Version 001 — Last revision on, May 2015
Product Name:
Product ID:
Synonyms:
Chemical Family:
Molecular Formula:
Manufacturer:
Telephone:
ULSD NO. 1 FUEL OIL
NCRA-079
Fuel Oil NO. 1; coal oil; range oil; kerosene; K-10; kerosene; petroleum, hydrocarbons
Mixture
NCRA
2000 South Main Street
McPherson, Kansas 67460, USA
620.241.2340 ( General )
620.241.2340 ( Emergency)
620.241.9269 (Fax)
MFA Oil Company
One Ray Young Dr.
Columbia, Missouri 65201
573.474.7028 (General)
573.474.1918 (fax) www.mfaoil.com
(Web)
Flammable liquid and vapor (H226).
May be fatal if swallowed and enters airways (H304).
Causes skin irritation (H315).
Causes eye irritation (H320).
Harmful if inhaled (H332).
Suspected of causing cancer (H351).
May cause damage to organs (H373).
Very toxic to aquatic life with long lasting effects (H410).
PREVENTION
Obtain special instructions before use (P201).
Do not handle until all safety precautions have been read and understood (P202).
Keep away from heat, sparks, open flames, hot surfaces. No smoking (P210).
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NCRA SDS fo r “ULSD NO. 1 Fuel Oil”
Keep container tightly closed (P233).
Ground/bond container and receiving equipment (P240).
Use explosion-proof equipment (P241).
Use only non-sparking tools (P242).
Take precautionary measures against static discharge (P243).
Do not breathe fume, mist, vapors, or spray (P260).
Wash thoroughly after handling (P264).
Use only outdoors or in a well-ventilated area (P271).
Avoid release to the environment (P273).
Use personal protective equipment as required (P281).
RESPONSE
IF SWALLOWED: Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician (P301
+ P331 + P310).
IF ON SKIN: Wash with plenty of soap and water (P302 + P352).
IF ON SKIN (OR HAIR): Remove/take off immediately all contaminated clothing. Wash with plenty of soap and water (P303 + P361 + P352).
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing (P304 +
P340).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing (P305 + P351 + P338).
IF EXPOSED OR CONCERNED: Get medical advice/attention (P308 + P313).
Call a POISON CENTER or doctor/physician if you feel unwell (P312).
Take off contaminated clothing and wash before reuse (P362).
IN CASE OF FIRE: Use foam, water fog, dry chemical, carbon dioxide, or vaporizing liquid type extinguishing agents for extinction (P370 + P378)
Collect spillage (P391).
STORAGE
Store in a well-ventilated place. Keep cool (P403 + P235).
Store locked up (P405).
DISPOSAL
Dispose of contents/containers to approved disposal sites in accordance with local, regional, national, and/or international regulations (P501).
Flammable liquid – Category 3 toxicity, inhalation – Category 4 corrosion/irritation – Category 2 damage/irritation – Category 2B
Carcinogenicity – Category 2
Specific target organ toxicity, repeated exposure – Category 2
Aspiration hazard – Category 1
Hazardous to the aquatic environment, long-term hazard – Category 1
Eye Health Effects:
Skin Health Effects:
Causes eye irritation.
Causes irritation and blood disorders.
Acute
Skin
Eye
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NCRA
Inhalation Health Effects:
SDS fo r “ULSD NO. 1 Fuel Oil”
Ingestion Health Effects:
Carcinogenic Effects:
Causes irritation, chest pain, headache, drowsiness, disorientation, mood swings, and loss of coordination, lung congestion, tremors, blood disorders, and coma.
Causes irritation, chest pain, headache, drowsiness, disorientation, mood swings, and loss of coordination, lung congestion, vomiting, diarrhea, aspiration hazard and coma.
Confirmed animal carcinogen with unknown relevance to humans.
Environmental Effects: Toxic to aquatic life.
Name
ULSD No.1 Fuel Oil
Contaminants:
May contain < 15 ppm sulfur.
Hazardous Ingredients
CAS # RTECS #
8008-20-6 OA5500000
EINECS #
232-366-4
% (Volume)
>99.0
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention.
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse.
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen should be administered by qualified personnel. Get immediate medical attention.
Aspiration hazard. DO NOT induce vomiting. If vomiting occurs, keep head lower than hips to help prevent aspiration. Get immediate medical attention. Give artificial respiration if not breathing.
For inhalation, consider oxygen.
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NCRA
Not available.
None.
