Material Safety Data Sheet 1 Petsul-500 CAS Number Synonyms Generic Chemical Name Product Type Emergency Phone Number 2 Hazardous Ingredients 3 Principle Hazards 4 Ingestion SUBSTANCE/PRODUCT IDENTIFICATION Petrico Limited PO Box 146 Belvedere Kent England DA17 6ER TEL: +44 (0) 1322 435685 e-mail: techservices@petrico.com 64742-52-5 / 64742-52-6 Sodium Salts of Sulfonic Acid Sodium Sulfonate As Above +44 (0) 79700-4370 COMPOSITION/INFORMATION ON INGREDIENTS Severely Hydrotreated heavy Naphthenic Distillate CAS # 64742-52-5/64742-52-6 HAZARDS IDENTIFICATION Aliphatic Petroleum Distillate PEL/TLV: 5mg/M3 STEL: 10mg/M3 FIRST AID MEASURES SEEK MEDICAL ATTENTION: Do NOT induce vomiting or attempt to give liquids to a semi or unconscious person. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Eyes Flush with water for at least 15 minutes. Get medical attention if eye irritation develops or persists. Skin Wash with soap and water. Get medical attention if irritation develops. Launder contaminated clothing before reuse. Inhalation Remove exposed person to fresh air if adverse effects observed. See section 11 Note to Physician: Treat symptomatically. Additional Information 5 Flash Point Upper Flammable Limit Lower Flammable Limit Extinguishing Media Firefighting Procedures Unusual Fire & Explosion Hazards Autoignition Point Explosion Data FIRE FIGHTING MEASURES 204 Deg. C (C.O.C) Not Determined. Not Determined. Water, CO2, dry chemical, alcohol foam. Water fogs should only be used by experienced fire-fighters as product may float and reignite on the surface of the water Recommend wearing self-contained breathing apparatus. None. Not determined. None known. PET/msds/08/04/99/issue 1 Page1 of 3 6 Spill procedures ACCIDENTAL RELEASE MEASURES Personal Protective Equipment must be worn, see Personal Protection Section for PPE recommendations. Ventilate area if spilled in confined space or other poorly ventilated areas. Prevent entry into sewers and waterways. Pick up free liquid for recycle and/or disposal. Residual liquid can be absorbed on inert material. 7 Handling Procedures HANDLING AND STORAGE Keep containers closed when not in use. Wash thoroughly after handling. Empty container contains product residue which may exhibit hazards of product. Storage Procedures No special storage precautions required. 8 Ventilation Procedures Hand Protection Eye Protection Respiratory Protection EXPOSURE CONTROLS/PERSONAL PROTECTION Use with adequate ventilation. Impervious Gloves. Chemical Safety Glasses. Under normal use conditions, respirator is not usually required. Clothing Recommendation Suitable clothing to minimise skin contact, Long sleeve shirt is recommended. 9 Vapour Pressure (mm Hg) pH Range Specific Gravity Water Solubility Flash Pt Deg C Molecular Wt Vapour Density Evaporation Rate Odour Appearance Viscosity Odour Threshold Boiling Point PHYSICAL AND CHEMICAL PROPERTIES <0.0003mm Hg @ 20 C Not Applicable 0.990 (15.6 Deg. C) Immisible. 204 (c.o.c) 500 (Typical) Heavier than air. Not Determined. Mild. Dark Brown Viscous fluid 45 cSt/ 100 Deg, C Not Determined. >150 Deg C 10 Stability STABILITY AND REACTIVITY Material is normally stable at moderately elevated temperatures and pressures. Strong oxidising agents and excessive heat, open flames. Will NOT occur. Oxides of carbon and Asphyxiants. Incompatibility Polymerisation Thermal Decomposition PET/msds08/04/99/issue 1 11 TOXICOLOGICAL INFORMATION Page 2 of 3 Eye Irritation Mild conjunctival transient irritant Skin Irritation May be absorbed over long periods but not expected to be toxic via this route – Prolonged contact with skin may have slight de-fatting effect leading to irritation. Not applicable under normal ambient conditions. Occupational Exposure: PEL/TLV = 2mg/M3. At high Temperatures or oil mist may cause mild irritation of the upper respiratory tract. Excessive inhalation may cause dizziness and nausea. Caution should be exercised to prevent aerosolising or misting this product Respiratory Irritation Dermal Toxicity Inhalation Toxicity Ingestion 12 13 Waste Disposal 14 UN Number IMDG ICAO ADR/RID Hazard 15 Symbols Precautionary Labels 16 None expected under normal use. Acute Dermal LD50 = >2g/Kg (Rabbits) Not applicable under normal ambient conditions. May cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Acute Oral LD50 = >5.0g/Kg (Rats) ECOLOGICAL INFORMATION THIS PRODUCT IS CLASSED AS A MARINE POLLUTANT. DISPOSAL CONSIDERATIONS Material, if discarded, not expected to be a characteristic hazardous waste. Disposal should be in compliance with all, Country,State and local laws. TRANSPORT INFORMATION Not applicable. Not applicable. Not applicable. Not applicable. REGULATORY INFORMATION EU Labelling: Symbols: R Phrases: R20 = Harmful by inhalation S Phrases: 7,15,16,24/25,28,36,37,39. OTHER INFORMATION This product has not been tested in long term chronic exposure. All safety precautions and handling procedures outlined in this MSDS must be followed in order to minimise exposure. END PET/msds/ 08/04/99 issue 1 Page 3 of 3