Dpt. PHL-Bio Biotechnology Project-management Interim report Nanotechnology in food Maxime Vander Elst, Geoffrey Meunier, François Dubs Sarah Massei, Veerle Sajdl, Maxim Verboven and Vincent van Veghel Supervisor: Ingrid Geirnaert Start Interim report: 13-10-2010 End Interim report: 15-11-2010 Contents What is nanotechnology? ...................................................................................................... 2 Nanotechnology in the food industry...................................................................................... 2 Nanotechnology in food packaging..................................................................................... 2 Smart food packaging ........................................................................................................ 3 Nanocapsules ....................................................................................................................... 3 Industrial coating in nanotechnology...................................................................................... 4 The productions of coatings ............................................................................................... 4 Advantages ........................................................................................................................ 4 Public perception ................................................................................................................... 4 1 Nanotechnology in the food industry Nanotechnology is an upcoming concept in the food industry. Researchers see nanotechnology as a technology that currently is undergoing an important development. The interest for nanotechnology in food increased thanks to the media-attention. It is an opportunity for consumers to change their eating habits to their nutritional needs and desirable flavors. Several questions arise from the use of nanoparticles in our food: how nanotechnology is used, why is it used, is it safe,…? A closer look at nanotechnology is needed to answer to these questions. (De Geeter H. 13-15) What is nanotechnology? The Oxford Dictionaries describe nanotechnology as “the branch of technology that deals with dimensions and tolerances of less than hundred nanometers, especially the manipulation of individual atoms and molecules.” A nanometer is one-billionth of a meter. Because of their small size, nanoparticles have a proportionally larger surface relative to their volume. Therefore, nanoparticles have more contact with their environment and they will react more strongly than larger particles. This makes new properties emerge at the nanoscale. These properties are either chemical, biological or physical. (Glorieux Eloi et al. 1-10) Nanotechnology in the food industry Nanofood describes food that has been produced, processed, cultivated or packed, using nanotechnology techniques or tools. The purpose of nanofood is to improve food safety, enhance nutrition and flavour, and cut costs. (Sekhon Bhupinder S. 115) Food products naturally contain nanoparticles. Proteins, polysaccharides and fats are present at the nanoscale. These particles can be manipulated to create different kinds of structures. For example, boiling an egg changes the structure at the nanoscale. Since the beginning of the 20th century, scientist started to develop new techniques to manipulate at nanoscale. This was made possible by new and more precise equipments. It is not only possible to manipulate 2 food products at the nanoscale but also to create new nanostructures. The applications where nanotechnology is used includes food packaging and food products that have nanosized ingredients and additives. These applications can improve food production, processing, packaging and storage. (De Geeter H. 13-15;Joseph Tiju and Morrison Mark) Nanotechnology in food packaging Nanotechnology can improve mechanical strength, reduce weight, increase the heat resistance and improve the barrier against oxygen, carbon dioxide and moist. Fine nanoparticles in plastics can improve the properties compared to the normal plastic. Nanocomposites can be used for its antimicrobial activity. The food packaging can contain nanosensors to give information about enzymes that are produced in the degradation of food molecules and makes them unsafe for human consumption. The food packaging can also be used to increase shelf life. It will let air and enzymes out of the package but not in. Bringing active nanoparticles into the polymer matrices could bring double advantages. This will improve the performance of food packaging materials and gives it an additional functionality. The challenge of using nanotechnology is to create low cost packaging that helps in weight, functionality and that it is easy to process. More improvements include using carbon nanotubes to improve its mechanical properties. This can also have powerful antimicrobial effects. E. Coli died immediately by direct contact with aggregates of carbon nanotubes. (Sekhon Bhupinder S. 115) Smart food packaging Smart food packaging reacts to environmental conditions or alerts the costumer for contamination or the presence of pathogens. Bayer has produced a transparent plastic film containing nanoparticles of clay. The nanoparticles are divided in the plastic and can block oxygen, carbon dioxide and moisture so it can’t reach the food. The nanoclay makes the plastic lighter, stronger and more heat resistant. In the Netherlands researchers are developing an intelligent packaging that releases a preservative if the food turns bad in the package. This type of packaging operates with a bio switch that’s developed with nanotechnology. Smart food packaging warns the consumer when oxygen gets inside the package or if the food goes bad. These types of packaging-methods are already used in brewing and dairy production. The packaging consists nanofilters that filter out microorganisms and even viruses. Nanopackaging can clean itself or has nanofilters that will remove bacteria from water or milk without boiling the liquids. Nanocapsules Another important use of nanotechnology are nanocapsules. These nanocapsules are synthetic colloidal systems of the vesicular type. They consist of a central lipophilic core, in which an active substance can be incorporated, surrounded by a thin polymer wall. Nanocapsules are already used in the food industry to modify the structure of food. The introduction of these capsules makes it possible to create new products. For example, Kraft Board have created a drink that, thanks to nanocapsules, changes colour and taste when it’s shaken. By drinking this solution, people absorb small amounts of 3 nanocapsules. Experts believe that they are safe and adequately developed. To obtain a nanocapsule, next principle should be followed. A volatile liquid phase (S1) includes a polymer, an oiled substance that forms