PETROLEUM GEOLOGY AND BASIC ROCK PROPERTIES Petroleum is not found in underground lakes or rivers, but it exists within the void space of certain rocks. Requirements for Commercial Oil Accumulations Certain requirements must be fulfilled for a commercial petroleum deposit to be present. These are 1. A source: material from which oil is formed 2. Porous and permeable beds (reservoir rocks) in which the petroleum may migrate and accumulate after being formed. 3. A trap: subsurface condition restricting further movement of oil such that it may accumulate in commercial quantities. 1 Source of Petroleum Most geologists conclude that: 1. Petroleum originates from organic material, primarily vegetable, which has been altered by heat, bacterial action, pressure and other agents over long periods of time. 2. Conditions favouring petroleum formation are found only in sedimentary rocks. 3. The principal sediments generally considered as probable source rocks are shales and limestones that were originally muds under saline water. 2 Porous and Permeable Beds (Reservoir Rocks) After its formation, petroleum may migrate from the source rock into porous and permeable beds where it accumulates and continues its migration until finally trapped. The forces causing this migration are 1. Compaction of sediments as depth of burial increases. 2. Diastrophism: crustal movements causing pressure differentials and consequent subsurface fluid movements. 3. Capillary forces causing oil to be expelled from fine pores by the preferential entry of water. 4. Gravity which promotes fluid segregation according to density differences. 3 4 Porosity Porosity is a measure of the void space within a rock expressed as a fraction (or percentage) of the bulk volume of rock Vb Vs Vp Vb Vb where = porosity Vb = bulk volume of rock Vs = net volume occupied by solid Vp = pore volume Rock porosity can be classified as 1. Absolute porosity: total porosity of the rock, regardless of whether or not the individual voids are connected, and 2. Effective porosity: only that porosity due to voids which are interconnected. It is the effective porosity which is of interest to the oil industry. 5 Geological porosity has been classified in two types: 1. Primary porosity (intergranular): Porosity formed at the time sediment was deposited. The voids contributing to this type are the spaces between individual grains of the sediment. 2. Secondary porosity: Voids formed after the sediment was deposited. Porosity of this type is subdivided classes into three based on the mechanism of formation. i. Solution porosity: voids formed by the solution of the more soluble portions of the rock in percolating surface and subsurface waters containing carbonic and other organic acids. Voids of this origin may range from small vugs to cavernous openings. ii. Fractures, fissures and joints: voids of this type are common in many sedimentary rocks and 6 are formed by structural failure of the rock under loads caused by various diastrophism such as folding and faulting. This form of porosity is extremely hard to evaluate quantitatively due to its irregularity. iii. Dolomitization: This is a process by which limestone (CaCO3) is transformed into dolomite Ca Mg(CO3)2. 2CaCO3 + MgCl2 Dolomite is CaMg(CO3)2 + CaCl2 normally more porous than limestone. Typical Porosity Magnitude Type of sedimentary rocks Clean, consolidated and reasonably uniform sand Carboniferous rocks (limestone and dolomite) porosity 20% 6 – 8% 7 Quantitative Use of Porosity Data Let us assume that porosity has been measured and may be used to determine the quantity of fluid which may be stored within the rock. Consider a bulk volume of rock with a surface area of 1 acre and a thickness of 1 foot. This constitutes the basic rock volume measurement used in oil field calculations, an acrefoot. It is a standard practice to express all liquid volumes in terms of barrels (bbl). Conversion factors used are: 1 acre = 43,560 ft2 1 acre-ft = 43,560 ft3 1 bbl = 42 gal = 5.61 ft3 1 acre-ft = 43,560 = 7758 bbl 5.61 Then the pore space within a rock, Vp (bbl/acre-ft) = 7758 x where is the porosity of the rock 8 Oil in Place = N = where 7758 So 7758 (1 - Sw ) Bo Bo N = tank oil in place, bbl/acre-ft So = Fraction of pore space occupied by oil (the oil saturation) Sw = The water saturation Bo = The formation volume factor for the oil at the reservoir pressure, res. bbl/STB The water within the pore is commonly called the connate water. The pore space is assumed to be occupied by oil and water only and that no free gas is present. So the equation above must be applied to the reservoir at or above the bubble point and is generally used to compute the initial oil in place (IOIP). For the gas stored in a particular sand a similar expression may be derived. The gas volume is commonly expressed in terms of SCF or in MCF (thousands of standard cubic feet). 