April, 2003 Selective Analysis of Tubewell Arsenic Screening Data from 36 Upazillas (BAMWSP Phase-II) ( Draft Prepared by M. Khaliquzzaman, Environment Team, WBOD) Executive Summary Data archived at the National Arsenic Mitigation Information Centre (NAMIC) and collected during the screening of tubewells in 36 Upazillas for Arsenic concentration have been selectively analyzed to look for trends. It is seen that the nature of Arsenic contamination looks quite different when viewed at different depths. The availability of Arsenic safe aquifers at different geographical areas also look quite interesting. Using proxy variables for analysis, it appears that water abstraction from the aquifers has not affected the aquifer arsenic concentration up to now. Attempts have been made to relate prevalence of arsenicosis to arsenic ingestion using a proxy parameter like average arsenic concentration but significant trends have not been found. It appears that the observations from such analysis may be useful for cost effective mitigation work and for better understanding of some of the aspect of the Arsenic problem in the groundwater. It is necessary to maintain a quality assured national archiving and data management system to this end. 1. Introduction The approach in this report is purely empirical. Data obtained during the Arsenic screening program for 36 Upazillas contain many more parameters than Arsenic concentrations in tubewells. These information have been analyzed to look for systematic trends. Consistency of such trends with current understanding of the Arsenic problem has not been specifically considered. However, certain definitions and issues have been discussed here for making the report self standing for the readers who are not so technically inclined and some discussions have been done on the different topics in terms of these terminologies. Below the zone of aeration extending from surface to only a few meters below the ground, the soil in Bangladesh is saturated with water. Saturation means that all pore spaces in the soil is filled with water and this zone is defined by a groundwater table. Bangladesh soils consist of unconsolidated sediments and the pore spaces are simply the openings between the grains. Lithologic drill logs show layers of gravel, sands of different grades, silt and clay down to great depths in succession. Hydrogeologists classify soil layers as to their ability to yield water to wells or springs. A layer which is permeable enough to supply water to wells or springs is referred to as an "Aquifer", while an “Aquiclude” is impermeable and an “Aquitard” tends to be very poorly permeable. The aquifers are sand or gravel layers that may be a few centimeters to many meters’ thick. Like other similar areas in the world, the sand intervals which constitute the aquifers are probably lens-shaped with varying degree of lateral and vertical interconnectedness. This interconnectedness usually decreases with depth. The extent of the of aquifers may vary from a few km2 to many thousands of km2 . So, a large aquifers may easily contain a trillion liters or even more water. Even a small aquifer would probably contain a couple of billion liters. 1 An aquifer is referred to as confined when it is bounded by aquicludes or aquitards that impede flow into it. The primary source of recharge to the aquifers is assumed to be historic runoff from the rainfalls. Groundwater is in principle renewable but in certain cases the period needed for replenishment (100s to 1000s of years) is very long in relation to the normal time-frame of human activity. For this reason, it is valid in such cases to talk of the utilization of non-renewable groundwater or the ‘mining of aquifer reserves’. Water in a confined aquifers can be literally thousands of years old. This is the reason for concern about the aquifer systems and their specific susceptibilities to negative impacts under abstraction stress. For water balance studies three and four aquifer models have been shown to be adequate. However, in reality in many regions of Bangladesh more aquifers can be found stacked on top of one another where from water can be extracted. The hydrogeology of Bangladesh area has been studied for more than fifty years and the details are available elsewhere[1-4]. Groundwater is a vital natural resource for the reliable and economic provision of potable water supply in both the urban and rural environment. It thus plays a fundamental role in human well-being. Until the emergence of the Arsenic problem, groundwater was hailed for providing the access to clean drinking water in Bangladesh. In the screening process tubewells have been found all depths up to 1000 ft or even more in a few cases. The relevant questions here to ask are: (i) at what depths good Arsenic safe aquifers are available at different geographic locations; (ii) if the tubewells currently safe will remain so in the future; (iii) do the concentration of Arsenic vary with time in the aquifers or depend on extraction; (iv) how Arsenic concentrations are related to prevalence of the arsenicosis symptoms etc. These and similar issues have been looked into in this report on the basis data obtained from the 36 Upzillas’ screening. 