Robinson 4:00 10 ETHICAL NANOTECHNOLOGY IN SOLAR POWER Alexander Marshall (alm236@pitt.edu) Furthermore, fossil fuels are finite resources and are being depleted at an alarming rate in relation to the growing population’s constant need for energy. THE GRAND CHALLENGE TO BEAT On February 15, 2008, the U.S. National Academy of Engineering met together in Boston in order to announce their “Grand Challenges for Engineering” in regards to the growing needs of a 21st century society. Due to the exponential growth of a human population, estimated to be 7 billion by the end of October 2011, today’s engineers are faced with the responsibility of “sustaining civilization’s continuing advancement, while still improving the quality of life”[nae]. Along with the increase in people comes an ever greater need for a reliable source of fuel to maintain the energy demands of a progressively more modern world. The solution to this issue is to incorporate a sustainable and renewable energy source that eliminates harm to the environment as well as the dependence on earth’s already strained finite resources. Solar energy has the potential to accomplish this problem. In fact, in just one day, enough power from the sun reaches the earth’s surface to meet the planet’s energy needs for one year [1]. However, today’s current methods of collecting and storing the sun’s energy are both inefficient and expensive resulting in only a small contribution to the world’s energy use. In order to address these issues, engineers must look at the challenge of “Making Solar Energy Economical” in order to provide society with a cheap, infinite energy source. The recent development of nanoparticles printed onto thinfilm with carbon nanotube solar funnels will help improve the efficiency as well as reduce the cost of photovoltaic devices. With the development of such innovations, however, the ethics must also be considered in order that society benefits as a whole as well as ensuring that any potential environmental or biological risks are entirely eliminated. Such ethical issues that must be considered in regards to nanotechnology in solar power are caution when using harmful materials, ensuring the availability of this technology to all members of society, and honesty concerning its capabilities and performance. By studying and researching this code of ethics students will learn about their responsibility to the modern world and understand the consequences of their actions. FIGURE 1 PROJECTED WORLD ENERGY DEMANDS [2] Solar energy, on the other hand, has the potential to solve all of these problems. This is due to its indefinite lifetime (the sun will never go away), little to no negative environmental impact, and free transmission from the sun. “Only a small fraction of the sun’s power output strikes the Earth, but even that provides 10,000 times as much as all the commercial energy that humans use on the planet” [3]. In spite of this, only 1% of the global energy consumed is produced by solar power [3]. Using current technology, solar power cannot yet compete on a large scale with fossil fuels due to its high production costs. The present-day method of making solar panels out of silicon crystals is timeconsuming and expensive, creating products that are heavy and difficult to make readily available to a remote areas of the world [4]. Today’s common solar sources produce electricity at a cost of about $0.30 per kilowatt hour (kWh), while electricity from wind costs about $0.05 per kWh and from natural gas about $0.03 per kWh [1]. In order for solar power to be feasible on a large-scale as well as in remote areas, this price must fall. In order for this to be done several important components must be altered. First, the process of manufacturing the panels has to become faster, cheaper, and easier. This will directly lower the prices of panels. Secondly, the method by which the panels collect and convert sunlight into electricity must be improved in order to raise the energy efficiency and thus increase output and WHY SOLAR? The current global dependence on fossil fuels has led to serious environmental and health consequences which can no longer be ignored. The huge carbon footprint which is being emitted from our current energy grid has led to an alarming increase in global temperatures as well as a serious pollution crisis which afflicts many dense population areas. University of Pittsburgh Swanson School of Engineering 1 10/31/11 Alexander Marshall In today’s modern world society has become increasingly dependent on technology and the energy that powers such innovations. This dependence has advanced to the degree where the slightest error on the part of the engineers trusted to do their jobs would be grave if not catastrophic. This requires the engineer to be aware of the many principles of ethical conduct that are entailed by such a profession with a tremendous amount of responsibility. The