DRAFT October 25, 2010 – V1.5 Geo-CAPE Coastal Ocean Ecosystem Dynamics White Paper (long version for HQ) White Paper Objectives: (1) Provide a detailed explanation of the Science Traceability Matrix – THE MISSION. (2) Justify the science (referring to Decadal Survey and scientific literature). (3) Explain the societal benefits and advancement in scientific understanding. (4) Provide an update on the work-to-date on the mission. (5) Describe the pre-launch activities and resources necessary to advance the mission. (6) Provide a plan for post-launch cal/val (resources and activities). I. Background (2-3 pages) a. Earth Science Decadal Survey The U.S. National Research Council (NRC), at the request of NASA, NOAA and the U.S. Geological Survey, conducted an Earth Science Decadal Survey review to assist these agencies in planning the next generation of Earth Science satellite missions. The final report recommended 17 missions including the Geostationary Coastal and Air Pollution Events (GeoCAPE) mission that focuses on measurements of tropospheric trace gases and coastal ocean color from geostationary orbit (NRC, 2007). The NRC placed Geo-CAPE within the second tier of mission launches, which NASA plans to launch after 2020 (NASA 2010). “A primary objective for observing coastal ocean regions is to determine the impact of climate change and anthropogenic activity on primary productivity and ecosystem variability (NRC 2007).” The oceans component of the Geo-CAPE focuses on coastal ecosystem dynamics and would provide upper ocean observations of water-leaving radiances, chlorophyll, primary productivity, particulate and dissolved organic carbon, particulate inorganic carbon, turbidity, sediment fluxes, land-ocean carbon fluxes, and phytoplankton community structure (ibid). The NRC DS report presented several coastal ocean science objectives for Geo-CAPE: • To quantify the response of marine ecosystems to short-term physical events, such as passage of storms and tidal mixing. • To assess the importance of high temporal variability in coupled biological-physical coastalecosystem models. • To monitor biotic and abiotic material in transient surface features, such as river plumes and tidal fronts. • To detect, track and predict the location of sources of hazardous materials, such as oil spills, waste disposal, and harmful algal blooms. • To detect floods from various sources, including river overflows. Over the past several years, NASA has initiated planning efforts and science and engineering studies for a geostationary ocean color mission. NASA’s Earth’s Living Oceans: The Unseen World: An advance plan for NASA’s Ocean Biology and Biogeochemistry Research document (NASA 2006) presents a description for a geostationary ocean color mission. This planning document describes the mission science and a preliminary set of instrument requirements for a geostationary hyperspectral imaging radiometer to study coastal ocean processes. The considerations for ocean color retrievals in coastal waters entails significant improvements in current ocean color sensor capabilities, which include: high frequency sampling each day, higher spatial and spectral resolution than current sensors, broad spectral coverage including UV-VIS-NIR and SWIR bands, high signal-to-noise ratio (SNR) and dynamic range, cloud 116100503 – Oct. 25, 2010 1 DRAFT October 25, 2010 – V1.5 avoidance, minimal polarization sensitivity or change (<0.2%), minimal stray light with narrow field-of-view (FOV) optics and low scatter gratings (<0.1%), no image striping or image latency, solar and lunar on-orbit calibration, etc. Details on the proposed instrument requirements are described in the NASA planning document (2006; http://oceancolor.gsfc.nasa.gov/DOCS/). The authors recommended that NASA (or in partnership with other U.S. federal agencies or international space agencies) contribute a regional sensor to a broader international effort to provide global coverage of the coastal oceans from geostationary orbit. Among the challenges posed by satellite observations of water leaving radiances from coastal waters is their small contribution to the total flux at the top of the atmosphere (TOA). Typical signals from oceans contribute <10% to the total flux, but the presence of colored dissolved organic material (CDOM) in coastal waters can reduce this reflectance even further to <1% of the total signal (see section V.a). As a result, it is imperative to adequately correct the signal for various atmospheric contributions to the total signal (see section II.d). Indeed, this was the motivation of the NRC (2007) for combining the air quality (AQ) and ocean color (OC) objectives from geostationary orbit into one mission: to enable optimal aerosol corrections to the OC retrievals. In highly urbanized coastal zones correcting for trace gases such O3 and NO2 are also critical, especially to avoid an atmospheric signature imposing a false impression of temporal and spatial variability within the coastal waters (see sections II.d and IV.a). By combining AQ and OC observations into a single mission, a unique opportunity arises for studying coupled atmospheric and coastal ocean processes, including terrestrial linkages via watershed processes. A discussion of such interdisciplinary topics are beyond the scope of the present white paper, however, the potential science that may be enabled by GEO-CAPE is addressed in a separate white paper (Jordan et al., in preparation). b. Geo-CAPE activities In August 2008, NASA convened a broad community workshop on the Geo-CAPE mission to refine the scientific goals, objectives and requirements for this mission and define the necessary investments to advance the mission concept for a Phase A mission start. The workshop report is posted at http://Geo-CAPE.larc.nasa.gov/documents.html. NASA assembled formal atmospheric and ocean science working groups between August 2008 and April 2009 and convened a working meeting in September 2009 to discuss Geo-CAPE mission science objectives and requirements. The agenda and presentations given at this meeting are posted at http://geocape.larc.nasa.gov/events-SEP2009SWGM.html. In March 2010, NASA convened a working meeting of the Geo-CAPE ocean and atmospheric science working groups. The meeting focused on preparing for mission design studies with goals of: endorsing draft Science Traceability Matrices (STMs) as starting points for mission design studies; identifying any needed instrument design studies; and specifying initial mission design studies and preparations. During this meeting, draft Geo-CAPE Atmospheric and Coastal Ocean Ecosystems Dynamics Science Traceability Matrices were endorsed by voice consensus as a sufficient, although not immutable, starting point for preliminary mission planning work. As living documents, the STMs are expected to further evolve pending the outcome of ongoing science pre-formulation studies. By the close of the meeting, the Science Working Groups (SWG) and Mission Design Coordination Group agreed to conduct a sequence of mission design studies. Currently, NASA is funding 116100503 – Oct. 25, 2010 2 DRAFT October 25, 2010 – V1.5 science and engineering studies for the Tier 2 Earth Science Decadal Survey missions including Geo-CAPE. Other Geostationary Ocean Color Observations Previous mission concept: GOES-R coastal waters imager Current ocean color sensors, for example SeaWiFS and MODIS and in the future VIIRS, are well suited for sampling the open ocean. However, coastal environments are spatially and optically more complex and require more frequent sampling and higher spatial resolution sensors with additional spectral channels. To address those issues, NOAA considered including a Coastal Waters imaging capability (HES-CW) as part of the Hyperspectral Environment Suite (HES) on the next generation Geostationary Operational Environmental Satellite (GOES-R). From 2004 to 2006, NOAA supported the COAST program to assess requirements for geostationary imaging in the coastal ocean. Based on the results of the first experiment in September 2006 a spatial sampling of 300 m or better and the MERIS channel set or better were recommended for coastal imaging (Davis, et al. 2007). In October 2006 due to budget and engineering concerns, NOAA dropped HES from the GOES-R program and the COAST program was terminated. NOAA still recognizes that it has strong requirements for coastal waters imaging, but it has no specific plan to meet those requirements at this time. Present Geostationary Ocean Color Instruments: GOCI On June 26, 2010, the Korean Geostationary Ocean Color Imager (GOCI) was launched on Ariane 5 as part of the Communication, Ocean and Meteorological Satellite (COMS-1) spacecraft, which was developed jointly by the Korean Aerospace and Research Institute (KARI) and EADS Astrium. The GOCI sensor is an 8-band (412, 443, 490, 555, 660, 680, 745, 865 nm) staring frame capture sensor with a targeted coverage area of 2500x2500km centered on 130˚E and 36˚N. GOCI’s 1 hour imaging frequency (8 times/day) and 500x500m local spatial resolution will permit unprecedented retrievals of coastal ocean dynamics. The Korea Ocean Research and Development Institute (KORDI) is planning a follow-on mission to GOCI (called GOCI-2) with a launch date of January 2018. Future Vision: constellation of Geostationary Imagers Geo-CAPE should be considered in the context of an emerging international constellation of ocean color radiometry sensors that will significantly improve our understanding of ocean biology, biogeochemistry and ecology in coastal and offshore waters. Given the regional nature of geostationary ocean color radiometry observations, a geographically distributed constellation of regionally-focused imagers is a crucial need in order to provide the desired global coastal coverage accompanied by high temporal revisits for dynamic regions (IGOS, 2006). NASA, via Geo-CAPE, could contribute one or more sensors/platforms (alone or as part of a mission of opportunity partnership with another U.S. or international space agency) to an international global effort that will join other regional efforts such as the recently launched GOCI on the COMS-1 platform from South Korea. The International Ocean Colour Coordinating Group (IOCCG) is working to facilitate international coordination and cooperation in this context through establishment of a Working Group on “Ocean Colour Observations from the Geostationary Orbit” that will articulate drivers, needs, requirements and evaluate present and 116100503 – Oct. 25, 2010 3 DRAFT October 25, 2010 – V1.5 planned capabilities with regard to geostationary ocean color observations in support of both research and applications. Science Traceability Matrix The main advantage afforded by a geostationary platform versus a low-earth polar orbit is the capability to image the same regions multiple times per day. Such a capability is vital to study coastal oceans where the physical, biological and chemical processes react on short time scales from seconds to a few days. From a geostationary vantage point, a sensor can stare at an instantaneous field-of-view (iFOV) to gain sufficient signal-to-noise to retrieve ocean reflectances during low light conditions such as at high solar zenith angles (early morning and late afternoon) and at high satellite view angles (e.g., high northern or southern latitudes). Furthermore, the flexibility of scanning throughout the day allows for greater opportunity to obtain non-cloudy pixels at any given location due to diurnal variability in cloud cover (e.g., morning fog along the Pacific northwest and afternoon clouds off the Florida coast). In spring 2009, a NASA Geo-CAPE Oceans Science Working Group (SWG) was assembled to help define a science traceability matrix (STM) for the oceans component of the Geo-CAPE mission. The STM summarizes the science questions, approach, measurement requirements and instrument requirements for the mission to the scientific community (see Table A1 in the appendix for a complete STM). The SWG endorsed the current draft of the coastal ecosystems dynamics STM at the March 2010 Geo-CAPE working meeting. The STM was presented to the ocean color