9 From the Gas Law PsVs PVp = Ts zT where subscript, s, denotes standard conditions, zs = 1.0, and is not shown. Then; Vs = G = Vp × PTs zTPs where G is the standard gas volume contained in Vp at conditions P, T, z. But: Vp = 43,560(1-Sw) ft3/acre-ft Ts = 4600 + 600 = 5200F Ps = 14.7 psia Substituting of these values in the equation gives: G = 43,560(1-Sw)x 520 p × 14 .7 zT Or G 1540(1 - S w )P MCF/acre - ft zT 10 Reserve estimation Any oil finding has to be interpretated in term of money or in term of economic evaluation. Initial Oil in Place (IOIP) has already being defined in term of bbl/acre.ft. It can also be expressed as IOIP 7758 volume of reservoir porosity oil saturation oil formation volume factor IOIP Where bbl 7758 Ah So Bo A = area of reservoir in acre h = height or thickness of reservoir in feet = porosity in fraction So = oil saturation in fraction Bo = Oil formation volume factor, res bbl/STB Only a portion of the IOIP that can be recovered. This portion is known as the oil reserve. 11 Oil reserve is dependent on the recovery factor (RF). Reserve = IOIP x RF Permeability Permeability is defined as a measure of a rock’s ability to transmit fluids. An empirical relationship was developed by a French hydrologist Henry D’arcy who studied the flow of water through unconsolidated sand. This law in its differential form is: v where k dP dL (1) v = apparent flow velocity = viscosity of the flowing fluid dP/dL = pressure gradient in the direction of the flow k = permeability of the porous media 12 Consider the linear system of the figure below dP P1 P2 q2 q1 dL L The following assumptions are necessary to the development of the basic flow equations: 1. 2. 3. 4. 5. 6. Steady state flow conditions exists The pore space of the rock is 100% saturated with the flowing fluid. Under this restriction, k is the absolute permeability. The viscosity of the flowing fluid is constant. Isothermal conditions prevail. Flow is horizontal and linear. Flow is laminar. With these restrictions, let v where q A (2) q = volumetric rate of flow of fluid A = cross-sectional area perpendicular to flow direction 13 Case 1: Linear Incompressible Fluid Flow Substitution of (2) into (1) gives q k dP A dL (3) Separation of variables and insertion of the limits depicted by the figure, gives q L k dL A 0 q= kA(P1 P2 ) μL P2 P1 dP (4) or k= quL AΔP (5) Unit for the above relationship is If then, q = 1 cm3/s A = 1 cm2 = 1 centipoise P/L = 1 atmosphere/cm k = 1 darcy 14 A permeability of one darcy is much higher than that commonly found in reservoir rocks. Consequently, a more common unit is the millidarcy, where 1 darcy = 1000 millidarcys Case II: Linear Compressible Fluid Flow Consider the same linear system(referring to the box figure), but the flowing fluid is now compressible. Assuming that Boyle’s law is valid (z = 1) P1q1 = P2q2 = constant P.q = - q2 L 0 kA dP × P = P2q2 μ dL dL kA 1 x P2 P2 P1 P dP From which kA P12 P22 1 q2 x x L 2 P2 15 Expressing the above equation in term of qg, the rate of gas flow at the average pressure in the system is kA P12 P22 1 qg x x L 2 P P P P 1 2 , and 2 But Therefore qg P12 P22 (P1 P2 )(P1 P2 ) 2 2 kA P L Which is exactly the same as equation (4). An expression for the standard flow rate, qgas is obtained from Charles’ Law: Ps qgs Ts Where P2 q2 kA 2 1 (P1 P22 ) Tf 2L Tf Ts = 600F (5200R) Ps = 1 atm Tf = flowing temperature Thus, kA(P12 P22 ) Ts 1 qgs x x 2L Tf Ps 16 Case III: Radial Incompressible Fluid Flow From the diffrential form of equation (1) with notation and sign convention as applied to radial flow in the figure. q k dp x A dr q Pe re Pw q q rw q h But radial flow Where A = 2rh r = radius or distance from centre, cm h = thickness of the bed, cm Substitution of 2rh for A and separation of variables gives q re rw dr 2hk r Pe Pw dP 17 Which when integrated is This is