MSDS Health Hazard Data for the chemicals used in the “Chip Fabrication Process” =========================================================================== Health Hazard Data: ACETONE =========================================================================== LD50-LC50 Mixture: (ORAL-RAT)8.5-10.7 G/KG;ALMOST NON-TOXIC Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: NO SLIGHTLY IRRITATING. INHALATION:CENTRAL NERVOUS SYSTEM DEPRESSION. DERMATITIS. INHALATION:CNS DEPRESSION. INGESTION:NOT A LIKELY ROUTE OF ENTRY. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: THIS MATERIAL IS NOT CONSIDERED TO BE A CARCINOGEN BY NTP, IARC, OR OSHA. Signs/Symptoms Of Overexp: EYES:IRRITATION. SKIN:REDDNESS, EDEMA OR DRYING OF THE SKIN. INHALATION:DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS. INGESTION:NOT A LIKELY ROUTE OF ENTRY. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: EYES:FLUSH WITH WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION. SKIN:WASH EXPOSED AREA WITH SOAP AND WATER. INHALATION:REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF NECESSARY. INGESTION:DO NOT INDUCE VOMITING. ASPIRATION MAY CAUSE CHEMICAL PNEUMONIA. =========================================================================== Health Hazard Data: METHANOL =========================================================================== LD50-LC50 Mixture: ORAL LD50:9100MG/KG IN RATS. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: NO Health Haz Acute And Chronic: LIQ/VAP CAN PENETRATE SKIN/MUCOUS MEMBRANE THERFORE CONTROL OF INHAL MAY NOT BE SUFFICIENT TO TPEVNET EXCESSIVE DOSE. HARMFUL IF INHAL/ABSORBED THRU SKIN,CAUSES DMG TO LIVER/KIDNEY/NERVOUS SYST.CAUSES EYE/SKIN/NOSE/THROAT IRRIT.MAY BE FATAL/CAUSE BLINDNESS IF SWALLOWED.CAN'T BE MADE NON-POISONOUS. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: PER MSDS:LISTED AS CARCINOGEN IN:IARC/NTP/ OSHA:NO. Signs/Symptoms Of Overexp: ACUTE:NON-SPEC DISCOMFT(NAU,WEAK),TEMP CNS DEPRESS W/ANETHETIC EFFECTS(DIZZ,HEAD,CONFUSION,INCOORD,UNCONSC),BLINDNESS. HIG EXPO:ABNOR LIVER/KIDNEY FUNCTION DETECTED BY LAB TEST,FATALITY FROM GROSS EXPO.INGEST(AS LITTLE AS 60ML)MAY CAUSE BLINDNESS,FATALITY.SKIN PERMEATION CAN OCCUR IN AMTS-PRODUCES SYS TOXICITY. Med Cond Aggravated By Exp: INDIVIDUALS W/PRE-EXISTING DISEASES OF RETINA OR LIVER MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES. Emergency/First Aid Proc: EYE:FLUSH IMMED/THOROUGHLY FOR 15MINS W/ WATER.IRRIT PERSISTS GET MED ATTN.SKIN:IMMED FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS WHILE REMOVING CONTAMIN CLOTH/SHOES.CALL DR.INHAL:IMMED MOVE TO FRESH AIR.NOT BREATHING GIVE ART RESP;BREATHING DIFFICULT GIVE OXY.CALL DR.INGEST:AS LITTLE AS 60ML MAY CAUSE BLINDNESS/FATALITY.IMMED GIVE 2 GL 7 =========================================================================== Health Hazard Data: AMMONIUM HYDROXIDE =========================================================================== Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: CONSIDERED A POISON BY CONSUMER PRODUCTS SAFETY COMMISION BECAUSE OF STRENGTH. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Signs/Symptoms Of Overexp: RASPY CONTINUOUS COUGHING, RUNNY NOSE, EYE, SKIN AND/OR THROAT IRRITATIONS. Med Cond Aggravated By Exp: SKIN CUTS, BURNS, OR ABRASIONS. IRRITATED EYES. RESPIRATORY AILMENTS. Emergency/First Aid Proc: EYES: FLUSH W/LRG QTY WATER 15 MIN. CALL PHYSICIAN. SKIN: REMOVE CLOTHING/WASH AREA WITH WATER. INGESTION: DO NOT GIVE LIQUID IF VICTIM IS UNCONSCIOUS OR DROWSY. OTHERWISE, DRINK PROMPTLY LRG QTY OF WTER. FOLLOW WITH FRUIT JUICE AND VEGETABLE OIL. AVOID ALCOHOL. CALL PHYSICIAN IMMEDIATELY. =========================================================================== Health Hazard Data: HYDROGEN PEROXIDE =========================================================================== LD50-LC50 Mixture: UNKNOWN Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: PRODUCT MAY BE CORR TO EYES/SKIN & IRRIT TO RESP TRACT.ACUTE:MODERATELY TOXIC. CHRONIC:NOT DETERMINED. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: PER MSDS:EXPERIMENTAL MUTAGEN. Signs/Symptoms Of Overexp: CAUSES BURNS; DECOMPOSES IN THE BOWEL BEFORE ABSORPTION YIELDING LARGE VOLUME OF OXYGEN WHICH MAY CAUSE BOWEL TO RUPTURE. Med Cond Aggravated By Exp: PERSONS W/PRE-EXISTING EYE OR SKIN DISORDERS OR CHRONIC RESPIRATORY DISEASE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. Emergency/First Aid Proc: EYE/SKIN:IMMED FLUSH EYE/SKIN W/WATER FOR 15MINS. REMOVE CONTAMINATED CLOTHING. CALL PHYSICIAN. INGEST:DO NOT INDUCE VOMITING. GIVE 1-2 GLASSES OF WATER. CALL PHYSICIAN IMMED. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHAL:REMOVE TO FRESH AIR. ASSES OF WATER.INDUCE VOMIT.CALL DR.NEVER GIVE ANYTHING (SUPPLEM) =========================================================================== Health Hazard Data: HYDROCHLORIC ACID =========================================================================== LD50-LC50 Mixture: LD50:ORAL(RBT) 900 MG/KG Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: CONTACT CAUSES PERMANENT DAMAGE TO EYES, SEVERE BURNS, AND ULCERATIONS ON SKIN. INHALATION OF VAPORS WILL DAMAGE RESPIRATORY TRACT. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT. 8 Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN; GET IMMED MED ASSISTANCE. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH WITH SOAP AND WATER. INHAL: MOVE TO FRESH AIR AND GIVE ARTF RESP IF BREATHING HAS STOPPED. INGEST: DO NOT INDUCE VOMITING. GIVE MILK OR WATER IF CONSCIOUS. GET IMMED MED ATTN. GET MED ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. =========================================================================== Health Hazard Data: HMDS PRIMER =========================================================================== LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE:VAPORS ARE IRRITATING TO EYES, NOSE & RESPIRATORY TRACT. OVEREXPOSURE TO VAPORS MAY RESULT IN HEADACHE, NAUSEA, VOMITING. VAPORS HAVE OBJECTIONABLE ODOR. INGESTION MAY CAUSE HEADACHE, NAUSEA, VOMITING & ABDOMINAL PAINS. INGESTION MAY CAUSE MODERATE TOXICITY. CONTACT W/EYES & SKIN CAUSES SEVERE (EFTS OF OVEREXP) Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: HLTH HAZ:IRRITATION & MAY CAUSE CHEMICAL BURNS. CHRONIC:PROLONGED, REPEATED CONTACT MAY RESULT IN DERMATITIS. PROLONGED OR WIDESPREAD CONTACT W/SKIN MAY LEAD TO ABSORPTION OF HARMFUL AMOUNTS OF MATERIAL. Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: INGEST:CONT MD AT ONCE. EYE:FLUSH IMMED W/ PLENTY OF WATER FOR AT LST 15 MINS. CONT MD AT ONCE. SKIN:FLUSH IMMED W/ PLENTY OF WATER FOR AT LST 15 MINS. REMOVE CONTAM CLTHG. CONT MD. WASH CLTHG BEFORE REUSE. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. CONT MD AT ONCE. NOTE TO MD:THERE IS NO SPECIFIC ANTIDOTE. TREAMENT OF OVEREXP SHLD BE DIRECTED AT(SUPDAT) =========================================================================== Health Hazard Data: SHIPLEY PHOTORESIST =========================================================================== Toxicity Data: Toxicological properties have not been thoroughly investigated. Effects: · Acute Effects: Corrosive to all body tissues. Eye and skin contact, inhalation and ingestion can cause severe irritation and burns. Onset of symptoms may be delayed. · Chronic Effects: Prolonged, repeated contact with skin can cause drying, cracking, defatting, dermatitis. · Routes of Entry: Inhalation of mists or vapors, eye and skin contact, ingestion, skin absorption. First Aid: · Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Contact physician at once. · Skin: Flush immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. Contact physician. Wash clothing before reuse. · Eyes: Flush immediately with plenty of water for at least 15 minutes. Contact physician. · Ingestion: Do not induce vomiting. Give large amounts of water. Never give anything by mouth to an unconscious person. Contact physician. =========================================================================== Health Hazard Data: SHIPLEY DEVELOPER =========================================================================== Toxicity Data: Toxicological properties have not been thoroughly investigated. Effects: 9 · Acute Effects: Corrosive to all body tissues. Eye and skin contact, inhalation and ingestion can cause severe irritation and burns. Onset of symptoms may be delayed. · Chronic Effects: Prolonged, repeated contact with skin can cause drying, cracking, defatting, dermatitis. · Routes of Entry: Inhalation of mists or vapors, eye and skin contact, ingestion, skin absorption. First Aid: · Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Contact physician at once. · Skin: Flush immediately with plenty of water for at least 15 minutes. Remove contaminated clothing. Contact physician. Wash clothing before reuse. · Eyes: Flush immediately with plenty of water for at least 15 minutes. Contact physician. · Ingestion: Do not induce vomiting. Give large amounts of water. Never give anything by mouth to an unconscious person. Contact physician. 10