community at the NASA Ocean Color Research Team meeting in May 2010 (http://oceancolor.gsfc.nasa.gov/MEETINGS/OCRT_May2010/). The SWG proposed the following set of science questions traceable to the NRC DS (2007) and NASA’s Ocean Biology and Biogeochemistry (OBB) Program long-term planning document (NASA 2006) that GeoCAPE can address. How do short-term coastal and open ocean processes interact with and influence larger scale physical, biogeochemical and ecosystem dynamics? How are variations in exchanges across the land-ocean interface related to changes within the watershed, and how do such exchanges influence coastal and open ocean biogeochemistry and ecosystem dynamics? How do natural and anthropogenic changes including climate-related forcing impact coastal ecosystem biodiversity and productivity? How do airborne-derived fluxes from precipitation, fog and episodic events such as fires, dust storms & volcanoes significantly affect the ecology and biogeochemistry of coastal and open ocean ecosystems? How do episodic hazards, contaminant loadings, and alterations of habitats impact the biology and ecology of the coastal zone? Q1. How do short-term coastal and open ocean processes interact with and influence larger scale physical, biogeochemical and ecosystem dynamics? The large-scale response of ocean circulation, biogeochemistry and ecosystems to atmospheric, climatic and anthropogenic forcing is the integral of processes occurring on smaller scales. Examples include vertical mixing, upwelling, primary production, grazing, as well as turbulent kinetic energy processes that can occur on inertial and semi-diurnal tidal frequencies (1-2 orders 116100503 – Oct. 25, 2010 4 DRAFT October 25, 2010 – V1.5 of magnitude higher than surrounding portions of the energy spectrum). Some of these processes are not easily discernible by the current generation of polar orbiting ocean color satellite sensors. Satellite missions such as Geo-CAPE, with associated field campaigns, will help determine precisely, how these small scale processes operate and impact biology, allowing for parameterization in larger scale predictive models. The interplay of these dynamic physical, chemical, and biological processes drives the transfer of matter and energy on regional and global scales, affecting Earth’s climate as well as human health and prosperity. Natural and anthropogenic perturbations alter these processes at spatial scales ranging from microscopic to basin-wide, and on time-scales ranging from minutes to decades and longer. Microorganisms at the base of the food web play a key role in integrating these scales, translating short-lived events to more easily recognized patterns and cycles of productivity observable at the ecosystem level. Gaining a more detailed understanding of how microorganisms respond to highly ephemeral, spatially varying processes is therefore central to attaining a predictive understanding of the longer term and larger scale consequences of environmental change. Q2. How are variations in exchanges across the land-ocean interface related to changes within the watershed, and how do such exchanges influence coastal and open ocean biogeochemistry and ecosystem dynamics? Exchanges of waterborne materials from land to ocean are a function of seasonal discharge dynamics, atmospheric deposition and land surface attributes that are influenced by a host of natural and anthropogenic processes. Land to ocean subsidies of nutrients, labile carbon, light attenuating substances and pollutants can have profound effects on estuarine and coastal ecosystems. Wetlands, estuaries and river mouths at the land-ocean interface are regions of vigorous biogeochemical processing and exchange, where land-derived materials are transformed to other compounds, affecting fluxes of carbon and nutrients to both the coastal ocean and the atmosphere. Changing climate, land use practices and air quality have the potential to alter coupled hydrologic-biogeochemical processes and the associated movement of water, carbon and nutrients through various terrestrial reservoirs. Such changes will ultimately influence the delivery of dissolved and particulate materials from terrestrial systems into rivers, estuaries, and coastal ocean waters. Watershed processes must be considered over spatial extents of hundreds to millions of square kilometers and varying time scales (hours to decades) in order to adequately characterize relationships among climate forcing and use practice/land cover change, and transport of materials through watersheds and, ultimately, to coastal regions. Within the coastal domain, similar spatial and temporal scales are required to characterize dynamics of terrestrial constituents and their effect on ecosystems. The objectives of describing processes controlling fluxes on land, their coupling to riverine systems, delivery of materials to estuaries and the coastal ocean and corresponding coastal ecosystem responses, necessitate the use of an integrated suite of models and remotely sensed data and targeted in situ observations. Q3. How do natural and anthropogenic changes including climate-related forcing impact coastal ecosystem biodiversity and productivity? How climate variability and global change will impact the biodiversity and productivity of coastal ecosystems is still the subject of significant debate. Coastal ecosystems (out to 150 km from shore) account for about 15% of global primary production but their importance is that they 116100503 – Oct. 25, 2010 5 DRAFT October 25, 2010 – V1.5 provide the great majority of marine living resources that are harvested for human consumption. Coastal ecosystems also receive the great majority of anthropogenic inputs (except CO2) due to their proximity to coastal human populations. The impacts on coastal ecosystems are hypothesized to occur via straightforward bottom-up nutrient supply processes. Coastal PP, diatoms and fish and other consumers all should decrease when (1) upwelling or other nutrient supply processes decrease, (2) nutrient levels in the thermocline/nutricline decrease, and (3) the thermocline/nutricline deepens. While these biogeochemical links are currently observable at longer time scales using polar orbiting satellites such as MODIS and SeaWIFS, Geo-CAPE observations will provide critical data linking the inertial and semi-diurnal frequency variability in ocean processes to the spectrum of biological response. Moreover, it will resolve strictly biological variability at sub-diurnal time scales (e.g. dinoflagellate vertical migration, phytoplankton growth) currently not resolvable using sun-synchronous polar orbiting satellites. Thermal stratification over a very shallow thermocline/nutricline for instance can foster coastal dinoflagellate blooms. These hypotheses require careful observation and testing that can be addressed with Geo-CAPE and associated field support. Q4. How do airborne-derived fluxes from precipitation, fog and episodic events such as fires, dust storms & volcanoes significantly affect the ecology and biogeochemistry of coastal and open ocean ecosystems? Atmospheric fluxes influence marine ecosystems in two ways, via direct deposition to the surface of marine waters and via indirect deposition to the watersheds emptying into those waters. Watershed processes have been discussed above in Science Question 2, here we will focus on direct deposition that can be in the form or wet or dry deposition. Although the atmosphere is often referred to as a passive vector in delivering material from terrestrial activity to the ocean, it has been shown that “cloud processing” – the transformation of materials due to interactions in the atmosphere – is important to understand bioavailability and effects on the ocean ecosystem (Hand et al 2004). For example, two key nutrients, nitrogen and iron, are known to have significant atmospheric depositional sources that are highly episodic. Dust storms are known to deposit significant amounts of iron both to open ocean and coastal ocean waters via dry deposition of dust aerosol particles. Similarly, recent work has indicated volcanic ash may also be a significant source of iron in some ocean waters via aerosol deposition. Unlike aeolian deposition of iron, nitrogen deposition is more important in coastal waters than open ocean areas due to the proximity of coastal ecosystems to anthropogenic source regions. Precipitation and fog are known to efficiently scavenge both inorganic and organic forms of nitrogen from the atmosphere enhancing their deposition by several orders of magnitude over that which occurs via dry deposition processes alone. However, the extent of the influence of atmospheric deposition of any of these materials depend strongly on many other factors within the aquatic ecosystem and it is not a simple matter to translate atmospheric wet deposition fluxes into ecological importance. In addition to nutrient delivery, other atmospheric constituents may be deposited to ocean waters from both natural (e.g., biomass mass burning) and anthropogenic (e.g., agricultural, industrial, residential, and combustion) sources. As with nitrogen deposition, various compounds from anthropogenic sources are expected to exert a greater influence in coastal waters than the open ocean due to their proximity to sources. Recently, it has been shown that atmospheric deposition of nitrogen and sulfur could also lower pH of coastal waters worsening the coastal ocean acidification problem (Doney et al 2007). Atmospheric constituents of greatest concern from such sources in coastal regions include toxic organic compounds (e.g., 116100503 – Oct. 25, 2010 6 DRAFT October 25, 2010 – V1.5 polycyclic aromatic hydrocarbons), trace metals (e.g., mercury), and persistent organic pollutants (e.g., polychlorinated biphenyls (PCBs)). Much work remains to understand how all the various compounds delivered to marine ecosystems from the atmosphere are biogeochemically cycled within those systems determining their ultimate fates. Q5. How do episodic hazards, contaminant loadings, and alterations of habitats impact the biology and ecology of the coastal zone? The effects of episodic hazards, such as hurricanes and other extreme storms, floods, tsunamis, chemical spills, harmful algal blooms, which occur often without warning and frequently are of short duration, are especially challenging to observe. Yet it is these same events that have the most severe and lasting effects on coastal ecosystems. Other severe impacts resulting from loss of coastal marshlands due to development and sea level rise occur so gradually over such long periods of time that they are likewise difficult to observe. In both cases, a geostationary observation platform provided by Geo-CAPE will permit more detailed assessment of the extent and duration of damage to coastal habitats from disasters. The recent Deepwater Horizon oil disaster, which has both episodic and long-term effects on the environment, is one example where the Geo-CAPE mission would have been extremely valuable. Effective response and prediction relies on accurate and timely information that is updated frequently. Assessment of impacts on coastal and open ocean communities requires both standing stock and rate measurements over many years. Data products The coastal ocean ecosystem dynamics data products that will be generated from Geo-CAPE observations are described in Table 1. The data products are classified as mission critical or highly desirable and also in terms of the maturity of the products based on current ocean color retrievals: climate data record (CDR), candidate CDR, research products, and exploratory products. Table 1. Classification of Satellite Data Products for GEO-CAPE Coastal Ocean Ecosystem Dynamics. Mission critical: products that drive measurement and instrument requirements. Highly desirable: products relevant to addressing mission science questions but not critical because the retrieval algorithm and/or field/lab measurement is not mature. The color code denotes the maturity of the satellite product. Mission Critical Normalized Spectral Remote Sensing Reflectances (and normalized water-leaving radiances) Chlorophyll a