FISHER SCIENTIFIC, CHEMICAL DIV. -- URANYL NITRATE,HEXAHYDRATE, U725 -- 6810-00N008681 ===================== ===================== Product Identification Product ID:URANYL NITRATE,HEXAHYDRATE, U725 MSDS Date:04/27/1986 FSC:6810 NIIN:00N008681 MSDS Number: BCQTT === Responsible Party === Company Name:FISHER SCIENTIFIC, CHEMICAL DIV. Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410-2802 Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 (GASTON L. PILLORI CAGE:IB464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410 Country:US Phone:201-796-7100 CAGE:IB464 ============= ============= Composition/Information on Ingredients Ingred Name:URANYL NITRATE,HEXAHYDRATE CAS:113520-83-7 RTECS #:YR3850000 Fraction by Wt: 100% Other REC Limits:N/K OSHA PEL:0.05 MG(U)/CUM TWA ACGIH TLV:0.2 MG(U)/CUM TWA ===================== ===================== Hazards Identification Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE & MUCOUS MEMBRANE IRRITANT.POISONING MAY DMG EYES,LUNGS,KIDNEYS,SKIN,LIVER,LYMPHATICS,BLOOD & BONE MARROW.URANIUM MAY CAUSE RADIATION DMG,CARCINOGENESIS.LONG TERM EXPOSURE TO SOLUBLE URANIUM SALTS HAS BEEN REPORTED TO CAUSE AN INCREASEIN CANCER OF LYMPHATIC & BLOOD-FORMING TISSUE OF MAN. Explanation of Carcinogenicity:LONG TERM EXPOS TO SOLUBLE URANIUM SALTS REPORTED TO CAUSE INCREASE CANCER OF LYMPHATIC & BLOOD FORMING TISSUE OF MAN. Effects of Overexposure:INH:ACUTE EXPOS-IRRIT LUNGS,KIDNEYS INFLAMN W/ URINATION DISORDERS.SUBSEQUENT LIQUER DMG.POSS NITRATE POISONING CAUSES CYANOSIS,METHEMOGLOBINEMIA,HYPOTENSION,TACHY,NERVOUS SYMP & POSS CONVUL & COMA.CH RONIC EXPOS-PULMONRY & RENAL DMG.SKIN:ACUTE-IRRIT.CHRONIC-DERMATITIS.EYE:ACUTEMOD TO SEV INJURY (SUPP DATA) Medical Cond Aggravated by Exposure:N/K ======================= ======================= First Aid Measures First Aid:INH:REMOVE TO FRESH AIR.W/ STOPPED BRTHING,GIVE O*2.KEEP WARM & REST.SKIN:REMOVE CONTAMED CLOTHING & SHOES.WASH AFFECTED AREA W/ SOAP/MILD DETERGENT & H*2O FOR APPROX 15-20 MINUTES.EYE:WASH W/ H*2O FO R AT LEAST 15 MINUTES.INGEST:IF CONSCIOUS,GIVE 2-4 GLASSES OF H*2O & INDUCE VOMIT.IN ALL ABOVE CASES,GET IMMED MED ATTN & ADVISE MED PERSON THAT VICTIM MAY BE CONTAMED W/ RADIOACTIVE MATL/CHEM BURN. ===================== ===================== Fire Fighting Measures Flash Point:NONCOMBUSTIBLE Lower Limits:N/K Upper Limits:N/K Extinguishing Media:DRY CHEMICAL,CO*2,H*20 SPRAY OR FOAM.W/LG FIRE,USE FLOODING AMT OF H*2O FROM A DISTANCE Fire Fighting Procedures:PRESS-DEMAND/OTHR POSITIVE PRESS SCBA W/FULL FACEPIECE.CALL LOCAL/STATE/DOE RADIOL RESPONSE TEAM.AVOID BRTNING DUST/VAPORS.EVACUATE 2500FT RADIUS (SUPP DATA) Unusual Fire/Explosion Hazard:SMALL FIRE & SEV EXPLOSION HAZARD WHEN SFOCHED/FRICTION/HEAT OR CONT W/ OXIDIZABLE MATL.H*2O MAY CAUSE SCATTERING OF MOLTEN