FISHER SCIENTIFIC, CHEMICAL DIV

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FISHER SCIENTIFIC, CHEMICAL DIV. -- URANYL
NITRATE,HEXAHYDRATE, U725 -- 6810-00N008681
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Product Identification
Product ID:URANYL NITRATE,HEXAHYDRATE, U725
MSDS Date:04/27/1986
FSC:6810
NIIN:00N008681
MSDS Number: BCQTT
=== Responsible Party ===
Company Name:FISHER SCIENTIFIC, CHEMICAL DIV.
Address:1 REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410-2802
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100 (GASTON L. PILLORI
CAGE:IB464
=== Contractor Identification ===
Company Name:FISHER SCIENTIFIC CO
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Phone:201-796-7100
CAGE:IB464
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Composition/Information on Ingredients
Ingred Name:URANYL NITRATE,HEXAHYDRATE
CAS:113520-83-7
RTECS #:YR3850000
Fraction by Wt: 100%
Other REC Limits:N/K
OSHA PEL:0.05 MG(U)/CUM TWA
ACGIH TLV:0.2 MG(U)/CUM TWA
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Hazards Identification
Reports of Carcinogenicity:NTP:NO
IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE & MUCOUS MEMBRANE
IRRITANT.POISONING MAY DMG
EYES,LUNGS,KIDNEYS,SKIN,LIVER,LYMPHATICS,BLOOD &
BONE
MARROW.URANIUM MAY CAUSE RADIATION
DMG,CARCINOGENESIS.LONG TERM
EXPOSURE TO SOLUBLE URANIUM SALTS HAS BEEN
REPORTED TO CAUSE AN
INCREASEIN CANCER OF LYMPHATIC & BLOOD-FORMING
TISSUE OF MAN.
Explanation of Carcinogenicity:LONG TERM EXPOS TO
SOLUBLE URANIUM SALTS
REPORTED TO CAUSE INCREASE CANCER OF LYMPHATIC &
BLOOD FORMING
TISSUE OF MAN.
Effects of Overexposure:INH:ACUTE EXPOS-IRRIT
LUNGS,KIDNEYS INFLAMN W/
URINATION DISORDERS.SUBSEQUENT LIQUER DMG.POSS
NITRATE POISONING
CAUSES
CYANOSIS,METHEMOGLOBINEMIA,HYPOTENSION,TACHY,NERVOUS
SYMP &
POSS CONVUL & COMA.CH RONIC EXPOS-PULMONRY & RENAL
DMG.SKIN:ACUTE-IRRIT.CHRONIC-DERMATITIS.EYE:ACUTEMOD TO SEV INJURY
(SUPP DATA)
Medical Cond Aggravated by Exposure:N/K
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First Aid Measures
First Aid:INH:REMOVE TO FRESH AIR.W/ STOPPED
BRTHING,GIVE O*2.KEEP WARM
& REST.SKIN:REMOVE CONTAMED CLOTHING & SHOES.WASH
AFFECTED AREA W/
SOAP/MILD DETERGENT & H*2O FOR APPROX 15-20
MINUTES.EYE:WASH W/
H*2O FO R AT LEAST 15 MINUTES.INGEST:IF
CONSCIOUS,GIVE 2-4 GLASSES
OF H*2O & INDUCE VOMIT.IN ALL ABOVE CASES,GET IMMED
MED ATTN &
ADVISE MED PERSON THAT VICTIM MAY BE CONTAMED W/
RADIOACTIVE
MATL/CHEM BURN.
