MATERIAL SAFETY
DATA SHEET
Chemtrec 24-Hour Emergency Telephone
Domestic North America
(800) 424-9300
International
(703) 527-3887
This MSDS complies with 29 CFR 1910.1200
(Hazard Communication)
1. Product and Supplier Identification / Product Hazard Summary
Product:
Sharkthane Hard Flex Pro 60-25 YELLOW A SIDE
Product No. 3004026025131
Trade Name: Sharkthane Hard Flex Pro 60-25 YELLOW A SIDE
Supplier:
Fiberlay Inc.
24 S. Idaho St
Seattle, Wa 98134
(206)782-0660
HMIS
HEALTH: 4
*CAUTION!
*May be harmful if swallowed or inhaled
*May be irritating to the skin eyes and respiratory
tract
*May cause allergic skin reaction
*Heated material may cause thermal burns
FLAMMABILITY: 1
*Warning! Flammable
Liquid & Vapor
REACTIVITY: 1
*Caution! Unstable at
high temperatures
SPECIFIC HAZARD: -G
2. Composition
Component
ACGIH TLV
OSHA PEL
Hazard Designation
Dicyclohexylmethane-4,4'-diisocyanate
.005 ppm
.005 ppm
5124-30-1
Isophorone diisocyanate
.005 ppm
.005 ppm
4098-71-9
3. Hazards Identification
Chronic Effects: Skin and respiratory sensitization
Skin Contact: Possible skin irritant and sensitizer
Eye Contact: Will cause eye irritation
Skin Absorption: Can be absorbed through skin
Ingestion: Will cause illness
Inhalation: Harmful, may cause an allergic reaction and lung damage
Carcinogenicity: Not listed as an IARC, OSHA or ACGIH potential carcinogen
Special precautions in handling and storage: Emergency eyewash stations and safety showers must be
close to any area of possible exposure
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4. First Aid Measures
Inhalation: Remove source(s) of contamination and move victim to fresh air. If breathing has stopped, give
artificial respiration, then oxygen if needed. Contact physician immediately.
Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention.
Skin Contact: In case of skin contact, wash thoroughly with soap and water; remove contaminated clothing
and launder before reuse; seek medical attention if rash develops.
Ingestion: Do not induce vomiting unless instructed by a physician. Contact physician
Immediately
After first aid, get appropriate in-plant, paramedic, or community medical support.
5. Fire Fighting Measures
Flash Point: >155°F (68°C) NFPA
LEL: Not Established
UEL: Not Established
Flammability Classification: Combustible liquid
Extinguishing Media: Water Fog, Dry Chemical, and Carbon Dioxide Foam
Fire and Explosive Hazards: High temperature will cause combustion
Fire-Fighting Instructions: Use supplied air full face respirators and impervious turn out gear
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a selfcontained breathing apparatus (SCBA) with a full face piece operated in pressure demand or positivepressure mode.
6. Accidental Release Measures
Small Spill: Evacuate the area. Clean-up should only be performed by trained personnel. People dealing
with a major spill should wear full protective clothing including respiratory protection. Prevent product spill
from entering sewers or waterways. Neutralize small spills with a decontaminant.
Large Spill: Contain and absorb large spills onto an inert, non-flammable adsorbent carpet (such as earth or
sand). Shovel into open-top drums or plastic bags for further decontamination of necessary. Wash the spill
area clean with a liquid decontaminant. Remove and properly dispose of residues. Notify applicable
government authorities if release is reportable (See CERCLA in Section 15).
7. Handling and Storage
Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact with skin.
Wear proper protective equipment. If ventilation is not sufficient, wear proper respiratory equipment. Avoid
moisture contamination. Reseal partial containers. Use good general housekeeping procedures.
Storage Requirements: Store in cool dry, well-ventilated area.
8. Exposure Controls, Personal Protection
Respiratory Protection: Follow OSHA respirator regulations 29 CFR 1910.134 and European
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Standard EN 149; wear an MSHA/NIOSH or European Standard EN149 approved respirator.
Protective Clothing/Equipment: Wear chemically protective gloves to prevent prolonged or
repeated skin contact. Wear protective eyeglasses or chemical safety goggles, per OSHA eye and
face protection regulations 29 CFR 1910.133 and European Standard EN166. Contact
lenses are not eye protective devices. Appropriate eye protection must be worn instead of, or in
conjunction with contact lenses.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after
using this material, especially before eating, drinking, smoking, using the toilet, or applying
cosmetics
9. Physical and Chemical Properties
Physical State: Viscous Liquid
Appearance: Yellow
Odor: Pungent
Vapor Pressure: <0.00048 mm @ 25°C
Vapor Density (Air=1): Not Established
Specific Gravity (H2O=1.05, at 25°C): 1.06 g/cm³
Water Solubility: Negligible, reacts
10. Stability and Reactivity
Stability: Stable, will react with amines, hydroxyl functional materials (Water)
Polymerization: Will Auto-polymerize at very high temperatures only
Chemical Incompatibilities: Strong acids, water, amines, alcohols, bases and oxidizers
Conditions to Avoid: Moisture, high heat, amines, strong oxidizers, acids and bases
Hazardous Decomposition Products: Fumes, carbon dioxide, carbon monoxide, oxides of nitrogen, traces of
HCN, dicyclohexylmethan-4,4'-diisocyanate
11. Toxicological Information
No data available
12. Ecological Information
No data available
13. Disposal Considerations
Disposal: These materials must be disposed of in accordance with local regulations.
14. Transport Information
IATA:
UN3334, Aviation Regulated Liquid, N.O.S. (Dicyclohexylmethane-4,4'-diisocyanate), 9
SHIPPING DESCRIPTION:
NA3082, Other Regulated Substances, Liquid, N.O.S., (Dicyclohexylmethane-4,4'-Diisocyanate), 9, III
REQUIRED HAZARD LABEL:
Class 9, Miscellaneous
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15. Regulatory Information
United States EPA Regulations:
SARA Title III (Superfund Amendments and Reauthorization Act)
311/312 Hazard Categories: Acute Health hazard. Chronic health hazard
313 Reportable Ingredients: This product contains the following substances subject to the
reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of
1986 and 40 CFR Part 372:
EPCRA SECTION 313 SUPPLIER NOTIFICATION
Chemical Name
CAS
Isophorone diisocyanate
CAS 4098-71-9
4,4'-methylenedicyclohexyl diisocyanate
CAS 5124-30-1
TSCA Inventory Status (40 CFR710): All components of these formulations are listed in the
TSCA Inventory.
California Proposition 65: These products do not intentionally contain any chemicals which have
been identified by the state of California to cause cancer, birth defects or other reproductive
harm.
16. Other Information
California Proposition 65 involving warnings of the presence of certain listed chemicals is now in
effect.
In order to comply with the California Law, even though some of the listed substances may not
represent a significant risk as defined by the regulations, we feel obligated to make the following
statement:
“Warning: This product may contain trace amounts of some chemicals considered by the State of
California to be carcinogens or reproductive Toxicants.”
Preparation Date: 2/10/2016
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