Unit 5 Study Guide 2. In soda pop, CO2(g) is a ______________, and water is the ______________. A) solute; solvent B) solvent; solute C) solution; solute D) solute; solution E) solvent; solution Ans: A 3. A mixture of sand and water is a(n) ______________. A) solution B) solvent C) solute D) aqueous solution E) none of these Ans: E 4. True or false? Approximately 38 g of NaCl can be dissolved in 100 g of water at 25°C. A solution prepared by adding 35 g of NaCl to 100 g of water at 25°C is unsaturated. A) True B) False Ans: A 6. When a solvent has dissolved all the solute it can at a particular temperature, it is said to be A) diluted B) unsaturated C) supersaturated D) saturated E) none of these Ans: D 8. An oven-cleaning solution is 40.0% (by mass) NaOH. If one jar of this product contains 457 g of solution, how much NaOH does it contain? A) 1.14 103 g B) 11.4 g C) 183 g D) 18.3 g E) none of these Ans: C 9. A nitric acid solution containing 71.0% HNO3 (by mass) has a density of 1.42 g/mL. How many moles of HNO3 are present in 2.02 L of this solution? A) 64.1 mol B) 32.3 mol C) 22.8 mol D) 3.09 10–2 mol E) none of these Ans: B 13. Determine the concentration of a solution made by dissolving 24.8 g of sodium chloride in 750.0 mL of solution. A) 0.318 M B) 33.1 M C) 0.424 M D) 0.566 M E) 18.6 M Ans: D 14. If you mix 20.0 mL of a 3.00 M sugar solution with 30.0 mL of a 4.11 M sugar solution, you will end up with a sugar solution of ________. A) 3.55 M B) 0.142 M C) 6.11 M D) 3.67 M E) 9.17 M Ans: D 15. You have 250.0 mL of 4.00 M sugar solution. You add 217.3 mL of water to this solution. Determine the concentration of the sugar solution after the water has been added. A) 4.00 M B) 2.39 M C) 2.88 M D) 2.14 M E) 2.47 M Ans: D 17. Which of the following aqueous solutions contains the greatest number of ions in solution? A) 2.0 L of 1.50 M sodium phosphate B) 2.0 L of 1.50 M magnesium chloride C) 3.0 L of 1.50 M sodium chloride D) 2.0 L of 2.00 M potassium fluoride E) 1.0 L of 3.00 M sodium sulfate Ans: A 19. What is the minimum volume of a 2.42 M NaOH solution needed to make 150.0 mL of a 0.800 M NaOH solution? A) 375 mL B) 24.8 mL C) 61.6 mL D) 120. mL E) 49.6 mL Ans: E 22. What volume of a 0.190 M Na2S solution contains 1.01 g of Na+ ions? A) 0.231 L B) 8.65 L C) 4.32 L D) 0.416 L E) 0.116 L Ans: E 35. What volume of a 0.550 M solution of potassium hydroxide can be made with 10.7 g of potassium hydroxide? (Ignore significant figures for this problem.) A) 19.5 mL B) 347 mL C) 191 mL D) 2884 mL E) 2.88 mL Ans: B 24. A 0.236-g sample of NaCl (molar mass = 58.44 g/mol) is dissolved in enough water to make 5.20 mL of solution. Calculate the molarity of the resulting solution. A) 0.777 M B) 4.04 10–3 M C) 1.29 M D) 0.889 M E) 0.633 M Ans: A 37. What mass of solute is contained in 417 mL of a 0.169 M magnesium fluoride solution? A) 4.39 g B) 70 g C) 10.5 g D) 1.13 g E) none of these Ans: A 26. A 54.5-g sample of SrCl2 is dissolved in 112.5 mL of solution. Calculate the molarity of this solution. A) 0.344 M B) 3.06 M C) 0.0387 M D) 4.38 M E) none of these Ans: B 38. What mass of solute is contained in 30.0 mL of a 1.56 M potassium bromide solution? A) 19.2 B) 5.57 C) 46.8 D) 2.54 E) none of these Ans: B 27. A 86.17-g sample of NaCl is dissolved in 250.0 mL of solution. Calculate the molarity of this solution. A) 1.475 M B) 344.7 M C) 5.898 M D) 7.131 M E) none of these Ans: C 40. A chemist needs 225 mL of 2.5 M HCl. What volume of 12 M HCl must be dissolved in water to form this solution? (Ignore significant figures for this problem.) A) 10.8 102 mL B) 15 mL C) 7.5 mL D) 21 mL E) 47 mL Ans: E 28. Calculate the mass of silver nitrate (in grams) in a 145 mL solution of 4.71 M AgNO3. (Ignore significant figures for this problem.) A) 800 g B) 0.800 g C) 116 g D) 30.8 g E) none of these Ans: C 32. The molarity of Cl– in 110. mL of a solution containing 3.33 g of CaCl2 is A) 0.273 M B) 0.0300 M C) 0.00330 M D) 0.546 M E) 0.366 M Ans: D 43. A 55.70-g sample of Ba(OH)2 is dissolved in enough water to make 1.20 L of solution. How many milliliters of this solution must be diluted with water in order to make 1.00 L of 0.100 M Ba(OH)2? (Ignore significant figures for this problem.) A) 369 mL B) 66.8 mL C) 325 mL D) 271 mL E) 557 mL Ans: A 44. What volume of 18.0 M sulfuric acid must be used to prepare 15.5 L of 0.188 M H2SO4? (Ignore significant figures for this problem.) A) 162 mL B) 218 mL C) 2.91 L D) 82.4 mL E) none of these Ans: A 46. You have 3.00 L of a 2.31 M solution of NaCl(aq) called solution A. You also have 2.00 L of a 2.00 