tennessee, offers LLW incineration, metal decontamination and metal melting. There is no DOE Complex-wide procurement vehicle, however Duratek has contracts and subcontracts at several DOE sites. Envirocare The Envirocare Facility, located in Clive UT, was discussed above as a disposal site. Envirocare treats and/or solidifies MLLW & liquid radioactive waste prior to disposal using macroencapsulation and stabilization in addition to PCB and organics removal. Envirocare treatment services can be procured through a Complex-Wide Indefinite Quantity Contract from the Chicago Operations Office. Pacific EcoSolutions (PEcoS) The PEcoS facility, located at Richland, WA, offers LLW thermal treatment and LLW/MLLW supercompaction, neutralization, stabilization and macroencapsulation. The facility can accept most kinds of waste under a Resource Conservation and Recovery Act (RCRA) Part B permit. There is currently no DOE-wide contract. DOE site contractors have been entering into direct procurements with PEcoS for waste treatment services. Rev.0 4 17 May 05 DRAFT Table 1 Commercial LLW/MLLW Disposal Facilities Commercial Vendor Envirocare Location Waste Accepted Restrictions Contract Vehicles Complex Wide: - DOE Chicago - MLLW: Oak Ridge - LLW: Ohio Clive, UT Class A LLW, MLLW & 11e(2) byproduct material Cannot accept class B & C waste. U.S. Ecology Richland, WA Class A, B & C LLW Duratek Barnwell, SC A, B & C LLW Cannot accept LLW from outside of Northwest compact. Cannot accept MLLW or 11e(2) byproduct material Army Corps of Engineers Army Joint Munitions Command Duratek has contracts and subcontracts at several DOE sites. Waste Control Specialists (WCS) Andrews, TX None, however license pending to accept class A, B & C LLW Cannot currently dispose of LLW Oak Ridge Perma-Fix/Diversified Scientific Services (DSSI) The Perma-Fix DSSI facility, located in Tennessee, offers thermal and non-thermal treatment for high organic MLLW. Wastes are combusted in a licensed boiler to meet land disposal restriction criteria. Perma-Fix treatment services can be procured through the Oak Ridge Broad Spectrum contract. Perma-Fix/Materials & Energy Corp. (M&EC) The Perma-Fix M&EC facility, located in Tennessee, treats both organic and inorganic MLLW (including PCB’s and Hg) using various non-incineration processes (e.g. vacuum thermal desorption). All waste codes are accepted and the license encompasses most isotopes. Perma-Fix treatment services can be procured through the Oak Ridge Broad Spectrum contract. Rev.0 5 17 May 05 DRAFT Waste Control Specialists (WCS) The WCS facility, located in Andrews, TX, was discussed above as a potential disposal site. WCS treats, (e.g. stabilization) processes and stores LLW & MLLW (including GTCC, PCB’s, sealed sources, solids and liquids). The current hazardous waste treatment capabilities include consolidation, repackaging, and stabilization for a wide variety of RCRA and TSCA wastes. Storage capability includes pre-packaged and treated LLW and MLLW, including GTCC and sealed sources. WCS treatment services can be procured through the Oak Ridge Broad Spectrum contract. LLW DOE Disposal and Treatment Capabilities Most DOE sites have the capability to dispose their LLW at their own on-site burial grounds. For example, Oak Ridge disposes waste from Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) remedial actions at its Environmental Management Waste Management Facility (EMWMF), an on-site CERCLA disposal facility. The Idaho National Laboratory (INL) operates a LLW disposal facility as part of the larger Radioactive Waste Management Complex (RWMC) for disposal of both contact-handled and remote-handled LLW. Recently, only two DOE sites, Hanford and the Nevada Test Site (NTS) have accepted LLW from other DOE sites. These two sites are discussed in more detail below. Currently, Hanford is not accepting LLW from other DOE sites because of a lawsuit with the State of Washington. Hopefully, this will be resolved shortly. The Toxic Substances Control Act Incinerator (TSCAI) is the only DOE facility capable of incinerating MLLW and, as such, is a unique DOE asset. Nevada Test Site The Nevada Test Site is a U.S. Department of Energy National Nuclear Security Administration Nevada Site Office facility. The site is approximately 1,375 square miles and is larger than the state of Rhode Island. Established in 1950 as the Atomic Energy Commission's proving ground for nuclear weapons testing, the site is located approximately 65 miles north of Las Vegas in the Great Basin desert. The facility is surrounded on three sides by federally owned and controlled land. Low-level waste is accepted for disposal from on and off-site DOE generators. Further, classified LLW is accepted for disposal from on and off-site DOE and DOD generators. Prior to waste acceptance, generators undergo a rigorous certification and acceptance process, which includes demonstrating compliance with the Nevada Test Site Waste Acceptance Criteria (NTSWAC). The NTSWAC provides requirements for the generator waste certification program, characterization, traceability, waste form, packaging, and transfer. The NTSWAC can be found at: (http://www.nv.doe.gov/programs/RadioactiveWasteAcceptance.htm). Rev.0 6 17 May 05 DRAFT There are two radioactive waste disposal facility areas on the Test Site: The Area 5 Radioactive Waste Management Site (RWMS) is a 732 acre facility (160 acres currently used for disposal) located north of Frenchman Flat (southeast corner of Nevada Test Site) and has a depth to groundwater of approximately 800 feet. The facility started operations in 1961 and began accepting off-site waste in 1976. Low-level waste is disposed in excavated trenches and pits, ranging in depth from 12 to 48 feet deep. The facility has a Mixed Waste Disposal Unit which, because it is operating under RCRA interim status, is currently restricted by the State of Nevada to disposal only DOE mixed low-level waste generated within the State of Nevada. A RCRA Part B Permit application is pending with the State to allow for the disposal of off-site generated MLLW. As of 13 March 2005, more than 350,000 m3 of LLW has been disposed at the Area 5 RWMS. Calculations based on existing inventory show that there is nearly 3 million m3 of remaining capacity in the existing 732 acres (including the developed 160 acres). The facility has the capability of easily expanding disposal operations to accommodate additional volumes of LLW. The Area 3 RWMS is the second low-level waste disposal facility at the Nevada Test Site. The 120 acre facility is located in Yucca Flat and has a depth to groundwater of approximately 1,600 feet. Disposal operations at the facility began in 1968. Low-level waste is actively disposed at the Area 3 RWMS. In addition, there is a closed, approved and permitted mixed LLW disposal cell at the facility. Waste disposed at the Area 3 RWMS is placed in subsidence craters formed by historic underground nuclear weapons tests. As of 13 March 2005, more than 550,000 m3 of low-level waste has been disposed in the facility and there is approximately 200,000 m3 of remaining capacity. The combined total of MLLW waste disposed (as of 13 March 2005) at both the Area 5 and 3 RWMS’s is 8,500 m3. The Nevada Site Office has submitted a revised RCRA Part B Permit Application which, if approved, would allow for an additional 20,000 m3 generated by approved DOE sites, both within or outside the state of Nevada. Hanford Site The Hanford Site was established in 1943 as part of the World War II nuclear weapons production effort. The Site occupies 586 square miles in southeastern Washington State (north of and adjacent to Richland, Washington). Disposal of solid LLW and MLLW currently occurs at two facilities – the Low Level