Silafluorene moieties as promising building blocks for constructing wide-energy-gap host materials of blue phosphorescent organic light-emitting devices DongDong Wang,a1* QingQing Liu,b Yue Yu,c Yong Wu,a XinWen Zhang,b* Hua Dong,c Lin Mac, GuiJiang Zhou,a Bo Jiao,c ZhaoXin Wu,c* RunFeng Chen,b aDepartment bKey of Applied Chemistry, School of Science, Xi’an Jiaotong University, Xi’an 710049, PR China Laboratory of Organic Electronics and Information Displays, Institute of Advanced Materials, School of Electronic and information Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210036, PR China cKey Laboratory for Physical Electronics and Devices of the Ministry of Education, School of Electronic and information Engineering, Xi’an Jiaotong University, Xi’an 710049,PR 1 China Corresponding author, Dongdong Wang, Tel: +08602982663914, fax:+08602982668559, Email: ddwang@mail.xjtu.edu.cn; Zhaoxin Wu, Tel: +08602982664867, fax:+08602982664867, Email: zhaoxinwu@mail.xjtu.edu.cn; XinWen Zhang, Tel: +008602585866332, fax: 008602585866396, Email: iamxwzhang@njupt.edu.cn. Electronic Supplementary Information Molecular structure 1H-NMR spectra 13C-NMR spectra 2 HRMS data 3