Polytex Sportbeläge
Produktions- GmbH
EC safety data sheet pursuant to 91/155/EC
Revised on: 10.02.2003
1.
Page: 1 of 5
Substance/Preparation and company name
Polytan 1000
Application:
Polyurethane primer for the production
of polyurethane surfaces
Polytex Sportbeläge Produktions- GmbH
Vinkrather Straße 43, 47929 Grefrath
Tel. 02158/91 85 40; fax: 02158/91 85 44
Manufacturer/Supplier:
Emergency information: Chemicals Dept.
2.
Composition/Details of components
Chemical characterisation:
CAS No.
a) 101-68-8
a) 5873-54-1
b) 64742-95-6
EWG No.
3.
Tel. 02158/91 85 40
Polyisocyanate dissolved in aromatic hydrocarbon
Designation
Diphenylmethandiisocyanate
Mixture of 2,4 and 4,4
Aromatic hydrocarbon
mixture
%
10-25
Symbol
Xn
R phrases
20-36/37/38, 42/43
10-24
Xn, N
10,37,51/53,65,66,67
a) 202-966-0/227-534-9
b) 265-199-0
Index No.
Possible dangers
Description of the danger:
Harmful if inhaled. Repeated inhalation of the vapours of aerosols may cause irritation and sensitisation
of the respiratory tract.
4.
First Aid
General information
- After inhalation:
- After skin contact:
- After eye contact:
- After ingestion:
Date of printing: 17.02.2016
Take the patient into the fresh air, keep them warm and seek medical
advice.
Remove contaminated, saturated clothing immediately; wash skin
with soap and water.
Rinse the eyes thoroughly with lots of clean water for at least 10
minutes, holding the lids open. Seek medical advice.
Do not make the patient vomit; do not give the patient anything to
eat or drink. Seek immediate medical advice.
Polytex Sportbeläge
Produktions- GmbH
EC safety data sheet pursuant to 91/155/EC
Product: Polytan 1000
5.
Revised on: 10.02.2003
Page: 2 of 5
Fire fighting
- Suitable fire fighting agents:
Foam, CO2, dry powder. Sand or soil may only be used for
small fires.
- Unsuitable fire fighting agents:
Full water jet.
- Special danger posed by the substance or preparation itself, its combustion
products or resultant gases:
Toxic and harmful substances may be released. Containers may rupture if overheated. If the product
reacts with water it produces CO2 gas. In sealed containers this may result in a hazardous build up of
pressure. Danger of bursting.
Possible combustion products are: Carbon monoxide, nitric oxide, hydrocarbon and HCN.
- Special safety equipment for fire fighting
Full protection suit and compressed air breathing apparatus
6.
What to do after accidental release
- Personal precautions
Avoid contact with the skin and eyes; do not inhale vapours. Remove sources of ignition, provide
adequate ventilation. Keep persons not involved away from the scene.
- Environmental protection
Do not allow to get into the sewer, the soil or open water.
- Cleaning / Mopping up
Mop up or enclose with sand, soil or absorbent material. Do not use flammable material such as saw
dust to mop up the product. Place in marked containers and then dispose of in a safe manner.
7.
Handling and storage
7.1
Handling
Instructions for safe handling
Only use in well ventilated areas Avoid inhaling vapours and spray mist.
- Fire and explosion protection instructions
Take precautions to prevent electrostatic charging.
7.2
Storage:
Store barrels dry and well sealed in a cool, well-ventilated place. Protect from direct sunlight and other
sources of heat or ignition.
Storage temperature:
Room temperature
8.
Exposure limits and personal protection equipment
Personal safety equipment
- Breathing protection
- Hand protection
- Eye protection
- Body protection
Date of printing: 17.02.2016
If there is a risk of inhalation, wear a half-mask with a combination
filter for organic vapours and particles
Wear safety gloves made of PVC or solvent-resistant rubber.
Close-fitting goggles
Long-sleeved safety clothing
Polytex Sportbeläge
Produktions- GmbH
EC safety data sheet pursuant to 91/155/EC
Product: Polytan 1000
9.
Revised on: 10.02.2003
Physical and chemical characteristics
- Form:
- Colour:
- Odour:
- pH value:
- Boiling temperature:
- Flash point:
- Ignition temperature:
- Explosion limits (20°C):
- Vapour pressure (at 50°C):
- Density (at 20°C):
- Solubility in/Miscibility with water:
- Viscosity:
- Distribution coefficient
n-octanol/Water (log POW):
10.
