Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 * * * Section 1 - Chemical Product and Company Identification * * * Product Use: Adhesive Manufacturer Information Beacon Chemical Company, Inc. 125 South MacQuesten Parkway Mount Vernon, NY 10550 Phone: (914) 699-3400 (9 a.m. to 5 p.m.) Fax: (914) 699-2783 Emergency # CHEMTREC (800) 424-9300 (24 hours) General Comments NOTE: CHEMTREC telephone number is to be used only in the event of chemical emergencies involving a spill, leak, fire, exposure, or accident involving chemicals. All non-emergency questions should be directed to customer service. * * * Section 2 - Composition / Information on Ingredients * * * CAS # Component Percent Proprietary Epoxy Resin <80 109-86-4 Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) <25 Component Related Regulatory Information This product may be regulated, have exposure limits or other information identified as the following: Glycol ethers. Component Information/Information on Non-Hazardous Components This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication). * * * Section 3 - Hazards Identification * * * Emergency Overview Product is a combustible adhesive compound. Toxic fumes and gases may be released during combustion. Contact may cause irritation to eyes and skin. Inhalation of vapors may produce respiratory tract irritation and cause central nervous system depression. May be absorbed through intact skin and may cause central nervous system depression. Overexposure to product may result in an increased risk of birth defects. Harmful or fatal if swallowed. Hazard Statements WARNING! COMBUSTIBLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED, INHALED, OR ABSORBED THROUGH SKIN. MAY CAUSE ALLERGIC SKIN SENSITIZATION REACTION. MAY BE IRRITATING TO EYES, SKIN, AND RESPIRATORY TRACT. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING NAUSEA, INCOORDINATION, AND HEADACHE. Possible birth defect hazard. Contains Methyl Cellosolve which may cause birth defects based on animal data. Prolonged or repeated overexposure may cause damage to the liver, kidney, central nervous system, and reproductive system, and may cause changes in the blood. Potential Health Effects: Eyes This product may cause irritation to the eyes. Symptoms include stinging, redness, and tearing. Potential Health Effects: Skin This product may cause irritation to the skin. Symptoms may include redness and a burning sensation. Ethylene Glycol Monomethyl Ether (EGME) is readily absorbed through the skin. EGME may cause reversible CNS depression and changes in the blood, including the red and white blood cells, following skin exposure. Prolonged or repeated skin contact may produce toxicity similar to that resulting from inhalation or ingestion exposure. Prolonged or repeated skin contact may cause allergic skin sensitization reactions with symptoms that may include rash, swelling, itching, and possibly blistering of the skin. Potential Health Effects: Ingestion This product may be harmful or fatal if swallowed. Ingestion of this product may result in severe gastrointestinal irritation and bleeding, damage to the liver and pancreas, and brain edema. The onset of symptoms may be delayed following the ingestion of this product. Potential Health Effects: Inhalation This product may cause irritation to the respiratory tract, including discomfort in the nose, sore throat, and coughing. This product may cause reversible CNS depression, including drowsiness, weakness, dizziness, loss of coordination, nausea, headache, and shaking. Changes in the blood, including red and white blood cells, may occur following inhalation exposure. In addition to these effects, prolonged or repeated exposure to vapors may also result in brain disorders as well as lung, kidney, and liver changes. Symptoms of chronic exposure may include headache, fatigue, decreased appetite, blurred vision, fever, staggering, decreased mental ability, anemia, and other blood changes. Overexposure to this product may result in an increased risk of birth defects. ____________________________________________________________ Page 1 of 7 Issue Date: 03/15/10 Print Date: 2/12/2016 Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 HMIS Ratings: Health: 2* Fire: 2 Reactivity: 0 Pers. Prot.: splash goggles/impervious gloves and clothing/vapor respirator (if ventilation is insufficient) Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard * * * Section 4 - First Aid Measures * * * First Aid: Eyes For eye contact, rinse immediately with plenty of water for at least 15 minutes. Seek medical advice. First Aid: Skin For skin contact, immediately wash skin thoroughly with soap and flush with plenty of water for 15 minutes. Immediately remove and discard contaminated clothing and shoes. Seek medical advice if symptoms develop or persist. First Aid: Ingestion If ingested, DO NOT INDUCE VOMITING. Seek immediate medical advice. Never give anything by mouth to a person who is unconscious or having convulsions. First Aid: Inhalation If inhaled, remove to fresh air. If breathing has stopped, perform artificial respiration. Seek immediate medical advice. First Aid: Notes to Physician Although controversial, ethanol therapy may be effective in preventing the toxicity of Ethylene Glycol Monomethyl Ether following