Faculty Engineering Department Chemical Engineering Course Title Chemical Engineering Thermodynamics I Course Code CHE 203 Status Core course Level 2 Credit Hours 3 Contact Hours 4 Pre-requisites (if any) Co-requisites (if any) Teaching Methodology Method of Evaluation CHE 201 and MATH 201 Instructor(s) Semester Offered Dr. Muataz Ali Atieh Email: motazali@kfupm.edu.my Office: 16-208 Tel: 8607513 Semester I, 2007-2008 Course Objectives 1. To develop a physical awareness of the phenomena in thermodynamics. Nill Lectures and tutorials Mid Term Quizzes Homework (Assignments) Final Examination TOTAL 30 % 15 % 05 % 40 % 100 % 2. To present the fundamental laws that governs thermodynamics and their applications. 3. To develop practical methodologies for solving engineering problems by thermodynamics. Bulletin Description 4. To illustrate the extremely wide variety of thermodynamics related applications in everyday life and in modern technology. The first law of thermodynamics is studied in detail. Material covered includes concepts of energy, enthalpy, heat effects, conservation of energy, and interaction between heat transfer, mechanical work and chemical energy liberation, equation of state, behavior of gases and liquids and standard heat of reaction, formation and combustion. Study of combined mass and energy balances and the principles of the second and third law of thermodynamics are also covered. Learning Outcome 1) Determine thermodynamic information for pure fluids and use it to perform thermodynamic calculations oriented to the analysis of chemical processes. 2) Evaluate the values of enthalpy, entropy, internal energy for pure and mixed fluids. 3) Evaluate the effect of pressure and temperature on the properties of fluids 4) Define and obtain thermodynamic properties of pure fluids such as the heats of evaporation, formation and combustion. 5) Define and use different equations of state 6) Use enthalpy concentration charts and humidity charts in solving problems. 7) Define and draw thermodynamic diagrams such as P-V and P-T diagrams for pure fluids. 8) Able to understand the basic knowledge that is being applied in solving the thermodynamics problems. 9) Understand the principles how the current thermodynamics related devices are operated. 10) COURSE OUTLINES / CONTENTS Able to develop a new thermodynamics related devices or at least can make modification to the current devices. WEEK TOPICS CHAPTER /BOOK Energy and Energy Balances 1-3 1. Forms of Energy: the first law of Chapter 7/1 Thermodynamics 2. Kinetic and Potential Energy 3. Energy Balance on Closed Systems 4. Energy Balance on Open Systems at Steady State 5. Tables of Thermodynamic Data 6. Energy Balance Procedures 7. Mechanical Energy Balance Balance on Nonreactive Processes 4-7 Chapter 8/2 1. Element of Energy Balance Calculations 2. Changes in Pressure at Constant Temperature 3. Changes in Temperature 4. Phase Change Operations 5. Mixing and Solution Balances on Reactive Processes 8-10 Chapter 9/3 1. Heat of Reaction 2. Measurement and Calculation of Heat of Reaction 3. Formation Reactions and Heat of Formation 4. Heat of Combustion 5. Energy Balance on Reactive Processes 6. Fuels and Combustion Volumetric Properties of Pure Fluids 11-13 Chapter 3/2 1. 2. 3. 4. PVT Behavior of Pure Substances VIRIAL Equations of State The Ideal Gas Application of the VIRIAL Equations 5. CUBIC Equation of State 6. Generalized Correlations for Gases 7. Generalized Correlations for Liquids 14-16 The Second Law of Thermodynamics Chapter 5/2 1. Statement of the Second Law 2. Heat Engines 3. Thermodynamic Temperature Scales 4. Entropy 5. Entropy Changes of An I deal Gas 6. Mathematical Statement of the Second Law 7. Entropy Balance for Open Systems 8. Calculation of Ideal Work 9. Lost Work 10. The Third Law of Thermodymanics 11. Entropy from the Microscopic Viewpoint References Required: Textbook: 1) Elementary Principles of Chemical Processes, 3/e, by Richard M. Felder and Ronald W. Rosseau, J. Willey (2000). 2) Introduction of Chemical Engineering Thermodynamics, 6/e, by J.C. Smith, H.C. Van Ness, and M.M. Abbot, McGrawHill (2001). Recommended: 1. Yunus A. Cengel (1997), Introduction to Thermodynamics, McGraw Hill. 2. Gordon J. Van Wylen and Richard E. Sonntag (1986), Fundamentals of Classical Thermodynamics, Wiley. 3. William Z. Black and James G. Hartley (1996), Thermodynamics, Addison-Wesley. 4. Michael J. Moram and Howard N. Shapiro (1995), Fundamentals of Engineering Thermodynamics, John Wiley & Sons