Joshua D

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Joshua D. Lawrence
Department of Chemistry,
Office: (318) 841-7362
Centenary College of Louisiana
FAX: (318) 841-7343
Shreveport, LA 71104
Email: [email protected]
PROFESSIONAL EXPERIENCE
Centenary College of Louisiana, Shreveport, LA
Associate Professor of Chemistry
(8/11 – present)
Assistant Professor of Chemistry
(8/05 – 8/11)
Research: Organometallic chemistry/organofluorine chemistry. Perfluoroalkylation of aryl C-H
bonds using FeI(CnF2n+1)L(CO)3 reagents in conjunction with Ag+ salts.
Teaching: General Chemistry I and II, General Chemistry Laboratory I and II, Analytical Chemistry
with Laboratory, Advanced Synthesis Laboratory, Advanced Inorganic Chemistry, and Chemical
Literature and Information Retrieval.
Service: Enrollment Management Committee (F-06 to S-09, Chair F-07 to S-09), Admissions
Committee (F-07 to S-09), Pre-Med Committee (F-07 to present), Honor Court (F-09 to present), Chair
of the Northwest Louisiana Local Section of the American Chemical Society (Jan. 08 to Dec. 09).
EDUCATION AND RESEARCH TRAINING
Yale University, New Haven, CT
Postdoctoral Associate/NIH Postdoctoral Fellow
(2/03 – 6/05)
Research: Organometallic chemistry. Catalytic transformations of alkyl and aryl C-H bonds.
Research Advisor: John F. Hartwig
University of Illinois at Urbana-Champaign (UIUC), Urbana, IL
(8/98 – 12/02)
Research: Bioinorganic chemistry. Ph.D. Thesis title: “Structural and functional models of the irononly hydrogenase enzymes”
Research Advisor: Thomas B. Rauchfuss
Rhodes College, Memphis, TN
(8/94 – 5/98)
B.S.-ACS in Chemistry
Research: Coordination chemistry. Honors Thesis Title: “Synthesis, characterization, and x-ray
crystallography of bis(phenanthroline) substituted-pyridine copper (II) complexes"
Research Advisor: David Y. Jeter
AWARDS/FELLOWSHIPS/GRANTS
Centenary College of Louisiana, Shreveport, LA
John Spencer and Virginia Doyle Hardy Professorship,
jointly awarded with Dr. Scott Chirhart ($5,000)
BoRSF Enhancement Grant ($16,361.25)
Petroleum Research Fund, Type G ($40,000)
Cottrell College Science Award, Research Corporation ($40,171)
Mattie Allen Broyles Inaugural Year Research Chair ($3,000)
Yale University, New Haven, CT
NIH Kirschstein-NRSA Individual Fellowship (total award, $39,700/year)
University of Illinois at Urbana-Champaign, Urbana, IL
T. S. Piper Award for Graduate Research in Inorganic Chemistry
Departmental Fellowships ($2500/year)
Excellent Teacher’s Assistant Rating
Curriculum vitae-1
(8/08-8/10)
(8/07-5/08)
(8/07-12/09)
(5/06-5/08)
(5/05-5/06)
(8/03-7/05)
(Spring 2002)
(Fall 1998-Spring 2002)
(Spring Semester 2001)
Joshua D. Lawrence
CITATIONS
The papers listed below have been cited in over 350 separate publications not originating from
UIUC or Yale. In addition, the work has been discussed, but not explicitly referenced, in:
“C-H-Aktivierung immer effektiver (C-H Activation becomes more effective),” Ullrich Jahn
Nachrichten aus der Chemie, 53, March 2005, “Water Splitting Goes Au Naturel,” Joe Alper, Science
2003, 299, 1686-1687, and “Can We Exploit Hydrogenases?” Chem. Eng. News 2002, 80, 35-39.
PUBLICATIONS (Centenary Students or Faculty in Bold)
Ruthenium-Catalyzed Regiospecific Borylation of Methyl C-H Bonds” Murphy, J. M.; Lawrence, J. D.;
Kawamura, K.; Incarvito, C.; Hartwig, J. F. J. Am. Chem. Soc. 2006, 128, 13684-13685.
“Photochemical and Thermal Borylation of Alkanes,” Hartwig, J. F.; Lawrence, J. D. In Handbook of
C-H Transformations; Dyker, G., Ed.; Wiley-VCH: Weinheim, 2005, pp 605.
“Regiospecific Functionalization of Methyl C-H Bonds of Alkyl Groups in Reagents with Heteroatom
Functionality,” Lawrence, J. D.; Takahashi, M.; Kawamura, K.; Bae, C.; Hartwig, J. F. J. Am. Chem.
Soc. 2004, 126, 15334 - 15335.
"New Class of Diiron Dithiolates Related to the Fe-Only Hydrogenase Active Site: Synthesis and
Characterization of [Fe2(SR)2(CNMe)7]2+," Lawrence, J. D.; Rauchfuss, T. B.; Wilson, S. R. Inorg.