2. Geographical depth distribution of Arsenic concentrations Maps showing geographic distribution of Arsenic concentrations from different surveys are now available. However, most maps do not show if there are any variations depending on the depth of the aquifers. In the absence of complete understanding of Arsenic mobilization in the aquifer systems, we have to rely on the empirical knowledge on the availability of arsenic safe water in the aquifers. In fact such availability can be considered as proxy for our lack of knowledge of the given aquifer. During the survey, the depth information for all the tubewells were collected from the owners. As written records were not available in many cases, the depth values have come from people’s memory. The reliability of the memory decreases with lapse of time, so for older tubewells the depth data may be less reliable than the recent ones. Again depths of 1000ft or more have been reported for tubewells dating back to sixties and seventies. It is not clear why people would spend money to sink tubewells to such depths when water could be found at shallower depths. So, there may be either recording, data entry or plain reporting errors in some such numbers. The 36 Upazilla screening were done using Merck kit which probably can be relied upon at 100ppb level. So, in preparing depth segregated maps, tubewells have been considered safe at this level. The depth segregated maps of 36 2 Fig. 1 – Depth segregated Map showing relative number of arsenic-safe (green) and contaminated aquifers (red) for 36 Upazillas. Red colour indicates contaminated fraction. 3 Upazillas for Arsenic safe and contaminated wells are shown in figure 1. It can be seen that arsenic-safe water can be found at all depths depending on the area. Aquifers at depth between 50-250 ft are most frequently contaminated and aquifers are least contaminated between 500-1000ft. It is interesting to note that contamination frequency appear to change for worse beyond 1000ft. This could be related to the inaccuracy of depth data as pointed out earlier. It is clear that empirical knowledge obtained in the screening program can be used in a cost effective manner to provide mitigation measure in contaminated areas by sinking tubewells at least depths where safe water is available. 3. Statistics of Safe and Contaminated tubewells In the previous section, we have looked at the depth distribution of Arsenic concentrations at different locations in a qualitative and visual way. We want look at the issue in a more quantitative way in this section. Selected cases are considered here. The graphical data for all the Upazillas are given in annex-1 (to be included). 3.1 Low contamination areas % of tubewells Three typical cases of statistical distribution of safe and contaminated tubewells in 3 low contamination Upazillas (~20% or less) are shown the figure-2 below. 120 100 80 60 40 20 0 1 2 3 4 5 6 7 8 (a) Alamdanga (20.3%) 120 100 80 60 40 20 0 1 2 3 4 5 6 7 8 (b) Rajhat(3.2%) 4 120 100 80 60 40 20 0 1 2 3 4 5 6 7 8 (c) Kulaura(3.9%) Fig-2. Percentage of safe and contaminated tubewells in three low contamination areas as function of depths. (--- Safe, --- Contaminated) Depth(ft) Groups: 1. <=15, 2. >15 to <50, 3. >=50 to <150, 4. >=150 to <250, 5. >=250 to <500, 6. >=500 to <750, 7. >=750 to <1000, 8. >=1000 It can be seen from these cases that the percentage of safe and contaminated wells do not appear to depend on depth. It is known that misclassification of tubewells can arise due to limitation of kits used in the analysis [5]. In the case of Rajhat and Kulaura, the percentages of contaminated wells at all depths are less than 10%. Such level of contamination in a survey especially using Merck kit could arise from misclassification. Even in the case of Alamdanga where percentage reaches around 20%, the depth distribution appears random. Such situation could arise from analytical skill related problems. So, in areas where pattern of contaminations as in fig-2 are observed, careful laboratory based quality assurance checks should be carried out. It is likely the areas showing this type of pattern may be entirely uncontaminated. It very surprising to note that of the about 38,000 total tubewells in Rajhat more than 15,000 have been sunk to depth of 1000ft or more although screening shows it to be low contamination area of average 3.2% contamination level and the probability of getting Arsenic safe water at lower depth is very high. In the absence of other water quality problem, this shows that considerable saving in cost could be done by using shallower aquifers if they are present. 