Irina A.Khotina
Vavilova Street, Moscow, Russia, 119991
Phone: +7-495-1359300
Cell: +7-910-4094145
email: khotina@ineos.ac.ru
Objective:
Leading Researcher, Polymer Chemistry, A.N.Nesmeyanov Institute of Organoelement Compounds
(INEOS RAS), Moscow
Education:
M.S., Polymer Chemistry, D.I.Mendeleev University of Chemical Technology, Moscow, 1971
Concentrations: Polymer Chemistry, Polymer Synthesis
Thesis: Iodine Sorbtion on Polyvinylpyrrolidon Matrix
Ph.D., Polymer Chemistry, INEOS RAS, 1983
Concentrations: Polymer Chemistry, Termostable Branched Polymers,
Dissertation: Synthesis of New Mono- and Diacetylaromatic o-Carborane-Containing Compounds and
Polyphenylene Type Polymers on their Basis
Habilitation, Phisical Chemistry, Organic Chemistry, Tver University, 2004
Concentrations: Phisical Chemistry, Organic Chemistry, Cross-Coupling Reactions
Dissertation: New Light Emitting Aromatic Polymers and Metallocomplex Reactions in their Synthesis.
Experience:
Supervisor, 2005 - 2007
INEOS RAS
Ph.D. Kushakova N., Dissertation: Synthesis and Study of Hyperbranched Polyphenylenes
Supervisor, 2006 - 2009
INEOS RAS
Ph.D. Rud D., Dissertation: The Preparation of Palladium Nanoparticles and Complexes on
Polyphenylene Matrices for Heterogenic Catalysis
Supervisor, 2008 - 2010
INEOS RAS
Ph.D. Shapovalov A., Dissertation: Fluorescent phenylene dendrimers and hyperbranched
polyphenylene, NMR and optical properties.
Research Skills:
Extensive knowledge of modern methods of polymer and organic synthesis and polymers
characterisation.
Presentations:
Khotina I.A., Kushakova N.S., Shapovalov A.V. (2007) Novel Semiconducting Organic Materials Based
on Branched Polyphenylenes for Electronic Applications.
Paper presented at the Fifth International Dendrimer Symposium (IDS5), Toulouse, France
Yuri Kabachi, Raisa Dvorikova, Irina Khotina (2009). Self-assembled functionalized amphiphilic block
copolymers on magnetic cores for antibodies interaction. Paper presented at the European Polymer
Congress EPF’09, Graz, Austria
Irina Khotina, Dmiry Rud, Natalia Kushakova (2009). Polyphenylens, cross-linked through Pd-carbene
complexes formation, for catalysis in Suzuki and Heck reactions. Paper presented at the European
Polymer Congress EPF’09, Graz, Austria
.Publications:
54 papers, 16 Russian patents, 4 reviews articles
The last:
1. S.Destri, W.Porzio, I.A.Khotina, C.Botta, R.Consonni. Synthesis and Characterization of New
Poly(aryleneneethynylene)s Based on 3-Hexyl Multisubstituted Oligothiophene Blocks. Macromol. Chem.
Phys., 202, 2572-2580 (2001)
2. I.A.Khotina, V.A.Izumrudov, N.V.Tchebotareva, A. L.Rusanov. Polyarylenevinylenes with dendronic
aromatic substituents in vinylene groups. Synthesis and optical properties. Macromol. Chem. Phys., 202,
2360 (2001)
3 I.A.Khotina, O.E.Shmakova, D.Y.Baranova, N.S.Burenkova, A.A.Gurskaja, P.M.Valetsky,
L.M.Bronstein. Highly branched polyphenylenes with 1,3,5-triphenylbenzene fragments via
cyclocondensation of acetylaromatic compounds and Ni0-catalyzed dehalogenation: Synthesis and light
emission. Macromolecules, (2003), 36, 8353.
4. Bronstein, Lyudmila M.; Linton, Christina N.; Karlinsey, Robert; Ashcraft, Earl; Stein, Barry D.;
Svergun, Dimitri I.; Kozin, Michael; Khotina, Irina A.; Spontak, Richard J.; Werner-Zwanziger, Ulrike;
Zwanziger,
Josef
W.
