UCSF Lab Standard Operating Procedure Chemical Process, Name or Hazard Class: Sodium Peroxide Please fill out the form completely. Insure all users have access to this SOP. Refer to instructions for assistance. Enter text. Department: Date SOP was written: Enter date. This lab specific SOP has been reviewed and approved by: Principal Investigator Name: Enter text. Principal Investigator Signature Lab Manager/Supervisor: Type of SOP: ☐ Process Enter text. ☒Hazardous Chemical ☐ Hazardous Class Purpose Sodium peroxide is a strong oxidizer that may react violently with water. When exposed to incompatible conditions, it can cause a fire or explosion. It is a corrosive chemical that can cause burns by all exposure routes. It may be harmful if inhaled, ingested, or absorbed through the skins. It can cause severe burns to the tissue of the mucous membranes, upper respiratory tract, skin, and eyes with irreversible damage. Sodium peroxide is mainly used as an oxidizing and bleaching agent. It is also used as an oxygen source for submarines and scuba gear. Physical & Chemical Properties/Definition of Chemical Group CAS#: 1313-60-6 Class: Oxidizer, water reactive, corrosive Molecular Formula: Na2O2 Form (physical state): Solid Color: Light yellow Boiling point: 657 °C (decomposes) Sodium Peroxide 1 Date: Click here to enter a date. Modified from SOP templates developed by UCLA EH&S (http://www.sop.ehs.ucla.edu/) Potential Hazards/Toxicity Sodium peroxide is a strong oxidizer with the potential to cause a fire or explosion under incompatible conditions. It may react violently with water. It may be harmful if ingested, inhaled, or absorbed through the skin. It may cause severe irritation to the gastrointestinal tract. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Causes skin and eye burns with severe eye damage. Symptoms of exposure include coughing, shortness of breath, headache, vomiting and nausea. Engineering Controls Chemical fume hood. Adequate exhaust and capture filtration. Electrically grounded lines and equipment. Personal Protective Equipment (PPE) Respirator Protection If lab personnel would like to use respirator on a voluntary basis, they must be trained and fit-tested by EH&S. This is a regulatory requirement. (http://or.ucsf.edu/ehs/8193-DSY/version/default/part/4/data/) Hand Protection Handle with gloves. Nitrile gloves are recommended. NOTE: Consult with your preferred glove manufacturer to ensure that the gloves you plan on using are compatible with sodium peroxide. Refer to glove selection chart from the links below: http://www.ansellpro.com/download/Ansell_8thEditionChemicalResistanceGuide.pdf OR http://www.allsafetyproducts.biz/page/74172 OR http://www.showabestglove.com/site/default.aspx OR http://www.mapaglove.com/ Eye Protection ANSI approved, tight-fitting safety glasses/goggles. Face shields are recommended. Skin and Body Protection Flame-resistant lab coat preferably made of anti-static material, long pants, and closed-toe shoes. Hygiene Measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. First Aid Procedures If inhaled Move person into fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Consult a physician. In case of skin contact Wash off with soap and plenty of water for at least 15 minutes while removing contaminated clothing. Consult a physician. Sodium Peroxide 2 Date: Click here to enter a date. Modified from SOP templates developed by UCLA EH&S (http://www.sop.ehs.ucla.edu/) In case of eye contact Flush eyes with plenty of water for at least 15 minutes lifting upper and lower eyelids and removing contact lenses. Consult a physician. Continue rinsing eyes during transport to hospital. If swallowed Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Special Handling and Storage Requirements Precautions for safe handling: Avoid contact with skin, eyes, and clothing. Avoid inhalation and ingestion. Avoid dust formation. Provide adequate exhaust ventilation. Keep away from sources of ignition- No smoking. Open and handle container with care. Conditions for safe storage: Keep container tightly closed in a cool, dry, and well-ventilated area. Incompatible with strong reducing agents, acids, sulfur, organic materials, alcohols and powdered metals. Do not allow contact with water. Store away from flammables. Store under inert gas. Spill and Accident Procedure Chemical Spill Dial 9-911 from campus phone or 415-476-1414 from cell phone or 415-2068522 (SFGH only) Spill – Assess the extent of danger. Assist contaminated or injured persons. Evacuate the spill area. Avoid breathing vapors. If possible, confine the spill to a small area using a spill kit or absorbent material. Keep others from entering contaminated area (e.g., use caution tape, barriers, etc.). Small (<1 L) – If you have training, you may assist in the clean-up effort. Use appropriate personal protective equipment and clean-up material for chemical spilled. Double bag spill waste in clear plastic bags, label and take to the next chemical waste pick-up. Large (>1 L) – Dial 9-911 from campus phone or 415-476-1414 from cell phone or 415-2068522 (SFGH only) for assistance. Chemical Spill on Body or Clothes – Remove clothing and rinse body thoroughly in emergency shower for at least 15 minutes. If discomfort persists, proceed to the Emergency Department. If no further discomfort is experienced, have the SDS ready and contact Poison Control Hotline at 1-800222-1222 for further exposure information. Notify your direct supervisor and EH&S at 415-4761300 during work hours, or 9-911 during non-working hours and weekends. Chemical Splash Into Eyes – Immediately rinse eyeball and inner surface of eyelid with water for 15 minutes by forcibly holding the eye open. If discomfort persists, proceed to the Emergency Department. If no further discomfort is experienced, have the SDS ready and contact Poison Control Hotline at 1-800-222-1222 for further exposure information. Notify your direct supervisor and EH&S at 415-476-1300 during work hours, or 9-911 during non-working hours and weekends. Sodium Peroxide 3 Date: Click here to enter a date. Modified from SOP templates developed by UCLA EH&S (http://www.sop.ehs.ucla.edu/) Medical Emergency Dial 9-911 (campus phone) or 476-6911 (cell phone) Note: All serious injuries must be reported to EH&S at 415-476-1300 within 8 hours. Non-Life Threatening Emergency– Go to Occupational Health Programs (OHP) Clinic, 415-8857580, 2330 Post Street, Suite 460 Hours of Operation for Appointments: Monday - Friday 7:30 a.m. - 4:00 p.m. (except Holidays). Note: All serious injuries must be reported to EH&S at 415-476-1300 within 8 hours. Needle stick/puncture exposure (as applicable to chemical handling procedure) – Wash the affected area with antiseptic soap and warm water for 15 minutes. For mucous membrane exposure, flush the affected area for 15 minutes using an eyewash station. Page the needle stick nurse by dialing 415-353-7842 (STIC). Decontamination/Waste Disposal Procedure Clean contaminated surfaces with soap and water and paper towels. Dispose of the paper towels as hazardous waste. Safety Data Sheet (SDS) Location Online SDS can be accessed at http://or.ucsf.edu/ehs/7241-DSY/msds.html Protocol/Procedure Quantities covered by this SOP: ______ (g , ml) to _______ (g, ml) Temperature range covered by this SOP: __ °C – __ °C General Overview and Purpose: Enter the experimental purpose Procedure: Enter experimental procedure. You can copy procedure from your lab notebook or from literature. NOTE Any deviation from this SOP requires approval from the Principal Investigator. Sodium Peroxide 4 Date: Click here to enter a date. Modified from SOP templates developed by UCLA EH&S (http://www.sop.ehs.ucla.edu/)