Product Name: Browning Treatment
Page: 1 of 5
This revision issued: February, 2016
Regent Industries Pty Ltd
Section 1 - Identification of The Material and Supplier
Canberra Discount Chemicals
3 Callan St
Mitchell, ACT 2911
Phone: (02) 6241 7119 (Business hours)
Fax: (02) 6253 8354
Chemical nature:
Water solution of sodium metabisulfite.
Trade Name:
Product Use:
Creation Date:
This version issued:
Browning Treatment
Colour Code
Removal of browning stains in carpets.
August, 2009
February, 2016 and is valid for 5 years from this date.
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Xn, Harmful. Hazardous according to the criteria of SWA.
Not a Dangerous Good according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria.
Risk Phrases: R22, R31, R41. Harmful if swallowed. Contact with acids liberates toxic gas (sulfur dioxide). Risk of
serious damage to eyes.
Safety Phrases: S20, S26, S36, S24/25, S37/39. When using, do not eat or drink. In case of contact with eyes,
rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. Wear suitable protective
clothing. Avoid contact with skin and eyes. Wear suitable gloves and eye/face protection.
SUSMP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
GHS Signal word: WARNING.
HAZARD STATEMENT:
AUH031: Contact with acids liberates toxic sulfur dioxide gas.
H302: Harmful if swallowed.
H319: Causes serious eye irritation.
PREVENTION
P102: Keep out of reach of children.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash contacted areas thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves, protective clothing and eye or face protection.
RESPONSE
P353: Rinse skin or shower with water.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice.
P370+P378: Not combustible. Use extinguishing media suited to burning materials.
STORAGE
P402+P404: Store in a dry place. Store in a closed container.
P403+P235: Store in a well-ventilated place. Keep cool.
SAFETY DATA SHEET
Issued by: Canberra Discount Chemicals
Phone: (02) 6241 7119 (business hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Browning Treatment
Page: 2 of 5
This revision issued: February, 2016
DISPOSAL
P501: If product can not be recycled, consider controlled incineration, or contact a specialist waste disposal
company (see Section 13 of this SDS).
Emergency Overview
Physical Description & colour: Clear, colourless, watery liquid.
Odour: Mild sulfur dioxide odour.
Major Health Hazards: may cause serious damage to eyes, harmful if swallowed.
Potential Health Effects
Inhalation:
Short term exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is a severe eye irritant. Symptoms may include stinging and reddening of eyes
and watering which may become copious. Other symptoms such as swelling of eyelids and blurred vision may also
become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy
exposure or delayed treatment is likely to cause permanent damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is harmful, but symptoms are not available. However, this product may be irritating to mucous membranes but is
unlikely to cause anything more than transient discomfort.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
SWA: No significant ingredient is classified as carcinogenic by SWA.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
Ingredients
CAS No
Conc,%
TWA (mg/m3) STEL (mg/m3)
Sodium metabisulfite
7681-57-4
10-30
5
not set
Water
7732-18-5
to 100
not set
not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The SWA TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day
for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no
longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures
at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this SDS with you when you call.
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about
30 minutes, seek medical advice.
SAFETY DATA SHEET
Issued by: Canberra Discount Chemicals
Phone: (02) 6241 7119 (business hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Browning Treatment
Page: 3 of 5
This revision issued: February, 2016
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until
chemical is removed.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
Only small quantities of decomposition products are expected from this products at temperatures normally achieved in
a fire. This will only occur after heating to dryness.
Fire decomposition products from this product are likely to be harmful if inhaled. Take suitable protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point:
Does not burn.
Upper Flammability Limit:
Does not burn.
Lower Flammability Limit:
Does not burn.
Autoignition temperature:
Not applicable - does not burn.
Flammability Class:
Does not burn.
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective chemically resistant clothing including eye/face protection, gauntlets and self contained breathing
apparatus. See below under Personal Protection regarding Australian Standards relating to personal protective
equipment. Suitable materials for protective clothing include rubber, PVC. If there is a significant chance that vapours
or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is
necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned
below (section 8). Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area
preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services.