Diffuse attenuation coefficient (490 nm) Inherent optical properties & products: Colored Dissolved Organic Matter (CDOM) absorption Particle absorption & scattering, 116100503 – Oct. 25, 2010 Highly Desirable Particle size distributions & composition (biogenic, mineral, etc.) Physiological properties (fluorescence quantum yields, etc.) Other plant pigments (carotenoids, photoprotective pigments, photosynthetic pigments, phycobilins, etc.) 7 DRAFT October 25, 2010 – V1.5 Phytoplankton and detritus absorption & scattering Euphotic depth Primary production Particulate Organic Carbon (POC) Particulate Inorganic Carbon (PIC) Photosynthetically available radiation (PAR) Fluorescence line height (FLH) Total suspended matter (TSM; coastal) Trichodesmium concentration Dissolved Organic Carbon (DOC; coastal) Net community production of POC Net community production of DOC Export production Terrigenous DOC Black carbon pCO2(seawater) Air-Sea CO2 fluxes Photooxidation Detection of vertically migrating phytoplankton Phytoplankton carbon Respiration HAB detection and magnitude Functional/taxonomic group distributions Petroleum detection, type & thickness CDR = Climate Data Record, Candidate CDR, Research products, Exploratory Products Approach The SWG has recommended an ocean sensor capable of accomplishing three observational approaches: (1) targeted, high-frequency, episodic event-based monitoring and evaluation of tidal and diurnal variability of upper ocean standing stocks, rate measurements and hazards from river mouths to the coastal ocean, (2) survey mode that measures diurnal, seasonal and inter-annual variations in the standing stocks, rate measurements and hazards for estuarine and continental shelf regions with linkages to open-ocean processes at appropriate spatial scales, and (3) to observe coastal regions at sufficient spatial scales to resolve near-shore processes, coastal fronts, eddies, and track carbon pools and pollutants. The measurement and instrument requirements necessary to address the science questions, observational approaches, and measurements are summarized in Table 2. These Figure 1. Planned coastal coverage requirements are consistent with the requirements for and conceptual scan scenes for the Geo-CAPE recommended by the NRC panel (NRC Geo-CAPE coastal ecosystems sensor. 2007) and a geostationary ocean color mission described Other ocean scenes can be scanned as in the OBB planning document (NASA 2006). necessary. Location 90W at equator but prefer 90W – to be revised for figure centered at 95W. Measurement and Instrument Requirements Coastal oceans are the most productive ecosystems in terms of primary, secondary, and tertiary production as they receive nutrient supplies from river discharges, non-point runoff, upwelling, and atmospheric deposition. Coastal oceans are more dynamic in time and more heterogeneous in space than the open ocean, therefore more demanding in measurement frequency (temporal) 116100503 – Oct. 25, 2010 8 DRAFT October 25, 2010 – V1.5 and resolution (spatial). The objective of differentiating the various phytoplankton functional groups (PFGs) also demands more spectral bands. While existing polar-orbiting multi-band instruments provide near-daily observations of the surface ocean at ~1-km resolution, the key science questions of the Geo-CAPE mission can only be answered through enhanced measurements of the spectral radiance with sufficient temporal frequency and spatial resolution. This measurement requirement further puts strict requirement on the instrument design. The threshold and goal requirements constitute the trade space within which the science objectives can be achieved. An optimal spatial resolution to resolve coastal ocean geophysical features (and hence in-water constituents) would be <200 to 100 m (ground sample distance; GSD) for turbid waters within 10km of the shore (Bissett et al. 2004; Davis et al. 2007). However, beyond 10km from shore, a GSD of 1km would be sufficient to resolve geophysical features (ibid). Since spatial resolution represents one of the principal drivers of instrument size and mass, a compromise must be made between resolving in-water constituents within the near shore and developing a geostationary satellite sensor that is both reasonable in size and mass and technologically feasible. The nadir threshold spatial resolution of 375 m represents the coarsest resolution acceptable to image estuaries and their larger tributary rivers (e.g., Chesapeake Bay and the Potomac River) as well as resolve eddies, coastal fronts, and moderately sized phytoplankton patches (Dickey et al. 1991). High frequency satellite observations are critical to studying and quantifying biological and physical processes within the coastal ocean. Current satellite-based products of ocean primary production, which represents the rate of carbon fixation in phytoplankton or photosynthesis, currently rely on no more than a single satellite observation per day of chlorophyll and other ancillary products. Due to cloud cover and gaps in coverage of LEO sensors such as SeaWiFS and MODIS, the number of satellite observations over an ocean region is reduced to only a few measurements per week at best. Since phytoplankton blooms develop over the course of a few days to a week, the complete dynamics of the blooms (such as the onset, peak and termination of the bloom are not captured by individual LEO sensors). Yet, the in situ derived primary production (PP) measurements used to validate this satellite product quantify PP over a 6 to 24 hour period. Furthermore, the physiology of phytoplankton cells (chlorophyll content, nutrient uptake, etc.) varies on a diel cycle, and this has a significant impact on the their growth rate and hence PP. Therefore, multiple observations per day over several days are necessary to derive robust satellite-based estimates of PP. Since tidal currents reverse within ~6 hours for semi-diurnal (and ~12 hours for diurnal tidal cycles), tracking hazards such as oil slicks or harmful algal blooms using a satellite sensor requires a minimum of three observations per day distributed 3 hours apart (Davis et al. 2007). The instrument requirements necessary to meet the science objectives and measurement requirements for the coastal ecosystem dynamics component of the Geo-CAPE mission are shown in Table 2. The broad spectral range permits atmospherically-corrected retrievals of spectral remote sensing reflectances from the ultraviolet (UV) to near-infrared (NIR). The contribution of water-leaving radiances to the top-of-the atmosphere (TOA) is typically <10%. This requires atmospheric correction to account for molecular scattering (Rayleigh), gaseous absorption (ozone, water vapor, oxygen, nitrogen dioxide), and aerosol scattering and absorption to the TOA radiances. The spectral range and resolution requirements have been established to provide appropriate atmospheric correction to the TOA radiances. Coastal data products will 116100503 – Oct. 25, 2010 9 DRAFT October 25, 2010 – V1.5 require spectral remote sensing reflectances from 350-760nm with a high signal-to-noise ratio (Table 3). Table 2: Measurement and instrument requirements for the Geo-CAPE coastal ecosystems dynamics sensor. Measurement Requirements Temporal Resolution Threshold Goal Targeted Events 1 hour 0.5 hour Routine Coastal U.S. 0.5 hour 3 hours Region of Special Interest 1 RSI at 3 scans/day multiple RSI at 3 scans/day (RSI) Other Coastal waters 50°N 4 times/year 3 hours to 45°S 375 m x 375 m 250 m x 250 m Spatial Resolution (nadir) Field of Regard for Ocean 50°N to 45°S; Color retrievals 162.5°W to 32.5°W Coastal Coverage (distance 375 km 500 km from coast to ocean) Instrument Requirements 345-900 nm; 3 SWIR bands 340-1100 nm; 3 SWIR bands Spectral Range 1245, 1640, 2135 nm 1245, 1640, 2135 nm UV-VIS: 0.5 nm FWHM; 0.25 nm FWHM; NIR: 0.5 Spectral Resolution NIR: 1 nm; SWIR: 20-50 nm nm; SWIR: 20-50 nm 1000:1 for 10 nm FWHM 1500:1 for 10 nm (380-800 Signal-to-Noise Ratio (SNR) (380-800 nm); 600:1 for 40 nm); 600:1 for 40 nm FWHM nm FWHM in NIR; 300:1 to in NIR; 300:1 to 200:1 for 100:1 for SWIR bands (20SWIR bands (20-50nm 50nm FWHM) FWHM) ±9° N to S & E to W imaging Field of Regard capability from nadir for Lunar & Solar Calibrations ±70° ±75° Solar Zenith Angle Sensitivity High sensitivity but nonDetector Sensitivity & saturating Saturation <0.5% Polarization <25% of pixel size during within 10% of pixel size Pointing Stability single exposure during single exposure (pixel tracking) 1% through mission lifetime <0.5% through mission Relative Radiometric lifetime Precision Complete characterization to Pre-launch Characterization achieve relative radiometric precision on orbit Monthly at ≤7° phase angle Lunar Calibration 3 years 5 years Lifetime Design 116100503 – Oct. 25, 2010 10 DRAFT October 25, 2010 – V1.5 Table 3: Minimum requirements for spectral bands and SNR to retrieve mission critical data products and necessary atmospheric corrections. Band Bandwidth1 Minimum Center1 SNR Application/Comments1 350 15 500 Absorbing aerosol detection 360 15 500 CDOM-chlorophyll separation; strong NO2 absorption 385 10 1000 CDOM-chlorophyll separation; strong NO2 absorption; avoid precipitous drop in solar spectrum at 400 nm 410 20 412 10 1000 CDOM-chlorophyll separation; SeaWiFS (20 nm) & MODIS (15 nm) bands; strong NO2 absorption 425 10 1000 CDOM-chlorophyll separation, strong NO2 absorption 443 10 1000 Chlorophyll-a absorption peak; SeaWiFS (20 nm) & MODIS (10 nm) bands; strong NO2 absorption 460 10 1000 Assessory pigments & chlorophyll 475 10 1000 Assessory pigments & chlorophyll 490 10 1000 SeaWiFS (20 nm) & MODIS (10 nm) bands; chlorophyll band-ratio algorithm 510 10 1000 SeaWiFS (20 nm) band; chlorophyll-a band-ratio algorithm; strong O3 absorption 532 10 1000 Aerosol lidar transmission band; MODIS (10 nm) band; strong O3 absorption 540 10 1000 Phycoerythrobilin pigment 555 10 1000 Bio-optical algorithms (e.g., band-ratio chlorophyll); MODIS-547 nm, SeaWiFS-555 nm; strong O3 absorption 583 10 1000 Phycoerythrin, strong O3 absorption 623 10 1000 Strong O3 absorption; Phycocyanin, cyanobacteria, 640 10 1000 Shallow water, Between O3 & water vapor absorption peaks 655 10 1000 Chlorophyll a&b, strong O3 absorption, weak water vapor absorption 665 10 1000 Fluorescence line height baseline, bandwidth constrained by water vapor absorption line & 678 band 678 10 1000 Fluorescence line height; HABs detection, band center offset from fluorescence peak by O2 absorption line 710 10 1000 Fluorescence line height; HABs detection; terrestrial "red edge"; straddles water vapor absorption band 748 10 600 Fluoescence line height baseline; Atmospheric correction-open ocean; MODIS band, between O2 A-band & water vapor absorption peaks 765 40 600 Atmospheric correction-open ocean; SeaWiFS band, O2 A-band absorption 820 15 600 Water vapor concentration/corrections. There are other water vapor absorption features that could be used. 865 40 600 Atmospheric correction-open ocean; SeaWiFS band (40 nm bandwidth); MODIS band-869 (15 nm bandwidth) 1245 20 300 Atmospheric correction-turbid water; MODIS band; bandwidth constrained by water vapor & O2 absorption peaks 1378 20 300 Detection and correction of cirrus clouds and high-altitude aerosols 1640 40 250 Atmospheric correction-turbid water 116100503 – Oct. 25, 2010 NO2 absorption 11 DRAFT 1 October 25, 2010 – V1.5 2135 50 100 Aerosol properties, turbid water aerosol correction Band centers, Bandwidth and Applications obtained from C. McClain per ACE Ocean requirement Platform requirements The requirement of multiple views per day can only be achieved on a geosynchronous platform. Further, to observe coastal waters from 50°N to 45°S over the entire continental U.S., Central America and South America, the platform needs to be located near 95oW on the equator. Ancillary data requirements A successful ocean color mission requires accurate pre-launch calibration/characterization and post-launch (in-orbit) vicarious calibration as well as extensive field measurements to validate the satellite measurements. Further, for accurate atmospheric and other corrections, the following measurements, often from