ingestion. * * * Section 5 - Fire Fighting Measures * * * Flash Point: 151 deg F (66 deg C) Method Used: Open Cup Upper Flammable Limit (UFL): 19.8% v/v Lower Flammable Limit (LFL): 1.8% v/v Auto Ignition: N/A Flammability Classification: Combustible Rate of Burning: Not available General Fire Hazards Product is combustible and presents a moderate fire hazard when exposed to heat and flame. Vapors are heavier than air and may travel to sources of ignition. Do not weld or cut near the container. Hazardous Combustion Products When heated to decomposition, ethylene glycol monomethyl ether emits acrid smoke and irritating fumes. Product may form oxides of carbon. Extinguishing Media Extinguish with water fog, dry chemical, alcohol foam, or carbon dioxide. Fire Fighting Equipment/Instructions Firefighters should wear full protective clothing including self contained breathing apparatus. Do not allow runoff from fire control to enter public drainage system or open water courses. NFPA Ratings: Health: 2 Fire: 2 Reactivity: 0 Other: Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * * * Section 6 - Accidental Release Measures * * * Containment Procedures Contain the discharged material. Eliminate all sources of ignition or flammables that may come into contact with a spill of this material. Absorb small spills with sand or other inert material. Clean-Up Procedures Do not flush spill to drain. Do not allow the spilled product to enter public drainage system or open water courses. Wear appropriate protective equipment and clothing during clean-up. Place spilled material into clean container, and seal tightly before disposal. Ventilate the contaminated area. Thoroughly wash the area with water after a spill or leak clean-up. Evacuation Procedures Isolate area. Keep unnecessary personnel away. Special Procedures None. Page 2 of 7 ____________________________________________________________ Issue Date: 03/15/10 Print Date: 2/12/2016 Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 * * * Section 7 - Handling and Storage * * * Handling Procedures Wear appropriate protective equipment when handling this material. Use non-sparking tools when opening or closing containers. Containers should be grounded when material is transferred. Do not get this material in your eyes, on your skin, or on your clothing. Do not breathe vapors produced by this product. Carefully follow manufacturer's instructions when mixing Parts 1 and 2 of the adhesive. Use this product with adequate ventilation. Keep this product from heat, sparks, or open flame. This product should not be used in elevated temperature conditions as ignition may result. Wash thoroughly after handling. Use special care to avoid inhalation and contact with vapors when this product is heated. Empty containers may contain hazardous residues. Storage Procedures Keep the container tightly closed and in a cool, well-ventilated place. Eliminate all sources of ignition. Do not store under oxidation conditions as peroxides may form that can cause an explosion. * * * Section 8 - Exposure Controls / Personal Protection * * * Exposure Guidelines A: General Product Information Attempts should be made to eliminate all contact with skin and eyes, and to limit inhalation exposure. B: Component Exposure Limits Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) (109-86-4) ACGIH: 5 ppm TWA; 16 mg/m3 TWA skin - potential for cutaneous absorption OSHA: 25 ppm TWA; 80 mg/m3 TWA Prevent or reduce skin absorption NIOSH: 0.1 ppm TWA; 0.3 mg/m3 TWA Potential for dermal absorption Engineering Controls Ventilation should be sufficient to effectively remove and prevent buildup of any vapors that may be generated during handling or thermal processing. Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear splash goggles. Personal Protective Equipment: Skin Use impervious gloves. It is recommended that gloves be tested to determine suitability for prolonged contact. Wear impervious garments to prevent all skin contact. Personal Protective Equipment: Respiratory If ventilation is not sufficient to effectively prevent buildup of aerosols or vapors, appropriate NIOSH-approved respiratory protection must be provided. Personal Protective Equipment: General Use good industrial hygiene practices in handling this material. Eyewash fountains and emergency showers are recommended. * * * Section 9 - Physical & Chemical Properties * * * Appearance: Physical State: Vapor Pressure: Boiling Point: Solubility (H2O): Freezing Point: Softening Point: Page 3 of 7 Medium yellow, clear Viscous Liquid 9.5 mm Hg @ 19 deg C (66 deg F) 229.1 deg F Not available <-18 deg C Not available Odor: pH: Vapor Density: Melting Point: Specific Gravity: Particle Size: Evaporation Rate: None 4.25 2.6 (air = 1) Not applicable 1.116 Not applicable 0.69% / hr ____________________________________________________________ Issue Date: 03/15/10 Print Date: 2/12/2016 Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 Physical Properties: Additional Information Density: 8.04 lbs/gal * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability Magnatac E645 Part 1 is stable at room temperature in closed containers under normal storage and handling conditions. Chemical Stability: Conditions to Avoid Heat, strong alkalis, strong oxidizing