Marplot and Aloha Exercises ALOHA This ALOHA exercise must be performed using the new ALOHA version 5.4.1.2. ALOHA 5.4.1.2 has the capacity to produce footprints for 3 different LOC simultaneously. This allows for many new options! The following exercise demonstrates a method for using UEL and LEL to predict the potential ignition area. Open ALOHA and select Butane as your chemical. Assume the following weather conditions: Wind Speed Wind Direction Ground Roughness Partly Cloudy Temperature Relative Humidity 10 mph S Open 5 50 degrees F 50% Set the Source as: Direct / Instantaneous / 12,000 gallons / Liquid Select Display / Threat Zone Question 2: What are your choices for the threat Zone? Select Toxic Area- What are the Choices? Select TEEL Go back and set the display Threat Zone to Flammable, note the information : Set the ALOHA LOC values as: Red Footprint: 60% LEL Orange Footprint: LEL Page 1 of 10 Yellow Footprint: 10% LEL Display the resulting footprint on MARPLOT. Open a new MARPLOT Layer; use the “polygon” tool to “draw” the LEL area while excluding the UEL area. This ALOHA’s “predicted” potential ignition zone. For safety purposes, you may elect to use 10% LEL instead. Use the MARPLOT Layer List to “Hide” the ALOHA Footprints. Your drawn “ignition zone” should be displayed. Exercise 2 Use ALOHA to model a release based on the following parameters. Location use your own location Chemical ammonia (anhydrous) Atmospheric Wind speed 10 mph Wind direction N Cloud cover 5 Temperature 70 Humidity 50% Source Direct / Instantaneous 8000 pounds Display the Threat Zone using the Default ERPG values as your Level of Concern (LOC). Display this on your Marplot map using our location. Draw outlines of the 3 Threat zones and save to a new layer called Ammonia Toxic 8000 lb. Also draw ERG protective zones. Question 4: Use the CAMEO Chemical Library to determine the following Level Of Concern values: LEL _____ Page 2 of 10 UEL ½ IDLH _____ ________ 10% LEL _____ Question 5: Run ALOHA plumes for all these LOC values. For LEL / UEL you will need to convert % to ppm and use the ALOHA User Specified LOC boxes! MARPLOT EXERCISES Create and print a MARPLOT map displaying the ALOHA plumes for: ERPG values IDLH / TLV values LEL / UEL values Use your MARPLOT county map for this exercise. 1) 2) 3) 4) Create a new map layer titled “VINYL ACETATE RELEASE” direct 5000 lbs. Locate a spot for your fictitious release to occur. Use the Sharing Menu to display the ERPG-1, 2, and 3 ALOHA footprints “Copy and paste” your screen to a Word document; here is one way to do that a. Use “Alt - Print Screen” keys to copy the screen; b. open a Word document; c. use “Control - V” keys, or “right-click – paste” to paste 5) Return to ALOHA and Display the LEL / UEL / 10% LEL Footprints (notice only the 10% LEL footprint is large enough for ALOHA to display a footprint) Page 3 of 10 ALOHA EXERCISES Use ALOHA to model a direct release of 150 pounds of CARBON DISULFIDE. Weather conditions are: Wind Speed: 7 mph Wind Direction: SSE Cloud Cover: 3 Temperature: 75 F Inversion: no Relative Humidity: 50% What is the Maximum Plume Distance when the LOC = IDLH __________ ERPG-1 __________ ERPG-2 __________ ERPG-3 __________ LEL __________ 10% LEL __________ What is the difference between measuring toxicity (ERPG) versus flammability (LEL)? How do you interpret the difference between ERPG and LEL plume distance? Page 4 of 10 MARPLOT EXERCISES Create and print a MARPLOT map displaying both the “Toxic” and the “Flammable Range” ALOHA plumes for CARBON DISULFIDE and the ERG suggested Immediate Isolation Area. Use your MARPLOT county map for this exercise. 1) 2) 3) 4) Locate a spot for your fictitious release to occur. Use the “Sharing” menu to display the ALOHA “Toxic” plume. Go to the “List” menu. Select the “New” button Open ALOHA and select Methylamine (1061) as your chemical. Question 1: Review the Text Summary. What value(s) will ALOHA use for the default Level of Concern? Assume the following weather conditions: Wind Speed Wind Direction Ground Roughness Partly Cloudy Temperature Relative Humidity 10 mph S Open 5 50 degrees F 50% Set the Source as: Tank Horizontal; 14 x 40 feet; 46,061 gallons capacity Tank contains Liquid at Ambient Temperature 85% full Leak is 3 inch, broken valve Leak location is halfway up the side of the tank Page 5 of 10 Select Display / Footprint menu Question 2: What is the “primary hazard” for Methylamine? Do the ERPG values reflect that hazard? Are any of the ERPG values reflective of the UEL or LEL? Question 3: Can you set the LOC values to UEL and LEL using the Display menu? Question 4: Set the ALOHA LOC values as: Red Footprint: UEL Orange Footprint: LEL Yellow Footprint: 10% LEL Question 5: How many “footprints” are now displayed on your ALOHA screen? Why? ALOHA: A local company keeps 55-gallon drums of a product named ETHYLENE