PROPPER MFG INC -- SERACULT DEVELOPER ======================================================= MSDS Safety Information ======================================================= FSC: 6550 NIIN: 01-243-3204 MSDS Date: 09/19/1991 MSDS Num: CKKPP Product ID: SERACULT DEVELOPER MFN: 01 Responsible Party Cage: 49198 Name: PROPPER MFG CO INC Address: 36-04 SKILLMAN AVE City: LONG ISLAND CITY NY 11101-1730 Info Phone Number: 718-392-6650 Emergency Phone Number: 718-392-6650 Preparer's Name: FRANK E. PLATKO, EXT 226 Review Ind: Y Published: Y ======================================================= Contractor Summary ======================================================= Cage: 49198 Name: PROPPER MFG CO INC Address: 36-04 SKILLMAN AVE City: LONG ISLAND CITY NY 11101-1730 Phone: 718-392-6650 ======================================================= Ingredients ======================================================= Cas: 64-17-5 RTECS #: KQ6300000 Name: ETHANOL Percent by Wt: 75. OSHA PEL: 1900 MG/M3;1000 PPM ACGIH TLV: 1880 MG/M3;1000 PPM ACGIH STEL: NOT ESTABLISHED -----------------------------Cas: 7722-84-1 RTECS #: MX0899000 Name: HYDROGEN PEROXIDE Percent by Wt: 5. OSHA PEL: 1.4 MG/M3;1 PPM ACGIH TLV: 1.4 MG/M3;1 PPM ACGIH STEL: NOT ESTABLISHED ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50 MALE RAT = 1193 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Effects of Exposure: SERACULT DEVELOPER NOT TESTED. FOR INGREDIENTS: ETHANOL IS EYE IRRITANT. HYDROGEN PEROXIDE (H2O2) IS SEVERE (CORROSIVE) EYE IRRITANT. SKIN: ETHANOL DEFATS SKIN. H2O2 (5-6%) MAY PRODUCE MILD BURNING SENSATION AND/OR BLEACHING/WHITENING OF SKIN WITH IRRITATION. INHALATION: ETHANOL CAUSES HEADACHE, DIZZINESS, DROWSINESS, LASSITUDE, APPETITE LOSS, DECRESAED MOTOR RESPONSE, EUPHORIA, NAUSEA & VOMITING. H2O2 IRRITATES/BURNS MUCOUS MEMBRANES. INGESTION: ETHANOL PRODUCES DIZINESS, EUPHORIA, DROWSINESS, EUPHORIA, DECREASED REACTION TIME, STAGGERING, NAUSEA, VOMITING, COMA. H2O2 CAUSES CHEMICAL BURNS TO MUCOUS MEMBRANES & GI TRACT. Explanation Of Carcinogenicity: SERACULT DEVELOPER NOT TESTED. ETHANOL: NO INFORMATION AVAILABLE. HYDROGEN PEROXIDE: IN MICE: IARC 28:155, 1982; IARC 36, 1985. HOWEVER, HYDROGEN PEROXIDE GENERALLY RECOGNIZED AS SAFE FOR USE AS A HUMAN FOOD ADDITIVE WITH NO RESIDUES. Signs And Symptions Of Overexposure: IRRITATION, MILD BURNING, HEADACHE, DIZZINESS, DROWSINESS, LASSITUDE, LOSS OF APPETITE, INABILITY TO CONCENTRATE, DECREASED MOTOR RESPONSE, EUPHORIA, NAUSEA, VOMITING, COMA Medical Cond Aggravated By Exposure: NOT PROVIDED First Aid: EYES: FLUSH IMMEDIATELY WITH LOW PRESSURE COLD WATER FOR 15 MINUTES. CONTACT PHYSICIAN. SKIN: FLUSH CONTACT AREA WITH WATER. WASH AREA WITH SOAP & WATER. RINSE THOROUGHLY. INHALATION: MOVE VICTIM TO FRESH AIR. IF BREATHING LABORED OR IF VIC TIM LOSES CONSCIOUSNESS, CONTACT PHYSICIAN IMMEDIATELY. IF BREATHING STOPS, ADMINISTER ARTIFICIAL RESPIRATION. USE OXYGEN AS REQUIRED. CONTACT PHYSICIAN IMMEDIATELY. INGESTION: IF FULLY CONSCIOUS, LUCID & NOT CONVULSING, DRINK SEVERAL GLASS ES OF WATER. CONTACT PHYSICIAN OR POISON CONTROL. DO NOT INDUCE VOMITING UNLESS INSTRUCTED BY CERTIFIED MEDICAL AUTHORITY. