COSHH ASSESSMENT FUEL GAS PROPANE BUTANE Page 1 of 2 Health Hazards : EXTREMELY FLAMMABLE GAS - MAY CAUSE FLASH FIRE OR EXPLOSION LIQUID CAN CAUSE FREEZE BURNS TO UNPROTECTED SKIN AND EYES VERY HIGH CONCENTRATIONS CAN ASPHYXIATE OR CAUSE DIZZINESS, DROWSINESS, HEADACHE AND SIMILAR NARCOTIC SYMPTOMS CYLINDERS OR STORAGE VESSELS INVOLVED IN A FIRE MAY EXPLODE GAS/VAPOUR HEAVIER THAN AIR. MAY ACCUMULATE IN CONFINED SPACES, PARTICULARLY AT OR BELOW GROUND LEVEL. BURNING GAS IN AN OXYGEN DEFICIENT ATMOSPHERE MAY PRODUCE CARBON MONOXIDE Department/ Work area: Various Approved use: Duration of use: variable As a fuel gas for heating appliances, fork lift trucks, and oxy fuel brazing/soldering Who is exposed and when? No of People exposed? Engineers during changing of cylinders and use of brazing/soldering equipment. Handlers Dependent on type of work during transport. How is/could anyone be exposed? High concentrations of gas in a confined area or catastrophic leak situation can exclude enough oxygen to be an asphyxiation hazard particularly at low level as gas is heavier than air. Gas leaking from storage vessels or equipment can form an explosive, flammable mixture with air. Vapour may travel and be ignited at remote locations and flash back. Risk assessment: Low Risk Providing that the following controls are followed Control measures Process enclosure Local exhaust ventilation Other ventilation Ensure good natural or forced general ventilation Method of work Personal protective equipment No smoking in vicinity of work area, or during connection/disconnection of equipment to cylinders and loading/unloading of vehicles. Leak-test all connections with soapy water solution. Cylinders must be stored, transported and used upright to ensure that the relief valve does not release liquid. Cylinders should be replaced in the open air Fuel gas has an odorant added to give early warning of a leak Steel toe-cap boots Gloves - leather for handling cylinders Approved standard issue overalls Safety glasses to be worn during connection and disconnection of cylinders Respirators Welfare Hygiene Other Transport: Yes No Description/approved type N/A Upright in manufacturers/suppliers cylinders with valves and caps tightly closed. The Transport of dangerous goods regulations may apply dependant on quantity carried. Product Classed as FLAMMABLE GAS Avoid transport on vehicles where the load space is not separated from the drivers Driver must be aware of the potential hazards Storage: Keep cylinders:Preferably store cylinders outdoors in a secure cage Indoors storage - limit the total quantity of flammable gases to a maximum of 50 Kg. (Acetylene and LPG) Tightly closed, secured upright and dry In a cool well ventilated area, at temperatures not exceeding 50C Away from sources of heat and ignition 3 m away from oxygen cylinders and other oxidants Spillage: - Leaks from cylinders or plant:Evacuate area and if safe to do so ventilate area Eliminate ignition sources. Post warning notices (including no smoking) Do not enter a poorly ventilated area where a leak is suspected as a flammable/explosive atmosphere or one lacking in oxygen may be present. Shut off at source if possible First aid: Inhalation - remove patient to fresh air and rest. If breathing stops give artificial respiration and call for medical assistance. Refer to a doctor or hospital COSHH ASSESSMENT FUEL GAS Page 2 of 2 PROPANE BUTANE Fire fighting measures: Vacate the area and call the fire brigade. If safe to do so, shut off the source of gas and allow fire to burn out. Small fires can be tackled with Dry Powder fire extinguisher. Fire should not be extinguished unless flow of gas can be immediately stopped. Keep storage vessels cool by spraying with water from a protected position if exposed to fire. DO NOT use water or foam to extinguish fires! Disposal of packaging and unused substance: Empty containers must be returned to the supplier or manufacturer. Unused product may be returned to the manufacturer or stored long term as above Manufacturer/supplier: Various – refer to Material Safety Data Sheets or details for appropriate cylinder(s) Substance: LPG Data sheet ref: N/A Hazardous components: Flammable gas Risk No and phrase: R12 Extremely flammable Safety No and phrase: S9/16/33A: Keep container in well ventilated place, away from ignition sources, including static discharge EEC Labelling Classification : Very toxic ( OEL:MEL ) Toxic ( or OES ) Irritant ( ) Harmful ( ) Corrosive ( N/A Any other comments: Assessor: Date: Date for review: ) Flammable ( )