Solubility Chart Anion Soluble Cations Insoluble* Cations Nitrate (NO3-) Acetate (CH3COO-) All common ions No common ions Chloride (Cl-) Bromide (Br-) Iodide (I-) Most ions Ag+, Pb2+, Hg+ Sulfate (SO42-) Most ions Ca2+, Ba2+, Sr2+, Ag+, Pb2+, Hg+ Carbonate (CO32-) Sulfite (SO32-) Phosphate (PO43-) NH4+, Li+, Na+, K+ Most ions Hydroxide (OH-) NH4+, Ba2+, Li+, Na+, K+ Most ions NH4+, Most ions Sulfide (S2-) Oxide (O2-) Li+, Na+, K+ Ca2+, Ba2+, Li+, Na+, K+ hydrolyse Most ions * Often, “insoluble” actually means “sparingly soluble” (dissolves to a small degree) rather than “completely unable to dissolve”. All compounds of the ammonium ion (NH4+) and alkali metals (group I) cations are soluble. All nitrates and acetates are soluble. All chlorides, bromides and iodides are soluble EXCEPT those of silver, lead and mercury (I). All sulfates are soluble EXCEPT those of calcium, barium, strontium, silver, lead and mercury (I). All carbonates, sulfites and phosphates are insoluble EXCEPT those of ammonium and alkali metals (group I) cations. All hydroxides are insoluble EXCEPT those of ammonium, barium and alkali metals (group I) cations. All sulfides are insoluble EXCEPT those of ammonium and alkali metals (group I) cations. All oxides are insoluble EXCEPT those of calcium, barium and alkali metal (group I) cations. These soluble ones actually hydrolyse (react with the water to form hydroxides).