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: DILUTE LEAKS & SPILLS WITH LARGE VOLUMES OF COLD WATER. DISCHARGE DILUTED WASTE IN ACCORDANCE WITH LOCAL, STATE & FEDERAL ENVIRONMENTAL REGULATIONS. Neutralizing Agent: NOT PROVIDED Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE & FEDERAL REGULATIONS. Handling And Storage Precautions: AVOID EXCESSIVE HEAT, HOT PIPES, OPEN FLAMES, SPARKS, IGNITION SOURCES. AVOID ULTRA VIOLET LIGHT (SUNLIGHT) & OTHER EADIATIONS SOURCES INCLUDING UV-EMITTING ROOM LIGHTS. Other Precautions: REPLACE BOTTLE CLOSURE WHEN NOT IN USE. THIS WILLDIMINISH ALCOHOL VAPORS & REDUCE THE RISK OF CONTAMINATION. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Method: TCC Flash Point: =16.1C, 61.F Flash Point Text: FOR ETHANOL Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICALS, UNIVERSALTYPE FOAMS APPLIED PER MANUFACTURER'S RECOMMENDATION. Fire Fighting Procedures: WEAR PROTECTIVE CLOTHING. USE SELF CONTAINED BREATHING APPRATUS (NIOSH CERTIFIED). DO NOT USE OXIDIZABLE SORBENTS. Unusual Fire/Explosion Hazard: OXYGEN EVOLUTION FROM THE DECOMPOSITION OF HYDROGEN PEROXIDE WILL SUPPORT COMBUSTION & MAY SERVE TO INTENSIFY A FIRE. ======================================================= Control Measures ======================================================= Respiratory Protection: NOT PROVIDED Ventilation: NOT PROVIDED ON MSDS. RECOMMEND GOOD AREA VENTILATION. Protective Gloves: NOT PROVIDED Eye Protection: NOT PROVIDED. RECOMMEND SAFETY GLASSES. Other Protective Equipment: NOT PROVIDED Work Hygienic Practices: NOT PROVIDED ======================================================= Physical/Chemical Properties ======================================================= HCC: F2 Boiling Point: =81.C, 177.8F Melt/Freeze Pt: <20.C, 68.F Vapor Pres: 21 MM HG @ 20C Spec Gravity: 0.86 Solubility in Water: COMPLETELY MISCIBLE Appearance and Odor: CLEAR, COLORLESS, WATER-LIKE LIQUID, CHARACTERISTIC SCENT OF ALCOHOL Percent Volatiles by Volume: APPROX 100 ======================================================= Reactivity Data ======================================================= Stability Indicator: NO CS, REDUCERS, OXIDIZERS Stability Condition To Avoid: ETHANOL IS GENERALLY STABLE EXCEPT WHEN EXPOSED TO EXCESSIVE HEAT & IGNITION SOURCES. HYDROGEN PEROXIDE SHOULD BE REGARDED AS UNSTABLE DUE TO WIDE RANGE OF INCOMPATIBLE MATERIALS. Materials To Avoid: ETHANOL: CONCENTRATED NITRIC & SULFURIC ACIDS & STRONG OXIDIZERS. EXCESSIVE HEAT MAY CAUSE CONTAINER PRESSURIZATION. H2O2: UV LIGHT MAY INDUCE PHOTO DECOMPOSITION. PH>4, IRON COPPER, HEAVY METALS, THEIR SALTS, ALLOYS, ORGAN Hazardous Decomposition Products: ETHANOL: CARBON MONOXIDE, CARBON DIOXIDE, H2O2: OXYGEN EVOLVED RESULTING IN FIRE INTENSIFICATION HAZARD. Hazardous Polymerization Indicator: NO ======================================================= Toxicological Information ======================================================= Toxicological Information: CONTAINS INGREDIENTS WHICH MAKE IT WHOLLY UNFIT FOR BEVERAGE PURPOSES. IF TAKEN INTERNALLY, SERIOUS HEALTH CONSEQUENCES MAY RESULT. SKIN ABSORPTION: HYDROGEN PEROXIDE: LD50 > 2000 MG/KG (RABBIT). FMC REF: I83-745, 1983. ======================================================= Ecological Information ======================================================= Ecological: NOT PROVIDED ======================================================= MSDS Transport Information ======================================================= Transport Information: NOT PROVIDED. SEE TRANSPORTATION