Burial Grounds (LLBG’s) and the Environmental Restoration and Disposal Facility (ERDF). Both facilities are on the Hanford Site’s Central Plateau. There are other burial grounds throughout the Hanford site, but these are no longer in operation. The LLBG’s actual consist of eight specific burial grounds. They started operation in the 1960’s and cover about 1,050 acres, portions of which have never been used. Over 280,000 cubic meters have been disposed in the LLBG’s. Solid LLW and MLLW from onsite and offsite generators have historically been disposed in the LLBG’s. As a result Rev.0 7 17 May 05 DRAFT of the Hanford Solid Waste EIS Record of Decision (ROD)2, disposal of solid LLW and MLLW has been limited to two RCRA-compliant (i.e., double-lined and with leachate collection) mixed waste trenched within the LLBG’s. There is an exception for naval reactor compartments which were subject to previous NEPA decisions. About 2/3 of the approximately 45,000 cubic meter capacity (in terms of physical trench dimensions) of the mixed waste trenches remains. As a result of a preliminary injunction in an ongoing litigation, receipt of solid LLW and MLLW from offsite generators for disposal is currently suspended (with some courtapproved exceptions). Washington State Initiative 297 which would also prevent the receipt of offsite waste to Hanford has not yet been enacted pending other litigation. Information on the Hanford Site "Solid Waste Acceptance Program" and their waste acceptance criteria can be accessed at: http://www.hanford.gov/wastemgt/wac/index.cfm The ERDF is authorized by the EPA under CERCLA. The ERDF meets RCRA design requirements (e.g. double-lined with leachate collection) for disposal. The ERDF is a modular facility of which two cells (1 and 2) are full, two cells (3 and 4) are nearly full, disposal has started in two more (5 and 6), and the construction of two more cells (7 and 8) is planned for FY 2007. It is being pursued as an alternative disposal site (i.e., as an alternative to the two mixed waste trenches in the LLBG’s) for the disposal of nonCERCLA LLW and MLLW from Hanford generators. Construction of a new disposal facility, the Integrated Disposal facility (IDF) was started based on the Hanford Solid Waste EIS ROD2. The IDF is proposed to accept both LLW and MLLW from onsite and offsite generators, as well as the future Immobilized LowActivity Waste from the treatment of Hanford’s tank waste. Construction of the IDF has been stopped due to delays in obtaining the permits necessary to continue construction. These delays are associated with the litigation concerning receipt of LLW and MLLW from offsite generators and the Hanford Solid Waste EIS. Toxic Substances Control Act Incinerator (TSCAI) The Toxic Substances Control Act (TSCA) incinerator located on the East Tennessee Technology Park (ETTP) Site in Oak Ridge, Tennessee is DOE’s only treatment alternative for wastes that require incineration. It provides cost effective treatment for radioactively contaminated polychlorinated biphenyl (PCB) wastes and also provides for treatment of mixed low-level waste (MLLW) requiring thermal treatment. It enables other DOE sites to meet their Site Treatment Plan and Federal Facilities Compliance Act milestones, as well as their accelerated clean-up schedules. The TSCA incinerator will continue operations until 2008. Beyond that date, its future is uncertain, but will be determined based on the inventory of wastes still needing thermal treatment and the availability of cost effective alternative treatment methods. Rev.0 8 17 May 05 DRAFT EM LLW Streams The EM Closure Sites, Rocky Flats, Fernald and Mound The EM closure sites, Rocky Flats, Fernald and Mound, are scheduled to close in FY06 with the LLW shipping campaigns terminating in FY05. These sites are predominantly shipping their LLW and MLLW to either the Nevada Test Site (NTS) or Envirocare. In general, the waste shipped to NTS consists of the waste that does not meet the Envirocare Waste Acceptance Criteria (WAC). The Miamisburg Closure Project, i.e., the Mound site, does not have any LLW or MLLW orphan waste streams. However the Fernald Closure Project has one orphan waste stream which consists of 27 pounds of combined organic laboratory standards. The waste is liquid in laboratory containers that are currently packaged in two 5-gallon containers inside one 85-gallon drum. The waste is a combination of several hundred vials of unused organic laboratory standards. The waste is characterized as Resource Conservation and Recovery Act (RCRA) regulated, Toxic Substances Control Act (TSCA) regulated PCB, low-level radioactive waste. Table 2 FY 04 & FY05 Rocky Flats, Fernald and Mound LLW Shipments Site Rocky Flats Fernald Mound Stream MLLW MLLW LLW LLW LLW LLW LLW Destination Envirocare Hanford NTS Envirocare Envirocare Envirocare NTS Quantity FY04 (m3) 14,227 0 63,500 86,900 110,000 41,000 5,120 Quantity FY05 (m3) 20,913 1,000 51,000 197,000 122,000 60,643 3,250 Originally, Rocky Flats had a number of waste streams designated as orphan. They have now resolved the treatment and disposal issues for these formally orphan waste streams. As an example of how Rocky Flats solved problematic waste streams disposal, one orphan waste stream was drums of RCRA/PCB waste requiring thermal treatment. The bulk of the RCRA/PCB drums, ~ 25 drums, went to Permafix for thermal destruction, thermal desorption treatment prior to disposal at Envirocare. The remaining RCRA/PCB drums, ~ 5 drums, did not meet Permafix’s Waste Acceptance Criteria (WAC). Rocky Flats added these drums to the Toxic Substances Control Act Incinerator (TSCAI) burn plan. Rev.0 9 17 May 05 DRAFT As another example of problematic waste disposition, Rocky Flats shipped approximately 690 half crates B374 Solidified Bypass Sludge and B374 Wet Slurry to WCS for stabilization. This waste is alpha contaminated MLLW between 10 – 100 nCi/gm, which was intended for disposition at Hanford. Because of a current lawsuit by the State of Washington and a recently passed ballot initiative prohibiting the importation of nuclear waste into the State of Washington, the B374 waste remained in storage at WCS. Rocky Flats sent B Pond sludges to WCS where they were blended with the B374 wastes until the composite mixture met the Envirocare WAC for disposition at Envirocare. Portsmouth and Paducah The Portsmouth Project has several problematic waste streams. Some RCRA-regulated Portsmouth waste streams are troublesome because key radiological constituents (99Tc, 235 U, and/or 235U assay) exceed the Nuclear Regulatory Commission license limits, and therefore the waste acceptance criteria (WAC) of commercial mixed waste treatment facilities. Appendix E contains a list of problematic Portsmouth waste streams. The Paducah Site Office has one orphan waste stream, a 14.5 kg, 0.21 m3 container of a RCRA mixed wood preservative, pentachlorophenol. This is a MLLW containing dioxin with a listing of F027 and D037. Perma-Fix is the only mixed waste treatment facility permitted for the F027 code. Currently there is no disposal option for treated F027 waste in the United States. The Paducah Site Office plans to treat the waste at Perma-Fix and then return the treated F027 waste to the site. They will then try to delist the treated F027 waste for disposal at Envirocare or NTS. In addition, there may be other Paducah problem waste streams because a significant amount of waste from the Paducah DOE Material Storage Area (DMSA) and D & D projects has not been fully characterized. The Portsmouth and Paducah Project Office (PPPO) does not yet have an estimate of the total lifecycle amount of LLW and MLLW. They have an estimated amount for the work scope contained in both sites’ current contracts. This