SDS fo r “ULSD NO. 1 Fuel Oil”
Health: 2 (Moderate)
Flammability:
Instability:
2 (Moderate)
0 (Minimal)
Other Hazards: Not applicable
Moderate fire hazard. Vapor/air mixtures are explosive above flash point. The vapor is heavier than air. Vapors or gases may ignite at distant ignition sources and flash back. Electrostatic discharges may be generated by flow or agitation resulting in ignition or explosion.
Use water, regular foam, regular dry chemical or carbon dioxide. Large fires: Use regular foam or flood with fine water spray. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate specialists.
Wear self-contained breathing apparatus for firefighting if necessary. In addition, wear other appropriate protective equipment as conditions warrant (see Section 8 ).
Move container from fire area if it can be done without risk. Cool containers with water spray until well after the fire is out. Stay away from the ends of tanks. For fires in cargo or storage area: Cool containers with water from unmanned hose holder or monitor nozzles until well after fire is out. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tanks due to fire. For tank, rail car or tank truck: Evacuation radius: 800 meters (1/2 mile). Do not attempt to extinguish fire unless flow of material can be stopped first. Flood with fine water spray. Do not scatter spilled material with high-pressure water streams. Cool containers with water spray until well after the fire is out. Apply water from a protected location or from a safe distance. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas.
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NCRA
Flammable Properties: See Section 9 for Flash Point, Explosive Limits, etc.
SDS fo r “ULSD NO. 1 Fuel Oil”
Shut off source if safe to do so. Wear respiratory protection. Avoid breathing vapors, fumes, mist, or gas. Ensure adequate ventilation. Remove all sources of ignition. No smoking. Evacuate personnel to safe areas. Wear appropriate protective equipment, including respiratory protection, as conditions warrant (see Section 8 ).
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment should be avoided. Contain liquid with sand or soil. Recover and return free product to proper containers. Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual liquids. Dike or divert spill into natural containment areas before it can enter watercourses. Assure conformity with applicable government regulations.
Notify shift foreman immediately should release occur. The shift foreman will notify appropriate personnel and may determine whether or not to call emergency response teams and supervisors, depending on the amount of chemical release. If the release occurs outside the facility, notify the NCRA refinery.
Avoid heat, flames, sparks and other sources of ignition. Stop leak is possible without personal risk. Reduce vapors with water spray.
Small spills: Absorb with sand or other non-combustible material. Collect spilled material in appropriate container for disposal. Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual liquids.
Large spills: Dike for later disposal. Remove sources of ignition. Keep unnecessary people away, isolate hazard area and deny entry. Use suitable absorbent materials such as vermiculite, sand, or clay to clean up residual liquids.
Use good personal hygiene practices and wear appropriate personal protective equipment. Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Avoid confined areas. Keep away from sources of ignition. No smoking. Take measures to prevent build-up of static electric charge. Use normal measures for preventive fire protection.
Store and handle in accordance with all current regulations and standards. Subject to storage regulations: U.S.
OSHA 29 CFR 1910.106. Keep separated from incompatible substances.
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NCRA SDS fo r “ULSD NO. 1 Fuel Oil”
Suggestions provided in this section for exposure control and specific types of protective equipment are based on readily available information. Users should consult with the specific manufacturer to confirm the performance of their protective equipment. Specific situations may require consultation with industrial hygiene, safety, and/or engineering professionals.
Respiratory Protection: The following respirators and maximum use concentrations are drawn from
NIOSH and/or OSHA.
1000 mg/m3
Any air-purifying half-mask respirator equipped with organic vapor cartridge(s).
Any supplied-air respirator.
2500 mg/m3
Any supplied-air respirator operated in a continuous-flow mode.
Any powered, air-purifying respirator with organic vapor cartridge(s).
5000 mg/m3
Any air-purifying respirator with a full face piece and an organic vapor canister.
Any air-purifying full face piece respirator (gas mask) with a chin-style, frontmounted or back-mounted organic vapor canister.
Any powered, air-purifying respirator with a tight-fitting face piece and organic vapor cartridge(s).
Any self-contained breathing apparatus with a full face piece.
Any supplied-air respirator with a full face piece.
Emergency or planned entry into unknown concentrations or IDLH conditions-
Any self-contained breathing apparatus that has a full face piece and is operated in a pressure-demand or other positive-pressure mode.
Any supplied-air respirator with a full face piece that is operated in a pressuredemand or other positive-pressure mode in combination with an auxiliary selfcontained breathing apparatus operated in pressure-demand or other positivepressure mode.