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Fire Fighting Measures
Flash Point:NONCOMBUSTIBLE
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:DRY CHEMICAL,CO*2,H*20 SPRAY OR
FOAM.W/LG FIRE,USE
FLOODING AMT OF H*2O FROM A DISTANCE
Fire Fighting Procedures:PRESS-DEMAND/OTHR POSITIVE
PRESS SCBA W/FULL
FACEPIECE.CALL LOCAL/STATE/DOE RADIOL RESPONSE
TEAM.AVOID BRTNING
DUST/VAPORS.EVACUATE 2500FT RADIUS (SUPP DATA)
Unusual Fire/Explosion Hazard:SMALL FIRE & SEV
EXPLOSION HAZARD WHEN
SFOCHED/FRICTION/HEAT OR CONT W/ OXIDIZABLE
MATL.H*2O MAY CAUSE
SCATTERING OF MOLTEN MATL.RELEASES (SEE OTHER
PRECAUT)
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Accidental Release Measures
Spill Release Procedures:SOIL:DIG HOLDING AREA.DIKE
FLOW OF SPILL W/
SOIL/FOAM/CONCRETE.ABSORB SPILL W/ CEMENT
POWDER/FLY ASH.NEUTRALIZE
SPILL W/AGENTS.H*20:NEUTRALIZE TO PH7.EXTRACT
PRECIPT.OCCU:USE
ABSORBENT MATL FOR SM SPI LL.FOR LG SPILL,DIKE
AHEAD OF SPILL (SUPP
DATA)
Neutralizing Agent:AGRICULTURAL/SLAKED LIME,CRUSHED
LIMETONE,SODIUM
BICARBONATE
====================== Handling and Storage
======================
Handling and Storage Precautions:PROTECT CONTR FROM
PHYSICAL DMG &
AVOID CONTACT W/ INCOMPATIBLES .
Other Precautions:UNUSUAL FIRE HAZ:TOXIC GASEOUS
NITROGEN OXIDED IF
INVOLVED IN FIRE.INCREASES FLAMMABILITY OF ANY
COMBUSTIBLE MATL.IF
SHAKEN,RUBBED/CRUSHED,CRYSTALS SHOW
TRIBOLUMINESCENCE WITH
OCCASIONAL DETONATION.
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Exposure Controls/Personal Protection
Respiratory Protection:2.5 MG(U)/CUM:HIGH EFFECIENT
PARTICULATE RSPTR
W/FULL FACEPIECE,SUPPLY AIR RSPTR,SCBA.20
MG(U)/CUM:TYPE C SUPPLY
AIR RSPTR W/FULL FACEPIECE IN PRESS DEMAND/OTHR
POSITIVE PRESS MODE
OR W/FULL FACEPIECE ,HELMET/HOOD W/CONSTANT
FLOW.ESCAPE:SCBA
Ventilation:PROCESS ENCLOSURE RECOMMENCED (MFR).
Protective Gloves:WEAR APPROPRIATE PROTECTIVE GLOVES
Eye Protection:CHEMICAL WORKERS GOGGLES & FACESHLD
Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE
CLTHG &
EQUIPMENT TO PREVENT SKIN CONTACT WITH SUBSTANCE.
Work Hygienic Practices:PROVIDE EYE-WASH STATION WITHIN
IMMEDIATE WORK
AREA FOR EMERGENCY USE
Supplemental Safety and Health
SIGNS & SYMP:EYE:CHRONIC-CONJUNCTIVITIS.INGEST:ACUTEMOUTH & STOMACH
IRRIT,TOXIC AMT MAY CAUSE EARLY SYMP OF NITRATE
POISONING & DELAYED
SYMP OF URANIUM TOXICITY.FIRE FGTING:KEEP AREA
CLEAR UNTIL DECL
ARED SAFE.SPILL PROC:DELAY CLEANUP OF LG OCC SPILL
TILL ARRIVAL OF
QUALIFIED AUTHORITY
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Physical/Chemical Properties
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:140 60C
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:2.8
pH:ACIDIC
Evaporation Rate & Reference:N/K
Solubility in Water:SOLUBLE
Appearance and
Odor:ODORLELL,YELLOW,DELIQUESCENT,RHOMBIC CRYSTALS.
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Stability and Reactivity Data
Stability Indicator/Materials to Avoid:YES
ORGANIC SOLVENTS & OTHER OXIDIZABLE
MATL,COMBUSTIBLES.ABSORBED ON
CELLULOSE TO FORM EXPLOSIVE CELLULOSE NITRATE
Stability Condition to Avoid:IN ETHER SOLN,MAY EXPLODE
UNDER
SUNLIGHT.H*2O SOLN IS ACIDIC,CORRODES METALS.MAY
TRIBOLUMINESCE/EXPLODE FROM FRICTION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION
MAY RELEASE
TOXIC OXIDES OF NITROGEN.
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Disposal Considerations
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE
W/ FEDERAL,STATE
& LOCAL REGULATIONS .
Disclaimer (provided with this information by the
compiling agencies):
This information is formulated for use by elements of
the Department
of Defense. The United States of America in no manner
whatsoever,
expressly or implied, warrants this information to be
accurate and
disclaims all liability for its use. Any person
utilizing this
document should seek competent professional advice to
verify and
assume responsibility for the suitability of this
information to their
particular situation.
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