information is presented in Appendix E, Table E-1. A detailed estimate of the total lifecycle LLW/MLLW from both sites will be developed later. The Portsmouth site will transition into full scale D&D shortly, with the Paducah site following into D&D in the 2010-2012 timeframe. Savannah River Site The Savannah River Site (SRS) disposes of LLW on site in either slit trenches (lower activity waste, mainly soil and debris), engineered trenches (higher isotopic concentrations), or vaults (still higher activities and large equipment). Some LLW is also disposed off-site at NTS or Envirocare. SRS LLW and MLLW streams planned for offsite disposition through FY 2030 is presented in Appendix A, Table A-1. The information in this table originates from the DOE Waste Information Management System (WIMS) database. SRS disposed of most of their LLW and MLLW streams onsite, with off-site disposal occurring at Envirocare and NTS. SRS has not identified any treatment or disposal orphan waste streams. Rev.0 10 17 May 05 DRAFT Oak Ridge The LLW and MLLW disposition data through FY 2030 for the Oak Ridge Site, which consists of the Oak Ridge National Laboratory (ORNL) and the National Nuclear Security Administration (NNSA) Y-12 site, is listed in Appendix B, Table B-1, which is extracted from the WIMS database. Table B-2 in Appendix B presents the current list of Oak Ridge problematic waste streams. A number of the waste streams are orphans because they contain classified shapes. There is a lack of treatment capacity for classified mixed waste. Materials and Energy Corp. (M&EC), an operating Oak Ridge contractor, plans to install a classified treatment and storage capacity under a special security plan. This should be operational soon. Idaho National Laboratory The Idaho National Laboratory (INL) disposes of most of its LLW on-site at the Radioactive Waste Management Complex (RWMC). The contact-handled (CH) LLW is sent to the CH-LLW disposal pit while the remote-handled (RH) LLW goes to the RHLLW concrete vaults.3 The projected INL waste streams are listed in Appendix C, Tables C-1 and C-24. This table omits LLW to be disposed in the INEEL Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Disposal Facility (ICDF). The ICDF data is currently unavailable. Table C-3 lists the known INL orphan waste streams. DOE Richland and the Office of River Protection Appendix D presents and LLW and MLLW data from the Richland Operations Office and Office of River Protection, referred to collectively as Hanford. The data is derived from the “Final Hanford Site Solid, Radioactive and Hazardous Waste Program EIS” document # DOE-EIS-0286F, Appendix B.5 All Hanford LLW and MLLW will be disposed on site at the Integrated Disposal Facility (IDF). CERCLA wastes are dispositioned at the Environmental Restoration Disposal Facility (ERDF). Although Hanford does not plan to ship any LLW or MLLW off-site for disposal, a few MLLW streams will be sent to either PECoS or Permafix for treatment. The PECoS facility will treat the waste by macroencapsulation and stabilization while the Permafix facility will conduct thermal treatment. Rev.0 11 17 May 05 DRAFT Commercial Contract Vehicles and Associated Costs Envirocare There are three contract vehicles available complex wide, through the DOE Ohio Field Office, through the Oak Ridge Operations Office or via the DOE Chicago Operations Office. In addition, the U.S. Army Corps of Engineers plans on establishing a new Envirocare contract in the 2005 autumn. The costs for using each contract are presented in Table 3. Costs are per October 2004. In addition to the above, some DOE sites have direct contracts with Envirocare. For example, SRS has a contract with Envirocare that is very similar to the Oak Ridge contract. Also, the INEL M&O contractor, BBWI, has their own contract with Envirocare. Currently Hanford is not disposing waste at Envirocare. Should they require Envirocare’s services in the future, they indicated they would probably contract directly with Envirocare. U.S. Ecology U.S. Ecology has disposal contracts with the U.S. Army Corps of Engineers and the U.S. Army Joint Munitions Command. These contracts are available for use by the DOE. The Corps of Engineers contract pertains to the U.S. Ecology Grandview Idaho site and has been recently extended, while the Joint Munitions Command contract is applicable to either the Grandview or Richland facilities. The U.S. Ecology base disposal rate at their Richland facility is $80.00 per ft3 plus $10,640 per manifested shipment plus $5,440 per container on each manifest. In addition to the base rate there are further charges based on the dose rate on the container surface and some supplementary taxes and fees. Barnwell Barnwell has the highest disposal rates among the three commercial disposal facilities. The rates for Atlantic Compact generators, i.e. South Carolina, New Jersey and Connecticut, are $263 per ft3 for class A, $368 per ft3 for class B, and $394 per ft3 for class C. In addition, there is a $6.00 per ft3 compact surcharge. For generators outside of the Atlantic Compact, the base rate is $600 per ft3 with an additional $6.00 per ft3 surcharge. Barnwell also has a calculated rate based on the waste amount and dose rate. The larger of the two rates, base rate or calculated rate, is applied. Furthermore, Barnwell charges an additional $0.399 per mci for all shipments equal or greater than 100 mci. Rev.0 12 17 May 05 DRAFT Table 3 Envirocare LLW/MLLW Contracts Available to EM Sites Contracting Site Chicago Oak Ridge Ohio Contract # AM0202CH11136 (9/2002-9/2007) AC0504OR22693 (6/2004-5/2009) AM2498OH20053 (7/1998-6/2008) Contract Services Waste Category Treatment and Disposal MLLW Soil-Like $1,382(1)(2) MLLW DebrisLike $1,848(1)(2) MLLW MicroEncapsulation $2,778 to 4,610(1)(2)(3) MLLW Soils Ranges from $528 at 13,000 yd3 to $309 at 28,000yd3 (4) MLLW Debris $746 @ 13,000 yd3 to $527 @ 28,000 yd3 (4) LLW Soils $ 145 (5)(6) LLW Debris $ 397 (4) Disposal Only Disposal Only Cost ($/yd3) Note: The Corps of Engineers anticipates establishing a new contract with Envirocare during the autumn of 2005. (1) The annual escalation factor is 1.5%. (2) The treatability study is approximately $16,000 for each different waste stream; also add 4% for winter shipments. (3) The charge varies depending upon the type of container, e.g. 55 gal. drum vs. a B25 box. (4) Price fixed for the duration of the contract. (5) For lined railcar/truck with disposable containers. For unlined railcar/truck with lined containers add $28-30 per yd3. (6) Annual escalation factor of 2%. Rev.0 13 17 May 05 DRAFT Other Contract Vehicles Other contract vehicles may be available for DOE sites. For example, the DOD Executive Agency for Low Level Radioactive Waste, part of the, Army Field Support Command, can negotiate contracts with any of the waste treatment/disposal facilities discussed above. Pre-Disposal Costs When considering the disposal cost of a given waste stream, the actual fee paid to the TSD facility is a fraction of the total cost. A significant portion of the total LLW/MLLW treatment/disposal cost are the expenses incurred in preparing and shipping the waste, referred to as pre-disposal generator costs. The primary components of pre-disposal generator costs are waste characterization, treatment, packaging and transportation. A DOE report on life cycle costs of waste disposal estimated that pre-disposal costs may represent as much as 90% of the total cost6. Unit pre-disposal costs are strongly influenced by the radioactive constituents in the waste, the physical form of the waste, the origin of the waste, its point of generation relative to its disposal destination, and the waste volume. Because the Department disposes of a wide variety of LLW/MLLW, the