Escape-
Any air-purifying full-face piece respirator (gas mask) with a chin-style, frontmounted or back-mounted organic vapor canister.
Any appropriate escape-type, self-contained breathing apparatus.
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NCRA
Eye/Face Protection:
SDS fo r “ULSD NO. 1 Fuel Oil”
Skin Protection:
General Considerations:
Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area.
Avoid skin contact. Use gloves impervious to the specific material handled to prevent skin contact. Users should check with manufacturers to confirm the breakthrough performance of their products. Use proper glove removal technique. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Wear appropriate chemical resistant clothing and gloves.
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Handle in accordance with good industrial hygiene and safety practice.
Provide local exhaust ventilation system. Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Ensure compliance with applicable exposure limits.
Component
ULSD No.1 Fuel Oil
(8008-20-6)
ACGIH TLV
TWA: 200 mg/m3
NIOSH REL
TWA: 100 mg/m3
OSHA PEL
---
Note: State, local, or other agencies or advisory groups may have established more stringent limits. Consult an industrial hygienist or similar professional, or your local agencies, for further information.
Component
ULSD No.1 Fuel Oil (8008-20-6)
Notations
NIOSH IDLH
---
Skin Notation
---
Sensitization
---
Physical Form
Appearance
Odor
Odor Threshold pH
Freezing Point
Melting Point
Liquid
Clear colorless
Not available
Not available
Neutral
Not available
-18 °C
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NCRA
Boiling Point
Flash Point
OSHA Flammability Class
Explosive Limits
Evaporation Rate
Vapor Pressure
Vapor Density
Specific Gravity
Density
Water Solubility
Partition Coefficient
Auto-ignition Temperature
151 - 301 °C
>50 °C by closed cup
II
0.7 % (LEL) – 5.0% (UEL)
Not available
5 mmHg @ 38 °C
4.5 (air=1)
0.8 (water=1)
Not available
Insoluble
Not available
210 o C
Decomposition Temperature Not available
Viscosity >1.3 cSt @ 40 C
Molecular Formula
Molecular Weight
Not available
Not available
Volatility
Coeff.Water/Oil Dist:
Not available
Not available
SDS fo r “ULSD NO. 1 Fuel Oil”
Stability:
Conditions to Avoid:
Incompatible Materials:
Decomposition Products:
Stable at normal temperatures and pressure.
Avoid heat, flames, sparks, and other sources of ignition. Containers may rupture or explode if exposed to heat. Keep out of water supplies and sewers.
Oxidizing materials, halogens
KEROSENE (FUEL OIL NO.1):
Chlorine: Vigorous reaction or possible ignition or explosion.
Fluorine: Possible ignition or explosion.
Magnesium Perchlorate: Possible explosion on heating.
Nitrogen Tetroxide: Possible explosion.
Oxidizers (Strong): Fire and explosion hazard.
Oxides of carbon
Thermal decomposition products: oxides of carbon.
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NCRA
Hazardous Polymerization: Will not polymerize.
SDS fo r “ULSD NO. 1 Fuel Oil”
Signs and Symptoms:
Aspiration Hazard:
Sensitization:
Specific Target Organs:
Carcinogenicity:
Germ Cell Mutagenicity:
Reproductive Toxicity:
Inhalation hazard is low due to the low vapor pressure. High concentrations of mist or vapor may cause mucous membrane irritation, a burning sensation in the chest, an odor of kerosene on the breath, and chemical pneumonitis. The symptoms can include headache, nausea, dizziness, weakness, ataxia, restlessness, and ringing in the ears. Disorientation and confusion may progress to drowsiness and coma and sometimes convulsions. Direct skin contact may cause defatting with dryness, irritation, dermatitis, and edema. Ingestion may cause local irritation with a burning sensation in the mouth, esophagus, and stomach; and vomiting, belching, and diarrhea with blood-tinged feces.
Aspiration into the lungs may occur readily during ingestion or subsequent vomiting or belching. Even small amounts may cause chemical pneumonitis with pulmonary edema and hemorrhage and may possibly be complicated by secondary bacterial
Aspiration hazard, DO NOT induce vomiting.
Repeated or prolonged exposure to skin may cause defatting and dermatitis.
Eyes, skin, respiratory system, central nervous system.
Confirmed Animal Carcinogen with Unknown Relevance to Humans.
Not available.
Not available.
Stimulants such as epinephrine may induce ventricular fibrillation..