Controlled
Synthesis
of
Novel
Metalated
Poly(aminohexyl)(aminopropyl)silsesquioxane Colloids. Langmuir (2003), 19(17), 7071-7083
5. Shtykova, Eleonora V.; Svergun, Dmitri I.; Chernyshov, Dmitri M.; Khotina, Irina A.; Valetsky, Peter
M.; Spontak, Richard J.; Bronstein, Lyudmila M.. Platinum Nanoparticles Generated in FunctionalityEnhanced Reaction Media Based on Polyoctadecylsiloxane with Long-Chain Functional Modifiers.
Journal of Physical Chemistr, B (2004), 108(20), 6175-6185.
6. I. A. Khotina, L. S. Lepnev, N. S. Burenkova, P. M. Valetsky, A. G. Vitukhnovsky. Phenylene
Dendrimers and Novel Hyperbranched Polyphenylenes as Light Emissive Materials for Blue OLEDs.
Journal of Luminescence (2004) 110(4), 232-238.
7. Bronstein, Lyudmila M.; Goerigk, Guenter; Kostylev, Maxim; Pink, Maren; Khotina, Irina A.;
Valetsky, Peter M.; Matveeva, Valentina G.; Sulman, Esther M.; Sulman, Michael G.; Bykov, Alexei V.;
Lakina, Nataliya V.; Spontak, Richard J. Department of Chemistry, Indiana University, Bloomington,
IN, USA. Structure and Catalytic Properties of Pt-Modified Hyper-Cross-Linked Polystyrene Exhibiting
Hierarchical Porosity. Journal of Physical Chemistry B (2004), 108(47), 18234-18242.
8. G. N. Panin, T. W. Kang, A. N. Aleshin, A. N. Baranov, Y.-J. Oh, I. A. Khotina. Electric field
switching between blue-green and red cathodoluminescence in poly.4,4’-diphenylene diphenylvinylene.
mixed with ZnO:Mg nanoparticles. Applied Physics Letters, (2005) 86, 113114.
9. Bronstein, Lyudmila M.; Khotina, Irina A.; Chernyshov, Dmitri M.; Valetsky, Peter M.; Timofeeva,
Galina I.; Dubrovina, Lidiya V.; Stein, Barry; Karlinsey, Robert; Triolo, Alessandro; Weidenmann, A.; Lo
Celso, F.; Triolo, Roberto; Khokhlov, Alexei R. Morphology of hybrid polystyrene-block-poly(ethylene
oxide) micelles: Analytical ultracentrifugation and SANS studies. Journal of Colloid and Interface Science
(2006), 299(2), 944-952.
10. Khotina I.A., Kushakova N.S., Rud D.A., Lovkov S.S., Ponomarev I.I., Valetsky P.M. (2006).
Novel macroligands on the basis of polyphenylenes for Pd-containing catalysts. Doklady Chemistry, V.
409, №3, 362-364.
11. I.P. Beletskaya, A.N. Kashin, I.A. Khotina, A.R. Khokhlov, Efficient and Recyclable Catalyst of
Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction,
Ostwald Ripening Process with Palladium Nanoparticles. Template for SYNLETT and SYNTHESIS ©
Thieme Stuttgart • New York, (2008), 01, 22.
12. Khotina I.A., Kushakova N.S., Rud D.A., Vitukhnovsky A.G. (2008). Branched polyphenylenes
and method of their producing. RU patent № 2321601.Khotina I.A., Kushakova N.S, Loginova T.P.,
Shapovalov A.V., Rud D.A., Babich S.A. (2009). Branched polyphenylenes with the branching point –
1.3.5-triphenylsubstituted benzene ring with high electroluminescence efficiency and method of their
producing. RU patent № 2370501.
13. Khotina I.A., Kushakova N.S, Loginova T.P., Shapovalov A.V., Pankov P.N. (2009). Method of
synthesis of luminescent nanoparticles of CdS, stabilized by polymeric matrixes. RU patent № 2370517.
Kushakova N.S, Shapovalov A.V., Rud D.A. Vitukhnovsky A.G., Krotov А.V., Timofeeva G.I., Khotina
I.A. (2009). Synthesis of branched polyphenylenes using Suzuki reaction and their spectral
characteristics. Macromolecular compounds, B series, V. 51, №10, 1844.
Grants and Fellowships:


ISTC Grant, Moscow (2007-2010), $12000
Federal Agency on Research and Education Grant, Moscow (2008 – 2009), $4000
Awards and Honors:
Skills and Qualifications:


Microsoft Office, Internet
Fluent in English
References:
Excellent references available upon request.