agents. Vapors are heavier than air and may travel to sources of ignition. Do not weld or cut near the container. Ethylene glycol monomethyl ether in air forms peroxides that are highly explosive. Incompatibility None identified. Hazardous Decomposition When heated to decomposition, ethylene glycol monomethyl ether emits acrid smoke and irritating fumes. Product may form oxides of carbon. Hazardous Polymerization Hazardous polymerization will not occur. * * * Section 11 - Toxicological Information * * * Acute Toxicity A: General Product Information This product may cause irritation to the eyes. Symptoms include stinging, redness, and tearing. This product may cause irritation to the skin. Symptoms may include redness and a burning sensation. Ethylene Glycol Monomethyl Ether (EGME) is readily absorbed through the skin. This product may be harmful if it is absorbed through the skin. This product may cause reversible CNS depression including drowsiness, weakness, tremor, loss of coordination, difficulty sleeping, lethargy, and shaking, and changes in the blood, including the hemoglobin and white blood cells, following skin exposure. Chronic skin exposure may cause encephalopathy and bone marrow depression. This product contains an epoxy resin that may cause allergic skin sensitization reactions with prolonged or repeated skin exposure to skin, and symptoms that may include rash, swelling, itching, and possibly blistering of the skin. Inhalation exposure may cause irritation to the respiratory tract, including discomfort in the nose, sore throat, and coughing. Reversible CNS depression with symptoms similar to those resulting from dermal exposure, and changes in the blood, including reduced white and red blood cell counts, hemoglobin, hematocrit, platelet counts, may occur following inhalation exposure. EGME may have cumulative toxicity. In addition to acute effects, prolonged or repeated inhalation exposure to vapors of EGME may also result in brain disorders as well as lung, kidney, and liver changes. Symptoms of chronic exposure may include headache, fatigue, decreased appetite, blurred vision, fever, staggering, decreased mental ability, anemia, toxic encephalopathy, bone marrow depression and other blood changes. Destruction of the thymus, reduction of the white blood cell counts, and damage to the spleen were seen in rats given EGME orally for 4 days. This product may be harmful or fatal if swallowed. Ingestion of this product may result in severe gastrointestinal irritation and bleeding, fatty degeneration of the liver, early necrosis of the pancreas, and brain edema. Individuals who are occupationally exposed to EGME and have pre-existing eye, respiratory, blood. neurological, and/or kidney conditions may be at increased risk. Persons also exposed to other bone marrow depressants or substances affecting the nervous system might also be more sensitive. Persons with allergy, eczema, or skin conditions may have conditions aggravated with exposure to epoxy resin component in product. B: Component Analysis - LD50/LC50 Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) (109-86-4) Inhalation LC50 Mouse: 1480 ppm/7H Oral LD50 Rat: 2370 mg/kg Dermal LD50 Rabbit: 1280 mg/kg Inhalation LC50 Rat: 1500 ppm/7H Oral LD50 Mouse: 2560 mg/kg Carcinogenicity A: General Product Information No information available. B: Component Carcinogenicity ____________________________________________________________ Page 4 of 7 Issue Date: 03/15/10 Print Date: 2/12/2016 Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 None of this product's components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP. Epidemiology An in-plant cross-sectional study of male workers exposed to EGME during manufacturing and packing found smaller testicular size, as well as a possible decrease in white blood cells and hemoglobin at higher exposure levels. In a retrospective study on workers at two semiconductor plants, increased risk of spontaneous abortion and subfertility occurred among females exposed to ethylene glycol ethers in a dose-related manner. Neurotoxicity In acute exposures, EGME can be a CNS depressant, and there have been human cases of chronic encephalopathy. Major effects of acute exposure to EGME are loss of coordination, weakness, difficulty sleeping, tremors, headache, lethargy, personality changes, blurred vision, nausea, vomiting, bedwetting, loss of appetite, agitation, convulsions, coma, and death. Mutagenicity EGME has not been active in genetic assays which detect primary DNA damage, mutations, or chromosome damage. It was inactive in the Ames Salmonella microsome assay, did not induce unscheduled DNA synthesis in human cells or chromosome aberrations in rat bone marrow, and was ambiguous for inducing sex-linked recessive lethal mutations in fruit flies. However, EGME was positive for inducing dominant lethal mutations in rats after treatment of males, and also induced abnormalities in the structure of sperm in mice. Teratogenicity EGME is the most potent glycol ether for inducing birth defects and male sterility in laboratory animals. EGME is known to cause CNS, cardiovascular, and skeletal birth defects, damage to the testes, reduction in sperm number, infertility, and abnormal sperm in experimental animals. Even a single exposure to