CZECH TECHNICAL UNIVERSITY IN PRAGUE FACULTY OF MECHANICAL ENGINEERING DEPARTMENT OF PROCESS ENGINEERING Waste Water Treatment – Lisbon (Frielas) Dr. Ing. Pavel Hoffman Department of Process Engineering Faculty of Mechanical Engineering Czech Technical University in Prague Alexandre Rio 1 Index 1. Introduction .............................................................................................................. 3 2. GENERAL DESCRIPTION OF THE WASTE WATER TREATMENT IN FRIELAS ...................................................................................................................... 4 3. Pre-Treatment.......................................................................................................... 6 3.1 Reception of the Affluent Waste Waters by pumping: ...................... 7 3.1.1 First Stage of Initial Elevation: ........................................................... 7 3.1.2 Second Stage of Initial Elevation: ..................................................... 7 3.2 Mean Bar-Screen: ............................................................................................ 7 3.3 Fine bar-screen: ............................................................................................... 7 3.4 Water-Flow measure of the screened waters: ..................................... 8 3.5 Traps for sand and Degreasing: ................................................................ 8 4. Primary Treatment ................................................................................................ 8 4.1 Primary Decantation: ......................................................................................... 8 5. Secondary Treatment .......................................................................................... 9 5.1 Intermediate Elevation: ................................................................................ 9 5.2 Homogenization and Equalization Tank: ................................................ 9 5.3 Biological Treatment – Activated Sludge: .............................................. 9 6. Control Treatment ............................................................................................... 10 6.1 Final Elevation: ............................................................................................... 10 6.2 Bio-Filtration: .................................................................................................. 10 6.3 Final Fine Water-flow Measurement: ..................................................... 10 6.4 UV Treatment: ................................................................................................ 11 7. Sludge Treatment ................................................................................................ 11 7.1 Thickening: ....................................................................................................... 11 7.2 Conditioning by hydrated whitewash addition:.................................. 11 7.3 Anaerobic Digestion: .................................................................................... 11 7.4 Sludge dewatering: ....................................................................................... 12 8. Biogas Valorisation ............................................................................................. 12 9. Dewatering Sludge Project ............................................................................ 12 10. Conclusion ............................................................................................................. 13 11. Terminology.......................................................................................................... 14 2 1.Introduction Lisbon - also known as the city of the seven hills, has always been highly dependent on the River Tagus and its estuary. Its foundation, growth and history are intimately linked with the Tagus. Much of what characterizes and distinguishes Lisbon in Europe and throughout the world is linked to this special geographical position and to the privileged natural conditions which it enjoys on the largest estuary in Europe (320 km2 and 50 km long). However, the environment and ecosystem of this beautiful and enormous estuary have been degraded in recent decades as a result of urban and industrial expansion. Today, almost one-fourth of Portugal's population (almost 2 million inhabitants) live and work in Lisbon and a variety of industrial complexes - the chemicals industry, the oil industry and ship-building and repairs - are based on the banks of the Tagus estuary, creating sources of pollution and environmental degradation for a significant part of it. The only reason that the level of pollution in the Tagus and its estuary has not reached even more worrying levels is because of the capacity of its tide to cleanse itself and regenerate the enormous volume of water. It is calculated that twice a day six billion cubic metres of water enter the Tagus estuary with the tides, thus reoxygenating the water and reducing, through dilution and other chemical changes, some of the effects of existing industrial and domestic pollution. The importance of Wastewater treatment stations is irrevocable to the maintenance of the Environment’s Health. Next it will be describe the functioning of one Water Treatment Station located near of Lisbon: Frielas. 3 2.GENERAL DESCRIPTION OF THE WASTE WATER TREATMENT IN FRIELAS The Waste Water Treatment Station in Frielas, created in 1999, receives the domestics and industrials effluents of a large geographic area that cover part of Lisboa, Loures, Odivelas, Amadora, and, in the near future, also Mafra and Sintra. The ETAR of Frielas daily receives about 40.000m3 of water, what it gives an average of 2 million litres/hour = 0,56 m3/s. This represents the total of 350 000 hab.eq (water flow) or 700 000 hab.eq (BOD5). The construction of this station had in mind the future increase in three phases: 1st Phase: year 2001, to 700.000 hab.eq 2nd Phase: year 2011, to 900.000 hab.eq 3rd Phase: year 2021, to 1.050.000 hab.eq The general architecture after the equalization has three independents lines of treatment. The expected water flows for the three different phases are: (1) Table 1 - Water flow Inlet Values (1) - The translation to English is on the last page of this work, on the Chapter 11. 