other satellite missions, are required: (1) ozone; (2) total water vapor; (3) surface wind velocity; (4) surface barometric pressure; (5) NO2 concentration. To address the key science questions of the Geo-CAPE mission, the following measurements are also required from other satellite missions, field measurements, and/or numerical models: (1) sea surface temperature (SST); (2) sea surface height (SSH); (3) ultraviolet radiation; (4) mixed layer depth (MLD); (5) atmospheric and surface ocean CO2; (6) pH; (7) ocean circulation; (8) tidal and other coastal currents; (9) aerosol and dust deposition; (10) run-off loading in the coastal zone; (11) wet deposition in the coastal zone. Benefits to society / societal impacts The societal benefits of ocean color have been extensively detailed in Report #7 (2008), “Why Ocean Colour? The Societal Benefits of Ocean Colour Technology” of the International Ocean Colour Coordinating Group (IOCCG), as well as in IOCCG Report #8 (2009), “Remote Sensing in Fisheries and Aquaculture”. As addressed in those previous reports and numerous other documents cited therein and elsewhere, ocean color can be utilized to support a number of important research and applied or operational efforts such as: assessments of climate variability and change through improved understanding of biogeochemical cycles (e.g., carbon pools and fluxes) and food web impacts; integrated ecosystem assessments and living marine resource management, e.g., marine protected areas, fisheries, aquaculture and threatened/endangered species; monitoring of coastal and inland water quality, e.g., pollutant and pathogen–laden runoff plumes and spills; assessments of natural and anthropogenic hazards, e.g., harmful algal blooms, oil and sewage spills, sediment resuspension events; improved understanding of ocean and coastal dynamics, e.g., eddies and blooms; development of robust indicators of the state of the ocean ecosystem, and, ecological modeling and forecasting activities. In support of these efforts, ocean color observations from a geostationary platform such as GeoCAPE will provide significantly improved temporal coverage of nearshore coastal, adjacent offshore and inland waters, and likely improved spatial and spectral coverage relative to current LEO sensors, which are generally more focused on global observations of open ocean waters. The higher frequency observations from geostationary will help mitigate the effects of cloud cover, as well as better resolve the dynamic, episodic, and/or ephemeral processes, phenomena and conditions commonly observed in coastal regions. A denser and more comprehensive ocean color data set will result, resulting in the further development, use and operational implementation of more timely and accurate products, e.g., harmful algal bloom forecasts, which 116100503 – Oct. 25, 2010 12 DRAFT October 25, 2010 – V1.5 in turn will provide better information to users in support of management and decision/policy making needs. Instrument and mission design studies Geo-MDI In preparation for the release of the NRC report, NASA conducted a series of mission planning and engineering studies in Autumn 2006 – Advanced Earth Science Mission Concept studies. The instrument developed for this study, Geostationary Multidisciplinary Imager (Geo-MDI), had similar requirements to those shown in Table 2 with the exception of the nadir spatial resolution of 250 m and the incorporation of additional requirements for retrieval of atmospheric trace gases and terrestrial vegetation products. A mission design study called Geostationary Multi-discipline Observatory (GMO) integrated mission #5 followed the instrument design studies and integrated three sensors (Geo-MDI, GeoMac and CISR) to simulate a Geo-CAPE mission payload (see http://geo-cape.larc.nasa.gov/documents.html for a summary). Geo-CEDI A follow-on Instrument Design Lab (IDL) study was conducted at GSFC in January 2010 to design an instrument that meets or exceeds the specific threshold requirements established by the Oceans SWG. The Coastal Ecosystems Dynamics Imager (CEDI) design developed from this IDL study meets or exceeds nearly all of the threshold requirements for the mission documented in the STM. Fig. 1 shows the layout of the optics and associated major subsystems. There are three separate spectrographs in Offner configurations that cover the spectral regions required for the various ocean color products and atmospheric correction algorithms. Table 3 provides the spectral coverage and resolution parameters for each band. 116100503 – Oct. 25, 2010 13 DRAFT October 25, 2010 – V1.5 Table 3. Geo-CEDI spectral design parameters. Spectral Design Parameters Coverage [nm] Resolution [nm] Band 1 345-600 0.5 Band 2 600-1100 0.5 Band 3 1200-2200 2.5 Each spectrograph band has an associated 2-dimensional focal plane optimized for sensitivity and dynamic range for that particular portion of the spectrum. One dimension of the focal plane is used for spatial discrimination while the second is used for spectral discrimination. In our baseline design all three focal planes are hybridized photodiode/readout integrated circuit (ROIC) structures using silicon (Si) detectors for the UV/VIS/NIR Bands and mercury cadmium telluride (HgCdTe) detectors for the SWIR Band. The typical integration times for Band 1 and Band 2 will be 200 ms and 12.5 ms for Band 3 to avoid saturation under cloudy conditions. The spectrographs share a common telescope via the use of two beam-splitters and the 2-axis scan mirror then projects a co-aligned image of the three slits onto the Earth’s surface. The current design has been optimized to obtain diffraction-limited performance in all three Bands and meets the spatial ground sampling and coverage requirements outlined in the following section. Table 4. Geo-CEDI scanner timing and spatial sampling. Sample Scale Scan Line Field of Regard Sample angular size 2.2 arc-sec x 1.25 deg. Sample Time 0.5 to 1.0 sec 0.625 x 1.25 deg. 8.5 to 17.1 minutes Comments E-W stepping (e.g., 0.8 sec Dwell for image co-adding + 0.2 sec step and settle) Relocate/Revisit Coastal Scenes (Nominally 72 to 84 scenes/day) The basic geometry and timing of the data accumulation is given in Table 4. Under threshold science requirements a single pixel field-of-view is 2.2 arc-sec, and this resolution must be maintained over an image sample dwell period of 0.8 seconds. CEDI has a north-to-south slit orientation (2048 pixels) and therefore scans east-to-west through step movements of the scan mirror. One of the challenges in designing an instrument capable of meeting the ocean threshold requirements from a geostationary orbit is the balance between achieving the required SNR (1000:1 in UV-Vis) over a large dynamic range (Lmax/Ltyp of 3 to 70 from UV to SWIR) while avoiding saturation of the detectors over bright scenes (e.g. imaging over clouds) and maintaining a short integration time of 1 second (0.8 sec scanning plus 0.2 sec for scan mirror stepping) for each line of pixels scanned. This challenge was overcome by co-adding consecutive multiple scans per line of pixels. For example, at typical ocean radiances at 70 solar zenith angle (SZA) would require co-adding two 0.4 sec scans for Bands 1 and 2 and 46 scans for Band 3 yielding a total integration time of 17.1 minutes for a scene size at nadir of 384 km x 768 km. Other scenarios can be envisioned which would reduce or increase the scan line dwell period (e.g. special events imaging of high impact that would require faster revisit times or unique processes which require more precision and longer dwell periods). 116100503 – Oct. 25, 2010 14 DRAFT 116100503 – Oct. 25, 2010 October 25, 2010 – V1.5 15 DRAFT October 25, 2010 – V1.5 SUMMARIZE 2010 MISSION STUDY II. Sensitivity analyses a. Atmospheric corrections M Wang, Tzortziou, Herman NEED INPUT FROM MENGHUA ON OZONE AND AEROSOLS From Jay Herman and Maria Tzortziou In order to retrieve underwater composition it is necessary to measure radiances at the top of the atmosphere (TOA) with a precision of 0.1% (in wavelength) and to within the NIST transfer standard for absolute radiometric accuracy (2 to 3%). However, absolute radiometric accuracy affects retrieval algorithms much less than loss of spectral precision. The 0.1% spectral precision is based on prior experience with MODIS and SeaWiFS, and is the requirement needed for the retrieval algorithms. Problems with measurement precision arise from instrumental sources (intrinsic signal to noise ratio based on the detector technology, readout noise, optical aberrations, and stray light) and from errors in atmospheric corrections needed to derive the underwater leaving radiances. For the rest of this discussion, it will be assumed that the instrumental characterization meets the measurement requirements (SNR > 1000:1, stray light less than 0.1%). The main sources of atmospheric correction arise from ozone absorption, aerosol scattering, and aerosol absorption. In coastal regions, NO2 absorption is an equally important source of retrieval error. O3 absorption and aerosol scattering can be handled by standard methods based on GEO CAPE measurements. Absorbing aerosol amounts are presently unknown for UV wavelengths, but can be derived from GEO CAPE measurements for cloud-free scenes. Aerosols and trace gas (mainly NO2) amounts require ground-based validation, which will be discussed in another section. Absorbing aerosols in coastal regions typically have an optical depth of a few tenths with weak wavelength dependence. In cloud-free scenes, the aerosol refractive index and optical depth could be derived. However, the underwater signal introduces a wavelength dependence that interferes with the aerosol retrieval. In the absence of independent ground-based estimates of aerosol absorption, the aerosols may introduce an error in the retrieval of underwater composition. In coastal waters, in addition to aerosols, atmospheric correction is needed for the presence of tropospheric trace gases such as NO2. Nitrogen dioxide has a strong absorption spectrum in the range 330 to 500 nm that varies rapidly with wavelength. Tropospheric NO2 amounts are highly variable in time and space, caused by both natural and anthropogenic emissions. Based on satellite observations (e.g. from OMI, GOME, SCIAMACHY), NO2 amounts in coastal waters near urban areas typically range from 0.2 to 0.8 DU (1 DU = 2.67 x 1016 molecules/cm2), but they can exceed 1 DU. These numbers apply to the east coast of the US from Boston, Mass. to Norfolk, Va., and to specific sites between Norfolk and the tip of Florida. 116100503 – Oct. 25, 2010 16 DRAFT October 25, 2010 – V1.5 One of the main challenges using current satellite NO2 data for atmospheric correction of coastal ocean color is their coarse spatial resolution (e.g. 12 km x 24 km at nadir view for OMI and even coarser for GOME and SCIAMACHY) relative to satellite ocean color measurements (e.g. 1 km x 1 km for MODIS) and expected variability at the land-ocean interface. Much higher-resolution, higher-frequency data from Geo-CAPE could contribute to understanding small-scale, short-term variability in coastal ocean processes and atmospheric composition. The question then arises about the accuracy needed in the NO2 measurement. Figure XX shows radiative transfer calculations of the percent error in water leaving radiances per DU of NO2 for NO2 altitude profiles 0 – 2 km, 0 – 3 km, and 0 – 4 km. If NO2 is mostly in the lower 2 km, then the error at 400 nm ranges up to 17% per DU for large solar zenith angle plus viewing zenith angle (SZA + VZA), which define the air-mass for photon transmission through the atmosphere. If we have an error of 0.2 DU, the error will be about 3.4% at 400 nm, and higher (up to 8%) if the NO2 is distributed between 0 and 4 km. In general, we should know the NO2 amount to within 0.2 DU to provide an adequate atmospheric correction. A slight error in the wavelength independent estimate for Fresnel reflection arising from an incomplete model of ocean surface conditions and wind speed will affect all wavelengths in a narrow range equally and not affect retrieval algorithms substantially. One component of wavelength dependent error arising from an incorrect estimate of Fresnel reflection is the amount of Rayleigh scattering back into the water with a l-4 wavelength dependence. This correction is dependent on the estimated wave structure derived from wind-speed estimates. 