EGME is sufficient to induce damage to the testes and reduce the sperm count in rats. EGME was teratogenic in mice, in rats exposed to 100 ppm, and in rabbits exposed to 50 ppm. EGME also caused birth defects in rats when applied dermally, and smaller litter size and poor survival were also found in rats exposed by the dermal route. Behavioral and neurochemical differences were seen in the offspring of rats given doses of only 25 ppm. One epidemiological study found no effects on human male fertility, but did find slightly reduced testicular size. Other Toxicological Information No additional information. * * * Section 12 - Ecological Information * * * Ecotoxicity A: General Product Information No additional information. B: Component Analysis - Ecotoxicity - Aquatic Toxicity Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) (109-86-4) LC50 (96 hr) rainbow trout: 15,520 mg/L. Cond: 12 degrees C.; LC50 (96 hr) bluegill: 10,000 ppm. Cond: Static, 23 degrees C. Environmental Fate In the atmosphere, Ethylene Glycol Monomethyl Ether (EGME) will photodegrade primarily by reaction with hydroxyl radicals in hours and rainout may be significant. Although no data on its rate of degradation in natural waters could be found, laboratory tests suggest that it will degrade in water. It will slowly volatilize, but will not sorb to sediment or bioconcentrate in aquatic organisms. Its fate when spilled on land is unknown, although volatilization from near-surface soil and leaching to groundwater are possible. Biodegradation of 100-1000 mg/L 2-methoxyethanol with activated sludge at 20 degrees C for 10 days resulted in 64.7% theoretical BOD. EGME's low octanol/water partition coefficient indicates that its adsorption to soil will be low and that it will not bioconcentrate in fish. This product is relatively volatile (vapor pressure 9.5 torr(1)) and would, therefore, evaporate from soil and other surfaces. * * * Section 13 - Disposal Considerations * * * US EPA Waste Number & Descriptions A: General Product Information Wastes from this product may be considered a RCRA ignitable waste, D001. B: Component Waste Numbers No EPA Waste Numbers are applicable for this product's components. Page 5 of 7 ____________________________________________________________ Issue Date: 03/15/10 Print Date: 2/12/2016 Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 Disposal Instructions Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. * * * Section 14 - Transportation Information * * * US DOT Information Shipping Name: Combustible liquid, N.O.S. (Methyl Cellosolve) Hazard Class: 3 UN/NA #: NA 1993 Packing Group: III Required Label(s): None Additional Info.: For ground shipment in the United States, shipment of this product is not regulated. International Transportation Regulations No additional information. * * * Section 15 - Regulatory Information * * * US Federal Regulations A: General Product Information No additional information. B: Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4). Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) (109-86-4) SARA 313: Form R reporting required for 1.0% de minimus concentration CERCLA: (Includes mono- and di- ethers of ethylene glycol; diethylene glycol and triethylene glycol R(OCH2CH2)n-OR' where n = 1 2 or 3; R = alkyl or aryl groups; R' = R h or groups which when removed yield glycol ethers with the structure R-(OCH2CH2)n-OH. Polymers are excluded from glycol category); Statutory RQ = 1 pound (.454 kg); no final RQ is being assigned to the generic or broad class (related to Glycol ethers) State Regulations A: General Product Information No additional information. B: Component Analysis - State The following components appear on one or more of the following state hazardous substances lists: Component CAS # CA FL MA MN Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) 109-86-4 Yes Yes Yes Yes NJ Yes PA Yes The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains a chemical known to the state of California to cause reproductive/developmental effects. Other Regulations A: General Product Information No additional information. B: Component Analysis - Inventory Component Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) CAS # 109-86-4 TSCA Yes DSL Yes C: Component Analysis - WHMIS IDL Page 6 of 7 ____________________________________________________________ Issue Date: 03/15/10 Print Date: 2/12/2016 EINECS Yes Material Safety Data Sheet Material Name: MagnaTac E645 Part 1 ID: BEA-001 The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List: Component CAS # Minimum Concentration Ethylene Glycol Monomethyl Ether (Methyl Cellosolve) 109-86-4 0.1% item 999 (1106) * * * Section 16 - Other Information * * * Other Information Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or any other warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental or consequential damages resulting from its use. Key/Legend EPA = Environmental Protection Agency; TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NIOSH = National Institute for Occupational Safety and Health; NTP = National Toxicology Program; OSHA = Occupational Safety and Health Administration This is the end of MSDS # BEA-001 Page 7 of 7 ____________________________________________________________ Issue Date: 03/15/10 Print Date: 2/12/2016