3.2 High contamination areas Four cases of statistical distribution of safe and contaminated tubewells in highly contaminated Upazillas (70% or more) are shown the figure-3 below. 100 90 80 70 60 50 40 30 20 10 0 1 2 3 4 5 6 7 8 (a) Faridganj (93.6) 5 120 100 80 60 40 20 0 1 2 3 4 5 6 7 6 7 8 (b) Raipur (79%) 120 100 80 60 40 20 0 1 2 3 4 5 8 (c) Tungipara (70.3%) 100 90 80 70 60 50 40 30 20 10 0 1 2 3 4 5 6 7 8 (d) Daudkandi (77.3%) Fig-3. Percentage of safe and contaminated tubewells in some high contamination areas as function of depths. (--- Safe, --- Contaminated) Depth(ft) Groups: 1. <=15, 2. >15 to <50, 3. >=50 to <150, 4. >=150 to <250, 5. >=250 to <500, 6. >=500 to <750, 7. >=750 to <1000, 8. >=1000 Although the curves look similar in three out of 4 cases shown here, the depths where safe water is available are quite different. Safe water is available at depth greater than 750ft at Faridganj. This depth is 500ft for Raipur and 250ft for Tungipara. It appears that for Daudkandi safe water with good probability is available only at the 250-500ft depth window. So, here again are the examples were screening information can be used for cost effective mitigation. Rather that wholesale sinking of tubewells at 1000ft or more depths 6 (which is being reportedly done now in many areas ), if data obtained in the screening process is used in an opportunistic and rational manner considerable cost saving can be done. 4. Arsenic concentration variation with time One of the questions which is of concern to many is whether the tubewells currently safe will remain so in the future or the concentration of Arsenic will change with time in the aquifers for worse due to stress imposed by abstractions. In order to obtain answer to such questions data have to be collected over extended period of time. Delay for such observation are not possible as answers are needed immediately. We have to find suitable proxy parameters which can reasonably replace the time parameter. One such proxy could be the age of the tubewells. As tubewells were sunk without specifically taking into consideration the aquifer properties, the average concentration of Arsenic in tubewells sunk at any given period should be statistically the same as any other period. So, any change in the concentration of Arsenic with tubewell age should represent its abstraction induced effect. Average concentrations for Arsenic in tubewells grouped by age were calculated for all the tubewells and also for the depth segregated groups. The results are shown in figure-4. Concentration Vs Year of Installation at Different Depth Mean Concentration (Mg/L) 0.2 0.15 0.1 0.05 1996 to 2001 1991 to 1995 1981 to 1990 1961 to 1980 1941 to 1960 1921 to 1940 1900 to 1920 0 Year of Installation All Depth <50 50-150 251-500 501-750 751-1000 151-250 Figure 4- Variation of average concentrations of Arsenic for all tubewells and depth segregated groups according to age. 7 It can be seen that for all the groups except >1000ft, the concentrations do not appreciably change with tubewell age. There appears to a slight decrease with time but this may not be very significant as these mostly relate to tubewells dating back to sixties. As pointed out earlier data for these tubewells may not be all that accurate. In the case of tubewells of depth greater than 1000ft, there may be even greater problem with data as discussed earlier and this is probably reflected in the increase in the Arsenic concentration for the tubewells between the period 1940-60. 