116100503 – Oct. 25, 2010 17 DRAFT October 25, 2010 – V1.5 Figure XX: Radiative transfer calculations of the percent error in water leaving radiances per DU of NO2 for NO2 altitude profiles 0 – 2 km, 0 – 3 km, and 0 – 4 km. b. Uncertainties for lab/field measurements (summarize ACE/Geo-CAPE activity) A joint activity between the Geo-CAPE Oceans SWG and the Aerosol, Cloud and ocean Ecosystem (ACE) Oceans SWG is underway to quantify uncertainties for field and laboratory measurements. c. Uncertainties of satellite products Products generated from Geo-CAPE, because of its remote-sensing nature, inherently contain some degree of uncertainties. The sources of uncertainties range from imperfect sensor engineering to retrieval algorithms [Antoine et al., 2008; Boss and Maritorena, 2006; Chami and Defoin-Platel, 2007; Salama and Stein, 2009]. Conventionally, the uncertainty (sometimes called “error”) of a product (such as Chl or Kd) has been evaluated statistically by comparing retrieved values from remote sensing with those from water samples measured concurrently, and an averaged “error” for the entire dataset [Darecki and Stramski, 2004; O'Reilly et al., 1998], or subgroups [Moore et al., 2009], has been derived. This quantity of “error” provides a general picture of the consistency between the remotely-sensed and the measured properties. It does not, however, isolate individual sources that contribute to the total uncertainty of a remotely-sensed data product. Derivation of ocean products from ocean-color measurements is a complex process [McClain et al., 2000], and is generally divided into two separate, but consecutive, steps: one is atmosphere correction [Gordon and Wang, 1994]; the other is ocean-color inversion [Carder et al., 1999; IOCCG, 2006; O'Reilly et al., 1998]. Each one of the two steps involves many sub-steps and/or variables, and contains different sources and magnitudes of uncertainties. To fully understand the quality of the ocean products derived from Geo-CAPE and then to characterize the spatial distribution of the uncertainties, it is necessary to account for all sources of uncertainties and quantify their contributions to uncertainties of the final products pixel wise. Specifically, it thus requires the development of a system to 1) analyze/quantify uncertainties of Geo-CAPE produced water-leaving radiance (the key product for derivation if in water properties) and 2) analyze/quantify uncertainties associated with the generation of ocean products from waterleaving radiance, per pixel [Lee et al., 2010; Maritorena et al., 2010]. III. Calibration & Validation a. Background/ Calibration Strategy Unlike land surface or clouds, the ocean reflectance is very small (often < 1%) due to strong absorption of the water molecules and other optically active constituents (OACs). Consequently, of the satellite measured (i.e., top-of-atmospheric or TOA) signals, only a small portion comes from the ocean. This portion varies with wavelength and concentrations of OACs but is typically < 10% for most ocean waters, but can change substantially from <1% in the blue wavelengths for CDOM-rich waters to > 50% in the green wavelengths for optically shallow waters. Because of the GEO-CAPE emphasis on coastal waters where CDOM is often high due to either terrestrial 116100503 – Oct. 25, 2010 18 DRAFT October 25, 2010 – V1.5 runoff or upwelling, the calibration and validation of GEO-CAPE is particularly more demanding than previous and existing ocean color instruments. Accurate estimates of the small ocean signal (spectral reflectance) require adequate 1) Calibration, including (a) Radiometric calibration, (b) Spectral calibration, (c) Spatial calibration (geo-location) 2) Atmospheric correction 3) Extensive validation Spectral calibration requires the use of standard light source in the laboratory (pre-launch), and can be verified or adjusted using known spectral features (e.g., solar Fraunhofer lines) after launch. Spatial calibration requires onboard GPS and the accuracy is often in the order of a half pixel (Wolfe et al., 2002). The most critical yet challenging calibration for a successful ocean color instrument is the radiometric calibration. From the experience and lessons learned from the proof-of-concept Coastal Zone Color Scanner (1978-1986) and based on radiative transfer theory, Gordon (1987) provided a thorough review on the calibration and methodology requirements of satellite ocean color instruments, followed by a recent update by Dinguirard and Slater (1999). The calibration includes pre-launch laboratory calibration (and sensor characterization) and post-launch in-orbit calibration. The former covers radiometric calibration to a few percent, spectral (wavelength) calibration including out-of-band response, polarization sensitivity, temperature response, and other characterizations (see below). The latter covers sensitivity monitoring (using a constant source, e.g., the moon) and vicarious calibration through tuning of the sensor gain by using well-defined ground measurement and a radiative transfer model. Because the same model is used for atmospheric correction, this latter calibration is extremely important because it represents a system tuning that accounts for all known and unknown uncertainties in the entire measurement system, including uncertainties in the solar extraterrestrial irradiance. Wang and Gordon (2002) showed that as long as the system is well characterized, vicarious calibration is sufficient to remove most errors, even if the pre-launch radiometric calibration is off by 10%. The pre-launch radiometric calibration, however, is still important in balancing the sensitivity and dynamic range. The pre-launch and post-launch calibrations are discussed separately below. Briefly, pre-launch calibration and characterization are conducted in the laboratory using NIST traceable equipment (Johnson et al., 1999). Post-launch calibration (McClain et al., 2000) can be made using 1) a well characterized and controlled measurement (e.g., MOBY); 2) another well calibrated in-orbit satellite instrument; 3) modeled surface reflectance in the absence of the above two (e.g., Evans and Gordon). All require a radiative transfer model to propagate the ocean surface signal to the TOA signal. In addition, monitoring a stable target (e.g., the moon) is essential to provide longterm stability correction. b. Pre-launch Calibration & Characterization Rigorous prelaunch characterization of the radiometric performance characteristics of a satellite sensor cannot be over-emphasized. Once on orbit, it is very difficult or impossible to determine quantitatively most sensor performance characteristics, e.g., out-of-band response, polarization 116100503 – Oct. 25, 2010 19 DRAFT October 25, 2010 – V1.5 sensitivity, etc. The prelaunch characterization, calibration and performance validation is a complex process, particularly as sensors become more sophisticated and uncertainty requirements more stringent in response to expanding science objectives. The GeoCAPE Ocean STM outlines the progression of requirements from science questions to sensor and mission requirements. What is often overlooked is a parallel progression of sensor performance requirements to test requirements, protocols, and metrology technology development needs. There are many examples of missions that are delayed because testing was inadequate, ambiguous, or simply inefficient. As the GeoCAPE formulation proceeds, calibration metrology must be included to ensure that the necessary capability is mature when the sensor is ready for testing. The GeoCAPE ocean radiometer requirements are particularly demanding because the water-leaving radiances are small, the science goals are broad, and the focus is on coastal and estuarine waters where scales of variability are small and the range of geophysical properties is greatest. Consequently, highly precise, accurate measurements of top-of-the-atmosphere (TOA) radiances are required for mission science goals to be met. One critical activity that must be undertaken early in the program is development of precise test requirements tied to performance specifications; that is, detailed descriptions of the radiometric tests that must be performed to verify that the sensor actually meets each performance specification. Once the tests are outlined, then the procedures and test set-ups must be defined for the particular instrument design. Different instrument designs will require, in general, tailored procedures and test fiducials. Finally, test facility environmental requirements such as available space, air quality, and lighting must be considered. Some tests may have special requirements that typical calibration laboratories cannot accommodate. Testing on both individual components as well as the full optical system is necessary; either component-level testing or system-level testing alone is not sufficient. Component-level testing is required for the development of a detailed instrument model that can estimate not only the imaging and straylight characteristics, but also polarization attributes, relative spectral response, and signal-to-noise ratios before system-level testing is undertaken. The model provides insight on whether or not the design is adequate before final fabrication is undertaken. Models require test data on individual components in the optical train (reflectance or transmittance, polarization dependence, etc.) as well as information on the detectors (wellcapacity, quantum yield, dark current, read noise, etc.). Often, the specific information required for detailed modeling, e.g., optical coating prescriptions, is not available because vendors consider such data proprietary. This may limit the fidelity of the model. Component testing can provide much of the necessary information for the instrument performance model. But component-level testing by itself cannot reliably establish the sensor performance because interactions between components (due to reflections, for example) cannot be tested. Systemlevel testing is required to validate the sensor performance requirements. Finally, all radiometric systems and sub-systems must be fully characterized to understand the performance of the system. If the sensor uses a solar diffuser or other device for tracking sensor degradation on orbit, that apparatus must also be characterized at a component-level, for example the diffuser bidirectional reflectance function, and at the system level. As with the primary optical path, a model must be developed for this element of the sensor. In conclusion, GeoCAPE will benefit from the advances in sensor characterization metrology as the other preceding Decadal Survey missions address the same issues. For example, NIST will continue to refine the laser-based facility known as the Spectral Irradiance 116100503 – Oct. 25, 2010 20 DRAFT October 25, 2010 – V1.5 and Radiance Responsivity Calibrations using Uniform Sources (SIRCUS) developed for the characterization and calibration of irradiance and radiance meters (Brown et al., 2006) and the hyperspectral image projector (HIP) to mimic the full spectral characteristics of a scene on-orbit (Allan et al., 2009), i.e., scenes from the HIP will be used to evaluate the instrument’s pointspread correction algorithm and response to complex scenes. c. Post-Launch Calibration/Validation (list requirements) Post-launch calibration and validation will at a minimum follow the approaches established for SeaWiFS and MODIS (Barnes et al. 2001; Franz et al. 2007; Hooker et al. 2007; Eplee et al. 2010; Eplee et al. in prep.) and expand upon them due to the more advanced capabilities of the Geo-CAPE sensor. The radiometric stability of the coastal ecosystem sensor will be monitored in orbit by scanning stable targets such as the moon (Barnes et al. 2004; Stone et al. 2005) and potentially the sun and locations on the earth. A hyperspectral sensor enables the use of solar