National Society of Professional Engineers (NSPE) Code of Ethics provides a template that engineers can follow so that they can perform their profession for society’s upmost benefit. Solar energy does not have many directly unethical features arising from its use since its very purpose is to eliminate those issues posed by fossil fuels. However, there are still principles to be considered when dealing with solar innovations. For example, one of the canons from NSPE code of ethics states “Engineers shall hold paramount the safety, health, and welfare of the public”[3]. This is perhaps the most serious of the canons as the ramifications for negligence are huge. For example, the use of cadmium, an extremely toxic metal used in the manufacturing of photovoltaic devices must be cautiously handled. If taken in large quantities, cadmium can cause kidney damage, respiratory problems, cancer, and even bone damage to humans [10]. Due to these high risks, the workers coming into contact with dangerous components such as this must be protected. Also, engineers must be completely honest about the potential risks of such substances since the need for truthfulness in solar power is stated by the California Solar Energy Industries (CSEI) Code of Ethics as “Members shall avoid deceptive acts in the solicitation of solar work” [11]. The ramifications of dishonesty can also extend to falsification of the potential output and efficiency. This could lead to great deal of harm as a solar panel’s expected energy output would not meet the demands, causing a serious dilemma. Another issue towards which little thought has been directed is making nanotechnology available to the entire world. The current front-runners in the development of nanotechnology are all affluent nations with many resources. Once these technologies are developed they will reduce cost as well as increase efficiency and output. These benefits would be best enjoyed by underprivileged nations, especially those with high populations, making energy available to a great deal more people. However, no one likes to give away newly developed technology. It is this selfishness that has caused AID’s medications to just begin arriving to impoverished countries, even though they were developed years ago. Engineers need to overcome this tendency and make cheap solar power available to all of society [12]. lower the price of electricity. Thirdly, the solar panels have to be a more convenient weight and size, increasing the number of locations where they can be installed. If these components can be achieved and effectively combined, the future of energy production could be dramatically altered [5]. NEW NANO-TECH In order to surmount these challenges against solar power, today’s engineers and scientists have explored, tested, and utilized innovative new ideas from the field of nanotechnology. One of the areas which holds the most promise is printable nanoparticles. Several companies have developed nanoparticle inks made from copper, indium, gallium, and selenide (CIGS) that can be sprayed onto flexible substrates to form layers of semiconductor raising panel efficiency up to 20% [6]. Although these surfaces are limited now to aluminum foil, research is being done to print these nanoparticle films directly onto clothes and buildings, thus reducing installation prices and eliminating the need for mounting steel, currently used to hold silicon panels. In these non-silicon film-panels the nanoparticles of CIGS selfassemble in a uniform distribution, ensuring that the atomic ratio of the elements is always correct [7]. The CIGS-onglass cell requires a layer of molybdenum to create an effective electrode. This extra layer isn't necessary in the CIGS-on-foil cell because the metal foil acts as the electrode[8]. A layer of zinc oxide (ZnO) plays the role of the other electrode in the CIGS cell. Sandwiched in between are two more layers -- the semiconductor material and cadmium sulfide (CdS). These two layers act as the n-type and p-type materials, which are necessary to create a current of electrons [6]. In order to increase the efficiency of the panel, carbon nanorods can be applied to this dye. Singlewalled carbon nanotubes (SWNTs) have long been regarded as promising components of nanocomposite photoanodes in photovoltaic devices because of their excellent electron mobility and one-dimensional shape [9]. Unlike normal panels, which act at optimum efficiency when hit directly by bright sunlight, the nanorods form a multi-layer coating that works like a series of light funnels. The top layer of nanorods takes the light hitting the panel at wide angles and bends it to a slightly narrower angle. Successive layers narrow the angle even further, funneling the light so it hits the active region of the panel at a ninety-degree angle, eliminating the need to rotate the panel with the sun [9]. Once this technology is made readily available