DATA. ======================================================= Regulatory Information ======================================================= Federal Regulatory Information: NOT PROVIDED State Regulatory Information: NOT PROVIDED ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: 49198 Trans ID NO: 152806 Product ID: SERACULT DEVELOPER MSDS Prepared Date: 09/19/1991 Review Date: 05/05/2000 MFN: 1 Tech Entry NOS Shipping Nm: ETHANOL, HYDROGEN PEROXIDE Multiple KIT Number: 0 Unit Of Issue: EA Container QTY: UNKNOWN Type Of Container: UNKNOWN ======================================================= Detail DOT Information ======================================================= DOT PSN Code: FTN DOT Proper Shipping Name: ETHANOL OR ETHYL ALCOHOL OR ETHANOL SOLUTIONS OR ETHYL ALCOHOL SOLUTIONS Hazard Class: 3 UN ID Num: UN1170 DOT Packaging Group: II Label: FLAMMABLE LIQUID Special Provision: T1 Packaging Exception: 150 Non Bulk Pack: 202 Bulk Pack: 242 Max Qty Pass: 5 L Max Qty Cargo: 60 L Vessel Stow Req: A ======================================================= Detail IMO Information ======================================================= IMO PSN Code: GNU IMO Proper Shipping Name: ETHANOL SOLUTIONS IMDG Page Number: 3219 UN Number: 1170 UN Hazard Class: 3.2 IMO Packaging Group: II Subsidiary Risk Label: EMS Number: 3-06 MED First Aid Guide NUM: 305 ======================================================= Detail IATA Information ======================================================= IATA PSN Code: KXW IATA UN ID Num: 1170 IATA Proper Shipping Name: ETHANOL SOLUTION IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID UN Packing Group: II Packing Note Passenger: 305 Max Quant Pass: 5L Max Quant Cargo: 60L Packaging Note Cargo: 307 Exceptions: A3, A58 ======================================================= Detail AFI Information ======================================================= AFI PSN Code: KXQ AFI Proper Shipping Name: ETHANOL OR ETHANOL SOLUTIONS OR ETHYL ALCOHOL OR EHTYL ALCOHOL SOLUTIONS AFI Hazard Class: 3 AFI UN ID NUM: UN1170 AFI Packing Group: II Special Provisions: P5 Back Pack Reference: A7.3 ======================================================= HAZCOM Label ======================================================= Product ID: SERACULT DEVELOPER Cage: 49198 Company Name: PROPPER MFG CO INC Street: 36-04 SKILLMAN AVE City: LONG ISLAND CITY NY Zipcode: 11101-1730 Health Emergency Phone: 718-392-6650 Label Required IND: Y Date Of Label Review: 05/05/2000 Status Code: A Origination Code: F Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Moderate Fire Hazard: Severe Reactivity Hazard: Slight Hazard And Precautions: SERACULT DEVELOPER NOT TESTED. FOR INGREDIENTS: ETHANOL IS EYE IRRITANT. HYDROGEN PEROXIDE (H2O2) IS SEVERE (CORROSIVE) EYE IRRITANT. SKIN: ETHANOL DEFATS SKIN. H2O2 (5-6%) MAY PRODUCE MILD BURNING SENSATION AND/OR BLEACHING/WHITENING OF SKIN WITH IRRITATION. INHALATION: ETHANOL CAUSES HEADACHE, DIZZINESS, DROWSINESS, LASSITUDE, APPETITE LOSS, DECRESAED MOTOR RESPONSE, EUPHORIA, NAUSEA & VOMITING. H2O2 IRRITATES/BURNS MUCOUS MEMBRANES. INGESTION: ETHANOL PRODUCES DIZINESS, EUPHORIA, DROWSINESS, EUPHORIA, DECREASED REACTION TIME, STAGGERING, NAUSEA, VOMITING, COMA. H2O2 CAUSES CHEMICAL BURNS TO MUCOUS MEMBRANES & GI TRACT. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.