The Reaction of Coke and Mentos Group # 8 Joe Tunnera Nick Vassiliadis Kevin Uyleman Marlborough High School STEM ECHS January 10, 2014 The Reaction of Soda and Mentos 1 Problem Statement: Which brand of soda, Coke, Diet Coke, Sunkist, or Barq’s, will shoot the highest when mixed with Mentos? Research Nucleation Nucleation is the extremely localized budding of a distinct thermodynamic phase. (Nucleation, 2013.) Nucleation is important in Group 8’s project because when soda is combined with Mentos, it creates a geyser. This happens because gas bubbles form off of the Mentos and rise to the top of the soda bottle/can/etc. Then the bubbles escape from the top at a high pressure, forming a geyser. Nucleation is more of a physical change that chemical change. Nucleation is important to Group 8’s project because without nucleation, there would be no geyser. Nucleation, in this experiment, can only happen with Mentos. Mentos Mentos are a key part of Group 8’s experiment. Mentos combines with soda and reacts through nucleation. The ingredients in a single Mento are sugar, glucose syrup, hydrogenated coconut oil, gelatin, dextrin, natural flavor, corn starch, and gum. The rough dimply surfaces of Mentos encourage bubble growth because they efficiently disrupt the polar attractions between water molecules, creating bubble growth sites. It has been determined that mint Mentos has the The Reaction of Soda and Mentos 2 biggest reaction of all of the Mentos flavors. Also, colored candies have a smaller geyser than candies that do not have coloring. Mentos would have no reaction without the independent variable, the soda. Control and Variables For the control of the experiment, Group 8 decided to use Coca Cola. Coca Cola would be the best choice for this experiment because it is one of the most common types of soda that a lot of people drink. For the independent variables for the project, it was decided to use only products sold by The Coca Cola Company. This way, the results of the experiment would have fewer problems because different soda companies use different ingredients to make the soda. So if the experiment only has one brand of soda, the results would be more balanced and the chemicals that caused the reaction would be found easier. In this experiment, Group 8 decided to use diet Coca Cola, Barq’s root beer and Sunkist orange soda as the independent variables. To find the chemicals in both the Mentos and soda that causes nucleation, it is necessary to find the ingredients in both the Mentos and the soda. Soda Ingredients The ingredients used to produce Coca Cola, the control in the experiment, are: carbonated water, high fructose corn syrup or sucrose, cane sugar, caramel color, caffeine, phosphoric acid, coca extract, lime extract, vanilla, and glycerin. (Coca-Cola, 2010) The ingredients in diet Coca Cola, an independent variable, are: carbonated water, caramel color, sweeteners (aspartame, acesulfame-K), natural flavorings including caffeine, phosphoric acid, citric acid. Contains a source of phenylalanine. (Diet Coke, 2010) The ingredients in Barq’s root beer, one of the independent variables, are: carbonated water, high fructose corn syrup and/or sucrose, caramel The Reaction of Soda and Mentos 3 Color, sodium benzoate (to protect taste) citric acid, caffeine, artificial and natural flavors, acacia. The ingredients in Sunkist orange soda are: carbonated water, high fructose corn syrup, citric acid, sodium benzoate, modified food starch, natural flavors, caffeine, ester gum, yellow 6, and red 40. All of the sodas (Coca Cola, diet Coca Cola, Barq’s root beer, and Sunkist orange soda) have carbonated water, some form of