Annex 1 - TEMPLATE Category 2.2 Installations for the production of pig iron or steel (primary or secondary fusion) with a capacity exceeding 2.5 tonnes per hour Please complete one description table for each of the permits considered (see note 1) Designation of the permit: Description of the installation _______________________ Of (use an identification code, see note 1) Status of the installation: □ new, □ existing, substantially changed Year permit issued/updated: 21/02/2005 Reasons for selecting this permit for which ELVs are reported under this exercise: two IPPC 2.2. category installations, the only one which has an Environmental Permit (EP) Number of emission sources with ELVs at the installation: 3 sources (but only one of IPPC category 2.2.) Brief description of production technology linked to these emission sources subject to ELVs: □ sinter plant, □ pelletisation plant, □ coke oven plant, □ blast furnace, □ basic oxygen steelmaking, electric steelmaking Production capacity for the whole installation: □ < 1Mt/a, 1-3 Mt/a, □ > 3 Mt/a Use of waste (please indicate whether as fuel or raw material): scrap Other relevant information: This installation covers a secondary activity which comes under IPPC category 2.3( a), associated with one of the three point sources (FF2) Please complete one or more ELV tables based on the number of emission sources / activities at the installation (see note 1) Emission source/activity concerned by this ELV Table: FF1 (electric arc furnace, forno de afinação e campânula de cobertura da nave) Air pollutant (see note 2) 1. Limit value (see note 3) 2. Unit (see note 4) 3. ELVs related time period (see note 5) 4. Reference conditions and remarks (see note 6) 5. Monitoring – frequency and duration (see note 7) 6. Enforcement rules (see note 8) 7.Limit values derived from (see note 9) 8. Techniques applied for emission reduction and associated actual performance ranges (see note 10) 9. ELV trend (see note 11) Particulates 15 mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV BREF MTD GBR (3) CO 1000 mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV GBR (3) MTD GBR (3) NOx 500 mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV GBR (3) MTD GBR (3) SOx 500 mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV GBR (3) MTD GBR (3) Metals and their compounds (e.g. Pb, Zn, Hg) Cd+Hg- 0.2 mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV GBR (3) MTD GBR (3) mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV GBR (3) MTD GBR (3) n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV - MTD As+Ni-1 Pb+Cr+Cu – 5 Zn – none metals - 8 H2S 50 polycyclic aromatic hydrocarbons none 2 PCDD/PCDF (1) Others? COVNM- none mg/Nm3 n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV - MTD n.a (4) 8 % O2 (2) P- twice a year duration (5) All samples below the ELV GBR (3) MTD COT-50 Inorganic chlorine compounds 250 GBR (3) – Inorganic fluorine compounds –50 Remarks (1) ELV to be established as an addendum after the 2005 monitoring exercise (2) em aditamento à LA encontra-se em análise a alteração do valor indicado para e % de O 2 tal e qual medido, given that not all the emissions channelled to this point source are combustion emissions [Translator's note: the meaning of the first part of this phrase is not clear. ] (3) Ministerial Order 286/93, 12.03.1993 (4 ) not applicable, because the monitoring is ad hoc (5) duration specified in the applicable monitoring rules 3 Emission source/activity concerned by this ELV Table: FF2(5) (Forno de reaquecimento da laminagem) Air pollutant (see note 2) 1. Limit value (see note 3) 2. Unit (see note 4) 3.. ELVs related time period (see note 5) 4. Reference conditions and remarks (see note 6) 5. Monitoring – frequency and duration (see note 7) 6. Enforcement rules (see note 8) 7. Limit values derived from (see note 9) 8. Techniques applied for emission reduction and associated actual performance ranges (see note 10) 9. ELV trend (see note 11) Particulates 300 mg/Nm3 n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV GBR (3) MTD GBR (3) CO 1000 mg/Nm3 n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV GBR (3) MTD GBR (3) NOx 180.5 (2) mg/Nm3 n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV BREF MTD GBR (3) SOx 100 mg/Nm3 n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV BREF MTD GBR (3) Metals and their compounds (e.g. Pb, Zn, Hg) Cd+Hg- 0,2 mg/Nm3 n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV GBR (3) MTD GBR (3) mg/Nm3 n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV GBR (3) MTD GBR (3) As+Ni-1 Pb+Cr+Cu – 5 Zn – none metals - 8 H2S 50 polycyclic aromatic hydrocarbons (4) n.a (6) 8 % O2 P- twice a year duration (7) All samples below the ELV - MTD PCDD/PCDF (4) n.a (6) 8 % O2 (2) P- twice a year duration (7) All samples below the ELV - MTD 4 Others? mg/Nm3 COVNMnone n.a (6) 8 % O2 (2) P- twice a year duration (7) All samples below the ELV GBR (3) MTD GBR (3) COT-50 Inorganic chlorine compounds 250 – Inorganic fluorine compounds 50 – Remarks (1) ELV to be established as an addendum after the 2005 monitoring exercise (2) em aditamento encontra-se em estudo a alteração destes valor para 500 mg/ Nm 3, para 8% de Oxigénio, valor estabelecido na portaria 286/93 de 12 de Março, visto no BREF aplicado ao sector, a técnica produtiva associada a estas emissões não apresentar nenhum valor de emissão associado, contrariamente ao assumido na LA, por lapso [Translator's note: the meaning of this phrase is not clear. " valor estabelecido na portaria 286/93 de 12 de Março" means "value laid down in Ministerial Order 286/93, 12.03.1993] (3) Ministerial Order 286/93, 12.03.1993 (4) unmonitored parameter (5) point source associated with secondary IPPC category 2.3(a) (6) not applicable because the monitoring is ad hoc (7) duration specified in the applicable monitoring rules 5 Emission source/activity concerned by this ELV Table: FF3 (Sistema de despoeiramento da zona de transformados) Air pollutant (see note 2) 1. Limit value (see note 3) 2. Unit (see note 4) 3. ELVs related time period (see note 5) 4. Reference conditions and remarks (see note 6) 5. Monitoring – frequency and duration (see note 7) 6. Enforcement rules (see note 8) 7. Limit values derived from (see note 9) 8. Techniques applied for emission reduction and associated actual performance ranges (see note 10) 9. ELV trend (see note 11) Particulates 300 mg/Nm3 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV GBR (2) MTD GBR (2) CO (1) mg/Nm3 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV GBR (2) MTD GBR (2) NOx (1) mg/Nm3 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV - MTD SOx (1) mg/Nm3 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV - MTD Metals and their compounds (e.g. Pb, Zn, Hg) Cd+Hg- 0,2 mg/Nm3 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV GBR (2) MTD GBR (2) mg/Nm3 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV GBR (2) MTD GBR (2) As+Ni-1 Pb+Cr+Cu – 5 Zn – none metals - 8 H2S (1) 6 polycyclic aromatic hydrocarbons (1) n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV - MTD PCDD/PCDF (4) n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV - MTD Others? COT-50 n.a (3) 21 % O2 P- twice a year duration (4) All samples below the ELV GBR (2) MTD mg/Nm3 Remarks (1) unmonitored parameter (2) Ministerial Order 286/93, 12.03.1993 (3) not applicable because the monitoring is ad hoc (4) duration specified in the applicable monitoring rules 7 GBR (2) Emission source/activity concerned by this ELV Table: ETARI 2 (Estação de tratamento dos efluentes do circuito refrigeração primário da aciaria) Water pollutant (see note 2) 1. Limit value (see note 3) 2. Unit (see note 4) 3. ELVs related time period (see note 5) 4. Reference conditions and remarks (see note 6) 5. Monitoring – frequency and duration (see note 7) Suspended solids (1) - CQO 150 mg/l O2 DAV - P24h discharge period COT none - DAV - P24h discharge period Hydrocarbons (1) - Metals and their compounds (e.g. Cu, Pb, Ni, Cd, Zn, Cr, Hg) (1) - 8 6. Enforcement rules (see note 8) 7. Limit values derived from (see note 9) 8. Techniques applied for emission reduction and associated actual performance ranges (see note 10) 9. ELV trend (see note 11) / All samples below the ELV GBR (2) MTD GBR (2) / All samples below the ELV GBR (2) MTD GBR (2) Others? DAV pH – 6.0-9.0 - P24h discharge period Temperature increase of 3 ºC in the receiving environment CBO- 40 Total residual chlorine- 1.0 Free residual chlorine- 0.5 Sulphides – 1.0 Sulphites . 1.0 Sulphates 2000 Total phosphorus10 mg/l O2 mg/l Cl2 mg/l Cl2 mg/l S mg/l SO3 mg/l SO4 mg/l P Ammoniacal nitrogen –10 mg/l NH4 Total nitrogen 15 mg/l N Nitrates – 50 mg/l NO3 Fluorides – 15 mg/l F Detergents - 2 mg/l Remarks (1) unmonitored parameter (2) Decree-Law No 236/98 of 1 August 1998 9 / All samples below the ELV GBR (2) MTD Emission source/activity concerned by this ELV Table: IWWTP 2 (Estação de tratamento dos efluentes do circuito de refrigeração secundário da aciaria), IWWTP 6 (Estação de tratamento final das águas residuais provenientes da secção de laminagem e transformados) and discharge point EH1 Water pollutant (see note 2) 1. Limit value (see note 3) 2. Unit (see note 4) 3. ELVs related time period (see note 5) Suspended solids 60 mg/l DAV CQO 150 mg/l O2 DAV COT none - DAV Hydrocarbons (1) - Metals and their compounds (e.g. Cu, Pb, Ni, Cd, Zn, Cr, Hg) Al- 10 mg/l Al Fe-2.0 mg/l Fe Mn-2.0 mg/l Mn Pb-1.0 mg/l Pb Cd-0.2 mg/l Cd Cr-2.0 mg/l Cr Cr (IV)- 0.1 mg/l Cr (IV) Cu- 2.0 mg/l Cu Ni-2.0 mg/l Ni Zn – 2.0 mg/l Zn 4. Reference conditions and remarks (see note 6) 5. Monitoring – frequency and duration (see note 7) 6. Enforcement rules (see note 8) 7. Limit values derived from (see note 9) 8. Techniques applied for emission reduction and associated actual performance ranges (see note 10) 9. ELV trend (see note 11) P- 24h / month (3) All samples below the ELV GBR (2) MTD GBR (2) - P- 24h / month (3) All samples below the ELV GBR (2) MTD GBR (2) - P- 24h / month DAV P- 24h / month 10 MTD All samples below the ELV GBR (2) MTD GBR (2) Others? DAV pH – 6.0-9.0 - P- 24h / month Temperature – temperature increase of 3 ºC in the receiving environment CBO- 40 mg/l O2 Total residual chlorine – 1.0 mg/l Cl2 Free residual chlorine – 0.5 mg/l Cl2 Sulphides – 1.0 mg/l S Sulphites . 