the basic expression for the steady state radial flow of a liquid. The units are the same as previously defined. Case IV: Radial Compressible Fluid Flow The same manner as in case II, the radial equations for gases may be obtained. By Boyle’s Law Where subscripts refer to position at which q is specified: well, external boundary, etc. 18 Conversions to Practical Units The standard units which define the darcy are useful in laboratory calculations. For computations pertaining to field problems it is more convenient to convert to practical units by use of appropriate constant. For example, convert to where q 2hk Pe Pw lnre / rw q Chk Pe Pw lnre / rw h = ft, k = darcy, Pe, Pw = psia, = cp, q = bbl/day Conversion factors needed: 1 bbl = 159,000 cm3 1 ft = 30.48 cm 1 atm = 14.7 psi Then: 159,000 cm3 / bbl q bbl/day x 24 x 3,600 s / day cm 1 atm 2 h ft x 30.48 k Pe Pw psi x ft 14.7 psi lnre / rw or q (24)(3600)(2)(30.48) hk(Pe Pw ) x (159,000)(14.7) ln(re / rw ) 19 q 7.07hk (Pe Pw ) ln(re rw ) Typical permeability magnitude In general, rocks having a permeability of 100 md or greater are considered fairly permeable, while rocks with less than 50 md are considered tight. Many productive limestone and dolomite matrices have permeability below 1 md but due to the associated solution cavities and fractures which contribute the bulk flow of the flow capacity. Current stimulation techniques of acidizing and hydraulic fracturing allow commercial production to be obtained from reservoir rocks once considered too tight to be of interest. The oil and gas reservoirs in Malaysia are having permeability between 50 to 2000 millidarcy. 20 Petroleum Traps In order for petroleum to accumulate in commercial quantities , it must, in its migration process, encounter a subsurface rock condition which halts further migration and causes the accumulation to take place. Numerous systems of trap classification exist, such as: 1. Structural traps: those traps formed by deformation of the earth’s crust by either faulting or folding. 21 2. Stratigraphic traps: those traps formed by changes in lithology, generally a disappearance of the containing bed or porosity zone. 22 3. Combination traps: traps having both structural and stratigraphic features. 23 Oil is found in flank sands, upper beds or the caprock A feature of all traps is the impermeable cap rock which forms the top of the trap. Subsurface Pressure 24 The elevated pressures encountered with depth are due to one or both of the causes: 1. Hydrostatic pressure imposed by the weight of fluid (predominantly water) which fills the voids of the rocks above and/ or contiguous with the reservoir in question. 2. Overburden pressure die to the weight of the rocks and their fluid content existing above the reservoir. It is more common to find subsurface pressures varying as a linear function of depth with a gradient close to the hydrostatic gradient of fresh to moderately saline water. Departures from this behaviour, both higher or lower, are considered abnormal. The abnormally high pressures are more important as a source of serious drilling and production hazards. Magnitude of subsurface Pressure 25 Pressure-depth relationships are commonly spoken of in terms of gradients. The hydrostatic gradient in fresh water is 0.433 psi/ft of depth which is the quotient of 62.4 lb/ft3 divided by 144 in2/ft2. Since most subsurface waters are saline, it is common to find the gradient to be more than 0.433 psi/ft. Studies from 100 high pressure wells in Texas-Louisiana Gulf Coast showed a pressure gradient of 1.0 psi/ft. This figure is commonly used and may be obtained by using an average water saturated rock specific gravity 0f 2.3. Hence the overburden gradient is 2.3 x 0.433 1.0 psi/ft Subsurface Temperature 26 The earth is assumed to contain a molten core, it is logical to assume that temperature should increase with depth. This temperature-depth relationship is commonly a linear function of the form: TD = Ta + D Where TD = temperature of the reservoir at any depth, D Ta = average surface temperature = temperature gradient, degrees/100 ft D = depth, hundreds of ft A normal gradient seems to about 1.60F/100 ft, although it should be noted considerable variations occur in various areas. Several devices for measuring subsurface temperature are available and will be discussed under temperature logging. 27