Chem. 2002, 41, 6193-6195.
“Bimetallic Carbonyl Thiolates as Functional Models for Fe-only Hydrogenases,” Gloaguen, F.;
Lawrence, J. D.; Rauchfuss, T. B. Inorg. Chem. 2002, 41, 6573-6582.
“Synthetic and Structural Studies on [Fe2(SR)2(CN)x(CO)6-x]x- as Active Site Models for Fe-Only
Hydrogenases,” Gloaguen, F.; Lawrence, J. D.; Schmidt, M.; Wilson, S. R.; Rauchfuss, T. B. J. Am.
Chem. Soc. 2001, 123, 12518-12527.
“Biomimetic Hydrogen Evolution Catalyzed by an Iron Carbonyl Thiolate,” Gloaguen, F.; Lawrence, J.
D.; Rauchfuss, T. B. J. Am. Chem. Soc. 2001, 123, 9476-9477.
“Beyond Fe-only Hydrogenases: N-Functionalized 2-Aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x = 5,
6),” Lawrence, J. D.; Li, H.; Rauchfuss, T. B. Chem. Commun. 2001, 1482-1483.
“Diiron Azadithiolates as Models for the Iron-Only Hydrogenase Active Site: Synthesis, Structure, and
Stereoelectronics,” Lawrence, J. D.; Li, H.; Rauchfuss, T. B.; Bénard, M.; Rohmer, M.-M. Angew.
Chem. Int. Ed. Engl. 2001, 40, 1768-1771.
Curriculum vitae-2
Joshua D. Lawrence
PRESENTATIONS (Centenary Students or Faculty in Bold)
“Perfluoroalkylation of aromatic C-H bonds in the presence of carboxylic acid and trialkylamine
functionalities.” Craigo, K. E.; White, R. G., Jr.; Lawrence, J. D. 241st ACS National Meeting, 2010
(poster)
“Perfluoroalkylation of arenes in air: Synthesis of a perfluorobutyl analog of ibuprofen.” McMahen, R.
L.; Craigo, K. E.; Lawrence, J. D. 239th ACS National Meeting, 2010 (poster)
“Elements of undergraduate ACS member development.” McMahen, R. L.; Miccoli, C. E.; Monds, L.
C.; Craigo, K. E.; Lawrence, J. D. 239th ACS National Meeting, 2010 (poster)
“Synthesis of fluorescein-appended perfluoroalkyl iron compounds for use as potential biofunctional
imaging agents.” Crouthers, D. J.; Rawson, A. E. Lawrence, J. D. 237th ACS National Meeting, 2009
(poster)
“Arene-limiting perfluoroalkylation with iron carbonyl compounds.” McMahen, R. L.; Julien, D.;
Lawrence, J. D. 237th ACS National Meeting, 2009 (poster)
“Ligand exchange reactions of FeI(C4F9)(CO)4.” Crouthers, D. J.; Lawrence, J. D. 235th ACS
National Meeting, 2008 (poster)
“Scope of arene perfluroalkylation using iron reagents.” Timpa, S. D.; Clark, M. P.; Larson, B. W.;
Lawrence, J. D. 235th ACS National Meeting, 2008 (poster)
“Strong traditions and Green initiatives in the Centenary College of Louisiana SAACS.” Miccoli, C. E.;
Davis, E. A.; Jackson, K.; Lawrence, J. D. 235th ACS National Meeting, 2008
“Perfluoroalkylation of Aromatic Compounds,” Hammad, A.; Jurewicz, J. A.; Clark, M. P.; Lang, G.
M.; Lawrence J. D. 233rd ACS National Meeting, 2007. (poster)
“Selective functionalization of primary alkane C-H bonds in the presence of remote functional groups,”
Lawrence, J. D.; Takahashi, M.; Bae, C.; Hartwig, J. F. 228th ACS National Meeting, 2004. (oral)
"Models of the Oxidized Active States of the Fe-only Hydrogenase Enzymes," Lawrence, J. D.; Linck,
R. C.; Reynolds, M. A.; Rauchfuss, T. B. 224th ACS National Meeting, 2002. (poster)
“Chelating Azadithiolate Ligands Inspired by Fe-only Hydrogenases,” Lawrence, J. D.; Li, H.;
Rauchfuss, T. B. 222nd ACS National Meeting, 2001. (poster)
“Mechanistic and Electrochemical Investigation of Fe-only Hydrogenase Models: Why does Nature
Choose Two Cyanides?” Lawrence, J. D.; Gloaguen, F.; Rauchfuss, T. B. 222nd ACS National Meeting,
2001. (poster)
“Structural Models of the Binuclear Site in the Fe-only Hydrogenases,” Lawrence, J. D.; Schmidt, M.;
Rauchfuss, T. B. 6th International Conference on the Molecular Biology of Hydrogenases, 2000. (poster)
Curriculum vitae-3
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