MATL.RELEASES (SEE OTHER PRECAUT) ================== ================== Accidental Release Measures Spill Release Procedures:SOIL:DIG HOLDING AREA.DIKE FLOW OF SPILL W/ SOIL/FOAM/CONCRETE.ABSORB SPILL W/ CEMENT POWDER/FLY ASH.NEUTRALIZE SPILL W/AGENTS.H*20:NEUTRALIZE TO PH7.EXTRACT PRECIPT.OCCU:USE ABSORBENT MATL FOR SM SPI LL.FOR LG SPILL,DIKE AHEAD OF SPILL (SUPP DATA) Neutralizing Agent:AGRICULTURAL/SLAKED LIME,CRUSHED LIMETONE,SODIUM BICARBONATE ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT CONTR FROM PHYSICAL DMG & AVOID CONTACT W/ INCOMPATIBLES . Other Precautions:UNUSUAL FIRE HAZ:TOXIC GASEOUS NITROGEN OXIDED IF INVOLVED IN FIRE.INCREASES FLAMMABILITY OF ANY COMBUSTIBLE MATL.IF SHAKEN,RUBBED/CRUSHED,CRYSTALS SHOW TRIBOLUMINESCENCE WITH OCCASIONAL DETONATION. ============= ============= Exposure Controls/Personal Protection Respiratory Protection:2.5 MG(U)/CUM:HIGH EFFECIENT PARTICULATE RSPTR W/FULL FACEPIECE,SUPPLY AIR RSPTR,SCBA.20 MG(U)/CUM:TYPE C SUPPLY AIR RSPTR W/FULL FACEPIECE IN PRESS DEMAND/OTHR POSITIVE PRESS MODE OR W/FULL FACEPIECE ,HELMET/HOOD W/CONSTANT FLOW.ESCAPE:SCBA Ventilation:PROCESS ENCLOSURE RECOMMENCED (MFR). Protective Gloves:WEAR APPROPRIATE PROTECTIVE GLOVES Eye Protection:CHEMICAL WORKERS GOGGLES & FACESHLD Other Protective Equipment:WEAR APPROPRIATE PROTECTIVE CLTHG & EQUIPMENT TO PREVENT SKIN CONTACT WITH SUBSTANCE. Work Hygienic Practices:PROVIDE EYE-WASH STATION WITHIN IMMEDIATE WORK AREA FOR EMERGENCY USE Supplemental Safety and Health SIGNS & SYMP:EYE:CHRONIC-CONJUNCTIVITIS.INGEST:ACUTEMOUTH & STOMACH IRRIT,TOXIC AMT MAY CAUSE EARLY SYMP OF NITRATE POISONING & DELAYED SYMP OF URANIUM TOXICITY.FIRE FGTING:KEEP AREA CLEAR UNTIL DECL ARED SAFE.SPILL PROC:DELAY CLEANUP OF LG OCC SPILL TILL ARRIVAL OF QUALIFIED AUTHORITY ================== ================== Physical/Chemical Properties Boiling Pt:B.P. Text:244F,118C Melt/Freeze Pt:M.P/F.P Text:140 60C Decomp Temp:Decomp Text:N/K Vapor Pres:N/K Vapor Density:N/K Spec Gravity:2.8 pH:ACIDIC Evaporation Rate & Reference:N/K Solubility in Water:SOLUBLE Appearance and Odor:ODORLELL,YELLOW,DELIQUESCENT,RHOMBIC CRYSTALS. ================= ================= Stability and Reactivity Data Stability Indicator/Materials to Avoid:YES ORGANIC SOLVENTS & OTHER OXIDIZABLE MATL,COMBUSTIBLES.ABSORBED ON CELLULOSE TO FORM EXPLOSIVE CELLULOSE NITRATE Stability Condition to Avoid:IN ETHER SOLN,MAY EXPLODE UNDER SUNLIGHT.H*2O SOLN IS ACIDIC,CORRODES METALS.MAY TRIBOLUMINESCE/EXPLODE FROM FRICTION. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE TOXIC OXIDES OF NITROGEN. ==================== ==================== Disposal Considerations Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/ FEDERAL,STATE & LOCAL REGULATIONS . 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