Fraunhofer lines for spectral calibration. Vicarious calibration of the coastal ecosystem sensor will be accomplished with in situ radiometric measurements from several ideal sites (oligotrophic, clean atmosphere, limited cloud cover, accessible) distributed at different latitudes (Hooker et al. 2007). The heritage site for the Marine Optical Buoy (MOBY; Clark et al. 1997) off the coast of Lanai, Hawaii, which has been used to vicariously calibrate MODIS and SeaWiFS, is not a good candidate for Geo-CAPE because of the spatial distortion due the extreme angle between the sensor and the site. As has been proven with other ongoing ocean color satellite missions, continuous calibration and validation of products are vital to the success of science quality data from satellites. Sustained mission lifetime observations will occur at selected time series locations and will be augmented by measurements made on cruises, moorings of opportunity, autonomous platforms and intensive field campaigns. Time-series sites will be recommended based on the dynamic range of variability of products and processes capable of being captured by Geo-CAPE. Additionally, collaboration with current and planned calibration/validation sites for other ocean color missions will be leveraged. Data from field observations will be archived in the NASA SeaBASS database, which stores bio-optical and biogeochemical data collected concurrently with satellite overpasses and uses these for continuous calibration and validation of satellite data products. Numerous federal, state, and local government agencies are mandated to monitor the nation’s coastal water bodies and Geo-CAPE can make a significant contribution towards effort. With its high spatial and spectral resolution and the possibility of repeat visits each day, Geo-CAPE overcomes some of the traditional hurdles faced by previous generation space based measurements for routine coastal monitoring. The significant concerns about the accuracy and validity of satellite-derived products can be addressed by using data obtained by routine monitoring for validation of Geo-CAPE products. Chlorophyll concentrations, turbidity, and suspended solids are all routine measurements using well established protocols on coastal ocean observing programs conducted by federal agencies such as NOAA (e.g. Integrated Ocean Observing System (IOOS; includes observatories in the North American East and West coasts, Gulf of Mexico and Great Lakes [http://www.ioos.gov/catalog/]; the NowCOAST portal to a variety of NOAA and non-NOAA data sets and forecasts [http://nowcoast.noaa.gov/]; Center for Coastal Monitoring and Assessment [http://ccma.nos.noaa.gov/]); NSF (Long Term Ecological 116100503 – Oct. 25, 2010 21 DRAFT October 25, 2010 – V1.5 Research sites (LTER; http://www.lternet.edu/sites/); NASA (e.g. Plumes and Blooms [http://www.icess.ucsb.edu/PnB/PnB.html]; Gulf of Maine North Atlantic Time Series, GNATS [www.bigelow.org/index.php/download_file/-/view/105]; http://seabass.gsfc.nasa.gov/seabasscgi/archive_index.cgi/BIGELOW/BALCH); EPA (e.g. http://www.epa.gov/emap/nca/index.html and http://www.epa.gov/ncer/science/ globalclimate/); U.S Fish and Wildlife [http://www.fws.gov/coastal/], USGS (e.g. United States Historical Climatology Network [http://cdiac.ornl.gov/epubs/ndp/ushcn/ ushcn_map_interface.html]), as well as a multitude of state environmental agencies, by local governments, as well as private partnerships with non governmental organizations such as the River Keeper (Waterkeeper’s alliances http://waterkeeper.org/). In addition to data available from these coastal observing programs, high resolution validation data can also be obtained from automated instrumentation on moorings and platforms such as those associated with the U.S. Integrated Ocean Observing System. For example, the Gulf of Maine buoys, a part of the Northeastern Regional Association of Coastal Ocean Observing System (NERACOOS) provide high frequency chlorophyll concentrations and turbidity measurements. VI. Geo-CAPE Enabling Activities (FY11 and beyond) a. Orbital instrument design studies Preparation for the Geo-CAPE mission requires instrument and mission design studies to ensure that all critical technological requirements are met. For fiscal year 2011, the Geo-CAPE science working groups have recommended that a pointing stability study be conducted to examine the state of the technology in meeting this challenging requirement for the coastal ecosystem sensor. Additional design studies are recommended to optimize the baseline CEDI design and to examine other optical designs. Technology development studies funded through the NASA Earth Science Technology Office (ESTO) can also b. Mission planning scenarios – Mannino, Davis, Hu The Geo-CAPE mission is unique in all its resolutions (spatial, temporal, spectral, and radiometric). To fully realize its capacity for optimal measurements of different coastal environments, mission planning is required to address the following aspects. Survey mode (“routine”) sampling A sampling strategy will be developed to dermine when and how often to sample each individual area shown in Fig. 1. Factors to consider include scientific questions to address (e.g., diurnal change or temporal aliasing), historical cloud cover statistics, seasonality of the study area, and engineering restrictions. A sampling strategy to use real-time cloud cover measurements from concurrent weather satellites will also be pursued to determine whether or not measurement is necessary. A data acquisition plan matrix will be developed for optimal sampling. Event sampling Unexpected events, natural or accidental such as the 2002 Florida “black water” event or the 2010 Gulf of Mexico oil spill, may occur during the lifespan of the Geo-CAPE mission. A strategy will be implemented to deviate the routine sampling plan to target on the events. Download data On-board processing Will all spectral bands and high-frequency sampling, data volume may be a limiting factor for real-time downlinking and processing. On-board processing options will be studied for spectral binning [others?] 116100503 – Oct. 25, 2010 22 DRAFT October 25, 2010 – V1.5 Masking [what is this?] c. Studies for Algorithm Development To get the desired product for studies of ecosystem or environment, in addition to achieve reliable/accurate measurements radiance at satellite altitude, robust algorithm(s) is the key to convert measured optical quantities to biogeochemical products. Historically, because ocean-color remote sensing was focused on the concentration of chlorophyll (Chl, a proxy for biomass) in the global oceans, the algorithm to convert waterleaving radiance (Lw, the quantity after removing atmosphere contributions and effects) to Chl has been heavily empirical in nature. Also, with a perspective of global mean (or total) Chl, one standard (or default) algorithm (or one default sets of algorithm coefficients), which remains the same for different locations and different phytoplankton life cycles, has been utilized for the generation of Chl from Lw. Studies have found that this practice may not produce optimal Chl products at some seasons, or for some specific locations, which in particular include many coastal waters. The Geo-CAPE mission, with its focus on US coastal waters, in particular trying to study/understand daily variations/dynamics of community phytoplankton and other biogeochemical properties, will thus strive to develop algorithms specifically tuned for such objectives, instead of using one empirical Chl algorithm for all coastal waters, for example. To achieve this goal, significant efforts are required in both theoretical evaluations and field measurements. On the theoretical front, for instance, atmosphere correction requires information of water vapor which is presently provided from climatological database. Geo-CAPE measures coastal environments from morning to afternoon, which will thus face different amount of water vapor in a day. It is then necessary to know the range of such daily variations and their likely impacts on atmosphere correction. Otherwise false daily variation of water constituents could be resulted. On the derivation of biogeochemical properties in the water column (including Chl, POC, …), it is important to obtain regional and temporal relationships between concentrations and their corresponding spectral properties (such as spectral absorption and scattering/backscattering coefficients). As articulated in detail in Zaneveld et al (2006), a remote sensor ultimately measures a total signal (a spectral radiance), and this total signal is primarily controlled by spectral total absorption and spectral total backscattering coefficients. For different coastal environments, or at different time of a day, the water environment under Geo-CAPE observation could have same spectral a and spectral bb, but they could be made of different components, and/or different concentrations. Thus, how to accurately divide the total information into that of desired products for the targeted coastal regions, and over different time of a day, remains a challenge. To meet this challenge, for waters in the various coastal regions, not only Chl and Lw need to be measured, the measurements (in the upper water column) should also include: spectral absorption of phytoplankton spectral absorption of dissolved organic matter Spectral scattering/backscattering coefficients of particles Particle composition and size distribution Suite of phytoplankton pigments 116100503 – Oct. 25, 2010 23 DRAFT October 25, 2010 – V1.5 In particular, these measurements should best be made to cover daily cycles. d. in-situ instrument development GEO-CAPE pre- and post-launch algorithm development and validations goals require enabling investments in development of in situ observational capabilities. The need for observations in a variety of coastal environments, spanning a wide range of conditions, seasons, and times of day will require a combination of high resolution time series sites and focused process studies. The opportunity to take advantage of new coastal ocean observatory infrastructure should also be exploited. Emerging optical and biogeochemical sampling technologies should be advanced as appropriate for various platforms including moorings, piers and towers, autonomous vehicles, ships, and small coastal boats. i) radiometers Hyperspectral radiometers capable of high frequency sampling will be needed both for above water time series observations and high resolution vertical profiling in shallow waters. Above water designs with automated solar-tracking capability and options for sky-radiance and sun irradiance measurements, in addition to water leaving radiance, will enable necessary advances in both in-water algorithms and atmospheric correction approaches. Wavelength ranges that extend into the UV and infrared will also be essential. Novel deployment strategies for hyperspectral and multispectral radiometers on aircraft and high-speed coastal vessels will be valuable in providing high spatial resolution mapping of representative coastal optical features and water mass types. Technologies also exist for deployment of radiometers on autonomous profiling floats and gliders. ii) IOP sensors Advances in capabilities of in situ instrumentation for measurements of inherent optical properties (IOP) permit the collection of ground truth information in support of algorithm develop and validation of products relevant to GEO-CAPE. Measurements of fundamental optical properties should include multispectral and hyperspectral absorption, scattering, backscattering, and volume scattering function. Such information is critical in understanding the basis for observed variations in remote sensing reflectance signatures and their relationship to optical properties and associated constituents that influence them. A key issue for long term deployment of IOP and other in situ sensors is the control of biofouling. Progress in this area has resulted in successful deployment of IOP sensors for extended periods between servicing. Progress in reducing the size and power requirements of sensors has enabled longer deployments and smaller