CHEMICAL REACTIONS Objective: Students will identify and write net ionic equations for synthesis, precipitation, decomposition, redox, anhydrides, combustion, acid base, and complex ion reactions. Safety Do not look directly into the flame when burning magnesium Tie back long hair Wear safety goggles and aprons If you are allegoric to sulfur, tell the instructor immediately Equipment 3-50 ml beakers 2-gas collecting bottles Pipettes (droppers) 1-graduated cylinder Deflagrating spoon Bunsen burner 2-wide mouth bottles 6-test tube 2-watch glasses 2-straws 1-generator bottle with tubing water trough crucible tongs Chemicals Magnesium oxide Universal indicator 0.1 M sodium hydroxide 0.1 M aluminum nitrate Hydrogen peroxide Magnesium metal Copper metal Charcoal 0.1 M copper (II) nitrate Solid sodium metal phenolphthalein 0.1 M iron (III) nitrate 0.1 M zinc metal magnesium dioxide sulfur 0.1 M silver nitrate 0.1 M 0.1 M hydrochloric acid 6.0 M ammonia 0.1 M sodium hydroxide Procedure Experiment 1 Place 2.00 g of magnesium oxide in a 50.0 ml beaker. Add 20.0 ml of water and mix. Place 2 drops of phenolphthalein into the mixture. Record your observations. Phenolphthalein is used to test for a base. Experiment 2 Place 20.0 ml of water in a 50.0 ml beaker. Use a straw and blow into the water for at least 5 minutes. Do not forget to breath. Partners may use two straws and take turns. Place 2 drops of universal indicator in the solution. Record your observations and compare it to the pH color chart. Experiment 3 Using crucible tongs place approximately 4.00 cm of magnesium metal into the flame of the Bunsen burner using tongs. Do not look directly into the flame. Record your observation. Experiment 4 Place 20 drops of iron III nitrate in a test tube. Add 20 drops of sodium hydroxide. Record your observations. Experiment 5 Place 1 small pieces of zinc metal in a 50.0 ml beaker. Add 10.0 ml of lead II nitrate. Do not dispose by pouring down the sink. Place disposal beaker under the hood. Experiment 6 Place 3 small pieces of copper in a 50 ml beaker. Add 10.0 ml of zinc nitrate. Do not dispose by pouring down the sink. Place disposal beaker under the hood. Experiment 7 Set up a gas-generating flask. Fill two wide mouth bottles full of water. Fill the water trough to the top with water. Make sure the overflow tubes are in the sink. Place 10.0 g of manganese dioxide in the generator bottle. Pour in 100.0 ml of hydrogen peroxide. Quickly stopper and collect the gas by water displacement as demonstrated by the instructor. Take the bottle from the water and cover with a watch glass. There should be enough gas generated to collect a second bottle of gas. Leave about 2 cm of water in the second bottle. Record your observations. The gas you collected is flammable. Keep away from open flames. Experiment 8 Fill a deflagrating spoon about half full with charcoal. Place the charcoal in the flame for 3 minutes. Quickly remove from the flame and insert into a bottle of the gas you collected. Do not pour the charcoal in the bottle. It should stay in the spoon. Record your observations. Experiment 9 Using your crucible tongs ignite a small piece of steel wool. When it ignites, quickly place it in the second bottle of gas with the 2 cm of water. Do not submerge the steel wool into the water. Record your observations. Experiment 10 - Teacher demonstration If you are allergic to sulfur, inform your instructor. Obtain a pea size amount of sulfur in a deflagrating spoon. Ignite the spoon and sulfur in the Bunsen burner. Slowly lower it into a bottle containing the same unknown gas collected in experiment 6. Record your observations. Experiment 11 Add 5 ml of iron (II) sulfate (it is acidified) to a beaker. Add potassium permanganate drop wise until you get a color change Experiment 12 Add 2 ml of silver nitrate to 2 ml of HCl. Experiment 13 To the above reaction add 5 ml of 6 M ammonia Experiment 14 Add 2 ml of copper II nitrate to 2 ml of sodium hydroxide. Experiment 15 To the test tube above add 3 ml of 6 M ammonia. Experiment 16 (teacher demonstration) Add a piece of sodium in a beaker of water. After the reaction has occurred, add a drop of phenolphthalein. Observations: Exp. 1 Exp. 2 Exp. 3 Exp. 4 Exp. 5 Exp. 6 Exp. 7 Exp. 8 Exp. 9 Exp 10 Exp 11 Exp 12 Exp 13 Exp 14 Exp 15 Reaction Type Questions 1. Write a balanced net ionic equation for the reaction in experiment 1. 2. Why was phenolphthalein used in experiment 1? 4. Write a balanced net ionic equation for the reaction in experiment 2. 5. After comparing your results with the pH chart in experiment 2, what should you Conclude about the solution produced? 7. Write a balanced net ionic chemical equation for the reaction that occurred in experiment 3. 8. Write a balanced net ionic equation for the reaction that occurred in experiment 4. 9. Write a balanced net ionic equation for the reaction that occurred in experiment 5. 10. Write a balanced net ionic equation for the reaction that occurred in experiment 6. 11. What flammable gas was produced in experiment 7? 12. Why was manganese dioxide used in experiment 7? 13. Write a balanced net ionic equation for experiment 7. 14. What element is the major component of charcoal? 15. Write a balanced net ionic equation for the reaction that occurred in experiment 8. 16. Name the nonflammable gas produced in experiment 8? 17. Write a balanced net ionic equation equation for the reaction that occurred in experiment 9. 18. Write a balanced net ionic equation for the reaction in step 10. 19. Write a balanced net ionic equation or the reaction in step 11. 20. Write a balanced net ionic equation for the reaction in step 12. 21. Write a balanced net ionic equation for the reaction in step 13. 22. Write a balanced net ionic equation for the reaction in step 14. 23. Write a balanced net ionic equation for the reaction in step 15. 24. Write a balanced net ionic equation for the reaction in step 16. 25. Write a balanced chemical equation for the reaction that occurred while the Bunsen burner was lit. Hint: The gas used in the lab was methane (CH4)