1.0 mg/l SO3 Sulphates 2000 mg/l SO4 Total phosphorus10 mg/l P Ammoniacal nitrogen –10 mg/l NH4 Total nitrogen 15 Nitrates – 50 Fluorides – 15 mg/l N mg/l NO3 mg/l F mg/l Detergents – 2 Total cyanides- 0.1 mg/l CN Oils and fats- 15 Mineral oils- 15 Chloroform-12 mg/l mg/l g/l 11 All samples below the ELV GBR (2) MTD GBR (2) Remarks (1) unmonitored parameter (2) Decree-Law No 236/98 of 1 August 1998 (3) for IWWTP 2 and IWWTP 6 the monitoring frequency is 24h / discharge period 12 Note 1: If no information is reported, please indicate the reasons in the remarks field at the bottom of the table (e.g. no IPPC-installations of this category in the Member States, no IPPC permit issued so far, no emissions to certain media). If an installation consists of more than one activity under the Annex I or an activity has several emission sources with different ELVs, please report ELVs for each activity/emission source in a separate ELV table. The identification code (e.g. a number, a letter) used to designate the permit should enable the Member States to track the installation concerned if further information is requested by the Commission. Note 2: Where limit values for other pollutants than those pre-selected in the template are set in the permit, these should be reported by adding to the template. It is noted that these parameters may be required to be controlled by virtue of legislation such as the waste incineration Directive or by virtue of the Stockholm convention on persistent organic pollutants, for example. Please find below some explanations for the expression of several pollutants (compare: Guidance document for EPER implementation, Appendix 3): - No distinction is made between particulates and total dust. - PM10 may already occur in several permits for new installations. It means total mass of particulate matter with particle diameters below 10 µm. - Metals and their compounds can be both metals bound on dust particulates or fugitive metals emissions. Please indicate which type of limit value you use in the permits in the “remarks” field. Please indicate single metals if you have single metals as emission limit values. If ELVs for metals have been grouped , please specify the grouping in the pollutants field and report the groups separately. - NOx means nitrogen monoxide and nitrogen dioxide expressed as nitrogen dioxide. - VOC means gaseous and vaporous organic compounds, including methane, use the expression NMVOC if methane is excluded. - TOC means total organic carbon. - SOx means sulphur dioxide and sulphur trioxide expressed as sulphur dioxide. - No Polycyclic aromatic hydrocarbons, please indicate the relevant measurement method (e.g. 16 PAH EPA or sum of 6 Borneff PAH. - HCl means total inorganic chlorine compounds expressed as HCl. - HF means total inorganic fluorine compounds expressed as HF. - PCDD/PCDF means polychlorinated dibenzodioxins and dibenzofurans expressed as toxicity equivalent. - COD means chemical oxygen demand. - BODn means biological oxygen demand. Indicate the relevant days in the “n”. Note 3: If there is no representative limit value for a pre-selected pollutant, please indicate this in the “limit value” field with a “none”. If emissions of these pollutants are prevented or reduced by prescribing technical measures rather than setting emission limit values, please indicate this in the “remarks” field. If the limit values applied are generally expressed as loads (e.g. t/day), these should be converted to a format that is “independent” of the size of the installation, such as concentration (e.g. g/l) or a specific emission (e.g. kg/t product). If this is not possible, please indicate this as “nc elv” (non-convertible emission limit value). If no data is available, please indicate it with “n.a.”. If a particular limit value contained in the permit is not yet in force by the end of the reporting period but it has to be met in a fixed year (e.g. 2007), such a value should also be reported, to the extent that it is representative, together with an appropriate remark. 