Contaminated area may be neutralised by washing with weak or dilute oxidising agent. Dilute hydrogen peroxide may
be suitable. This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations
prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of
contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this SDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store packages of this product in a cool place. Make sure that containers of this product
are kept tightly closed. Pressure may build up in sealed containers, so do not seal tightly. Make sure that the product
does not come into contact with substances listed under "Incompatibilities" in Section 10. Check packaging - there
may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Occupational Protective Clothing: AS/NZS 4501
set 2008, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
SAFETY DATA SHEET
Issued by: Canberra Discount Chemicals
Phone: (02) 6241 7119 (business hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Browning Treatment
Page: 4 of 5
This revision issued: February, 2016
SWA Exposure Limits
TWA (mg/m3)
STEL (mg/m3)
Sodium metabisulfite
5
not set
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Protective glasses or goggles must be worn when this product is being used. Failure to protect
your eyes may lead to severe harm to them or to general health. Emergency eye wash facilities must also be
available in an area close to where this product is being used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour:
Odour:
Boiling Point:
Freezing/Melting Point:
Volatiles:
Vapour Pressure:
Vapour Density:
Specific Gravity:
Water Solubility:
pH:
Volatility:
Odour Threshold:
Evaporation Rate:
Coeff Oil/water distribution:
Autoignition temp:
Clear, colourless, watery liquid.
Mild sulfur dioxide odour.
Approximately 100°C at 100kPa.
Below 0°C.
Water component.
2.37 kPa at 20°C (water vapour pressure).
No data.
No data.
Completely soluble in water.
No data.
No data.
No data.
No data.
No data
Not applicable - does not burn.
Section 10 - Stability and Reactivity
Reactivity: No significant decomposition products. Releases sulfur dioxide in the presence of acids.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30°C. Keep containers tightly
closed. Under no circumstances should the container be sealed.
Incompatibilities: strong acids, zinc, tin, aluminium and their alloys.
Fire Decomposition: Only small quantities of decomposition products are expected from this products at
temperatures normally achieved in a fire. This will only occur after heating to dryness. Oxides of sulfur (sulfur dioxide
is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. sodium compounds.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Local Effects:
Target Organs:
There is no data to hand indicating any particular target organs.
Classification of Hazardous Ingredients
Ingredient
Risk Phrases
Sodium Metabisulfite
>=10%Conc<25%: Xi; R41; R31
SAFETY DATA SHEET
Issued by: Canberra Discount Chemicals
Phone: (02) 6241 7119 (business hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Browning Treatment
Page: 5 of 5
This revision issued: February, 2016
Section 12 - Ecological Information
Insufficient data to be sure of status.
Section 13 - Disposal Considerations
Disposal: This product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for
its intended use. If it has been contaminated, it may be possible to separate the contamination in some way. Only if
neither of these options is suitable, consider landfill.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good by ADG, IATA or IMDG/IMSBC criteria. No special
transport conditions are necessary unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredient: Sodium metabisulfite, is mentioned in the SUSMP.
Section 16 - Other Information
This SDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code
AICS
SWA
CAS number
Hazchem Code
IARC
NOS
NTP
R-Phrase
SUSMP
UN Number
Australian Code for the Transport of Dangerous Goods by Road and Rail (7 th edition)
Australian Inventory of Chemical Substances
Safe Work Australia, formerly ASCC and NOHSC
Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to emergency
services especially firefighters
International Agency for Research on Cancer
Not otherwise specified
National Toxicology Program (USA)
Risk Phrase
Standard for the Uniform Scheduling of Medicines & Poisons
United Nations Number
THIS SDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW
TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS SDS IN THE CONTEXT OF HOW
THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE,
THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT
TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This SDS is prepared in accord with the SWA document “Preparation of Safety Data Sheets for Hazardous
Chemicals - Code of Practice” (December 2011)
Copyright © Kilford & Kilford Pty Ltd, February, 2016.
http://www.kilford.com.au/ Phone (02)9251 4532
SAFETY DATA SHEET
Issued by: Canberra Discount Chemicals
Phone: (02) 6241 7119 (business hours)
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)