sugar, and natural flavoring, which all could contribute to the chemical reaction of nucleation. Misc. Diet sodas have been known to have a bigger reaction with Mentos than regular soda. The geysers of diet sodas traveled about seven meters in length. Also, soda that didn’t have caffeine in them had about the same size geyser as the sodas with caffeine. The size of the geysers depends on factors that affect the growth rate of carbon dioxide bubbles. Diet Coke creates more bubbles than regular Coke because the surface tension of the water is lower because Diet Coke contains a sweetener aspartame. (Muir, 2008.) Hypothesis Based on these facts, it is hypothesized that the diet Coca Cola will have the tallest geyser because of the lower surface tension due to the artificial sweetener, aspartame. Design and Preform an Experiment Materials: 40 Mentos 10 Two Liter Coke Bottles 10 Two Liter Diet Coke Bottles 10 Two Liter Sunkist Orange Soda Bottles 10 Two Liter Barq’s Root Beer Bottles 1 Geyser Tube The Reaction of Soda and Mentos 4 1 Meter Stick 1 Ladder 1 Adding Machine Tape 1 Pen 1 Sharpie 1 Piece of Lined Paper 1 Hammer 10 Nails Procedure: 1. Mark adding machine tape every ten centimeter with meter sticks for four meters. 2. Set up ladder to full height against a tree perpendicular to the ground. 3. Climb ladder with adding tape and nail the top of the tape to the tree with the hammer. Make sure that the zero meter mark is touching the ground. 4. Nail adding tape every meter until the ground. 5. Take down ladder. 6. Place soda bottle thirty centimeters away from tape. 7. Place one Mento inside the geyser tube. 8. Take off cap of soda. 9. Screw geyser tube onto open end of soda tightly 10. Release Mento by pulling red lever. 11. Watch, measure, and record data of how high the geyser goes. 12. Repeat steps 6-11 ten times each for all four soda types. Analyze and Draw a Conclusion Table 1: Height of Geyser (m) Trial 1 2 3 4 5 6 7 8 9 10 AVG Coke (m) 4.2 3.45 2.8 3.1 2.5 3.4 2.9 2.6 3.1 1.8 2.985 Height of Geyser Diet Coke (m) 2.7 3.35 4.3 4.1 3.9 3.1 2.95 4 4.5 3.7 3.66 Sunkist (m) 1.3 0.4 1.1 1.6 0.9 0.85 1.9 0.6 1.1 0.55 1.03 Barq's (m) 3.5 1 0.3 2.15 1.7 1.55 1.5 1.7 1.6 1.9 1.69 The Reaction of Soda and Mentos 5 Graph 1: Avg Height of Geysers Average Heights of the Geysers 4 3.66 m 3.5 2.985 m 3 2.5 Coke (m) Diet Coke (m) 2 1.69 m Sunkist (m) Barq's (m) 1.5 1.03 m 1 0.5 0 Graph 2: Heights of the Geysers Height of Geysers 5 4.5 Height of Geyser 4 3.5 3 Coke (m) 2.5 Diet Coke (m) 2 Sunkist (m) 1.5 Barq's (m) 1 0.5 0 0 2 4 6 Trial 8 10 12 The Reaction of Soda and Mentos 6 Table 2: Confidence Intervals Lower 95% Confidence Limit Mean Upper 95% Confidence Limit 1 1 1 Control - Coke 2.456 2.985 3.445 2 2 2 Diet Coke 3.226 3.66 4.094 3 3 3 Sunkist 0.691 1.03 1.369 4 4 4 Barq's 1.106 1.69 2.274 5 5 5 Graph 3: Confidence Intervals of Geyser Heights 95% Confidence Intervals of Geyser Heights 4.5 4 3.5 Height (m) 3 2.5 2 1.5 1 0.5 0 0 0.5 1 Control-Coke 1.5 2 Coke 2.5 Sunkist 3 3.5 4 4.5 Barq's Table 3: P-values p-values Control-Coke Diet Coke Sunkist Barq's ControlCoke 1 0.013 2.868 0.0005 Diet Coke Sunkist Barq's 0.013336123 2.868 2.504 1 0.0005 5.656 0.0221 0.0221 1 1 2.504 5.656 The Reaction of Soda and Mentos 7 Conclusion The reason for this project was to see which soda, Coca-Cola, Diet Coke, Sunkist, or Barq’s, will create the highest geyser. Through a process called nucleation, the Mento reacts with the soda and carbon dioxide bubbles form off of the Mento and get put to the side and forced out through the top. Nucleation is boosted in Diet Coke because Diet Coke contains an artificial sweetener called aspartame. To test