13 Note 4: It is important to define the unit of each limit value in the “unit” field. Possible units are concentrations (mg/m³, mg/l, etc.), efficiency (e.g. % reduction/conversion), specific emission data like the mass, expressed in terms of certain specific parameters (e.g. kg/t output). It is not appropriate to use the unit mass/time (e.g. kg/y, tonnes/d) because these limit values are site-specific. Note 5: Indicate the time period the ELVs is related to. For instance the ELVs could refer to the following time period (please use the abbreviation as below): DAV HHAV HAV YAV daily average value half hourly average value hourly average value yearly average value Note 6: If there are any references to certain conditions for those limit values, e.g. certain oxygen content in the exhaust gas, there is a possibility to indicate this in the “reference conditions” field of the limit value. In case of insufficient space in the table letters or numbers can again be used and explained at the bottom of the table or on an additional page. Each reported limit value can be specified or explained in more detail in the “remarks” field, e.g. validity for water emission limit values only for direct water discharges or only for a certain unit in the installation or for certain capacities. It is crucial to mention those restrictions of reported limit values. Please use the “remarks” field for instance if the limit value is only valid for a specific unit of the installation, e.g. only for the combustion unit of an installation. Note 7: To improve comparability it is important to indicate how limit values are expressed with the link to how they should be monitored. In the field “monitoring” give an indication on the frequency and the duration of the sampling. For instance, it could be one 24 hours sampling each month to check the compliance with a Yearly Average Value or continuous sampling. Please provide information if the monitoring is carried out before abatement. When describing the frequency and the duration, please use the following abbreviation: C P Calc continuous measurement method including continuous sampling periodical measurement method (please specify in this case) calculation method using consumption of raw materials Note 8: The field “enforcement rule” refers to the rules used by competent authorities to determine, on the basis of the monitoring carried out, the compliance of the installations with the limit values set up in the permits (e.g. 4 samples below ELV out of 5, percentage of samples below the ELVs). Note 9: The field “Limit Values derived from” asks for information about where the respective limit value is derived from. Further explanations can be provided as a remark at the bottom of the table. One possibility is that on national level general binding rules exist with fixed limit values for this sector and this pollutant. Please use GBR as abbreviation and give a reference to this rule at the bottom of the page. If there are several of them, please add a number like GBR1. Please mention here, if possible, the techniques that can achieve the limit value. In those sectors where the limit values are derived from finalised BREFs please use the expression BREF and mention, if possible, the techniques that can achieve the limit value. Where the limit values are derived from national BAT documents please use the expression NBAT and mention, if possible, the techniques that can achieve the limit value. If the limit value was set based on international sources like OSPAR decisions use INT as abbreviation. Please indicate the source at the bottom of the page. 14 Another possibility is that a certain experience using a special technique was the reason for the limit value (e.g. special abatement techniques or primary measures, etc). Then use EXP as the abbreviation and explain it at the bottom of the page. This abbreviation could be used as well if the limit value is the result of an expert judgement. Last possibility is any other reason. Please use OTH as abbreviation and explain it at the bottom of the page. Note 10: in this field, useful information can be reported if possible on the performance ranges of the installation concerned during the reporting period compared to the limit values set in the permit. Performance should be reported using the same units and time periods as for ELVs. It is then useful to indicate the techniques applied to reach this level of performance. For the best performing installations Member States are invited to supply specific information on any special drivers for achieving the level of environmental performance and the economics associated with these installations in order to supply useful information to follow developments in BAT. Note 11: In order to illustrate the trends across the EU resulting from the implementation of IPPC Directive, Member States are invited to indicate the previous ELVs (if any) set for the installation concerned as well as the time frame of these previous ELVs. Please indicate in the remarks field at the bottom of the table if different units, time period, monitoring frequency and duration were established for the previous ELVs. 15 16