Petrographic Report: Polished Thin Section CA-01P Rock Type: quartz-sulphide-iron oxide vein in clay- and iron oxide-altered crystal tuff The thin section is dominated by a 3 cm wide vein that covers 85% of the thin section and consists of milky white vuggy quartz bearing sulphides and iron oxides. The vugs in the hand sample are 1 to 4.5 cm wide and host euhedral hexagonal quartz needles coated with blue-black lepidocrocite. The host rock is preserved in thin edges around the vein selvages, and is a clay- and iron oxide-altered crystal tuff that has undergone some silicification proximal to vein selvages. In thin section, the host rock is also preserved as small, rounded clasts (0.5 to 2 mm wide) close to vein selvages. The host rock comprises rounded to sub-angular primary quartz and fine-grained smectite (± minor kaolinite) and sericite overprinted by cryptocrystalline limonite. Sericite occurs in greater abundant where smectite is absent, and vice versa. Secondary quartz occurs in multi-crystalline blades and short, discontinuous cross-cutting veins (up to 0.1 mm wide) with minor iron oxides, and overprints limonite. Secondary quartz in the host rock is contemporaneous with the much wider quartz vein. Thin wormy hematite-lepidocrocite veins (up to 0.04 mm wide, greater than 0.5 mm long) overprint and offset limonite and quartz veins. Intergrown hematite and lepidocrocite also occurs as sub-rounded cubes that are likely pseudomorphs after pyrite. The vein is vuggy and composed of coarse-grained subhedral bladed to euhedral zoned hexagonal quartz with minor sulphides and iron oxides, and is contemporaneous with the secondary quartz veins within the host rock. Pyrite is the dominant sulphide and occurs as very fine anhedral grains between quartz crystals, and as coarser, rounded to euhedral cubes and pyritohedra, gernerally fractured and/or rimmed by later hematite and lepidocrocite. Pyrite grains are disseminated randomly throughout the vein, but locally aligned with the vein selvages, outlining growth zones in the vein. Trace amounts of droplet-shaped native gold (Fig. 1) and galena (Fig. 2) occur as inclusions in pyrite and chalcopyrite. Native gold and galena were not observed as inclusions in any other mineral. The reflectivity of the gold is less than normally observed, suggesting it is probably the typical electrum found in epithermal mineralization and comprised of approximately one third silver by weight. Mineral Host rock (as clasts) Quartz-1 Limonite Smectite (/kaolinite) Quartz-2 Hematite Lepidocrocite Sericite Quartz-sulphide-hematite vein Quartz-2 Pyrite Hematite Lepidocrocite Smectite Chalcopyrite Covellite Native gold Cliffmont Sample CA-01P Modal Percent Abundance Size Range (mm) 3 3 2 2 2 2 1 Up to 0.1 mm Cryptocrystalline Up to 20 microns Up to 0.4 mm Up to 0.4 mm Up to 0.5 mm Up to 60 microns 43 17 12 9 3 1 trace trace Up to 5 mm Up to 1.8 mm Up to 1.5 mm Up to 80 microns Up to 80 microns Up to 0.5 mm Up to 0.3 mm Up to 50 microns Page 1 Pyrite is typically completely or partly replaced by hematite and minor lepidocrocite (Fig. 3). Lepidocrocite also occurs as thin veins (up to 0.08 mm wide) filling fractures and between grain boundaries, and in some places rims the inside of vugs. Small patches (up to 0.07 mm wide) of rusty brown, fine smectite occur towards the ends of some of these lepidocrocite veins. Minor chalcopyrite occurs as anhedral grains filling grain boundaries between quartz. It is commonly associated with pyrite, and generally exhibits replacement by covellite at grain boundaries. Covellite rims on chalcopyrite range in thickness from less than a micron to 40 microns wide. Locally the percentage of replacement may vary up to 100% covellite after chalcopyite. The rock is consistent with an epithermal gold deposit type ore deposit. Although severely altered and veined, the rock only displays minor evidence of deformation in the form of offset secondary quartz veins along lepidocrocite veins. qtz gn au py py cov qtz cpy Figure 1: Photomicrograph of a rounded inclusion of native gold (au) hosted in pyrite (py) within the quartz vein (qtz). In the lower part of the photo, an anhedral grain of chalcopyrite (cpy) replaced by covellite (cov) around its rim sits between quartz grains. Photo taken in plane polarized reflected light. Figure 2: Photomicrograph of an inclusion of galena (gn) in pyrite (py) within coarse vein quartz (qtz). Photo taken in plane polarized reflected light. Figure 3: Photomicrograph of the remnants of a fractured pyrite (py) grain nearly completely replaced by hematite (hem) and lepidocrocite (lpd). Photo taken in plane polarized reflected light. py lpd hem Cliffmont Sample CA-01P Page 2