Oakton Community College Generic Course Syllabus I. Course Prefix Course Number Course Name CHM 122 General College Chemistry II II. Credit Lecture 4 3 Lab 3 Prerequisites: CHM 121 with minimum grade of C, and MAT 140 or MAT 149 with minimum grade of C, or consent of instructor. III. Course (Catalog) Description Course continues CHM 121. Content includes kinetics, chemical equilibrium, acid-base theory and equilibria, solubility equilibria, electrochemistry, thermodynamics, nuclear chemistry, coordination compounds, and an introduction to organic and biochemistry. Weekly laboratory activities. IV. Learning Objectives Students who successfully complete this course will be able to do the following at an acceptable level. A. State the meaning of reaction rate and discuss the factors which affect it B. Write the rate law for a reaction given an appropriate set of initial concentrations of reactants and associated initial rates C. Calculate the amount of reactant remaining after a given period of time when furnished with the half life, for either first or second order reactions D. Write possible multi-step mechanisms consistent with a given chemical reaction, and determine the rate law for a reaction predicted by a particular simple mechanism. E. Determine the equilibrium constant for a reaction equation given 1) the equilibrium concentrations of reactants and products, or 2) the initial concentrations of reactants and products and the equilibrium concentration of one of them F. Calculate the equilibrium concentration of reactants and products given the equilibrium constant for the reaction and the initial concentrations G. Understand the concept of (and ways of) shifting the equilibrium position of a chemical system H. Understand the common ion effect 1 I. Describe the various acid-base theories J. Calculate the pH, [H3O+], pOH, or [OH-] of a solution at 25oC given the value of any one of these variables and at any temperature given Kw for that temperature K. Calculate concentrations of all species present in a solution of a weak polyprotic acid when the initial concentration and all Ka values are given L. Calculate the pH of an aqueous solution (a) of a salt of known concentration, (b) of a strong or weak acid or base of known initial concentration, (c) of a buffer system with known initial concentrations, and (d) at various stages of an acid/base titration, given the relevant Ka or Kb values. M. Describe the function of an indicator and select an appropriate indicator for a specified acid/base reaction N. Calculate the solubility of a slightly soluble salt (in water or in a solution with a common ion) and the equilibrium concentration of all ions present, given the Ksp O. Calculate the Ksp value of a slightly soluble salt from solubility data P. Understand the meaning and significance of Ssys, Ssurr, Suniverse, and the qualitative relationship between Suniverse and Gsys Q. Predict which physical or chemical processes increase a system's entropy R. Understand the meaning of “exothermic”, “endothermic”, “spontaneous”, and “non-spontaneous”, and be able to determine through calculation which of these correspond to a proposed reaction if conditions and appropriate thermodynamic data are given. S. Describe the meaning of, and qualitative and quantitative relationships between Q, G, and Ecell. T. Describe the meaning of, and relationships between K, Go, and Ecello and distinguish these from Q, G, and Ecell U. Balance equations of oxidation-reduction reactions occurring in acidic or basic solution V. Sketch electrolytic or voltaic cells indicating cathode, anode, positive and negative electrode, direction of current flow, Ecell, and half reactions W. Determine EMF (Ecell) for standard cells from values of standard reduction (or oxidation) potentials, and for non-standard cells using the Nernst equation X. Discuss the basic chemistry of common metals Y. Name, describe the geometry, and identify isomer possibilities for coordination compounds formed from common metal ions and ligands Z. Describe the physical phenomena which lead to a compound being colored AA. Describe common nuclear reaction types and energy changes associated with them BB. Use the n/p ratio and band of stability to predict the most likely nuclear decay reaction for a nuclide CC. Name and draw structural formulas for simple alkanes, alkenes, alkynes, aromatics, alcohols, ethers, aldehydes, ketones, carboxylic acids, esters, and amino acids 2 DD. Identify the building blocks making up proteins and nucleic acids; describe different levels of structure for proteins and nucleic acids and relate structure and function EE. Describe and give examples of carbohydrates and lipids (particularly triglycerides) FF. Determine the presence or absence of various cations in aqueous solution by using qualitative analysis logic and reactions GG. Determine the concentration of various species through titration and spectrophotometric techniques V. Academic Integrity Students and employees at Oakton Community College are required to demonstrate academic integrity and follow Oakton’s Code of Academic Conduct. This code prohibits: cheating, plagiarism (turning in work not written by you, or lacking proper citation), falsification and fabrication (lying or distorting the truth), helping others to cheat, unauthorized changes on official documents, pretending to be someone else or having someone else pretend to be you, making or accepting bribes, special favors, or threats, and any other behavior that violates academic integrity. There are serious consequences to violations of the academic integrity policy. Oakton’s policies and procedures provide students a fair hearing if a complaint is made against you. If you are found to have violated the policy, the minimum penalty is failure on the assignment, and a disciplinary record will be established and kept on file in the office of the Vice President for Student Affairs for a period of 3 years. Details of the Code of Academic Conduct can be found in the Student Handbook. VI. Outline of Lecture Topics A. Kinetics Factors affecting rates of chemical reactions Determining rate and rate laws from experimental data Half life and first order reactions; half life and second order reactions Rate laws and reaction mechanisms 3 B. Equilibrium Concept, and determination of equilibrium constants Predicting the direction of a reaction for a system not at equilibrium Equilibrium concentration of reactants and products Effect of pressure and temperature on equilibrium C. Acids and Bases Acid – base