5. Prevalence of Arsenicosis Symptoms Prevalence of arsenicosis data were collected during screening. The normalized prevalence rate per 100,000 population has been plotted as function of average Arsenic concentration for all the Upazillas in figure-5. Patients vs Mean Concentration Patients/100,000 350.0 300.0 250.0 200.0 150.0 100.0 50.0 0.0 0.000 0.100 0.200 0.300 0.400 0.500 0.600 Concentration (mg/l) Figure-5 Prevalence rate for patients per 100,000 population as function of average concentration of Arsenic in tubewell water for 36Upazillas. The linear relationship between cumulative dose and prevalence rate is expected. If average concentration can be taken as proxy for cumulative dose, this linear relationship should be expected for the graph in fig-6 also. Although there appears to be a general increase, the scatter is too great to show any definitive correlation. For average concentration to represent the cumulative dose, the underlying assumption is that age distribution of tubewells is the 8 same in all the areas. In order to assess the impact of length of exposure the prevalence rates for phase-I and II screening have been compared this is shown in table 1. Table 1: Arsenicosis prevalence data from screening -Phase I & II Phase Upazi llas I 6 II 36 Total 42 Tube wells Total Contaminated(%) Population Patients 80,390 48.19 1,698,410 1,139 544,651 46.49 8,674,202 9,188 625,041 46.71 10,372,61 10,327 Patients Per 100,000 67 106 Comments Merck Kits used Hach Kits used 100 As the degree of contamination in both the phases are rather similar and the measurements are shifted in time (by ~ 2 years), the rate of increase in the observed prevalence of patients may be statistically significant. It appears that the prevalence rate for patients has increased approximately at the rate of 20 per hundred thousand per year. Attempt was therefore made to look at the age distribution tube wells in different regions. Two selected age distributions are shown here (fig-6). The distributions do not looks any different. It is therefore not understandable why there is such poor correlation between concentration and the prevalence rate. Singair:TW Count 3000 2500 2000 1500 1000 500 19 50 19 53 19 56 19 60 19 63 19 66 19 69 19 72 19 75 19 78 19 81 19 84 19 87 19 90 19 93 19 96 19 99 0 9 Kalaroa: TW Count 2000 1800 1600 1400 1200 1000 800 600 400 200 98 01 20 19 92 95 19 19 89 19 83 86 19 19 77 80 19 19 71 74 19 19 65 68 19 19 61 19 55 19 19 50 0 Figure-6: Age distribution of tubewells in two randomly selected Upazillas 6. Discussions Selective analyses of the data from NAMIC show that a considerable insight into the Arsenic problem can be obtained from such data which is basically a byproduct of the BAMWSP screening program and obtained at minimal incremental cost. Such data and their analyses can supplement and in some cases may even substitute data that can be obtained through very expensive research and over a long period of time. Present analysis has shown that the nature of geographic distribution of Arsenic contamination looks quite different when viewed at different depths. The availability of Arsenic safe aquifers at different geographical areas also look quite interesting. Using proxy variables it appears that water abstraction from the aquifers has not affected the aquifer arsenic concentration up to now. A general raising trend for the prevalence of arsenicosis has been observed with higher arsenic ingestion represented by the proxy parameter of average arsenic concentration but significant correlations have not been found. It appears that observations of such analysis may be useful for cost effective mitigation work and for better understanding of some of the aspect of the Arsenic problem in the ground water. It is to be noted that all the analyses in this report were performed by the staff members of (NAMIC). The data base available at NAMIC and the further data from the on going larger screening program (147Upazillas) will be invaluable for improving the cost effectiveness of the future mitigation programs. It is, therefore, necessary to ensure that the archived data and management system of NAMIC be maintained beyond the tenure of BAMWSP. 10 7. References 1. D. G. Kinniburgh and P. N. Smedley, Arsenic contamination of groundwater in Bangladesh, BGS Technical Report WC/00/19, Vol. 1-4 (2001). 2. UNDP., Groundwater Survey: The Hydrogeological Conditions of Bangladesh, UNDP Technical Report DP/UN/BGD-74-009/1(1982) 3. J.A. Barker and R. Herbert, The pilot study into optimum well design: IDA 4000 Deep Tubewell II Project, Vol-4: Well and Aquifer modeling: Part 2, BGS Technical Report WD/89/11(1989). 4. P. K. Aggarwal, P.K. Basu, R.J. Poreda, K.M. Kulkarni, K. Froehlich, S.A. Tarafdar, M. Ali, N. Ahmed, A. Hussain, M. Rahman, S. R. Ahmed, Isotope Hydrology of Groundwater in Bangladesh: Implications for Characterization and Mitigation of Arsenic in Groundwater, Report IAEA – TC Project: BGD/8/016 (2000) 5. M. Khaliquzzaman , Quality Assurance Sampling Plan for Tubewell Monitoring with Hach Kit, Unpublished Report, Environment Team, WBOD (October, 2002) 11