amount of pre-disposal costs also varies extensively depending on the waste stream. Predisposal costs for on-site CERCLA disposal cells are much lower than for other TSD facilities because of the low costs associated with bulk landfill disposal as well as the large waste volumes. On the other hand, low volume waste streams requiring treatment, extensive characterization and special packaging could require pre-disposal cost exceeding $5,000/m3. The authors of the DOE report reference above conclude that it is difficult to accurately assess pre-disposal costs because the pre-disposal cost elements (characterization, treatment, packaging and transportation) are not customary DOE project accounting categories. There is no uniform complex-wide protocol for collecting and reporting such costs. However, because pre-disposal costs represent such a significant fraction of the total life cycle waste disposal costs, they also represent a significant life cycle cost savings opportunity. LLW and MLLW Disposition Gap Analysis Given the LLW and MLLW disposition data above, the study team conducted a gap analysis to identify potential bottlenecks and disposal capacity. First, the team designed a Waste Breakdown Structure (WBS) to categorize each major waste stream from the Phase I sites. The WBS is discussed in more detail in Appendix F. We then classified each waste stream per the WBS. The Phase I off-site LLW/MLLW treatment and disposition paths were then mapped onto an integrated waste disposition template. In general, adequate capacity exists at both commercial and federal disposal facilities for the bulk of the Department’s LLW. However, disposal of alpha MLLW between 10 Rev.0 14 17 May 05 DRAFT 100 nCi/gm remains a problem. The Department had planned to dispose of this type of waste at the Hanford site. Currently, legal obstacles preclude this disposal option. The State of Washington is suing the Department to prevent the importation of radioactive waste, including LLW. Issues pertaining to a recently-passed Washington state ballot initiative, Initiative 297, also need to be resolved before LLW shipments to Hanford can be resumed. The Department is now storing MLLW between 10 – 100 nCi/gm until Hanford becomes available. Should LLW shipment to Hanford remain impossible, the Department will have to consider commercial disposal options. At present there are no commercial waste sites that can accept alpha LLW between 10 - 100 nCi/gm. However, WCS has applied for a license modification that will allow it to dispose of LLW and MLLW, including this category of waste. Currently, each EM site is responsible for the disposal of its Low Level Waste (LLW). This decentralized approach could result in decreased cost efficiencies. For example, across the DOE Complex multiple contractors may seek disposal options for the same or very similar material. Consequently, opportunities may be missed for economies of scale. Sites cannot take advantage of economies of scale if they are seeking individual disposal contracts. Furthermore, sites may be competing for waste disposal capacity or overwhelming capacity because of schedule overlaps. Inefficiencies may also result because individual sites need to maintain duplicative capabilities. For example, small generators must maintain characterization programs for relatively small volumes and lack of priority for LLW disposal can result in costly storage. In addition disposal of some Mixed Low Level Waste (MLLW) can be difficult. Federal and commercial treatment capacity for most MLLW exists, but these treatment facilities have limited throughput and storage space. Individual sites often compete for access to treatment. Furthermore, there is no offsite disposal path available today for MLLW with radionuclide concentrations levels of 10 – 100 nCi/g (alpha MLLW). Although adequate treatment and disposal capacity exists for the bulk of the Department’s LLW and MLLW, some bottlenecks exist in throughput capacity. Treatment facilities have limited throughput and storage space, which may result in individual sites competing for access, e.g. TSCAI. As another example of a bottleneck, ORP’s revised plan for Hanford Tank waste may generate approximately 600 m3 of MLLW that may require thermal treatment. The throughput of the existing demo plant is inadequate to achieve the closure plan schedules. The current plant would require 70 years to treat all the tank waste. Even when adequate capacity exists, MLLW shipments may be infrequent, thereby stressing capacity at certain times of the year while under utilizing the same capacity at other times. Conclusions and Recommendations There is adequate capacity at both DOE and commercial Treatment, Storage and Disposal (TSD) facilities for the bulk of the Department’s LLW and MLLW. However, as noted in the gap analysis discussion above; problematic MLLW and 10-100 nCi/g orphan waste streams exist. To increase the efficiency of LLW and MLLW disposal, this report makes the following recommendations: Rev.0 15 17 May 05 DRAFT Consolidate Problem Wastes Prior to Treatment or Disposal To mitigate treatment or disposal bottlenecks, the Department could consolidate problematic wastes in a centralized location. This central facility could receive wastes from other sites to accelerate cleanup and prepare the waste for treatment and disposal. This would reduce the infrastructure and expertise requirements at each individual site for characterization, processing, and packaging. Consolidation should occur at sites with longer term missions and the appropriate NEPA analyses in place. Waste consolidation will allow sites to remove wastes, reduce the mortgage associated with storage, and enhance coordination of treatment and disposal opportunities. Consolidation may allow for an economy of scale as all similar wastes, even from different sites, could be disposed of in a single campaign. This should reduce the cost to disposition small waste quantities. The sites with small waste quantities would still characterize waste to the consolidated site’s WAC. Once the waste was consolidated, the cost per unit for disposing of the waste should be reduced by the economy of scale. Consolidating waste would provide cost savings by reducing overhead and mortgage costs at individual sites. For example, the alpha contaminated MLLW between 10 - 100 nCi/g, could be consolidated and stored until a suitable disposal site became available. This may also reduce the inter-site competition for treatment and disposal capacity. Problematic wastes could be stored at the consolidation site until treatment schedules can be synchronized more efficiently between the storage and treatment/disposal site. Develop a LLW/MLLW Database A centralized LLW/MLLW database can assist the Department in developing a corporate approach to LLW/MLLW treatment and disposal and consequently improve efficiencies. As observed above, because each site disposes its LLW and MLLW individually, opportunities may be lost for economies of scale. Multiple sites with similar waste streams may be able to negotiate more favorable disposal rates. Furthermore, with each site independently disposing waste, some sites may be maintaining duplicative capabilities. In addition to capacity issues, lack of centralized planning may result in various sites competing for limited treatment or disposal capability, e.g. TSCAI. Previously, EM had developed such a centralized database, the Integrated Planning, Accountability, and Budgeting System (IPABS) Stream Disposition Data (SDD). This system documented EM’s management strategy for more than 4,000 waste, contaminated media, spent fuel, and nuclear materials streams. Because of the complexity of the effort, EM discontinued the IPABS SDD. It may, however, be