4 And for the inlet pollutants content: (2) Table 2 – Inlet Pollutants content (2) – Again, the translation is on the page 14 o f this work. 5 To aim the goals for the quality of the final effluent the station is divided in 3 main ways for the liquid line: 1. 2. 3. 4. Pre-Treatment Primary Treatment Secondary Treatment Control Treatment For the treated effluents, the preview characteristics are shown in the next tables. The values are considered like MVA (Maximum Values Admitted). Table 3 – Effluent quality after the bio-filtration Table 4 – Quality for the effluent after the UV disinfection To obtain these values the station has the following treatment: 3.Pre-Treatment Receptions of the sewage in the gravity way: The waste water arrives in the station by four collectors: Frielas Collector with Ø 400mm (at the station entrance it turns in 200 mm) and the Industrial Park collector Rio da Costa collector with Ø 1500mm and P collector ovoid with 600 x 900 mm (they enter on the 2nd stage of the initial elevation). In both stages of initial elevation, the effluents are unloaded in an out-let drain on the base of the screws to limit the effluents velocity. 6 3.1 Reception of the Affluent Waste Waters by pumping: By pumping, arrives to the station the affluent from the elevation station 3 (EE3) that are unloaded on the repartition channel of the bar screen. 3.1.1 First Stage of Initial Elevation: The elevation is made by Archimedean screws (2 + 1 of reserve), on the out-side and with a security covering to limit the smells release. 3.1.2 Second Stage of Initial Elevation: The elevation is made by Archimedean screws (3 + 1 of reserve), on the out-side and with a security covering to limit the smells release. 3.2 Mean Bar-Screen: To the repartition channel of the bar-screen arrive a huge water-flow by the Archimedean screws from the primary elevation and the water-flow from the EE3. The water-flow is divided by four channels, going by a first stage of vertical bares with automatic clean and 40mm between each bare. The solids residues recuperation is made by transportable rug. They put the residues in containers. 3.3 Fine bar-screen: The water-flow goes to a second stage with vertical bars (10mm between each bare) and also with automatic clean. The solid waste is recuperated by a second unity of transportable rug which routed the solid waste into the containers. 7 3.4 Water-Flow measure of the screened waters: After the bar-screen the effluent flow rate is measured by a ultrasonic probe installed in a Parsha II channel. 3.5 Traps for sand and Degreasing: The sand, oils and graisse removal is made in the same combined equipment, with three treatment tanks. The oils and graisses are removed by air injection in shrouded of membranes, allowing the flotation. After that, they are scraped in the surface and routed to a boiler, downstream the tanks, where are through, by water injection, until the graisse well. After they can be routed to a flotation separator or to a graisse tank if the separator is damaged. The sands are deposited in the bottom by gravity where are removed by “sand removal pumps” to “sand classifiers” witch deposited them in containers. 4. Primary Treatment 4.1 Primary Decantation: The effluents are submitted to a lamellar primary decantation in rectangular tanks, with the possibility of the reagents introduction (coagulants and flocculants). The system is divided in 4 lamellar decantation lines, equals between them: One tank of fast mixture to coagulant addition One tank of fast mixture to pH correction by the milk of lime addition One tank of slow mixture to flocculant addition Lamellar sedimentation tank in the final of each line 8 After the decantation the effluents proceed to the intermediate elevation by one pipe where the water flow is measured. The settled sludge is took by pumps of eccentric rotor type and routed to the thickeners. 5. Secondary Treatment 5.1 Intermediate Elevation: Upstream of the equalization tanks there is the intermediate elevation, made by 4 Archimedean screws (3 + 1 reserve), witch allows elevate the total water-flow for the equalization tanks. 5.2 Homogenization and Equalization Tank: The three equalization tanks have the total volume = 16 465 m3 and they communicate between them by the surface unloader and by a motorized wall valve located near from the each tank floor. They limit the affluent waterflow to the biological treatment (4.650 m3/h), and they also regulate the effluent contents. To preserve the solid material waste in suspension, and also to homogenize and refresh the residual waters each tank is equipped with agitation and aeration systems. 5.3 Biological Treatment – Activated Sludge: This treatment has the followings equipments: Six aeration tanks with unitary volume = 4000m3 where, with the presence of O2, it will occurs the degradation of the organic matter by aerobic microorganisms Six pairs of secondary settlers witch allows separate the treated water of the activated sludge – in a way to re-use the biomassa, depuration base. Sludge Recirculation, allowing another route through the aeration tanks in activated sludge. Allows also the maintenance of an environment where 9 the relation between the BOD affluent and the activated sludge mass corresponds to the mass content preview to be functional. Excess Biological Sludge extraction to the flotation 6. Control Treatment 6.1 Final Elevation: Allows elevate the effluent from the secondary treatment to the biofiltration by 3 centrifugal pumps (2 + 1 reserve), installed in pipes. 