Liquid
Yellow to brown
Mild, aromatic
Not applicable
164 °C
62 °C
450 °C
Lower: 0.9% vol.
Upper: 9.5% vol.
29,3 mbar
1 g/m3
Insoluble, reacts with water
190 +/- 70 mPas at 23 °C
Not applicable, reacts with water and octanol
Stability and reactivity
Conditions to be avoided:
Substances to be avoided
Hazardous decomposition products
11.
Page: 3 of 5
High temperatures
Reacts with water, amines, alkalis and acids
Unlikely in normal industrial applications.
Toxicology information
- Irritation effects
Eyes:
Irritates the eyes and respiratory tract.
Skin:
Repeated and/or lengthy contact may cause skin degreasing and sensitisation.
12.
Ecology information
Do not allow the product to get into open water, effluent or the soil. The product transforms into a solid,
insoluble reaction product (polyurea) with a high melting point at the edges with water and also
generates carbon dioxide. This reaction is greatly increased by active substances on the limit surfaces
(for example liquid soap or water-soluble solvents).
Date of printing: 17.02.2016
Polytex Sportbeläge
Produktions- GmbH
EC safety data sheet pursuant to 91/155/EC
Product: Polytan 1000
13.
Revised on: 10.02.2003
Page: 4 of 5
Disposal information
May be incinerated in a suitable plant pursuant to local official regulations.
14.
Transport instructions
Land transport ADR/RID and GGVS/GGVE:
Ocean-going ship transport IDMF/GGVSea:
15.
Not a hazardous substance
Not a hazardous substance
Regulations
Identification pursuant to the Hazardous Substances Directive with corresponding EC Directives
- Code letter and
hazard code of the product:
Xn, harmful
- Substance name on the identification
panel (label):
Contains Diphenylmethane-4,4`-diisocyanate,
isomers and homologues
- R phrases:
R 20:
Harmful if inhaled
R 36/37/38:
Irritates the eyes, respiratory organs and the skin
R 42/43:
Sensitisation possible by inhalation and skin contact
R 52/53:
Harmful for aquatic organisms, can have long term harmful effects in
open water
- S phrases:
S 23:
S 26:
S 28:
S 38:
S 45:
S 61:
- VbF:
- National regulations
Do not inhale vapour/aerosol
If the product comes into contact with the eyes, rinse thoroughly with
water and seek medical advice.
If the product comes into contact with the skin wash it off
immediately with soap and water.
Use breathing apparatus if ventilation is inadequate
In the event of an accident or feeling unwell seek immediate medical
advice (show this label if possible)
Avoid release into the environment. Obtain special instructions;
consult the safety data sheet.
A III
Safety at work:
TRGS 900 “Limit values” for diphenylmethane-4,4`-diisocyanate:
0.005 ml/m3 (ppm) = 0.05 mg/m3
Peak limit category I
- Technical Regulations for Air: TA Air 3.1.7, Organic substances for diphenylmethane-4,4`diisocyanate:
Class I mass concentration of 20 mg/m3 and less with a mass flow or
0.1 kg/h and over
TA Air for aromatic hydrocarbons:
Class II
- Potential water polluting class: 2 –for water polluting (internal classification)
Date of printing: 17.02.2016
Polytex Sportbeläge
Produktions- GmbH
EC safety data sheet pursuant to 91/155/EC
Product: Polytan 1000
16.
Revised on: 10.02.2003
Page: 5 of 5
Other information
Relevant R phrases
R 10:
R 20:
R 36/37/38:
R 42/43:
R 52/53:
R 65:
R 66:
R 67:
Flammable
Harmful if inhaled
Irritates the eyes, respiratory organs and the skin
Sensitisation possible by inhalation and skin contact
Harmful for aquatic organisms, can have long term harmful effects in open
water
Harmful; may cause lung damage if ingested
Repeated contact may cause brittle or cracked skin
Vapours may cause drowsiness and numbness
The information in this safety data sheet is based on our current knowledge and is designed to describe
the product in terms of the appropriate safety precautions. It does not constitute any assurance of
properties of the product described herein.
This safety data sheet replaces all previous versions.
Date of printing: 17.02.2016