feasible to develop a system of fewer waste streams and minimal data that can meet the Department’s corporate need without being onerous. Perhaps the WBS developed during this project could prove to be an acceptable starting point. Cost information could be a significant component of any LLW/MLLW database. However, there are no uniform requirements for defining, monitoring and reporting waste Rev.0 16 17 May 05 DRAFT disposal costs. Across the Complex, there are significant site-to-site protocol differences in collecting cost information. If the Department is to use life cycle cost metrics to guide disposal site decisions, standardized protocols should be established to improve the bases for such decisions and for any subsequent analysis. Reduce Pre-Disposal Costs Pre-disposal costs are those costs incurred in preparing and transporting a given waste stream for disposal. Pre-disposal costs typically include: waste characterization, waste treatment, packaging and transportation. Pre-disposal costs are a major portion of the total waste disposal cost and therefore represent significant life cycle cost savings opportunities. Pre-disposal cost savings may be realized by: Rev.0 Developing a common pre-disposal cost chart of accounts for use by all waste generators. Re-evaluating site generator pre-disposal costs on a common basis. Establishing contractor incentives to reduce pre-disposal costs. 17 17 May 05 DRAFT References 1. General Accounting Office (GAO) report GAO-04-604, Low-Level Radioactive Waste, Disposal Availability Adequate in the Short Term, but Oversight Needed to Identify any Future Shortfalls, dated June 2004. 2. Record of Decision for the Solid Waste Program, Hanford Site Richland WA: Storage and Treatment of Low Level Waste and Mixed Low Level Waste and Storage, Processing and Certification of Transuranic Waste for Shipment to the Waste Isolation Pilot Plant, Federal Register, Vol. 69 No. 125, dated 30 June 2004. 3. Adler Flitton, M.K. and Mullen, C.K., Low-Level Waste Forecasting Assessment for the Idaho National Engineering and Environmental Laboratory, EDF-1591, Rev. 3, dated Aug. 2003. 4. Low-Level Waste Forecasting Assessment for the Idaho National Engineering and Environmental Laboratory, EDF-1591, Revision ID: 4; dated 22 July 2004. 5. Final Hanford Site Solid, Radioactive and Hazardous Waste Program EIS, document # DOE-EIS-0286F, Appendix B, dated Jan. 2004. 6. U.S. Dept. of Energy, Office of Environmental Management, Report to Congress, The Cost of Waste Disposal: Life Cycle Cost Analysis of Disposal of Department of Energy Low-Level Radioactive Waste at Federal and Commercial Facilities, dated July 2002. Rev.0 18 17 May 05 DRAFT APPENDIX A SAVANNAH RIVER SITE Table A-1 Off-Site Disposition of Savannah River Site LLW and MLLW Streams Material Quantity (m3) Destination FY05 FY06 FY07 FY08 FY09 FY10 FY11FY15 FY16FY20 FY21FY25 FY26FY30 MLLW Debris Envirocare 5.12 5.12 0 0 0 0 0 0 0 0 MLLW Metal Envirocare 0.6 0.6 0.61 0 0.61 16.5 166.1 85.7 13.5 0.2 MLLW Debris Envirocare 0.4 0.4 0.4 0.4 0.4 0.4 2.0 2.0 2.0 2.0 MLLW Other Liq. Envirocare 0.08 0.08 5.9 11.7 11.7 11.7 58.5 39.8 7.0 0 MLLW Other Liq. Envirocare 0.9 0.9 0.9 0.9 0.9 0.9 4.4 0 0 0 MLLW Soil, Sed., Sludge Envirocare 1.2 1.2 0.9 0.6 0.6 0.4 3.0 4.0 4.5 4.2 MLLW Debris Envirocare 80.5 80.5 18.3 56.8 16.6 17.7 116.1 119.8 233.4 146.3 LLW Soils Sed. Sludge NTS 5681 5681 0 0 0 0 0 0 0 0 MLLW Metal Envirocare 1.2 1.2 0.4 0.4 0.4 0.4 2.1 0.4 0 0 MLLW Debris Envirocare 0.3 0.3 0 0 0 0 0 0 0 0 Rev.0 19 17 May 05 DRAFT APPENDIX B OAK RIDGE NATIONAL LABORATORY Table B-1, Disposition of Off-Site Oak Ridge LLW and MLLW Streams Destination Material NTS LLW Debris LLW Soil* LLW Metal LLW Liq.. LLW Debris LLW Metal LLW Debris LLW Soil* LLW Metal MLLW Debris MLLW Soil* MLLW Liq. MLLW Debris (1) MLLW Debris (2) MLLW Debris (3) LLW Metal (3) LLW Debris (4) LLW Debris (3) MLLW Debris (3) MLLW Soil (3)* MLLW Metal (3) MLLW Debris (3) MLLW Debris (3) LLW Soil* (3) LLW Debris (3) LLW Debris (3) LLW Debris (3) MLLW Soil* (3) LLW Soil* (3) LLW Metal (3) LLW Metal (3) LLW Debris (3) LLW Debris (3) LLW Debris (3) MLLW Debris (3) GTS Duratek Envirocare TSCAI TBD (orphans) Quantity (m3) FY05 FY06 FY07 FY08 FY09 FY10 11-15 16-20 21-25 26-30 4211 1053 4006 10 10 0 347 645 0 2764 9 69 0 0 0 0 0 0 0 0 0 1144 8.1 1.5 0 36.4 0 0 0 0 0 0 0 2.21 223 4274 33 1928 10 10 0 271 5923 28 74 9 83 0.43 6.5 7.4 45 0 158.7 955.7 3410 295 581.5 8.1 1.5 1.6 35.4 0 0 0 0 7.8 0 66.5 1.1 3640 3086 0 417 10 0 0 274 334 4 0 9 0 0 0 8.2 15 0 158.7 955.7 3410 548 721.0 8.1 1.5 3.0 36.4 0 21.2 0 163 46.7 259 395 0 4250 419 0 8 0 0 17 717 231 64 0 8640 0 0 0 5.8 0 0.01 0 0 0 0 51.1 0 0 0 0 0 21.2 0 163 23.3 259 204 0 133 193 0 0.4 0 0 0 694 9 152 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 27.8 0 0 2 0 3140 0 0 0 966 26 159 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.25 0 52.8 0 0 0 27.8 0 0 2 0 9411 0 0 0 106 0 27 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0.03 0 52.8 0 0 0 6.9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 * Soil, Sediment and Sludge (1) (2) (3) (4) Rev.0 Orphan – no existing LDR treatment and disposal options. Orphan – No existing pretreatment option to remove classification issues. Orphan – Undecided destination, incomplete characterization. Orphan – Technology gap. Seven unirradiated mixed oxide (MOX) fuel rods containing U and Pu. 20 17 May 05 DRAFT Table B-2, Oak Ridge LLW and MLLW Problematic Waste Streams Waste Stream Remain On-Site Containers Final Treated Vol. (m3) Planned Treatment Planned Treat Facility Lack of Treatment capacity for classified MW. Classified Mixed Waste (D-Codes) 99 50.65 Shred Stabilization M&EC Classified Mixed Waste (F-Codes) 16 4.17 Shred/VTD/ stabilization/ debris wash M&EC Classified Mixed Waste (U-Codes) 3 Dioxin/Fur an Mixed Wastes Planned Disposal Status 18 1.3 8.06 Shred/VTD/ stabilization/ debris wash VTD/ debris wash/ Chem Ox M&EC to install classified treatment/storage capacity under special security plan. Lack of treatment capacity and RCRA Subtitle C disposal capacity for classified mixed waste. M&EC to install classified treatment/storage capacity under special security plan. Lack of treatment capacity and RCRA Subtitle C disposal capacity for classified mixed waste. M&EC M&EC to install classified treatment/storage capacity under special security plan. Lack of RCRA Subtitle C disposal capacity. M&EC M&EC to install classified treatment/storage capacity under special security plan for classified portion (6 containers) NTS NTS/ Hanford NTS/ Hanford NTS/ Hanford Envirocare to submit permit modification to include dioxin/furan waste codes. Rev.0 21 17 May 05 DRAFT Table B-2, Oak Ridge LLW and MLLW Problematic Waste Streams (Continued) Waste Stream RH Mixed Wastes Combust Code Mixed Wastes RTG Remain On-Site Containers 1 150 Final Treated Vol. (m3) 0.42 31.2 Planned Treatment Stabilization VTD Planned Treat Facility M&EC/ ORNL M&EC Planned Disposal Status Lack of treatment capacity for RH MW. Evaluating facility modifications at M&EC to handle high dose. Working agreement to treat at ORNL hot cell under TDEC temporary authorization or permit. Lack of treatment capacity for mixed wastes bearing combustion technology treatment standards. NTS E-Care Submit application for variance for alternative treatment technology IAW 268.42. Lack of approved Type B cask for shipment and burial at NTS. 2 0.1 None None Obtain NTS determnatn on Type B equivalent inner package for disp. NTS Revise shipping Cask CoC/SARP for Sr-90 RTG’s. Dose hazards associated with repackaging. Generator characterztn inadequate for NTS. Perform characterztn. RH LLW Vaults 29 116 None None Design and certify DOT compliant packaging for Type A shipment. NTS Vaults do not meet DOT