CHLOROHYDRIN. These are not pressurized containers. You have been asked to determine if a spill of this product at the company loading dock (outside of the building) could have any impact on a residential neighborhood that is .3 miles north of the facility. Assume the following weather conditions: Wind Speed Wind Direction 4 mph S Page 6 of 10 Ground Roughness Partly Cloudy Temperature Relative Humidity Open 5 90 degrees F 50% First, use the Direct/Instantaneous Source option to create the “worst-case” scenario for a 55-gallon release. Use the ALOHA default TEEL values for your Level of Concern. Is there a problem? Question 1: List the Maximum Footprint Distance for the TEEL values for the Direct/Instantaneous Source: TEEL-1 TEEL-2 TEEL-3 ____________ ____________ ____________ Now use the “Puddle” source option for a 440 square foot puddle containing 55 gallons of this product. Question 3: Using the Puddle Source information, what is your estimate of the time necessary for a 55-gallon pool of this product to completely enter the atmosphere? Question 4: According to the ALOHA predictions, is it likely the product could impact on the neighborhood 0.3 miles north of the facility: For “Worst-Case” conditions? Yes No For “Puddle” conditions? Yes No Page 7 of 10 ALOHA Use the Chemical ETHANOL. Scenario: A 8,000 gallon semi-trailer placarded 1170 is stopped at a local convenience store. The liquid product is gushing from a failed 2” valve located at the bottom of the tank, rear end of the truck. 30 minutes have elapsed before you are consulted. Responders at the scene estimate tank size as 25 feet by 8 feet. The liquid runoff has been contained in the parking lot; no estimate of the pool/puddle size is currently available. Assume the following weather conditions: Wind Speed Wind Direction Ground Roughness Partly Cloudy Temperature Relative Humidity 10 mph S Open 5 65 degrees F 50% Question 1: Is it possible to model this substance using ALOHA? Question 2: With the information currently available, which ALOHA Source Option(s) could be utilized? Question 3: What value will you use for the Level of Concern? Explain why the available LOC values are all the “same” number. Question 4: Analyze the “footprint” information for a “Tank” Source release. Explain why ALOHA does not “draw” the plume/footprint for a Tank Source, but does “draw” a footprint for a “Direct/Instantaeous” source. Question 5: What is the ALOHA estimate for the size of the puddle from the tank release? Page 8 of 10 ****************************************************************** Question 1: Can you model a BORON TRIFLUORIDE release using ALOHA? Question 2: In what physical state does ALOHA need BORON TRIDLUORIDE to model a release at “ambient temperature”? Question 3: Use ALOHA to model a release based on the following parameters. Location use your own location Chemical boron trifluoride Atmospheric Wind speed 10 mph Wind direction N Cloud cover 5 Temperature 70 Humidity 50% Source Direct / Instantaneous 1000 pounds Question 4: Display the footprint. Use the CAMEO Chemical Library to determine the following Level Of Concern values: ERPG-1 ERPG-2 ERPG-3 Question 5: Run ALOHA plumes for all 3 available LOC values. Make sure to change your units from ppm to mg/m3! MARPLOT EXERCISES Create and print a MARPLOT map displaying a radius for the 3 ALOHA plumes for BORON TRIFLUORIDE from the above scenario. Page 9 of 10 Use your MARPLOT county map for this exercise. 1) 2) 3) 4) 5) 6) 7) 8) 9) 10) 11) 12) 13) 14) Create a new map layer titled “BORON TRIFLUORIDE RELEASE” Locate a spot for your fictitious release to occur. Use the Sharing Menu to display the ERPG-1 ALOHA footprint Use the Polygon Tool to trace around the footprint; when finished, select “OK” Name the new “object” “BT with ERPG = 2 mg/m3” Make the object color “PINK” and select a “Fill Pattern” Select “OK”. Repeat steps 4 – 7 with these changes: a. Change LOC to ERPG-2; display footprint on map b. Object name is “BT with ERPG = 30 mg/m3” c. Make the color BLUE and the fill pattern different Repeat steps 4 – 7 with these changes: a. Change LOC to ERPG-3 display footprint on map b. Object name is “BT with ERPG = 100 mg/m3” c. Make the color RED and the fill pattern different Print the map. Save it as a bitmap file to your desktop (use the “File” menu). Make sure to give it a name! Minimize all screens until you can see your desktop. Use a “photo editor” program to open the bitmap you just saved. You can now “edit” the picture using the photo editor functions. Edit the photo and print it. You should now be able to e-mail the picture. If you can, e-mail it to someone you know or someone in your office, then print it again. You may also “Export” the picture to other MARPLOT users as a “.mie” file. The other MARPLOT users would “Import” the .mie file, and the picture will appear EXACTLY as it does on your computer. Page 10 of 10