the nucleus, the active ingredient and a lipophilic surfactant. This S1 phase is mixed with another liquid phase (S2). The S2 phase contains the nonsolvent constitutions of the S1 phase. The phases are fully miscible. Nanocapsules are formed immediately. The obtained nanocapsules have a diameter of 200 nm. The S1 solvent can be eliminated by vaporization under reduced pressure. The miscibility of the S1 and the S2 phases makes it possible to exchange the insoluble components between S1 and S2. The insoluble polymer in the S2 phase and the oiled substance in the S1 phase separate from the other substances because they are not soluble in a watery solution. The wall of the nanocapsule is formed at the interface between those substances and the soluble substances. The polymers in the nanocapsules are biodegradable and nontoxic. The L’Oréal group used this property in their advantage. They took an exclusive worldwide license for the application of nanocapsules in their cosmetic products. By capturing specific nutrients and food particles in nanocapsules, they can be transported through the stomach and the intestinal without getting harmed. Once they get to their destination, the nanocapsules will dissolve and the nutrients and food particles are released. (Nanotechnology and food;Holster Paul and Vas Cristina Roman 16;Ozimek Lech, Pospiech Edward, and Narine Surech 401-12) Industrial coating in nanotechnology Nanotechnology is also used for protecting the material in a food company. Food packaging with nanotechnology gives protection to the food. Industrial coatings with nanotechnology will give floors, machines and worktables protection. This industrial coating is the perfect way to work save and in hygienic conditions. The industrial coating with nanotechnology gives the food industry many advantages. So it is used in lots of food companies like in The Greenery in Barendrecht. This is a company that works with fruit acids. These acids are very strong and the main cause for degeneration on different kinds of material in the food industry. These coatings, developed by Idétrading in Barendrecht, protect the worktables, floors and machines from degeneration and damaged surfaces. Another example is VanDrie Group in Hasselt, a company well known as a slaughterhouse. Without the industrial coating produced by Idétrading they would be over their head with lots of extra expenses. A few of these extra expenses are aggressive cleaning products and lots of water for cleaning blood, fat and much more on the worktables and floors. (Sekhon Bhupinder S. 115) The productions of coatings The product Lotux is received by manipulating the molecular structure of Teflon with nanotechnology. The coatings contain small nanoparticles with components that arrange themselves on the surface of the desired worktables, floors or machines. It takes different steps to create these coatings. The first step in the coating is that the nanoparticles arrange themselves in an intelligent way. The second step is that binding components from the coating will move 4 themselves on the surface. They will close the surface so it can breathe and protect itself from degeneration. During this self-binding process an ultrathin transparent layer will be formed, which will guarantee protection and lots of advantages in the food industry. (Dammers Ferry 19) Advantages The industrial coating made with nanotechnology has advantages. It protects surfaces from bacteria’s, fats, oils, moist and these products won’t attach as quick as without the coating. Another advantage is that it isolates the material. Cleaning will be easier because you don’t need to use unfriendly material to clean the surfaces. Environmental friendly cleaning products can be used. The coating has a positive effect on the life span of the desired material. Last but not least, total costs in the company that uses this coating are not as high anymore. (Dammers Ferry 19) Public perception Nanotechnology an important key technology in our century. This technology can create products with a lot of benefits for food production and packaging. But important for the future of nanotechnology is the public perception! The public knowledge of nanotechnology is very limited. But even though the public in the United States of America doesn’t know a lot about nanotechnology, they are convinced that the benefits are bigger than the risks. In Europe, the public isn’t that optimistic. Those who are creating food with nanotechnology have to win the trust of the consumers. As an example, there are functional foods. These are products that promise improvements in targeted physiological functions. These are benefits that the consumers can experience. So, the producers must communicate the benefits very clearly. When the benefits are tangible so the consumer can notice them, these will be easier to market. Nanotechnology is a very recent technology, and the public isn’t well informed. So, participants must give information about specific nanotechnology foods. Without this information, the term nanotechnology will not evoke meaningful associations. Trust in the food industry has an impact on the effect evoked by the information about nanotechnology. Recent studies made it clear that consumers were hesitant to buy nanotechnology foods or food with nanotechnology 5 packaging. A conclusion we can make, is that the benefits associated with the nanotechnology in food applications may not provide enough additional value for the consumers to buy these products. Consumers have more trust in food packaging than in nanofood. The importance of social trust in the food industry shows that an event with negative consequences could have a disastrous impact on trust in the industry. This makes it harder for the consumers to accept nanofood. (Siegrist Michael et al. 459-66) Reference List Nanotechnology and food. 2010. nederland, NanoBio-RAISE. 11-11-2010. Ref Type: Report Dammers Ferry. "betere hygiëne dankzij nanotechnologie." VMT.11 (2009): 19. De Geeter H. "waarom? daarom." Nutrinews.2 (2010): 13-15. Glorieux Eloi, et al. "Voorstel van revolutie." Vlaams parlement.1 (2010): 1-10. Holster Paul and Vas Cristina Roman. Nnocapsules. 10, 1-6. 2010. cientifica. 11-11-2010. Ref Type: Report Joseph Tiju and Morrison Mark. "Nanotechnology in Agriculture and Food." European Nanotechnology Gateway (2006). Ozimek Lech, Pospiech Edward, and Narine Surech. nanotechnologies in food and meat processing. 401-12. 2010. scientiarum polonorum ACTA. 11-11-2010. Ref Type: Report Sekhon Bhupinder S. "Food nanotechnology – an overview." Nanotechnology, Science and Applications.3 (2010): 1-15. Siegrist Michael, Cousin Marie-Eve, Kastenholz Hans, and Wiek Arnim. Public acceptance of nanotechnology foods and food packaging: The influence of affect and trust. 459-66. 2010. Zurich, Appetite. Ref Type: Report 6