Type A/B specs. Repackage some vault contents into smaller DOT complaint packages. Rev.0 22 17 May 05 DRAFT APPENDIX C IDAHO NATIONAL LABORATORY Table C-1 Disposition of Idaho National Laboratory LLW Streams, FY05 – FY12 Waste Type CH RH Quantity (m3) Destination FY05 FY06 FY07 FY08 FY09 FY10 FY11 FY12 RWMC 10,455 6,012 6,045 6,017 4,812 4,284 4,267 4,167 Hanford 0.5 0.27 0.51 150 900 900 900 900 NTS 0 0 0 0 360 360 360 360 Total 10,455 6,012 6,045 6,167 6,072 5,544 5,527 5,427 RWMC Vaults 66 64 64 64 64 2 2 2 RWMC Bulk Pit 47 63 59 64 64 64 64 64 Hanford 0 0 0 0 0 27 27 27 Hanford GTC3 Total 0 0 0 0 0 3 3 3 113 127 123 128 128 96 96 96 Table C-2 Disposition of Idaho National Laboratory LLW Streams, FY13 – FY30 Waste Type CH RH Quantity (m3) Destination FY13 FY14 FY15 FY16-20 FY21-25 FY26-30 RWMC 919 919 1,030 3,797 3,784 3,784 Hanford 900 900 900 4,500 4,200 4,200 NTS 360 360 360 0 0 0 Total 2,179 2,179 2,290 8,297 7,984 7,984 RWMC Vaults 2 5 5 12 17 12 RWMC Bulk Pit 41 39 39 207 201 207 Hanford 27 27 27 133 133 133 Hanford GTC3 3 3 3 13 13 13 Total 73 74 74 365 364 365 CH = Contact handled waste RH = Remote handled waste RWMC = Radiological Waste Management Complex Remote handled waste is defined by the Idaho National Engineering and Environmental Laboratory Waste Acceptance Criteria as waste having a radiation limit of > 500 mR/h at 1 meter. Conversely, contact handled waste is defined by the same document as waste having a radiation limit < 500 mR/h at 1 meter. Rev.0 23 17 May 05 DRAFT Table C-3 Idaho National Laboratory Orphan Waste Containers Volume (m3) Treatment Disposal 1 3.09 Macro Envirocare 1 0.68 ANL RWMC 17 30.90 Macro/Stab Envirocare 1@ PECoS WIR (has been resolved) 88 121.57 Macro/Stab Hanford 21 @ PECoS Class B&C; U134; Hanford Disposal Opening 10 7.47 Macro Hanford 3@ PECoS Class B&C; Hanford Disposal Opening 12 33.38 Aerosols/Stab/DF INEEL/PECoS/PESI/Envirocare 35 7.46 Thermal Envirocare 30 20.39 Specialty WIPP 6 4.09 Direct Disposal Hanford 200 229.02 Total Rev.0 Status Issues Transportation S1G Sodium Specialty PCB’s TRU Hanford Disposal Opening 25 @ PECoS 24 17 May 05 DRAFT APPENDIX D RICHLAND OPERATIONS OFFICE AND THE OFFICE OF RIVER PROTECTION Table D-1 LLW Generated by Hanford (Richland and ORP) (m3) Stream # 1 2 Stream Name LLW Cat1 LLW Cat3 2005 2006 2007 2008 2009 2010 2011 3,107 3,120 3,117 3872 4,611 3,827 3,902 20122046 36,156 561 551 534 534 349 345 1,513 30,782 The above data are from the “Final Hanford Site Solid, Radioactive and Hazardous Waste Program EIS” document # DOE-EIS-0286F, Appendix B Cat 1 LLW is the largest waste volume at Hanford. It has the lowest radioactive concentrations and can be placed directly into the Low Level Burial Ground (LLBG) trenches without treatment and, in some cases, without additional packaging. Cat 1 LLW can be either CH or RH waste. Originally, Cat 2 LLW was defined. However, this category was a small waste volume and now the previous Category 2 material is managed as Cat 3 LLW. Cat 3 LLW is defined as having radionuclide concentrations greater than the limits specified in the Hanford Site Solid Waste Acceptance Criteria (HSSWAC) for Cat 1 LLW, but lower than the maximum concentration limits defined for Cat 3 LLW. Cat 3 LLW is similar to Cat 1 LLW except that it has a higher concentration of certain radionuclides and requires greater confinement for burial in the LLBG. Cat 3 LLW may also be CH or RH waste. Greater confinement in the LLBG has typically been provided by either packaging the wastes in high-integrity containers (HIC) or by in-trench grouting prior to burial. Typical sources of Cat 3 LLW are operation or cleanout of hot cells and canyon facilities, removal of HLW storage tank equipment, and other operations that handle higher activity items. Hanford is not planning on shipping any LLW or MLLW off-site for disposal. They will, however, be shipping some MLLW off-site for treatment. Rev.0 25 17 May 05 DRAFT Table D-2 LLW from Off-Site Generators to be Received by Hanford (m3) Stream # 1 2 Stream Name 2005 2006 2007 2008 2009 2010 2011 LLW Cat 1 lower bound 663 1,121 376 369 387 369 373 20122046 11,669 upper bound 20,585 21,043 20,298 20,291 2,798 2,764 3,980 82,892 lower bound 115 17 25 18 17 17 17 621 upper bound 2,293 2,196 2,203 2,196 281 279 412 8,408 LLW Cat 3 The lower bound numbers include wastes from off-site generators approved for shipment to Hanford. The upper bound numbers include all waste in the lower bound data as well as potential future off-site waste that may be managed at the Hanford site. Table D-3 MLLW Generated by Hanford (Richland and ORP) (m3) Stream # 11 Stream Name Treated & Ready for Disp. 2005 2006 2007 2008 2009 2010 2011 1,183 863 1,111 1,612 2,164 2,136 2,613 20122046 12,726 12 RH & NonStandard 111 97 43 56 112 118 123 1,743 13A CH Inorg. Solids & Debris 426 377 329 368 385 381 688 12,724 13B CH Org. Solids & Debris 190 187 160 171 201 190 153 2,241 14 Elemental Lead 10 11 8 9 10 9 6 65 15 Elemental Mercury 0 1 1 1 1 1 1 1 MLLW Treated and Ready for Disposal – waste that has been treated meet the applicable RCRA and state requirements for land disposal. The River Protection Project (RPP) will Rev.0 26 17 May 05 DRAFT be the primary Hanford generator of MLLW. The RPP waste includes long length equipment from Hanford tank retrieval operations which will be macroencapsulated. MLLW received from off-site generators is assumed to arrive in a regulatory compliant form and ready for disposal. MLLW RH and Non-Standard Packages – this waste has physical and chemical characteristics similar to other MLLW, but requires a shielded facility and special equipment for remote handling. In the future, some non-standard packages of CH waste may also be received for which there is no treatment facility. This waste would remain in storage until treatment facilities are available. MLLW CH Inorganic Solids and Debris – Inorganic solid waste may include substances such as sludges, paints and dried inorganic chemicals. Debris waste must meet the requirements defined in state regulations. Inorganic debris waste often contain metal, ceramic, and concrete items and may result from removal of failed or obsolete equipment or from disposal of items used in process operations. They may also result from the cleanout or decommissioning of inactive facilities. These wastes generally require treatment by stabilization or macroencapsulation before disposal. MLLW CH Organic Solids and Debris – Organic solid waste may include substances such as resins, organic absorbents, and activated carbon. Organic debris waste meet the regulatory requirements for debris waste and have a great than 10% organic/carbonaceous content. Typical wastes include paper, wood and plastic. These wastes are normally required to be thermally treated if capacity is available. As there are no Hanford facilities with thermal treatment capability, DOE has been authorized to treat organic debris waste by macroencapsulation. MLLW Elemental Lead – Most of the lead waste has surface contamination and some of the lead is radioactive from neutron activation. Some lead must be treated as mixed waste by macroencapsulation, or other approved technology, before disposal. MLLW Elemental Mercury – Elemental mercury is a contaminant for several different types of waste. Waste can contain liquid mercury from various items (e.g. switches, thermometers and chemical process equipment). Mercury can be removed from bulk waste by thermal desorption and then solidified by amalgamation. Table D-4 provides the Hanford’s expectations of the MLLW streams that may arrive from other sites in the complex. As in Table D-2, the lower bound numbers include wastes from off-site generators approved for shipment to Hanford. The upper bound numbers include