to the public on a large, affordable scale, its use will increase dramatically, decreasing carbon emissions as well as energy prices. However, due to this increased, widespread usage engineers must think of the ethics behind their actions and the consequences that straying for such a code would have. ETHICAL EDUCATION’S BENEFITS As a current student studying engineering, I am currently in the process of developing the skills necessary to be successful in the working world. While I still have much to IMPORTANCE OF ETHICS 2 Alexander Marshall collection in photovoltaic devices. ” Nature Nanotechnology. [Online Article].Avalible:http://www.nature.com/nnano/journal/v6/n6/full/nnano.20 11.50.html#/synthesis-of-nanocomposites [9]E. Ortlip.(January, 2009). “Nanotechnology Makes Solar Power More Affordable.”Science Line. [Online Blog Post]. Avalible: http://scienceline.org/2009/01/blog-ortlip-solar-energy-light-renewable/ [10]Godt, J. (September 2006) “The Toxicity of Cadmium and Resulting Hazards for Human Health.” PubMed Central. [Online Article]. Availible: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC1578573/ [11] (July 2007). “NSPE Code of ethics for Engineers.” National Society of Professional Engineers. [Online Article].Avalible. http://www.nspe.org/Ethics/CodeofEthics/index.html [12] Grossman. J “Nanotechnology’s Role in Making Cheap Solar Power.” Small Talk Podcasts. 14 Oct. 2006. Exploratorium. 16 Apr. 2007. http://www.exploratorium.edu/ti/podcasts/smalltalk.php. learn, I strive for the goals and expectations that are required of me. I am aware of the tremendous accountability and that I have towards a society that is so reliant on my abilities. This is due to the research, evaluation, and writing on the subject of the code of engineering ethics. After doing extensive reading on this code I am now aware what I must do to serve humanity to my fullest capabilities. I believe that the best method for learning these fundamentals to an engineering education are through an analytical research paper that allows students to examine the significance of ethics on their own. Even though a Code of Ethics exists, I would never have taken the time to study it in depth. To ensure that future engineers are prepared for what is anticipated of them and to avoid disasters or tragedies, this research paper should be incorporated into all Engineering Schools. ADDITIONAL SOURCES (2008). “The Nanotech Revolution in Solar Power.” Lightbucket. [Online Blog Post].Availible: http://lightbucket.wordpress.com/2008/03/06/thenanotech-revolution-in-solar-power/ CONCLUSION As the earth’s population continues to increase so will its energy needs. Nanotechnology incorporated into solar power solves this crisis while also leaving no impact on the environment and expanding the energy grid to those unable to obtain power. In doing so, one of the 14 Grand Challenges is solved and humanity can breathe a little easier. However, in doing so the ethics governing the actions of engineers must consider the consequences of their actions. In order to ingrain the weight of these responsibilities, engineers must be taught from their earlier years that their profession has the potential to change lives. Looking forward it can be hoped that all the Grand Challenges are solved, uniting this expanding world with links of technology. ACKNOWLEDGEMENTS I would like to thank my roommate Mustafa for helping me edit this paper. I would also like to thank my ten, working fingers, working human brain, and ability to write in a comprehensible language for helping me finish this. REFERENCES [1] Johnson D. (2008, April). “Nanotechnology and Solar Power” Ieee Spectrum Magazine. [Online Article]. Availible: http://spectrum.ieee.org/techtalk/semiconductors/devices/nanotechnology_and_solar_power [2] (2010) “Make Solar Energy Economical.” National Academy of Engineering Grand Challenges For Engineering. [Online]. Available: http://www.engineeringchallenges.org/cms/8996/9082.aspx [3]http://www.popularmechanics.com/science/3861147 [4] Lovegren S. (2005, June). “Spray On Solar Cells Are True Breakthrough.” The National Geographic Magazine. [Online Article]. Availible:http://news.nationalgeographic.com/news/2005/01/0114_050114_ solarplastic_2.html [5] Woody T. (April, 2010). “A Novel Way to thin-Film Solar Cell?.” The new York Times. [Online Article]. Avalible: http://green.blogs.nytimes.com/tag/applied-quantum-technology/ [6] Harris W. “How Thin-film Solar Cells Work.” How Stuff Works: A Discovery Company. [Online Article]. Avalible: http://science.howstuffworks.com/environmental/green-science/thin-filmsolar-cell3.htm [7] Chandler, D. L. (May, 2011). “Solar Power Goes Viral.” MIT News. [Online Article]. Avalible: http://web.mit.edu/newsoffice/2011/solar-virus0425.html [8] Hammond P. T.. A. M. Belcher.(April, 2011). “Virus-templated selfassembled single-walled carbon nanotubes for highly efficient electron 3