Non-methane Hydrocarbons On Pluto’s Surface: From near- and mid- infrared spectra of Pluto’s surface we have learned much about this cold, distant world. Volatile ices including CH4, N2, and CO have been detected on Pluto’s surface (Cruikshank et al. 1976; Owen et al. Xxxx). We know that there is methane diluted in nitrogen on Pluto’s surface from the shift in band centers (xx) and that very little of Pluto’s surface (<6%), at least on one side, has pure N2 ice (Olkin et al. 2007). But there are still outstanding questions, such as “Where is the ethane?”. Ethane is expected on Pluto’s surface due to photolysis of methane. Recently, Cruikshank et al (2006) has suggested the faint spectral feature at 2.404 microns is due to ethane not 13CO as previously thought (xxref). However, this detection of ethane is still an open question partially because the stronger 2.46 micron feature of ethane has not been detected. Additionally, other wavelengths have not produced a definitive detection. Olkine et al. (2007) presented spectra of one face of Pluto in the 3-4 micron region with no detection of ethane, see Figure 1. There was a possible detection of ethane (the wavelength of the features do not correspond well with the model) on a different face of Pluto (Sasaki et al 2000), see Figure 2. One of our scientific goals for this project is to make a comprehensive spectral model from the visible to 4 microns covering all rotational phases of Pluto to further investigate the possibility of tholin and ethane on Pluto’s surface. This proposal covers the wavelength range from xx to xx microns. (For the 1 to 2.5 micron wavelength observations I am applying to the IRTF with SpeX and in the visible xx.) In previous work (Olkin et al. 2007), we found that combining 3-4 micron spectra with 1 to 2.5 micron spectra led to greater insight into the surface features on Pluto. In particular, we were able to constrain the amount of pure N2 on Pluto’s surface to less than 6% and identify a spectral signature consistent with Titan tholin (Khare et al. 1984xx). We are now proposing to observe Pluto’s spectrum over this range wavelengths for a complete rotation and during the same season with concurrent photometric observations to calibrate the spectra well against slit loss. A Comprehensive Look at Pluto: Our second scientific goal requires a long-term observational program. Pluto’s atmosphere, insolation and surface properties are all intertwined and need to be considered together to improve our understanding processes in the outer solar system. Pluto’s surface frosts support the atmosphere by vapor pressure equilibrium, Pluto’s atmosphere transports the volatiles through sublimation and condensation, and the insolation and surface properties determine the temperatures on Pluto’s surface which controls the surface pressure of Pluto’s atmosphere. This is a unique time for observing Pluto. We are able to combine the strength of an aggressive stellar occultation campaign (to probe Pluto’s changing atmosphere), observations from New Horizons that will be able to get high phase observations, and spectral observations that will span the visible wavelengths out to 4 microns. All these observations will occur at a time when Pluto is receding from the Sun reducing the amount of insolation that Pluto receives (xxquantify) and the atmosphere is undergoing significant changes (Sicardy et al. Xx). The first two pieces of this program are already in place. One of us (Leslie Young) leads an active campaign to observe stellar occultations by Pluto. Now that Pluto has moved into the galactic plane the number of opportunities has increased significantly. The first stellar occultation by Pluto was observed in 1988 and it was 14 years later until another was observed. However with the more dense star field in the background, we have observed an occultation by Pluto in both 2006 and 2007 and these more favorable conditions will continue for the next xx years. The second piece is the ability to get unprecedented high-phase observations. With the launch of the New Horizons spacecraft in January 2006, there will be annual observations of Pluto using the panchromatic visible wavelength imager to achieve photometric observations at phase angles not achievable from Earth. In order to put these high-phase observations in context, we need complementary observations. The near-ir observations proposed here are the best-suited wavelength range to understand the distribution and properties (such as grain size) of Pluto’s surfaces ices since that is where these molecules interact the most with the light. These observations will (hopefully) be supplemented with visible wavelength spectra and mid-IR spectra in the 3-4 micron range. We propose a new long-term project to explore Pluto’s surface properties. Each year we will use SpeX (big dog) to observe spectra from xx to xx microns covering a complete rotation of Pluto near minimum phase and then another spectrum of a single Pluto face near maximum phase angle (1.xx degrees). We will also take photometric observations using guide dog to characterize Pluto’s rotational light curve and to calibrate our spectral observations. These observations will complement two other observing programs that are already in place: (1) a campaign of stellar occultation observations and (2) annual panchromatic visible-wavelength photometry using the LORRI instrument on New Horizons at higher phase angles than achievable from Earth.