the problem, first, set up the ladder and tape the measure tape to a high surface. After, take down the ladder and bring out all of the soda. Place one bottle of soda on a certain spot, about 15-20 cm, away the measure tape. Put one Mento is the geyser tube and attach it to the bottle. Release the tube and record the height of the geyser. Repeat this process until you have finished all of your testing. Based on the averages, the diet coke had a higher geyser when one Mento is put into it with an average of 3.66 m high. The second highest average goes to Coca-cola with an average of 2.985 m tall. The third was Barq’s with an average of 1.69 m. And Sunkist was the last with an average of 1.03 m. If the data is collected in the same fashion and the same factors play a role in every trial, there is a 95% confidence that the average geyser height of Coca-Cola will be between 2.456 m and 3.445 m. With the Diet Coke, there is a 95% confidence that the average will be between 3.226 m and 4.094 m. With the Sunkist, however, the confidence interval goes down tremendously: between 0.691 m and 1.369 m. And Barq’s confidence interval is between 1.106 m and 2.274 m. The Reaction of Soda and Mentos 8 The t test results for the variables supports the confidence interval conclusions. Becacuse the pvalue of Coke and Diet Coke is 0.013336123, or less than 0.05, the average height of Diet Coke is higher than that of Coke. Also, because the p-value of Coke and Sunkist ≥ 0.05, the Coke had a higher geyser than Sunkist. Based on the data, the hypothesis is proven correct. The Diet Coke did have the highest geyser because of boosted nucleation because of an artificial sweetener, aspartame. Sunkist and Barq’s did not live up to the performance of Coke and Diet Coke. The sources of error group 8 had to deal with was the wind. The wind would blow the adding machine tape a little bit, even with it nailed to a tree. The will could also blow the geyser a little, which could decrease some geyser heights. Also, some geysers were hard to measure by the naked eye. This could throw the data off a little. This project does not have much importance. But it is actually important in chemistry. In the chemical industry, nucleation is used in the process of preparing metal powders that can serve as catalysts. The Reaction of Soda and Mentos 9 References Coca Cola Company (2010). Coca?Cola : Cherry Coke : Coca?Cola Vanilla : Ingredients & GDAs - Coca-Cola GB. Retrieved December 2, 2013, from http://www.cocacola.co.uk/brands/coca-cola.html Coca Cola Company (2010). Diet Coke Ingredients & Nutrition : Weight Loss & Diabetes Coca-Cola GB. Retrieved December 2, 2013, from http://www.cocacola.co.uk/brands/diet-coke.html Coca Cola Company (2010). Fanta Orange : Lemon : Can & Bottle Nutritional Information Coca-Cola GB. Retrieved December 2, 2013, from http://www.cocacola.co.uk/brands/fanta.html Muir, H. (2008, June 12). Science of Mentos-Diet Coke explosions explained - physics-math 12 June 2008 - New Scientist. Retrieved November 27, 2013, from http://www.newscientist.com/article/dn14114-science-of-mentosdiet-coke-explosionsexplained.html#.UpTVsMSsim5 [Nucleation]. (2014, June 14). Retrieved from http://www.scientificamerican.com/article.cfm?id=bring-science-home-coke-mentos [Two Mentos Rolls]. (2012, February). Retrieved from http://www.couponcloset.net/wpcontent/uploads/2011/02/mentos1.jpg Wikipedia (2013, November 30). Diet Coke and Mentos eruption - Wikipedia, the free encyclopedia. Retrieved December 3, 2013, from http://en.wikipedia.org/wiki/Diet_Coke_and_Mentos_eruption [Nucleation]. (2014, June 14). 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