6.2 Bio-Filtration: At the end of secondary settler, to obtain the demanded quality (BOD and TDS), the effluents are submitted to a bio-filtration treatment. This treatment phase occurs in BIOSTYR filters, filled with a floater material composed by polystyrene balls denominated BIOSTYRENE, colonized by a depurated biomass. The secondary effluent inlet in the filters is made by an ascendant flow, accompanied with air. This air is delivery in co-current by perforated distributors net, located in the bottom of the filter. The BIOSTYRENE are kept in the filter by a concrete flag-stone cover equipped with mole cricket. In a single equipment occurs also the elimination of the soluble pollution and the effluent clarification by the filtration through the biomass waterbed. This is the Bioreactor of piston type, to the liquid and gaseous phase. 6.3 Final Fine Water-flow Measurement: In the pipes, that connect the treated effluent from the bio-filtration to the UV disinfection, is installed one electromagnetic water flow meter. 10 6.4 UV Treatment: Before the effluent rejection on the reception environment, to guarantee the biological fixed quality (200 E. coli. / 100 ml), the effluent is disinfected by UV radiation. The system is composed by 3 parallel channels, equals between them, each one with 3 benches of 23 modules with 8 lamps each, placed paralleled to the flow. It means 552 lamps by channel and a total of 1656. The treated effluent is redirected to “Real Ditch” that is connected to the river bank (“Ribeira da Póvoa”) by a tide gate system that allows the isolation of the ditch and the effluent discharge even if the surface-liquid level of the river bank is higher. 7.Sludge Treatment 7.1 Thickening: The primary sludges are thickened by gravity in two circular thickeners with 20m of diameter. The excess biological sludges are thickened by flotation (with or without addition of polyelectrolyte), in two circular recipients with 11m of diameter. 7.2 Conditioning by hydrated whitewash addition: After thickening, the sludges (primary and biological) are mixed in a mixed sludges tank where they suffer conditioning by hydrated whitewash (lime milk) addition. 7.3 Anaerobic Digestion: After conditioning, the mixed sludges are submitted to a stabilization by mesophilic anaerobic digestion, in 4 digesters of 400m3, mechanically agitated. 11 7.4 Sludge dewatering: Sludge, in the digestion phase, must be kept in a constant temperature (35 ≈ 39ºC), that’s why is necessary to warm them. In this way, the mixed sludge at the digestion entrance is pre-heated in a heat exchanger, by the digested sludge that goes out to the dewatering. After that, the sludge stay in a permanent recirculation, passing through heat exchangers where are heated by hot water, to compensate the thermal lost of the digesters. There are 2 boilers, using the produced biogas as fuel to the water heating that will circulate in the referred heat exchangers. 8.Biogas Valorisation The produced biogas during the digestion is treated to the impurities removal and deposited in two gasholders of 1050m3 each and valorised by combustion in 2 cogeneration engines. These engines can work with biogas and with fuel and they convert part of energy from the biogas combustion in electric energy. 9.Dewatering Sludge Project In association with Engineering University of Lisbon (Instituto Superior Técnico), the Waste Water Treatment Station in Frielas realized one important study of sludge dewatering: “Dewatering process of mixed primary and waste activated, anaerobically digested, sludge using an advanced membrane filter press system” The experimental work was conducted at the pilot-plant from the “Centro de Processos Químicos da UTL” using an integrated filtering and dewatering system. The global dewatering cycle involved an initial filtration step, followed by the membrane squeezing using hot-water and a final step of vacuum drying. 12 The results showed that it is possible to achieve competitive values of final humidity when comparing to other more common technologies such as beltfilter presses and centrifuges. The final humidity of the filtration cakes ranged from 47% to 76% comparing to the maximum expectable value at Frielas of 74% (using centrifuges). To obtain these results, diatomite was used as precoat and, in some cases, as body feed. The same cationic floculant used for dewatering with centrifuges at Frielas (ZETAG 51) was used at various concentrations as body feed. These results show that is possibly not only reduce the humidity rates in the sludge but also decrease the volume, the unpleasant smells and increase the biological stability. Figure 1 –Advanced membrane filter press system 10.Conclusion The effluent treatment scheme is almost the same in all WWTP, at least in the liquid line and in the first stages of sludge treatment. The problem is the final destiny of the sludge. The direct application on the soil requires one exigent quality control to avoid contamination, the deposition in sanitary land- 13 fills is too expensive, and last possibility is the incineration, which also requires attention with the gaseous emissions. In all those possibilities, it’s better to have the less water content possible in the sludge to decrease de volume, weight and also the price with the transportation or to facility the combustion in the incinerators. That’s why is so important to invest in systems more efficient in the sludge dewatering. 11.Terminology Caudal = Water Flow Caudal médio diário = Diary Average Water Flow Caudal de ponta = Instantaneous Water Flow CBO5 = BOD5 (biochemical oxygen demand during a 5 days period at 20ºC (mg O2/l)) CQO = COD (chemical oxygen demand (mg O2/l)) Coliformes fecais = Faecal Coliforms N-NTK – Total Kjeldahl Azote P Total = Total Phosphorus Tempo Pluvioso = Wet Weather Tempo Seco = Dry Weather SST = TUS (total undissolvent solids (g/l)) SSV – TVSS (total volatile suspended solids (g/l)) 14