theory Definition and determination of pH and pOH Relative strength of various acids and bases Determination of the pH of strong acids and bases D. Acid – Base Equilibria Determination of the pH of weak acids and bases Hydrolysis of salts; determination of the pH of salt solutions Polyprotic acids Buffers and common ion effect Titration curves E. Solubility of Slightly Soluble Compounds Determination of solubility product and dissociation constants Common ion effect on solubility Effect of pH on solubility Qualitative analysis of metal ions F. Thermodynamics Enthalpy and the first law of thermodynamics Entropy and the second law of thermodynamics Exothermic and endothermic reactions; spontaneous and nonspontaneous reactions Gibbs free energy and spontaneity; standard Gibbs free energy and equilibrium constants G. Electrochemistry Voltaic cells Electrolytic cells Half reactions of water; electrolysis of aqueous solutions Standard EMF and equilibrium constants H. Nuclear Chemistry Nuclear equations Nomenclature of subatomic particles Nuclear decay and half life Applications I. Descriptive Chemistry Main group elements Transition metals including structure and nomenclature of complexes J. Structure of Carbon and Carbon Compounds Overview of organic functional groups, including nomenclature and properties Introduction to isomerism in organic compounds 4 Polymers J. Biochemistry Amino acids and proteins Nucleotides and nucleic acids Sugars and starches Lipids (especially triglycerides) Laboratory Activities The laboratory activities will include a safety overview including the location and demonstration of the use of laboratory safety equipment. There are weekly hands-on activities which include 12-14 of the specific activities listed below. A. B. C. D. E. F. G. H. I. J. K. L. M. N. O. Analysis of an Unknown Chloride Rates of Chemical Reactions. I – The Iodination of Acetone Rates of Chemical Reactions. II – A Clock Reaction Determination of Equilibrium Constant for a Chemical Reaction Qualitative Analysis of Group I Cations pH Measurements—Buffers and Their Properties Acid-Base Titration Curve Determination of Solubility Product Constant of PbI2 Qualitative Analysis of Group III Cations Voltaic Cell Measurements Preparation of Copper(I) Chloride Determination of an Equivalent Mass by Electrolysis Determination of the Hardness of Water Preparation of Aspirin Absorption Spectra of Some Ni2+ Complexes VII. Methods of Instruction Lectures which may be supplemented with classroom discussion, use of molecular models, use of multimedia, and/or use of computer based materials at the discretion of the instructor. Hands-On Laboratory Activities Individual and/or Group Problem Solving VIII. Course Practices Required College-level writing skills on tests and laboratory write-ups Communication skills for discussion and articulation of questions Adherence to standard safety practices while in the laboratory 5 IX. Instructional Materials The course textbook is Chemistry: A Molecular Approach, 2nd edition Tro, c 2011 or comparable text. The laboratory text is Chemical Principles in the Laboratory, customized 9th edition by Emil Slowinski, Wayne Wolsey, and William Masterton, c 2009 or comparable text. Beginning with the Spring 2007 semester, students will be required to purchase their own Chemical Safety/Splash Goggles. These goggles must meet the following criteria: Fit snuggly against the forehead and face, protecting against splashes Be impact resistant; ANSI rating of Z87 or higher Include only indirect venting Two varieties of such goggles compliant with the above criteria are available for purchase in the bookstore (cost range ~ $6-$12). Students may also elect to find an alternative source for purchase, so long as the goggles meet the above criteria and are approved by the instructor. X. Methods of Evaluating Student Progress Depending upon the instructor, any combination of the following assessments may be used to evaluate student progress and determine the course grade. Quizzes, tests, and/or examinations which may include essay, short answer, multiple choice, true/false, and/or problem solving questions Laboratory assignments, reports, results and/or practicals Individual and/or group written reports Individual and/or group oral reports Individual and/or group problem solutions XI. Other Course Information A. Reading the text and laboratory material ahead of the class or laboratory session is expected. B. Regular attendance at all sessions is expected. Missed laboratory sessions will not be able to be made-up. C. Class policies on make-up of exams and accepting of late work will be determined by the individual instructor. D. Students will be required to review and sign off on their review, understanding, and adherence to basic laboratory safety regulations. 6 E. Support services include the availability of open computer laboratories, the college library, and the availability of free tutoring through the Learning Center and/or office hours with the course instructor. F. Students who have a documented learning, psychological, or physical disability may be entitled to reasonable academic accommodations or services. To request accommodations or services, the student needs to contact the ASSIST office in the Learning Center. All students are expected to fulfill essential course requirements. The college will not waive any essential skill or requirement of a course or degree program. G. Oakton Community College recognizes the broad diversity of religious beliefs of its constituencies. The college has embraced a practice of shared responsibility in the event a religious observance interferes with class work or assignments. Students who inform instructors in advance of an intended absence for a major religious observance will not be penalized. The instructor will make reasonable accommodation for students, which may include providing a make-up test, altering assignment dates, permitting a student to attend another section of the same course for a class period or similar remedies. Instructors are not responsible for teaching material again. Instructors should inform students of this practice at the beginning of the semester so that arrangements can be made accordingly. Similar consideration is accorded to faculty, staff and administrators and is provided for in their respective contracts. Effective beginning term: Fall 2011 Ending term: Syllabus prepared by: Gary Mines Date: Reviewed by Dept./Prog. Chair: Approval by Dean: John Carzoli Nancy Prendergast 5/2011 Date: 5/2011 Date: 5/2011 7