Component
ULSD No.1 Fuel Oil
(8008-20-6)
Category
Exposure Routes
Toxicological Information
Data
Symptoms
Target Organs
Short-Term Exposure
Long-Term Exposure
Inhalation; ingestion; skin and/or eye contact. irritation eyes, skin, nose, throat; burning sensation in chest; headache, nausea, lassitude (weakness, exhaustion), restlessness, incoordination, confusion, drowsiness; vomiting, diarrhea; dermatitis; chemical pneumonitis (aspiration liquid).
Eyes, skin, respiratory system, central nervous system.
The substance slightly irritates the skin and the respiratory tract. Swallowing the liquid may cause aspiration into the lungs with the risk of chemical pneumonitis.
The substance may cause effects on the nervous system.
The liquid defats the skin.
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NCRA SDS fo r “ULSD NO. 1 Fuel Oil”
Note: Data for Exposure Routes, Symptoms, and Target Organs were obtained from the NIOSH Pocket Guide to Chemical Hazards. Data for
Short- and Long-Term Exposure were obtained from the International Chemical Safety Cards from the International Occupational Safety and
Health Information Centre.
Toxicity: Toxic to aquatic life.
Persistence & Degradability: Readily biodegradable in the environment.
Bio-accumulative Potential: Not expected to bio-accumulate in aquatic organisms.
Mobility:
Other Adverse Effects:
Not available.
Not available.
The generator of a waste is always responsible for making proper hazardous waste determinations. The transportation, storage, treatment, and disposal of this waste material must be conducted in compliance with all applicable federal, state, and local requirements and regulations.
Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. Dispose in accordance with all applicable regulations.
The U.S. EPA has not published waste number s for this product’s components.
Shipping Name: Kerosene
ID Number: UN1223
Hazard Class: 3
Packing Group: III
Required Label(s): 3
CERCLA/SARA Section 311/312 (Title III Hazard Categories)
Acute Health: Yes
Chronic Health: No
Fire Hazard: Yes
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NCRA
Pressure Hazard:
Reactive Hazard:
No
No
SDS fo r “ULSD NO. 1 Fuel Oil”
This material may contain one or more of the following chemicals identified by the EPA under Title 40 of the Code of Federal Regulations (CFR), including the CAA (40 CFR 50-97), CERCLA (40 CFR 302.4), SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65), and/or TSCA (40 CFR 700-766).
Components Listed by Selected Parts of US 40 CFR
Component CAA CERCLA SARA Section 302 SARA Section 313 TSCA
ULSD No.1 Fuel Oil
(8008-20-6)
Not listed Not listed Not listed Not listed Not listed
This material may contain one or more chemicals identified on individual state hazardous substances lists.
Contact each jurisdiction for more information.
Right-To-Know:
Massachusetts, Pennsylvania, New Jersey, Rhode Island
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65):
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Version 001 – Last revision on 2014-12-27.
Prepared by Certified Environmental Management, Ltd. (www.cemih.com).
ACGIH
ANSI
CAA
CAS
CEIL
CERCLA
CFR
EINECS
EPA
GHS
IARC
NFPA
NTP
OSHA
PEL
RCRA
RQ
SARA
STEL
TLV
TPQ
TSCA
TWA
UN
American Conference of Governmental Industrial Hygienists
American National Standards Institute
Clean Air Act (United States)
Chemical Abstracts Service
Ceiling Exposure Limit
The Comprehensive Environmental Response, Compensation, & Liability Act (United States)
Code of Federal Regulations (United States)
European chemical Substances Information System
Environmental Protection Agency (United States)
Globally Harmonized System
International Agency for Research on Cancer
National Fire Protection Association
National Toxicology Program (United States)
Occupational Safety and Health Administration (United States)
Permissible Exposure Limit (OSHA)
Resource Conservation and Recovery Act (United States)
Reportable Quantity
Superfund Amendments and Reauthorization Act (United States)
Short Term Exposure Limit (15 minutes)
Threshold Limit Value (ACGIH)
Threshold Planning Quantity
Toxic Substances Control Act (United States)
Time Weighted Average (8 hours)
United Nations
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NCRA
SDS fo r “ULSD NO. 1 Fuel Oil”
The information presented in this Safety Data Sheet is based on data believed to be accurate as of the date this (Material) Safety Data Sheet was prepared. However, neither the NCRA, Inc., nor any of their subsidiaries, vendors, or contractors, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. No responsibility is assumed for any damage or injury resulting from abnormal use or from any failure to adhere to recommended practices. The information provided above, and the product, are furnished on the condition that the person receiving them shall make their own determination as to the suitability of the product for their particular purpose and on the condition that they assume the risk of their use.
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