all waste in the lower bound data as well as potential future off-site waste that may be managed at the Hanford site. MLLW from off-site generators is assumed to arrive in a regulatory compliant form and ready for disposal. Rev.0 27 17 May 05 DRAFT Table D-4 MLLW from Off-Site Generators to be Received by Hanford (m3) Stream # 11 12 13A 13B 14 15 Stream Name Treated &Ready for Disposal lower bound 0 0 0 0 0 0 0 20122046 28 upper bound 19,500 19,500 19,500 19,500 1,521 1,305 1,307 38,731 RH & NonStandard lower bound 0 0 0 0 0 0 0 0 upper bound 0 0 0 0 0 0 0 0 CH Inorg. Solids & Debris lower bound 0 0 0 0 0 0 0 0 upper bound 0 0 0 0 0 0 0 0 CH Org. Solids & Debris lower bound 2 2 2 2 2 2 2 43 upper bound 2 2 2 2 2 2 2 43 Elemental Lead lower bound 0 0 0 0 0 0 0 0 upper bound 0 0 0 0 0 0 0 0 lower bound 0 0 0 0 0 0 0 0 upper bound 0 0 0 0 0 0 0 0 Elemental Mercury 2005 2006 2007 2008 2009 2010 2011 Table D-5 MLLW to be sent from Hanford to Commercial Treatment (m3) 2005 2006 2007 2008 2009 2010 2011 628 578 500 551 599 583 850 20122046 15,074 Per the “Final Hanford Site Solid, Radioactive and Hazardous Waste Program EIS” document # DOE-EIS-0286F, MLLW streams 13A CH Inorganic Solids and Debris, 13B CH Organic Solids and Debris, 14 Elemental Lead and 15 Elemental Mercury are to be send to commercial treatment facilities. This table was created by summing the annual projections from these waste streams. Rev.0 28 17 May 05 DRAFT The waste streams will be sent to either PECoS or Permafix. The PECoS facility will treat the waste by macroencapsulation and stabilization while the Permafix facility will conduct thermal treatment. Assuming that streams 13 A, CH Inorganic Solids and Debris, 13 B, CH Organic Solids and Debris and 14 Elemental Lead, will require stabilization or macroencapsulation treatment. Furthermore, assume stream 15, Elemental Mercury, will require thermal desorption followed by solidification by amalgamation. The Hanford MLLW sent to commercial facilities would be: Table D-6 Hanford MLLW to be Sent to Commercial Treatment, by Treatment Site (m3) 2005 2006 2007 2008 2009 2010 2011 PECoS 628 577 499 550 598 582 849 20122046 15,073 Permafix 0 1 1 1 1 1 1 1 Rev.0 29 17 May 05 DRAFT APPENDIX E PORTSMOUTH AND PADUCAH SITES Table E-1 Disposition of Off-Site Paducah LLW and MLLW Streams (FY05-FY12) Material Type Destination Debris Liq./Solv./Oils PPE Trash Soil Soil, Sludge Envirocare LLW Trtmt Residue Compct Metal Metal Equip. UF4 Drums PPE Trash TSCA/E-care Soil Sludge Lime Residue Debris Trtmt Residue MLLW Envirocare PPE Trash Compct Metal Excess Chem Metal Equip. Solids TSCA Solids TSCA/E-care MLLW Solids TSCA/E-care PPE Trash Soil Classifd Metal Debris LLW NTS Metal Equip. Asbestos Solids TSCA Soil MLLW TSCA/NTS Liq. TSCA MLLW TSCAI Debris LLW TBD Waste Water PPE Trash TBD DewtrdSludge Soil MLLW Debris Liq./Solv./Oils TSCA/TBD PPE Trash Compct Metal Total Envirocare Total NTS Rev.0 FY05 Quantity (m3) FY06 FY07 FY08 FY09 FY10 FY11 FY12 153 0 0 300 0 39 1,928 425 639 0 87 132 0 4 39 0 142 0 715 0 136 0 0 0 0 2,009 2,855 266 0 541 10 1,500 0 0 0 0 1 62 376 0 146,597 5,671 553 0 0 300 0 3 15,821 32,350 0 0 233 1 0 33 0 42 10 0 6 10 0 10 0 0 0 2,301 4,673 0 30 0 0 0 4 0 0 0 1 62 161 0 49,372 7,004 30 708 0 0 7 0 3 1,305 11,069 0 0 1,688 6 0 48 0 0 0 0 10 10 388 10 0 0 0 1,304 0 0 30 387 0 0 4 0 0 75 1 62 161 0 15,246 1,721 866 0 0 0 0 0 1,790 2,145 0 0 1,572 6 0 39 0 0 0 1 10 10 0 10 0 0 0 1,940 36 0 30 0 0 0 1 0 0 75 0 62 287 0 6,449 2,006 5,680 0 0 0 0 <1 1,209 1,703 0 0 927 0 0 72 0 0 0 0 13 10 0 10 0 0 0 2,509 399 743 30 0 0 0 0 0 0 0 0 62 233 0 9,624 3,681 1,098 0 0 0 0 0 0 3,583 0 0 4,166 0 0 52 0 1 0 0 13 10 800 10 0 1,014 0 8 0 0 30 805 0 0 0 0 0 0 0 62 107 0 9,733 1,857 2,385 495 0 5,521 0 0 0 2,297 0 92 9,371 0 0 4 0 12 0 0 0 10 0 10 0 821 0 0 0 0 30 0 0 0 0 0 0 0 0 62 54 0 20,197 851 17 May 05 750 1,485 0 3,675 0 0 0 316 0 36 279 3 0 105 0 0 0 0 0 10 0 10 4 321 0 1,066 0 0 30 0 0 0 0 59 15 592 0 0 0 0 6,669 1,421 DRAFT Table E-2 Disposition of Off-Site Paducah LLW and MLLW Streams (FY13-FY19) Material Type Destination Debris Liq./Solv./Oils PPE Trash Soil Soil, Sludge Envirocare LLW Trtmt Residue Compct Metal Metal Equip. UF4 Drums PPE Trash TSCA/E-care Soil Sludge Lime Residue Debris Trtmt Residue MLLW Envirocare PPE Trash Compct Metal Excess Chem Metal Equip. Solids TSCA Solids TSCA/E-care MLLW Solids TSCA/E-care PPE Trash Soil Classifd Metal Debris LLW NTS Metal Equip. Asbestos Solids TSCA Soil MLLW TSCA/NTS Liq. TSCA MLLW TSCAI Debris LLW TBD Waste Water PPE Trash TBD Dewtd Sludge Soil MLLW Debris Liq./Solv./Oils TSCA/TBD PPE Trash Compct Metal Total Envirocare Total NTS Rev.0 Quantity (m3) FY13 FY14 FY15 FY16 FY17 FY18 FY19 0 0 31 0 7 0 0 0 0 0 543 2 61 164 0 0 0 0 0 10 0 10 22 2,176 0 1,656 0 0 30 0 0 0 0 59 15 592 0 0 0 1,678 828 3,884 2,049 0 42 0 11 0 0 0 0 0 8,552 0 0 164 0 0 0 0 0 10 0 10 0 3 0 1,656 0 0 30 0 0 0 0 59 15 592 0 0 0 0 10,838 1,689 31 706 0 67 9,884 11 0 0 0 0 0 8,775 0 0 163 0 0 0 0 0 10 0 10 0 0 0 1,656 0 0 30 0 0 0 0 0 15 592 0 0 0 0 19,626 1,686 2,823 0 37 43,107 7 0 0 0 0 0 1,409 0 3 163 0 0 0 0 0 10 0 10 0 0 2,355 1,666 0 0 30 0 0 0 0 59 0 0 0 0 0 0 47,569 4,051 2,823 0 23 45,940 2 0 0 0 0 0 1,319 0 58 40 <1 0 0 0 0 10 0 10 0 0 3,767 405 0 0 30 0 0 0 0 0 0 0 0 0 0 0 50,225 4,202 706 0 3 3 0 0 0 0 0 0 127 0 0 0 <1 0 0 0 0 10 0 10 0 0 3,297 0 0 0 30 0 0 0 0 0 0 0 0 0 0 0 859 3,327 0 0 0 0 0 0 0 0 0 0 6 0 0 0 0 0 0 0 0 10 0 10 0 0 0 0 0 0 30 0 0 0 0 0 0 0 0 0 0 0 26 30 17 May 05 DRAFT Paducah Waste Streams without Viable Treatment/Disposal Options The Paducah site has identified one waste steam that may be problematical. The Pentachlorophenol waste stream does not meet the appropriate Waste Acceptance Criteria (WAC) because of its EPA hazard code. In addition, there may be other problem waste streams because there is still a lot of waste from the DMSA and D & D Projects at Paducah that has not been fully characterized. RCRA/MIXED WOOD PRESERVATIVE (Pentachlorophenol) One container (14.5 kg) (0.21 m3) Dioxin waste F027, D037 Mixed waste Perma-Fix is the only mixed waste facility with the F027 code on their permit. Currently there is no disposal option for treated F-027 waste in the United States. Treat waste at Perma-Fix, and return treated F-027 waste to Paducah. Padcuah will try to delist treated F-027 waste for disposal at Envirocare or NTS Portsmouth (PORTS) Troublesome Waste Streams Several RCRA-regulated waste streams at PORTS have been identified as troublesome because one or more of the key radiological constituents (99Tc, 235U, and/or 235U assay) exceed the Nuclear Regulatory Commission license limits, and therefore the waste acceptance criteria (WAC), of the available commercial mixed waste treatment facilities (either Broad Spectrum facilities [PermaFix or Waste Control Specialists] or Envirocare of Utah). For example, the commercial treatment facilities are generally limited to 350 grams of 235U onsite. Each of the PORTS troublesome waste streams is briefly summarized below. For each waste stream, the following information is provided: The volume currently in inventory The basis (hazardous waste code) for which it is hazardous Available radiological characterization information The treatment technology to be utilized Projected disposal path for the treated waste W015 – Heavy Metal Sludge 26 containers (110’s and B-25’s) (841 ft3; 23.8 m3) (22, 827lbs) Characteristic for metals D006, D008, D009 Many containers with high 235U gram content, 99Tc On site Chemical Oxidation/Stabilization treatment Disposal at NTS Rev.0 32 17 May 05 DRAFT W016 – Microfiltration Sludge and Filters 10 containers (drums) (41 ft3; 1.2 m3) (1,021 lbs.) Characteristic for metals D006, D008 High 235U gram content On site Stabilization treatment