M solution of AgNO3(aq) called solution B. You mix these solutions together, making solution C. Calculate the concentration (in M) of Na+ ions in solution C. A) 0M B) 2.31 M C) 3.47 M D) 0.86 M E) 1.39 M Ans: E 48. You have 3.00 L of a 3.74 M solution of NaCl(aq) called solution A. You also have 2.00 L of a 2.00 M solution of AgNO3(aq) called solution B. You mix these solutions together, making solution C. Calculate the concentration (in M) of Ag+ ions in solution C. A) 0M B) 1.44 M C) 2.24 M D) 0.800 M E) 3.61 M Ans: A 49. You have 3.00 L of a 3.00 M solution of NaCl(aq) called solution A. You also have 2.00 L of a 1.66 M solution of AgNO3(aq) called solution B. You mix these solutions together, making solution C. Calculate the concentration (in M) of NO 3 ions in solution C. A) 0M B) 0.664 M C) 1.14 M D) 1.66 M E) 1.80 M Ans: B 50. You have two HCl solutions, labeled solution A and solution B. Solution A has a greater concentration than solution B. Which of the following statements is/are true? A) If you have equal volumes of both solutions, solution B must contain more moles of HCl. B) If you have equal moles of HCl in both solutions, solution B must have a greater volume. C) To obtain equal concentrations of both solutions, you must add a certain amount of water to solution B. D) Adding more moles of HCl to both solutions will make them less concentrated. E) At least two of the above statements are true. Ans: B 52. If you mix 40.0 mL of a 0.366 M solution of K2CrO4 with 40.0 mL of a 0.366 M solution of AgNO3, what mass of solid forms? A) 4.86 g B) 2.43 g C) 2.84 g D) 14.6 g E) 7.32 g Ans: B 54. For the reaction between 200.0 mL of 0.100 M silver nitrate and 95.00 mL of 0.100 M sodium chloride, the concentration of silver ions in solution after the reaction is complete is A) 0.00 M. All of the silver ions are used up to make the precipitate. B) 0.100 M. The silver ions do not participate in the chemical reaction and are considered spectator ions. C) greater than 0.100 M. For every 1.0 mol of silver nitrate there are 2.0 mol of silver ions in solution. D) less than 0.100 M. Even though silver ions do not react, they are diluted when mixed with the sodium chloride solution. E) less than 0.100 M. Some, but not all, of the silver ions are used to make the precipitate. Ans: E 56. Calculate the volume of 0.188 M HNO3 required to neutralize 25.0 mL of 0.250 M NaOH. A) 18.8 mL B) 33.2 mL C) 4.70 mL D) 30.1 mL E) none of these Ans: B 58. In the following acid-base neutralization, 1.61 g of the solid acid HC6H5O neutralized 11.61 mL of aqueous NaOH solution base by the reaction NaOH(aq) + HC6H5O(aq) H2O(l) + NaC6H5O(aq) Calculate the molarity of the base solution. A) 1.47 M B) 17.1 M C) 7.21 M D) 0.139 M E) 0.199 M Ans: A 63. Which of the following solutions contains the smallest number of ions? A) 555.7 mL of 1.0 M lithium nitrate B) 386.4 mL of 2.0 M potassium hydroxide C) 197.8 mL of 2.0 M iron(III) chloride D) 233.4 mL of 1.0 M sodium sulfate E) At least two of the above contain the smallest number of ions. Ans: D 65. How many moles of chloride ions are in 62.6 mL of a 2.00 M aluminum chloride solution? A) 0.125 mol B) 0.0313 mol C) 0.0417 mol D) 0.751 mol E) 0.376 mol Ans: E 67. 15.0 mL of 0.30 M sodium phosphate solution reacts with 20.0 mL of 0.23 M lead(II) nitrate solution. What is the concentration of nitrate ions left in solution after the reaction is complete? A) 0.0 M B) 0.13 M C) 0.26 M D) 0.066 M E) 0.09 M Ans: C 70. You have three ammonium sulfate solutions on a lab table in front of you. All of the solutions came from a 500.0mL volumetric flask containing 3.00 M ammonium sulfate. Solution 1 contains 124.4 mL of the 3.00 M solution. Solution 2 contains 55.8 mL of the 3.00 M solution. Solution 3 contains 24.4 mL of the 3.00 M solution. How many moles of ions does Solution 2 contain? A) 0.167 mol B) 1.17 mol C) 0.502 mol D) 0.335 mol E) 0.251 mol Ans: C 72. You have three sodium carbonate solutions on a lab table in front of you. All of the solutions came from a 500.0mL volumetric flask containing 3.00 M sodium carbonate. Solution 1 contains 100.0 mL of the 3.00 M solution. Solution 2 contains 50.0 mL of the 3.00 M solution. Solution 3 contains 10.0 mL of the 3.00 M solution. What is the new concentration of Solution 2 if 16.5 g of solid sodium carbonate is added and dissolved? (Assume no volume change.) A) 3.11 M B) 12.1 M C) 1.91 M D) 6.11 M E) 0.611 M Ans: D 74. What mass of solute is contained in 50.0 mL of a 2.09 M potassium chloride solution? A) 23.9 g B) 1.78 g C) 104.5 g D) 7.79 g E) 35.7 g Ans: D