autonomous platforms including floats and gliders. iii) Biogeochemical sensors In addition to optical measurements, Geo-CAPE algorithm development and validation demands advances in sensors that provide direct or proxy information about products or constituents of interest. Emerging technologies that characterize particles and plankton, nutrients and other chemicals (hydrocarbons, etc.), carbon system components and pH, and rate processes 116100503 – Oct. 25, 2010 24 DRAFT October 25, 2010 – V1.5 (respiration, primary production, nutrient uptake) have the potential to greatly expand the impact of Geo-CAPE. Approaches to be explored include optical spectrometry, mass spectrometry, flow cytometry, optical imaging, multi-isotope incubation, and other analytical techniques that can be automated in a robust manner. These types of technologies will be important for developing reliable algorithms, but also for new approaches that merge in situ and remotely sensed information for more complete system characterization and ultimately improved predictive or forecasting skill for complex coastal systems. e. directed field campaigns and immediate priorities for calibration/ validation research Enabling Activities In addition, the new capabilities provided by Geo-CAPE, such as continuous coverage over daylight hours, require field activities in addition to the standard calibration and validation associated with other ocean color missions. Field observations with corresponding capability to the Geo-CAPE sensor will be critical in the pre-launch phase for the purpose of developing algorithms or identifying proxy measurements that will exploit the new capabilities of the GeoCAPE instruments. Investments that are made during the pre-launch phase will offer the capability for calibration and validation efforts after launch. The pre-launch efforts will identify critical in-water measurements that are required to take full advantage of the Geo-CAPE sensor. The hyperspectral, high temporal and spatial resolution of Geo-CAPE will require corresponding capabilities in the field at several sites in the coastal ocean. Given the hyperspectral nature of the Geo-CAPE mission, hyperspectral radiometric measurements will be vital. The value of the AERONET-OC network, operating SeaPRISM instruments has been thoroughly discussed by the Science Working Group. A major drawback of the current SeaPRISM design is the limited spectral resolution of the observed wavelengths. A hyperspectral redesign of the SeaPRISM, or a new instrument will undoubtedly be required. In addition to radiometry, hyperspectral observations of inherent optical properties (IOPs, absorption and scattering) will be required to deconvolve the total radiometry measurements, attributing the absorption and scattering contributions of the optically active constituents (phytoplankton, non-algal particles, colored dissolved organic matter). Platforms of opportunity and lower cost in situ time series of hyperspectral data should be investigated. Existing timeseries should be analyzed to determine if they meet requirements and recommendations provided for improvements if needed. The unique nature of Geo-CAPE lies in its ability to observe the same scene multiple times per day. The assessment of standing stocks of phytoplankton and carbon pools will allow for better quantification and constraint of process rate estimates. The multiple views per day along with ancillary observations will lend insight into the physical, chemical, and biological formation and evolution of water masses. Discussion is underway regarding the prioritization of satellite products and processes and the selection of sites to investigate these. The Science Working Group has identified the 116100503 – Oct. 25, 2010 25 DRAFT October 25, 2010 – V1.5 products that are still in research or exploratory status as warranting investment at this stage in the planning process. Several of the exploratory products have been demonstrated in open ocean case 1 waters (phytoplankton dominated) but similar retrieval success has yet to be proved in optically complex case 2 waters (optical properties vary independently) and in dynamic coastal regimes. Some of these products include (in no particular order), primary production and respiration, net community production of DOC/POC, fluorescence dynamics over the day, seawater pCO2, differentiation of phytoplankton functional types, and detection of surface manifestations of phytoplankton vertical migration. The Science Working Group has pointed out the value of utilizing field sites associated with an ongoing time series to allow a greater context of the measurements and reducing the costs associated with enabling activity field programs. The selection of field sites for the enabling investigations will depend on the prioritized products and processes. The selection of the field sites will maximize the number of products/process that can be addressed. The site selection will be based upon extent of existing time series measurements, the dynamic range of variability for the parameters of interest and geographical coverage of different regimes (i.e coastal upwelling, run-off dominated, stratified, etc.). In addition, if feasible, the coincident observations of atmospheric aerosol and trace gas properties will provide important information given the interdisciplinary nature of the mission with atmospheric and oceanic instruments being flown on the same platform. Interdisciplinary Science Studies Among the recommendations made at the August 2008 workshop, was a suggestion that an effort be made to delineate potential interdisciplinary research that would benefit from observations anticipated from Geo-CAPE. The emphasis on atmospheric boundary layer observations for key trace gases such as O3 and NO2, along with the high spatial resolution of the ocean color sensor, and the high resolution permitted by a geosynchronous orbit is expected to provide key information that may be combined with in situ data and models to help us better understand the complicated dynamics and biogeochemical cycles along our urbanized coast lines. There are myriad and complex interconnections between the atmosphere and coastal waters, with crucial terrestrial linkages as well. For example, both anthropogenic and natural sources of nutrients have atmospheric vectors (particularly for N and Fe) that contribute to the supply of these elements in marine ecosystems, but their bioavailability depends upon the form in which they are deposited and upon the organisms in the water that might make use of them [add refs]. The carbon cycle in coastal waters is particularly complex involving CO2, CO, VOCs, and aerosols, with coastal waters functioning both as sources and sinks. Much work remains to be done to understand the processes involved in this cycle [add refs]. There is also an increasing body of evidence that suggests marine ecosystems may play an important role in urban air quality by providing halogen radicals that contribute to the oxidative capacity of the boundary layer along the coastal margins [add refs]. For a more thorough discussion of interdisciplinary science topics and the role Geo-CAPE may play in helping us to better understand these coupled atmosphereocean biogeochemical processes, please see the companion white paper Geo-CAPE: Interdisciplinary Science Potential [Jordan et al., 20xx]. References 116100503 – Oct. 25, 2010 26 DRAFT October 25, 2010 – V1.5 Allan, D. W., Rice, J. P., and Goodman, J. A., Hyperspectral projection of a coral reef scene using the NIST hyperspectral image projector, Proc. SPIE,7334, 733415, 2009. Antoine, D., F. d’Ortenzio, S. B. Hooker, G. Be´cu, B. Gentili, D. Tailliez, and A. J. Scott (2008), Assessment of uncertainty in the ocean reflectance determined by three satellite ocean color sensors (MERIS, SeaWiFS and MODIS-A) at an offshore site in the Mediterranean Sea (BOUSSOLE project), J. Geophys. Res., 113, C07013, doi:07010.01029/02007JC004472. Barnes, R.A., R. E. Eplee Jr., F. S. Patt, H. H. Kieffer, T. C. Stone, G. Meister, and J. J. Butler C. R. McClain (2004) Comparison of SeaWiFS measurements of the Moon with the USGS lunar model, Applied Optics, 43:5838–5854. Bissett, W.P., Arnone, R., Davis, C.O., Dickey, T., Dye, D., Kohler, D.D.R. and Gould, R. 2004. From meters to kilometers- a look at ocean color scales of variability, spatial coherence, and the need for fine scale remote sensing in coastal ocean optics, Oceanography, 17, 3243. Boss, E. S., and S. Maritorena (2006), Uncertianties in the products of ocean-colour remote sensing, in Remote Sensing of Inherent Optical Properties: Fundamentals, Tests of Algorithms and Applications, edited by Z.-P. Lee, International Ocean-Colour Coordinating Group, Dartmouth, Canada. Brown, S. W., Eppeldauer, G. P., and Lykke, K. R., Facility for spectral irradiance and radiance responsivity calibrations using uniform sources, Appl. Opt.,45, 8219-8237, 2006. Carder, K. L., F. R. Chen, Z. P. Lee, S. K. Hawes, and D. Kamykowski (1999), Semianalytic Moderate-Resolution Imaging Spectrometer algorithms for chlorophyll-a and absorption with bio-optical domains based on nitrate-depletion temperatures, J. Geophys. Res., 104, 5403-5421. Chami, M., and M. Defoin-Platel (2007), How ambiguous is the inverse problem of ocean color in coastal waters?, J. Geophys. Res., 112, C03004, doi:03010.01029/02006JC003847. Clark, D.K., Gordon H.R, Voss K.J., Ge. Y., Broenkow W, et al. (1997) Validation of atmospheric correction over the ocean. J. Geophys. Res., 102, 17209–17. Darecki, M., and D. Stramski (2004), An evaluation of MODIS and SeaWiFS bio-optical algorithms in the Baltic Sea, Remote Sens. Environ., 89, 326-350. Davis, C.O., M. Kavanaugh, R. Letelier, W.P. Bissett and D. Kohler. 2007. Spatial and spectral resolution considerations for imaging coastal waters. Coastal Ocean Remote Sensing, edited by Robert J. Frouin, ZhongPing Lee, Proc. of SPIE, 6680, doi: 10.1117/12.734288. Dickey, T.D. 1991. The emergence of concurrent high-resolution physical and bio-optical measurements in the upper ocean and their applications. Review of Geophysics, 29, 383413. Dinguirard, M., and P. N. Slater (1999). Calibration of space-multispectral imaging sensors: A review. Remote Sens. Envion. 68:194-205. Doney, S.C., N. Mahowald, I. Lima, R.A. Feely, F.T.M.J.-F. Lamarque and P.J. Rasch (2007). "Impact of anthropogenic atmospheric nitrogen and sulfur deposition on ocean acidification and the inorganic carbon system." Proceedings of the National Academy of Sciences 104(37): 14580-14585. Eplee, R.E. Jr., J.-Q. Sun, G. Meister, F.S. Patt, X. Xiong, and C.R. McClain (2010) Cross calibration of SeaWiFS and MODIS using on-orbit observations of the Moon, Appl. Opt., in press. 116100503 – Oct. 25, 2010 27 DRAFT October 25, 2010 – V1.5 Eplee, R.E. Jr., G. Meister, F.S. Patt, and C.R. McClain (submitted) The on-orbit calibration of SeaWiFS, Appl. Opt., submitted. Evans, R. H., & Gordon, H. R. (1994). Coastal Zone Color Scanner system calibration: a retrospective examination. Journal of Geophysical Research, 99, 7293– 7307. Franz, B.A., S.W. Bailey, P.J.Werdell, and C.R. McClain (2007) Sensor-independent approach to the vicarious calibration of satellite ocean color radiometry, Appl. Opt. 46, 5068–5082. Gordon, H. R. (1987). Calibration requirements and methodology for remote sensors viewing the ocean in the visible. Remote Sens. Environ., 22:103-126. Gordon, H. R., and M. Wang (1994), Retrieval of water-leaving radiance and aerosol optical thickness over oceans with SeaWiFS: A preliminary algorithm, Applied Optics, 33, 443452. Hand, J.L., N.M. Mahowald, Y. Chen, R.L. Siefert, C. Luo, A. Subramaniam and I. Fung (2004). Estimates of atmospheric-processed soluble iron from observations and a global mineral aerosol model: Biogeochemical implications, Journal of Geophysical Research 109(D17205): doi:10.1029/2004JD004574. Hooker, S.B., McClain, C.R. and Mannino, A. (2007) NASA strategic planning document: a comprehensive plan for the long-term calibration and validation of oceanic biogeochemical satellite data, NASA Special Publication 2007-214152, NASA Goddard Space Flight Center, Greenbelt, Maryland, 31 pp. IOCCG (2006), Remote Sensing of Inherent Optical Properties: Fundamentals, Tests of Algorithms, and Applications, in Reports of the International Ocean-Colour Coordinating Group, No. 5, edited by Z.