Macroencapsulation/shredding for filters Disposal at Envirocare W018 – Ion Exchange Resins 265 containers (drums, B-25s) (3,192 ft3; 90.4 m3) (127,504 lbs.) 262 drums characteristic hazardous waste (DOO8 - <240 ppm Hg) 3 B-25 boxes of F001 Resin from x-701E – NOTE: each of these is >200 grams of 235U in each container Some containers with high 235U gram content, some with high 235U assay, 99Tc (1213x106 pCi./g) Airborne rad contamination (99Tc, 235U) anticipated during sampling/treatment – may require a glovebox or some type of enclosure On site Stabilization treatment for drums On site Vacuum Thermal Desorption (VTD) treatment or possibly offsite TSCAI Incineration for B-25 boxes (need to evaluate if TSCAI candidate – metals content and number of grams per box may not meet TSCAI WAC) Disposal at NTS W022 – Waste Decontamination Solids 412 containers (F Cans, drums) (1,581 ft3; 44.8 m3) (68, 566 lbs.) Characteristic for metals D010/D011/D018, also F001/F002 On site Stabilization treatment Disposal at Envirocare W025 – HEPA Filters 4 containers (Lab Pack, drum, B-25 box), (202 ft3; 5.7 m3) (2,410 lbs.) 3 containers characteristic for metals D006/D008/D009 1 container F001 (Evaluate moving this to MWIR W001 with other F001 Treatment Filters) Some containers with high 235U gram content, some with high 235U assay On site Macroencapsulation treatment Disposal at Envirocare Rev.0 33 17 May 05 DRAFT W026 – Metal Shavings and Scrap 204 containers (5 are classified) (drums) (1,796 ft3; 50.9 m3) (75,523 lbs.) Characteristic for metals D006, D007, D009, (1 unclassified container F001, F002) Some containers with high 235U gram content, some with high 235U assay 1 container on site F001 VTD treatment Non classified treat onsite – On site Macroencapsulation treatment or treat at Duratek followed by disposal at NTS or on site disposal cell Classified – must be treated onsite, disposal following treatment at NTS W027 – X-705A Incinerator Ash 41 containers (F Cans, Drums) (167 ft3; 4.7 m3), (3,950 lbs.) 25 are in X-326 L Cage – HEU Characteristic for metals D006, D007, D008, D009, D011 Some containers with high 235U gram content, some with high 99Tc Airborne rad contamination (235U, 99Tc, Transuranics) expected sampling/treatment - may require a glovebox or some type of enclosure On site Stabilization treatment Disposal at NTS during W036 – Seal Dismantling Scrap Metal 3 containers (drums) (30 ft3; 0.8 m3) (1,269 lbs.) Characteristic for metals D006, D008 Containers expected to have high 99Tc On site Macroencapsulation treatment Disposal at Envirocare W043 – Filter Tank Gunk (Dissolved trap material (sludge)) 98 containers (drums) (1,048 ft3; 29.7 m3) (47,990 lbs.) Some containers with high 235U gram content, some with high 99Tc Characteristic for metal D009 Additional TCLP metals characterization data needed. Some rad and characterization data available. Airborne rad contamination (235U, 99Tc, Transuranics) expected during sampling/treatment - may require a glovebox or some type of enclosure On site Stabilization treatment Disposal at NTS W059 – Bag Filters 6 containers (drums) (35 ft3; 1.0 m3) (675 lbs.) Characteristic for metals D006/D009/D010/D011 Containers have high 99Tc On site Macroencapsulation treatment Disposal at Envirocare Rev.0 34 17 May 05 DRAFT W082 – HEU Waste 2 containers (8 ft3; 0.2 m3) (F- Can, drum) F-Can – D011 – Need to evaluate if this needs to be moved to W027 with other Filter Ash containers Drum – Lab Pack Characteristic for metals D008, P015 – Lab Pack container list indicates presence of Tower Ash – Transuranics present Airborne rad contamination (235U, 99Tc, Transuranics) expected during sampling/treatment - may require a glovebox or some type of enclosure Treat drum onsite with disposal at NTS W083 – Alumina Trap Material 188 containers (F-Cans, Drums, B-25 Boxes) (1,918 ft3; 54.3 m3) Characteristic for metals D004, D005, D006, D007 Additional TCLP metals characterization data needed. Some rad and characterization data available. Some containers with very high 235U gram content (i.e. 858 grams), some with high 99 Tc Airborne rad contamination (235U, 99Tc, Transuranics) expected during sampling/treatment - may require a glovebox or some type of enclosure On site stabilization treatment Disposal at NTS Rev.0 35 17 May 05 DRAFT APPENDIX F WASTE BREAKDOWN STRUCTURE Phase I 1. Level 1 – Generator Program a. EM – 01 b. NNSA – 02 c. NE – 03 d. SC – 04 2. Level 2 – Generator Site a. Oak Ridge – 01 b. Savannah River Site – 02 c. Idaho National Lab – 03 d. Hanford (to include the Office of River Protection) – 04 e. Fernald Closure Project – 05 f. Miamisburg Closure Project – 06 g. Portsmouth Project – 07 h. Paducah Site – 08 3. Level 3 – Waste Class a. Digit 1 – category i. Unknown = 0 ii. LLW = 1 iii. MLLW = 2 iv. 11e1 = 3 v. 11e2 = 4 vi. 11e3 = 5 b. Digit 2 – Is it GTCC? i. Unknown = 0 ii. No = 1 iii. Yes = 2 c. Digit 3 – Shielding/Handling Requirements i. Unknown = 0 ii. CH = 1 iii. RH = 2 d. Digit 4 – Level of transuranic radionuclides i. Unknown = 0 ii. < 10 nCi/gm = 1 iii. 10-100 nCi/gm = 2 Rev.0 36 17 May 05 DRAFT Appendix F, Waste Breakdown Structure (WBS), Phase I 4. Level 4 – Physical Waste Description (see note 4) a. Unknown – 00 b. Debris – 01 c. Metals – 02 d. Soil – 03 e. Liquid – 04 f. Other – 05 5. Level 5 – Treatment (see notes 5, 6 and 7) a. Unknown – 00 b. None – 01 c. Incineration – 02 d. Macroencapsulation – 03 e. Stabilization – 04 f. Vapor Thermal Desorption (VTD) – 05 g. Supercompaction – 06 h. Solidification – 07 i. Neutralization – 08 j. Metal Decontamination – 09 k. Metal Melting – 10 l. Other – 11 6. Level 6 – Disposal Site a. Unknown – 00 b. TBD – 01 c. Envirocare – 02 d. WCS – 03 e. U.S. Ecology – Richland, WA site – 04 f. U.S. Ecology – Grandview, ID site – 05 g. Barnwell, SC – 06 h. Oak Ridge Environmental Management Waste Management Facility (EMWMF) – 07 i. Savannah River Site Waste Management Complex – 08 j. Idaho National Laboratory Radioactive Waste Management Complex (RWMC) – 09 k. Idaho National Laboratory CERCLA Disposal Site – 10 l. Hanford Low Level Burial Grounds (LLBG) – 11 m. Hanford Environmental Restoration and Disposal Facility (ERDF) – 12 n. Hanford Integrated Disposal facility (IDF) (projected facility) – 13 o. Nevada Test Site Area 5 Radioactive Waste Management Site – 14 p. Nevada Test Site Area 3 Radioactive Waste Management Site – 15 Rev.0 37 17 May 05 DRAFT Appendix F, Waste Breakdown Structure (WBS), Phase I Notes: 1. The Generator Program, Level 1, is defined as the DOE program who “owns” the waste now, irrespective of which program may have originally generated the waste. 2. The WBS will include a dictionary that will define and describe each term and category. 3. Low Activity Waste is a level 3 waste class item that may be necessary pending future regulatory action. 4. We plan to also have a separate are, not linked to the WBS, were each individual waste stream will be described on a separate sheet. This will allow more information, such as chemical composition, to be included. This section will augment Level 4, Physical Waste Description. 5. The WBS will use a separate designator in level 5, Treatment, to indicate the site where treatment is occurring, e.g. Permafix, WCS, Envirocare. 6. The dictionary will explain that in Level 5, Treatment, if a waste stream is treated and cannot go directly to disposal, it will be treated as a new waste stream. For example, if a waste stream is to undergo Vapor Thermal Desorption (VTD) and then will be incinerated; the product from the VTD step is a new waste stream as it feeds to the incineration step. 7. For the Treatment (5) and Disposal Site (6) levels, the WBS will also include an “R” or “T” designator to indicate rail or truck transport mode. Rev.0 38 17 May 05