(General revision for units 3) Points of comparison Oxygen gas Carbon dioxide nitrogen Percentage in air: 21 % 0.03 % 78% Preparation :- By adding hydrogen peroxide to manganese dioxide Adding dilute hydrochloric acid to calcium carbonate as a catalyst Passing air over concentrated sodium or potassium hydroxide, then hot copper Proprieties : 1- Oxygen is a colorless, tasteless and odorless gas. It scarcely dissolves in water. 1-it is colorless and odorless. 1-nitrogen is a colorless, tasteless and odorless gas. 2-It is heavier than the air. 3- It does not 2- Oxygen does not burn and does burn, but it helps in not help in burning. combustion. So, 3- It has a neutral it is used for effect on litmus extinguishing paper with its two fires. colors. 4- The 4- Oxygen is magnesium heavier than air as ribbon keeps it replaces the air. burning and turns into a magnesium oxide (with white color) and 2- It scarcely dissolves in water 3- When it combines with a lighted magnesium ribbon composing a white substance. By adding a little water, a very pungent smell “ammonia” emits 4- can be condensed to a liquefied state the carbon (coal) deposits on the wall of the cylinder Importance *(uses ) 1- Water consists of oxygen united with hydrogen 2- Ozone is also composed of oxygen(protects the Earth from harmful radiation) A-Refrigeration on converting it into a liquid by pressure and cooling. Then, pressure is relieved composing dry ice that we use in refrigeration. 3- Oxygen gets compressed in iron B-extinguishing cylinders and used fires. in: A-Mechanical ventilation. C- Used to make soft drinks. B- During surgeries. During diving and D- used to make climbing bread bubbled mountains. as yeast which (Because oxygen produces carbon becomes lighter dioxide by 1- used in filling car tires. 2- Liquid nitrogen is used as a treatment to skin tumors. 3- It contributes in composing gunpowder and ammonium nitrates included in the composition of soil fertilizers. 4-Liquid nitrogen is used for cooling food products. 5- It is commercially used in the manufacture of ammonia to produce when we have rise above the Earth’s surface). C-used in cutting and welding metals when combined with acetylene gas to produce “oxyacetylene” flame whose temperature reaches 3500oC . fermentation when it is added. Carbon dioxide gets expanded due to the heat making bread porous and tasty. E-contributes in the photosynthesis process. fertilizers 6-Nitrogen is used in the tanks of liquified explosives and during the manufacture of electronic devices. 7-Nitrogen is used to make stainless steel. 8- It is used to store petroleum and some flammable materials. 1-Oxygen - The atmosphere consists of a mixture of gases such as oxygen 21%, nitrogen 78%, carbon dioxide and other gases 1%. - The atmosphere contains solid particles such dust and smoke. - These particles have advantages and disadvantages: o Disadvantages: these particles are considered air pollutants. o Advantages: these particles help in condensing water vapor and turn it into rain or snow. The importance of the atmosphere: 1-Contains the ozone layer which helps in protecting Earth from harmful radiation coming from outer space such as the ultraviolet radiation. 2- Adjust the temperature of the earth Oxygen gas: 1. Produced by plants from the photosynthesis process. 2. One oxygen molecule consists of 2 oxygen atoms. 3. Oxygen composes 1/5 of air volume. 4. Collected by displacing water downward because it rarely dissolves in water. 5. Colorless, odorless and tasteless. 6. Doesn’t burn but helps in burning. 7. Heavier than air. Preparation of oxygen: 1- Oxygen is prepared by the dissociation of hydrogen peroxide into oxygen and water. 2- This dissociation needs the help of a catalyst which is manganese dioxide. - The catalyst remains without a change in quantity and properties. - Iron combines with oxygen in the presence of humid to form iron rust. - Burning iron cleaning wires causes the wires to combine with oxygen forming iron oxide and resulting increase in weight. Oxygen Hydrogen peroxide Water Manganese dioxide The importance of oxygen: - Water consists of oxygen united with hydrogen. - Important for respiration, food combustion and the burning of fuel. - Ozone consists of oxygen O3. Uses of oxygen in our life: Oxygen is compressed in iron cylinders and used in: 1. Mechanical ventilation for patients who suffer from difficulties in breathing. 2. During surgeries. 3. During diving and climbing mountains. Oxygen becomes lighter when we rise above Earth surface. 4. In cutting and welding metals. By combining oxygen with acetylene a flame of 3500 °C is produced “oxy-acetylene flame”. 2-Carbon Dioxide - Carbon dioxide molecule consists of 3 atoms: 1 carbon atom and 2 oxygen atoms. - The percentage of carbon dioxide in the atmosphere is 0.03%. Sources of carbon dioxide: 1- The combustion (burning) of organic materials such as wood – coal – fuel. 2- Respiration process (exhalation). The increase of carbon dioxide percentage causes: 1- The raising of Earth temperature. 2- Suffocation and difficulties in breathing. Preparation of carbon dioxide in laboratory: - Add diluted hydrochloric acid to calcium carbonate. - Bubbles of a gas will be evolved and collected by displacing air upwards. - The gas is CO2. - Backing soda and vinegar or lemon also can be used to prepare CO2. Properties carbon dioxide: 12345- Colorless and odorless. Doesn’t burn and doesn’t help in burning. Heavier than air, so it is collected by displacing air upwards. Can’t be collected by displacing water because it dissolves easily in water. A magnesium ribbon keeps burning in a cylinder filled with carbon dioxide resulting a white substance (magnesium oxide) and a black substance (carbon) coal The importance of carbon dioxide: 1- Important for the photosynthesis process. 2- Used in refrigeration by making the dry ice. 3- Is used in extinguishing fires (except magnesium fires) because it doesn’t help in burning. 4- Is used in making bread by adding yeast which produces CO2 by fermentation. CO2 cause the bread to be porous and tasty. 5- Is used in making soft drinks. 3-Nitrogen - The molecule of nitrogen consists of 2 nitrogen atoms. - Nitrogen is called azote which means lifeless because it doesn’t help in burning and it is not included in the respiration process. The existence of nitrogen: 1234- Nitrogen represents 78% of the atmosphere. Nitrogen oxides are formed in the atmosphere during lightening. Nitrogen oxides reach soil with rain water. Legume plants such as peas, soybeans and clovers produce proteins by the help of a specific type of bacteria that lives in their roots. Preparation of nitrogen :- Properties of nitrogen 1- Nitrogen is colorless, odorless and tasteless. 2- Scarcely dissolves in water. 3- Doesn’t help in burning except with magnesium. 4- Can be condensed to liquefied state. 5- When combined with lightened magnesium it composes a white substance and by adding water to this substance ammonia pungent smell is produced. The importance of nitrogen: a. Used to fill car tires. b. Liquefied nitrogen is used to treat skin tumor. c. Contributes in composing gunpowder. d. Contributes in making soil fertilizers. e. Used as inactive element in in tanks of liquefied explosives and during the manufacturing electrical devices. f. Small amounts are used to fill some types of lamps. g. Is used to store petroleum and other flammable materials