-P. Lee, p. 126, IOCCG, Dartmouth, Canada. Johnson, B.C., E.A. Early, R.E. Eplee, Jr., R.A. Barnes, and R.T. Caffrey (1999). The 1997 Prelaunch Radiometric Calibration of SeaWiFS. NASA Tech. Memo. 1999-206892, Vol. 4, S.B. Hooker and E.R. Firestone, Eds., NASA Goddard Space Flight Center, Greenbelt, Maryland, 51 pp. Lee, Z., R. Arnone, C. Hu, P. J. Werdell, and B. Lubac (2010), Uncertainties of optical parameters and their propagations in an analytical ocean color inversion algorithm, Applied Optics, 49(3), 369-381. Maritorena, S., O. H. F. d'Andon, A. Mangin, and D. A. Siegel (2010), Merged satellite ocean color data products using a bio-optical model: Characteristics, benefits and issues, Remote Sensing of Environment, 114 1791-1804. McClain, C.R. (2009) A Decade of Satellite Ocean Color Observations, Annu. Rev. Mar. Sci, 1, 19–42 McClain, C.R., E.J. Ainsworth, R.A. Barnes, R.E. Eplee, Jr., F.S. Patt, W.D. Robinson, M. Wang, and S.W. Bailey, 2000: SeaWiFS Postlaunch Calibration and Validation Analyses, NASA Tech. Memo. 2000-206892, Vol. 9-11, S.B. Hooker and E.R. Firestone, Eds., NASA Goddard Space Flight Center. McClain, C. R., R. A. Barnes, J. R.E. Eplee, B. A. Franz, N. C. Hsu, F. S. Patt, C. M. Pietras, W. D. Robinson, B. D. Schieber, G. M. Schmidt, M. Wang, S. W. Bailey, and P. J. Werdell (Eds.) (2000), SeaWiFS Postlaunch Calibration and Validation Analyses, Part 2., 57 pp., NASA Goddard Space Flight Center, Greenbelt, Maryland. Moore, T. S., J. W. Campbell, and M. D. Dowell (2009), A class-based approach to characterizing and mapping the uncertainty of the MODIS ocean chlorophyll product, Remote Sensing of Environment, 113 2424-2430. 116100503 – Oct. 25, 2010 28 DRAFT October 25, 2010 – V1.5 NASA, 2006. Earth’s Living Ocean: The Unseen World. An advanced plan for NASA’s Ocean Biology and Biogeochemistry Research, DRAFT, 2006. NRC, 2007. Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond. The National Academies Press, Washington, D.C. O'Reilly, J., S. Maritorena, B. G. Mitchell, D. Siegel, K. L. Carder, S. Garver, M. Kahru, and C. McClain (1998), Ocean color chlorophyll algorithms for SeaWiFS, J. Geophys. Res., 103, 24937-24953. Salama, M. S., and A. Stein (2009), Error decomposition and estimation of inherent optical properties, Applied Optics, 48(26), 4947-4962. Stone, T.C., H.H. Kieffer and I.F. Grant (2005) Potential for calibration of geostationary meteorological satellite imagers using the Moon, Proceedings of SPIE, 5882, doi: 10.1117/12.620097. Wang, M., and H. R. Gordon (2002). Calibration of ocean color scanners: how much error is acceptable in the near infrared? Remote Sens. Environ. 82:497-504. Wolfe, R. E., M. Nishihama, A. J. Fleig, J. A. Kuyper, D. P. Roy, J. C. Storey, and F. S. Patt (2002). Achieving sub-pixel geolocation accuracy in support of MODIS land science. Remote Sens. Environ. 83:31-49. APPENDIX 1 Oil Spill Monitoring from GEO-CAPE Every year, huge quantities of oil and petroleum products enter the sea, land, and groundwater (NAS, 2003). Monitoring of oil spill at sea is critical in assessing of spill’s characteristics, fate, and environment impact. Satellite instruments for spill monitoring include optical, microwave, and radar (e.g., synthetic aperture radar, SAR) sensors, each having its own advantages and disadvantages (Fingas and Brown, 1997 and 2000; Brekke and Solberg, 2005). Although SAR is perhaps the most often used, it suffers from high cost, lack of coverage, and difficulty to differentiate oil from other suspicious features (Alpers and Espedal, 2004). Most importantly, the only SAR signal is the dampened surface backscattering due to modulation of the oil slick/film to surface wave, which is difficult to use for thickness estimates. Optical instruments provide alternative means that can potentially overcome these difficulties. In particular, ocean color instruments on geostationary platforms may present unprecedented opportunities to monitor oil spill and other oil pollution events. The DeepWater Horizon (DWH) 116100503 – Oct. 25, 2010 29 DRAFT October 25, 2010 – V1.5 oil spill event in the Gulf of Mexico in spring and summer 2010 presents an example of why a geo-stationary, well-designed ocean color sensor is required. The use of optical remote sensing to detect oil spill started decades ago (e.g., McDonald et al., 1993). Hu et al. (2003) first demonstrated the advantage of using the quasi-operational satellite instrument MODIS for spill monitoring in a turbid lake, where 2 images per week were obtained after cloud screening, with no cost. The detection was possible because the high water turbidity provided a “bright” background where the highly light-absorbing oil films could be visualized. In the oligotrophic ocean, the water background is also dark, making oil detection difficult. However, Hu et al. (2009) showed that when MODIS imagery contained sun glint (i.e., specular reflection of the solar beam), high contrast was found between oil slicks and the background water. The contrast is not due to the difference between optical properties of the oil film and the water (as evidenced by the lack of contrast in other glint-free images), but due to the oil-modulation of the surface capillary waves – the same principle for SAR measurements (Chust and Sagarminaga, 2007). However, quantification of the relationship between sun glint magnitude, reflectance contrast, oil film thickness, and oil type still remains problematic, mainly due to lack of continuous observations and in situ groundtruthing measurements. Fig. 1 shows several MODIS examples of the DWH oil spill, which started after the tragedy explosion of the DWH oil rig (28.74oN, 88.37oW) on 21 April 2010. Figs. 1a and 1b show the suspicious slick feature among the scattered clouds. The feature shows spectral shape that is different from that of nearby clouds, with relatively lower reflectance in the blue wavelengths due to enhanced Rayleigh scattering along the sun glint beam. MODIS images from subsequent days show the spatial evolution of the slick, confirming that this is surface oil. Figs. 1c and 1d show two other examples from the same day from MODIS/Terra and MODIS/Aqua observations, respectively. Due to changes in the solar/viewing geometry, the same oil slicks show positive contrast in the morning but negative contrast in the afternoon. Further, the spatial contrast in some of the slicks in Fig. 1d diminished due to combined effect of both optical properties and surface Fresnel reflection of the oil film. 116100503 – Oct. 25, 2010 30 DRAFT October 25, 2010 – V1.5 (a) (b ) (c) (d ) Fig. 1. MODIS 250-m images showing oil slicks in the northern Gulf of Mexico due to oil spills from the DWH sunken oil rig (marked as a cross). (a) and (b) MODIS image on 22 April 2010 overlaid on a Google-Earth map shows that the oil rig is approximately 40 km southwest of the Mississippi River mouth. The image shows the oil slick and the surrounding clouds. (c) MODIS image on 29 April 2010 (16:55 GMT) shows the oil slicks in positive contrast. (d) MODIS image on the same day but at 18:30 GMT shows the same oil slicks in negative contrast and no contrast. The horizontal scale of (b)-(d) is about 120 km. The quasi-operational MODIS (and supplemental MERIS) 250-m observations provided the first images of oil spill at the beginning of the event, when SAR coverage was limited. As the spill developed from late April to July, coordinated efforts among the international remote sensing communities led to enhanced SAR coverage by using multiple SAR instruments, tilted to observe the spill whenever possible. However, the thickness of the oil film is impossible to obtain from SAR observations. In contrast, there are some preliminary evidence from laboratory measurements that oil film thickness may be obtained from surface reflectance measurements in the visible and shortwave-infrared (Svejkovsky and Muskat, 2006; Król et al., 2006; JPL unpublished data). The limited observations have not considered the influence of the surface bidirectional Fresnel reflectance that strongly modulates the reflectance signal, not to mention of the optical properties related to oil types (e.g., new or emulsified). As a result, one of the 116100503 – Oct. 25, 2010 31 DRAFT October 25, 2010 – V1.5 controversies in estimating the daily spill volume of the DWH event comes from the unknown thickness of the oil slick. In summary, several applications of MODIS (and other) multi-spectral imagery in spill monitoring have shown the following advantages: 1) Wide and daily coverage (> 2000 km swath) 2) Medium resolution (250 – 300 m) 3) Multi-spectral from 412 to 2130 nm However, existing ocean color instruments also suffer from several weaknesses, including 1) Cloud contamination 2) Lack of ability to detect small-scale (10s of meters) slicks 3) Lack of continuous observation (the multi-sensor approach suffers from inter-calibration problems) 4) Unknown relationship between optical contrast (from visible to shortwave-IR) and oil thickness 5) Unknown relationship between spectral shapes and oil thickness/type 6) Unknown ability to differentiate oil and other features, for example Sargassum slicks, Trichodesmium patches, phytoplankton or fish induced surface surfactant, shoals, and coastal freshwater jets. GEO-CAPE will provide continuous observations during the same day, which can improve spatial coverage (assuming non-persistent clouds) and temporal coverage (#1 and #3). More importantly, the multi-observations from the same instrument at hyperspectral wavelengths will provide potential capabilities to derive information on oil thickness and type (#4 and #5) as well as to differentiate oil from other features (#6). Combined with the cloudfree (#1) and higher-resolution (#2) SAR observations as well as targeted groundtruthing measurements, GEO-CAPE may provide completely novel information on oil slicks and therefore significantly enhance our capability in spill monitoring. The research community, on the other hand, needs to put more effort in studying the optical properties of oil, both in the laboratory and in the field. References and further readings Alpers, W., and H. A. Espedal (2004). Oils and surfactants. In: C. R. Jackson and J. R. Apel (eds) Synthetic Aperture Radar Marine User’s Manual. U.S. Department of Commerce, Washington, DC, September 2004. pp263-275. Brekke, C, and A. H. S. Solberg (2005). Oil spill detection by satellite remote sensing. Remote Sens. Environ. 95:1-13. Chust, G., and Y. Sagarminaga (2007). The multi-angle view of MISR detects oil slicks under sun glitter conditions. Remote Sens. Environ. 107:232-239. Fingas, M., and C. Brown (1997). Remote sensing of oil spills. Sea Technology, 38:37-46. Fingas, M., and C. Brown (2000), Oil-spill remote sensing – An update. Sea Technology, 41:21-26. Hu, C., et al. (2003). MODIS detects oil spills in Lake Maracaibo, Venezuela. EOS, Transactions, AGU, 84(33):313,319. Hu, C., X. Li, W. G. Pichel, and F. E. Muller-Karger (2009). Detection of natural oil slicks in the NW Gulf of Mexico using MODIS imagery. Geophys. Res. Lett. Vol. 36, L01604, doi:10.1029/2008GL036119. Król, T., A. Stelmaszewski, and W. Freda (2006). Variability in the optical properties of a crude oil – seawater emulsion. Oceanologia, 48:203-211. 116100503 – Oct. 25, 2010 32 DRAFT October 25, 2010 – V1.5 MacDonald, I. R., et al. (1993). Natural oil slicks in the Gulf of Mexico visible from space. J. Geophys. Res. 98(C9);16,351-16364. NAS. 2003. Oil in the sea III. Committee on Oil in the Sea: Inputs, Fates, and Effects, Ocean Studies Board and Marine Board, Divisions of Earth and Life Studies and Transportation Research Board, National Research Council. The National Academies Press. Svejkovsky, J., and J. Muskat (2006). Real-time Detection of Oil Slick Thickness Patterns with a Portable Multispectral Sensor. Final Report submitted to the U.S. Department of the Interior Minerals Management Service, Herndon, VA, July 31, 2006, Contract No. 0105CT39144. 116100503 – Oct. 25, 2010 33